Abstract: A method of fabricating metallic Cu nanowires with lengths up to about 25 ?m and diameters in a range 20-100 nm, or greater if desired. Vertically oriented or laterally oriented copper oxide structures (CuO and/or Cu2O) are grown on a Cu substrate. The copper oxide structures are reduced with 99+ percent H or H2, and in this reduction process the lengths decrease (to no more than about 25 ?m), the density of surviving nanostructures on a substrate decreases, and the diameters of the surviving nanostructures have a range, of about 20-100 nm. The resulting nanowires are substantially pure Cu and can be oriented laterally (for local or global interconnects) or can be oriented vertically (for standard vertical interconnects).

Abstract: This invention refers to a pyrometallurgical method for the continuous reduction of oxidized copper through combustion gases in countercurrent to the continuous gravitational flow of liquid copper that disperses through a packed bed reactor with ceramic grains.

Abstract: The present invention relates to a method of operating a converter, in particular a Peirce-Smith converter or a converter with similar design or mode of operation, and to an apparatus, for instance a plant, for carrying out the method. The method comprises the step of: loading the converter with a starting material comprising said metal, the metal in the starting material being chemically bound at least in part to at least one compound substance, in particular sulphur; maintaining a temperature within the converter interior space, which is above the melting temperature of the starting material; and supplying an oxygen-containing process gas into the converter interior space through injection nozzles arranged in the wall of the converter, the gas supplied through the injection nozzles comprising carbon dioxide, preferably very cold, technically pure carbon dioxide, as well as oxygen gas and/or air.

Abstract: This invention refers to a pyrometallurgical method for the continuous reduction of oxidized copper through combustion gases in countercurrent to the continuous gravitational flow of liquid copper that disperses through a reactor with a bed covered with ceramic grains.

Abstract: A process for recovering non-ferrous metals, in particular copper, nickel and cobalt, from metallurgical residues containing these non-ferrous metals at an oxidation state of greater than or equal to zero, in an alternating current type plasma arc electric furnace comprising a plurality of electrodes, containing a liquid copper heel covered by a fluid slag comprising at least one fusion-reduction phase, comprising charging of metallurgical residues comprising the non-ferrous metals onto the heel contained in the plasma arc electric furnace, fusion of the metallurgical residues in the fluid slag or at the slag-metal bath interface, reduction of at least the non-ferrous metals to oxidation state zero, and intense stirring of the copper heel by injection of inert gas, preferably nitrogen and/or argon, so as to avoid crust formation and to accelerate the reduction reaction and to cause the copper-miscible non-ferrous metals to pass into the copper heel.

Abstract: The present invention relates to a method of operating a converter, in particular a Peirce-Smith converter or a converter with similar design or mode of operation, and to an apparatus, for instance a plant, for carrying out the method. The method comprises the step of: loading the converter with a starting material comprising said metal, the metal in the starting material being chemically bound at least in part to at least one compound substance, in particular sulphur; maintaining a temperature within the converter interior space, which is above the melting temperature of the starting material; and supplying an oxygen-containing process gas into the converter interior space through injection nozzles arranged in the wall of the converter, the gas supplied through the injection nozzles comprising carbon dioxide, preferably very cold, technically pure carbon dioxide, as well as oxygen gas and/or air.

Abstract: An improved method of reducing a mixed metal oxide composition comprising oxides of nickel, cobalt, copper and iron in a hydrogen atmosphere to produce a mixture of the respective metals, the improvement wherein the atmosphere further comprises water vapour at a concentration, temperature and time to effect selective reduction of the oxides of nickel cobalt and copper relative to the iron oxide to produce the metallic mixture having a reduced ratio of metallic iron relative to metallic nickel, cobalt and copper.

Abstract: In the operation, a flux mainly composed of silica ore and a non-ferrous metal-ore raw-material are charged into a smelting furnace via a conveying system. In order to increase the production amount of the metal, the flux is conveyed and treated through a first system, in which the flux is crushed in a ball mill and dried in the bail mill, and the crushed and dried flux is conveyed directly before the smelting furnace. The non-ferrous metal ore is treated and conveyed through a second system, in which it is dried with a drier and then conveyed directly before the smelting furnace. In the drier of copper concentrate, the flux is not dried at all.

Abstract: A method of treating ore particles to facilitate subsequent processing of the ore particles to recover valuable components from the ore is disclosed. The method includes exposing the ore particles to microwave energy and causing structural alteration of the ore particles. In one embodiment structural alteration is achieve without significantly altering the mineralogy, i.e., composition, of the ore. In another embodiment structural alteration is achieved with minimal change to the sizes of the ore particles. In another embodiment the method includes exposing the ore particles to short duration, high energy pulses of microwave energy.

Abstract: A method to enhance the extraction of an element from an ore includes subjecting the ore, or element bearing material to electromagnetic radiation to induce pyrolysis of the material. The residue of the pyrolysis may then be processed in a conventional manner to extract the element. The radiation used in the invention has a wavelength longer than microwave radiation, and is preferably 100 mm or longer. Preferably, radio waves are used as the radiation to effect pyrolysis.

Abstract: A method of producing an oxygen-free copper wire material, containing: continuously guiding a molten copper obtained by melting electric copper, into a tundish through a conduit; injecting the molten copper in the tundish, into a rotational movable mold; cooling and solidifying the molten copper, to form an ingot; and continuously drawing the ingot out of the mold, followed by continuous rolling; the method further containing: allowing the molten copper in the conduit to react with a solid reducing agent, under blowing an inert gas thereinto; allowing the molten copper in the tundish to react with a solid reducing agent, under blowing an inert gas thereinto; and adding a phosphorus compound to the molten copper, so that the phosphorus content in the ingot would be from 1 to 10 ppm; and controlling the temperature of the molten copper in the tundish from 1,085 to 1,100° C.

Abstract: The invention relates to a method for increasing the capacity of a waste-heat boiler (1) processing gases obtained from a metallurgic smelting furnace, such as a flash smelting furnace, and for reducing dust accretions, where liquid is added into the waste-heat boiler (1) of the smelting furnace. The invention also relates to an apparatus for increasing the capacity of a waste-heat boiler (1) processing gases obtained from a metallurgic smelting furnace, such as a flash smelting furnace, and for reducing dust accretions, in which case the waste-heat boiler is provided with at least one nozzle (2) for adding liquid.

Abstract: The method for smelting copper sulfide concentrate essentially consisting of the steps of: adding SiO2 source material and CaO source material for flux to the copper sulfide concentrate, and subjecting the copper sulfide concentrate to oxidation melting to produce slag and at least one selected from the group of white metal and blister copper, so that at least part of Fe in the copper sulfide concentrate is removed to the slag while at least part of S is removed in the form of SO2, and that copper is concentrated in the form of at least one selected from the group of white metal and blister copper, and wherein the composition of the slag is controlled such that the weight ratio CaO/(SiO2+CaO) is in the ramge of 0.6 to 0.85, while the weight ratio Fe/(FeOx+SiO2+CaO) is in the range of 0.5 to 0.6.

Abstract: There is provided conductive paste wherein conductive fillers composed of copper micro-fibers are mixed into thermoplastic resin or thermosetting resin.

Abstract: In a copper flash-smelting works, forced oxidation of dust is prevented, adhesion of dust to a boiler water tube is reduced, and on-line ratio and productivity index is improved. The temperature at the WHB radiation section outlet is greatly reduced and the atmosphere within the WHB radiation section is controlled by blowing the mixed gas of nitrogen gas and air from the feed aperture established in the wall into the boiler radiation section of the waste heat boiler of the flash-smelting furnace in a copper flash-smelting works.

Abstract: A method for producing solid metal product is disclosed including the steps of providing carbon and metal bearing compounds in compacts, coating the compacts with treatment materials, encapsulating the compacts with carbonaceous containing materials to form a residual layer, and treating the residual layer before introduction of the compacts into a furnace. The compacts contain carbon containing metal bearing compounds, and are coated with mixtures of carbonaceous materials dispersed within a binder material such as a viscous liquid, molasses, alcohol, or fuel oil. The coated compacts are treated to form a hardened outer residual layer. The outer residual layer provides for a sacrificial outer coating on the compacts that reacts with any oxidizing gaseous components within the furnace, while the carbon containing metal bearing compounds within the compacts are heated and metallized inside the compounds.

Abstract: A metal volatilization process is described in which metal oxide pieces in a reaction chamber are reduced to form reduced metal and at least a portion of that metal is volatilized and used for coating a variety of substrates, including those which are susceptible to heat damage. The metal oxides formed must have curved surfaces which maintain a non-zero contact angle with their support during reduction. Preferably the reduction phase is preceded by an oxidation phase which is conducted in the same chamber, and uses as the starting materials oxidizable metal pieces which also are curved to maintain a non-zero contact angle with the support, so that general curved shapes will be maintained throughout the oxidation and reduction phases of the process. Vacuum is unnecessary, and the process can be operated at ambient pressures.

Abstract: A method for submerged injection of materials into a liquid pyrometallurgical bath by means of a lance, characterised in that a first gas consisting of or containing oxygen is conveyed to said bath along a first path within the lance, a combustible fluid is conveyed to said bath along another path within the lance, and a further gas consisting of or containing oxygen is conveyed to said bath along a further path within the lance, the first path being arranged so that the first gas acts as a coolant for the lance.

Abstract: There is disclosed an apparatus for smelting copper which includes a blister copper-producing device. A plurality of anode furnaces are provided for refining the blister copper produced in the blister copper-producing device into copper of higher quality. A blister copper launder assembly, which has a main launder and a plurality of branch launders branched off from the main launder, is provided to connect the converting furnace and the anode furnaces together. A selecting device may be attached to the launder assembly for selectively bringing the main launder into fluid communication with one of the branch launders.

Abstract: There is disclosed an apparatus for smelting copper which includes a smelting furnace, a separating furnace, a converting furnace, and launders connecting these furnaces in series. In the smelting furnace, copper concentrate is melted and oxidized to produce matte and slag. In the separating furnace, the matte is separated from the slag. In the converting furnace, the matte separated from the slag is oxidized to produce blister copper. A plurality of anode furnaces are provided for refining the blister copper produced in the converting furnace into copper of higher quality. A blister copper launder assembly, which has a main launder and a plurality of branch launders branched off from the main launder, is provided to connect the converting furnace and the anode furnaces together. A selecting device may be attached to the launder assembly for selectively bringing the main launder into fluid communication with one of the branch launders.

Abstract: A copper smelting process is disclosed in which copper concentrate is smelted in a furnace to produce purified copper. Flue gas discharged from the furnace is treated to produce sulfuric acid. Furthermore, waste liquid discharged during the production of sulfuric acid is treated to produce gypsum, and the gypsum thus produced is recycled to the furnace as a flux. The flue gas may be exhausted from either or both of a smelting furnace and a converting furnace, and the gypsum may be preferably introduced into the converting furnace.

Abstract: The process for converting a copper sulphide matte to blister copper, is achieved by adding the copper sulphide matte and flux to a suitable agitated slag phase; and injecting, from a discharge tip at the lower end of a top-submerged lance, an oxidizing gas suitable for reacting with the matte to produce blister copper which forms or adds to a continuous blister copper phase below the slag phase. The lance tip is located within the slag phase at a depth enabling the injected gas to agitate the slag phase, and to react with copper sulphide matte dispersed therein, while precluding a substantial proportion of the gas from contacting the continuous blister copper phase.