With Sulfur Compounds Or Peroxides Or Oxygen Patents (Class 8/109)
  • Patent number: 10900166
    Abstract: The present invention generally relates to a method for changing the color of a textile material to obtain a vintage and/or worn appearance comprising the steps of contacting the fabric textile material with a nitrate salt, activating the nitrate salt by the addition of an acid catalyst until the desired color change is achieved.
    Type: Grant
    Filed: June 8, 2018
    Date of Patent: January 26, 2021
    Assignee: ACTICELL GMBH
    Inventors: Christian Bruno Schimper, Paul Pachschwöll, Hubert Hettegger
  • Patent number: 10844538
    Abstract: The present invention is directed to a method of increasing the brightness of non-wood fibers and nonwoven fabric fabrics produced by the method. In one aspect, the method includes forming a mixture of non-wood fibers and exposing the mixture to a brightening agent to produce brightened fibers. The brightening agent is oxygen gas, peracetic acid, a peroxide compound, or a combination thereof. The brightened fibers have a brightness greater than the fibers of the mixture before exposure as measured by MacBeth UV-C standard.
    Type: Grant
    Filed: May 19, 2015
    Date of Patent: November 24, 2020
    Assignee: GPCP IP HOLDINGS LLC
    Inventor: Jeffrey A. Lee
  • Publication number: 20150139977
    Abstract: The invention relates to enzymes having xylanase, mannanase and/or glucanase activity, e.g., catalyzing hydrolysis of internal ?-1,4-xylosidic linkages or endo-?-1,4-glucanase linkages; and/or degrading a linear polysaccharide beta-1,4-xylan into xylose. Thus, the invention provides methods and processes for breaking down hemicellulose, which is a major component of the cell wall of plants, including methods and processes for hydrolyzing hemicelluloses in any plant or wood or wood product, wood waste, paper pulp, paper product or paper waste or byproduct. In addition, methods of designing new xylanases, mannanases and/or glucanases and methods of use thereof are also provided. The xylanases, mannanases and/or glucanases have increased activity and stability at increased pH and temperature.
    Type: Application
    Filed: October 22, 2014
    Publication date: May 21, 2015
    Inventors: David Weiner, David Blum, Alexander Varvak, Shaun Healey, Kristine Chang, Geoff Hazlewood, Thomas Todaro, Grace Desantis, Hwai Chang, Connie Jo Hansen, Scott W. Beaver, Thomas Woodward, Charles Hancock
  • Patent number: 8845756
    Abstract: Present invention relates to an oxidizing composition for keratin fibers especially for human hair with improved lightening effect and therefore, improved colouring and bleaching effects are easily achieved of the compositions applied after mixing with the said composition. Present inventors have surprisingly found out that a composition comprising at least one oxidizing agent and additionally at least one alkalizing agent, at least one carbonate source and at least one urea derivative delivers an improved and homogeneous lightening performance and leaves hair in an improved cosmetically acceptable conditioned status.
    Type: Grant
    Filed: December 23, 2011
    Date of Patent: September 30, 2014
    Assignee: KAO Germany GmbH
    Inventors: Dominic Pratt, Ovidiu Feieriova
  • Patent number: 8840682
    Abstract: Present invention relates to an oxidizing composition for keratin fibers especially for human hair with improved lightening effect and therefore, improved coloring and bleaching effects are easily achieved of the compositions applied after mixing with the said composition. Present inventors have surprisingly found out that a composition comprising at least one oxidizing agent and additionally at least one alkalizing agent, at least one carbonate source and at least one urea derivative delivers an improved and homogeneous lightening performance and leaves hair in an improved cosmetically acceptable conditioned status.
    Type: Grant
    Filed: December 23, 2011
    Date of Patent: September 23, 2014
    Assignee: Kao Germany GmbH
    Inventors: Dominic Pratt, Ovidiu Feieriova
  • Patent number: 8784503
    Abstract: The invention relates to a high-strength and abrasion-resistant fibrous material and to a method for the production thereof. According to said method, a natural fiber material is solubilized in an alkaline manner. The fibrous material is treated with an alkaline material, without being subjected to mechanical stress a) at a temperature of between 5 and 30° C. and then b) at a temperature of between 80 and 150° C., and is then optionally washed and/or dried.
    Type: Grant
    Filed: June 23, 2008
    Date of Patent: July 22, 2014
    Assignee: Flasin Faser GmbH
    Inventor: Herbert Costard
  • Patent number: 8673023
    Abstract: A method for manufacturing a coloring agent for keratin fibers from a first composition A and a second composition B is provided. The method comprises directing the first composition A from a container A by a filler apparatus through an inlet opening into a second container B containing the second composition B. In container B, as a result of the introduction of composition A and/or the action of the filler apparatus, at least one exit opening is formed out of which the coloring agent for keratin fibers exits from container B as a mixture of compositions A and B.
    Type: Grant
    Filed: October 15, 2012
    Date of Patent: March 18, 2014
    Assignee: Henkel AG & Co. KGaA
    Inventors: Frank Janssen, Juergen Schoepgens, Armin Wadle, Thomas Foerster, Lisa Chen
  • Patent number: 8668745
    Abstract: The invention provides an agent for lightening keratinic fibers, the agent containing in a cosmetic carrier (i) at least one acyl pyridinium derivative of formula (I), (ii) at least one alkalizing agent selected from triethanolamine, 2-amino-2-methylpropan-1-ol, 2-amino-2-methylpropane-1,3-diol, lysine, ornithine and/or an alkalizing agent mixture comprising at least one basic amino acid and at least one alkanolamine, and (iii) at least hydrogen peroxide as an oxidizing agent.
    Type: Grant
    Filed: June 13, 2013
    Date of Patent: March 11, 2014
    Assignee: Henkel AG & Co. KGaA
    Inventors: Wibke Gross, Ralph Nemitz, Astrid Kroos, Frank Janssen, Astrid Kleen, Hartmut Manneck, Katja Guenther
  • Patent number: 8617255
    Abstract: The present invention relates to bleaching composition for keratin fibers, especially human hair, comprising at least one compound with bleaching and/or highlighting effect and a magnesium salt. Further object of the present invention is the use of at least one magnesium salt in a bleaching and/or highlighting composition for keratin fibers, especially for human hair, comprising at least one compound with bleaching and/or highlighting effect for preventing temperature increase going above 50° C., preferably above 45° C. and more preferably above 40° C. in a period of at least 60 min after mixing water free bleaching and/or highlighting composition and oxidizing lotion.
    Type: Grant
    Filed: December 23, 2011
    Date of Patent: December 31, 2013
    Assignee: KAO Germany GmbH
    Inventors: Jonathan Wood, Sabine Schäfer
  • Patent number: 8597371
    Abstract: The invention provides an agent for lightening keratinic fibers, the agent containing in a cosmetic carrier (i) at least one acyl pyridinium derivative of formula (I), (ii) at least one cationic polysaccharide, and (iii) at least hydrogen peroxide as an oxidizing agent.
    Type: Grant
    Filed: June 13, 2013
    Date of Patent: December 3, 2013
    Assignee: Henkel AG & Co. KGaA
    Inventors: Wibke Gross, Ralph Nemitz, Astrid Kroos, Frank Janssen, Astrid Kleen, Hartmut Manneck, Katja Guenther
  • Patent number: 8444706
    Abstract: The present invention relates to an oxidizing composition for treatment of keratin fibers comprising a combination of; (a) at least one anionic associative copolymer, (b) at least one anionic non associative copolymer; (c) at least one peroxide agent; (d) at least one persulfate agent; (e) at least on alkalizing agent; and (f) a carrier medium suitable for hair treatment. The oxidizing composition described is suitable for composition used in conventional hair treatments such as dyeing, bleaching, and permanent waving or relaxing/straightening of the keratinous fibers, particularly human hair, requiring an oxidizing composition.
    Type: Grant
    Filed: July 24, 2012
    Date of Patent: May 21, 2013
    Assignee: The Procter & Gamble Company
    Inventors: Wilfried Burg, Matthias Morand, Anette Sallwey, Manfred Schmitt
  • Patent number: 8308822
    Abstract: The present invention relates to an oxidizing composition for treatment of keratin fibers comprising a combination of; (a) at least one anionic associative copolymer, (b) at least one anionic non associative copolymer; (c) at least one peroxide agent; (d) at least one persulfate agent; (e) at least on alkalizing agent; and (f) a carrier medium suitable for hair treatment. The oxidizing composition described is suitable for composition used in conventional hair treatments such as dyeing, bleaching, and permanent waving or relaxing/straightening of the keratinous fibers, particularly human hair, requiring an oxidizing composition.
    Type: Grant
    Filed: May 19, 2011
    Date of Patent: November 13, 2012
    Assignee: The Procter & Gamble Company
    Inventors: Wilfried Burg, Matthias Morand, Anette Sallwey, Manfred Schmitt
  • Patent number: 8277516
    Abstract: Agent for lightening keratinous fibers comprising in a cosmetic carrier (i) at least one oxidation agent, (ii) at least one acylpyridinium derivative of Formula (I) and (iii) at least one ammonium compound comprising hydroxyl groups of Formula (II).
    Type: Grant
    Filed: April 12, 2012
    Date of Patent: October 2, 2012
    Assignee: Henkel AG & Co. KGaA
    Inventors: Wibke Gross, Ralph Nemitz, Astrid Kroos, Georg Knuebel
  • Patent number: 8277517
    Abstract: Method for lightening keratinous fibers, wherein a cosmetic carrier comprises (i) at least one oxidation agent, (ii) at least one acylpyridinium derivative of formula (I) and (iii) at least one amino acid comprising hydroxyl groups and/or the physiologically compatible salts thereof and/or the alkyl esters thereof.
    Type: Grant
    Filed: April 12, 2012
    Date of Patent: October 2, 2012
    Assignee: Henkel AG & Co. KGaA
    Inventors: Wibke Gross, Ralph Nemitz, Astrid Kroos, Georg Knuebel
  • Patent number: 8268013
    Abstract: In one embodiment, the invention provides a method of removing color from dyed hair, the method comprising applying to the hair a color removal composition comprising a sulfur-containing nucleophile or a precursor thereof.
    Type: Grant
    Filed: June 29, 2011
    Date of Patent: September 18, 2012
    Assignee: Perachem Limited
    Inventors: Jamie Anthony Hawkes, David Malcolm Lewis, Celine Gauche
  • Patent number: 8137412
    Abstract: Bleaching method for keratin fibers, using an agent comprising a bleach activator system comprising at least one cationic acylpyridinium derivative of formula (I), and hydrogen peroxide and use of agents for bleaching keratin fibers, in particular human hair, comprising at least one cationic acylpyridinium derivative, for reinforcing the bleaching capacity with concomitant improvement in the condition of the fibers.
    Type: Grant
    Filed: June 9, 2011
    Date of Patent: March 20, 2012
    Assignee: Henkel AG & Co. KGaA
    Inventors: Georg Suenger, Wibke Gross
  • Publication number: 20120036648
    Abstract: The flame retardant viscose is obtained by adding silica to the viscose and subsequently fixing the silica to the fibre, such that the final flame retardant fibre will have regenerated cellulose and a silica polymer providing the fibres with flame retardant properties. Conventionally, the regeneration of the viscose mixture is carried out using zinc sulphate, while the final phase of washing of the fibre is accomplished using sulphuric acid. Both zinc and sulphuric acid are highly contaminating products from the environmental point of view. The invention consists, on the one hand, of replacing the zinc sulphate with aluminium sulphate and, on the other, of replacing the sulphuric acid with hydrogen peroxide or oxygenated water, this minimising the contaminating effect of the process to an extraordinary extent.
    Type: Application
    Filed: May 20, 2009
    Publication date: February 16, 2012
    Inventors: Javier Oreña Tesouro, Angel Bercedo Miro
  • Patent number: 8034122
    Abstract: Agent for lightening keratin fibers containing in a cosmetic carrier (1) at least one cationic 2-acylpyridinium derivative of formula (I), wherein R is a C1-C6 alkyl group, a C2-C6 alkenyl group, a C2-C6 hydroxyalkyl group, a C1-C6 alkoxy C2-C6 alkyl group, a carboxy C1-C6 alkyl group, an aryl C1-C6 alkyl group, a heteroaryl C1-C6 alkyl group, a mono- or di-(C1-C6 alkyl)amino C2-C6 alkyl group, a 3-oxobutyl group, a 2-oxopropyl group, an aryl group or a heteroaryl group, R? is a C4-C4 alkyl group, a C2-C6 hydroxyalkyl group or a C1-C6 alkoxy C2-C6 alkyl group, and X? is a physiologically acceptable anion, (2) at least one alkyl ether sulfate, and (3) an oxidizing agent, especially hydrogen peroxide.
    Type: Grant
    Filed: March 8, 2011
    Date of Patent: October 11, 2011
    Assignee: Henkel AG & Co. KGaA
    Inventors: Wibke Gross, Denise Fuhr, Ralph Nemitz
  • Patent number: 7981166
    Abstract: Agent for bleaching keratin fibers comprising in a cosmetic carrier at least one cationic acyl pyridinium derivative of formula (I) where R is a C1-C6-alkyl group, a C2-C6-alkenyl group, a C2-C6-hydroxy alkyl group, a C1-C6-alkoxy-C2-C6-alkyl group, a carboxy-C1-C6-alkyl group, an aryl-C1-C6-alkyl group, a C1-C6-dialkylamino-C2-C6-alkyl group, a heteroaryl-C1-C6-alkyl group, a 3-oxobutyl group, a 2-oxopropyl group, an aryl group, or a heteroaryl group, R? is a C1-C4-alkyl group, a C2-C6-hydroxy alkyl group, or a C1-C6-alkoxy-C2-C6-alkyl group, X? is a physiologically compatible anion, at least one toxicologically safe co-bleaching activator and/or the physiologically compatible salt thereof, and hydrogen peroxide.
    Type: Grant
    Filed: November 5, 2010
    Date of Patent: July 19, 2011
    Assignee: Henkel AG & Co. KGaA
    Inventors: Wibke Gross, Denise Fuhr, Ralph Nemitz, Kristin Mielich
  • Publication number: 20090265862
    Abstract: Liquid bleaching composition comprising a hypohalite bleach, a trimethoxy benzoic acid or a salt thereof, a pigment and/or a dye and an alkali metal salt of silicate, an alkali metal periodate or mixture thereof and the process for treating a surface using said composition.
    Type: Application
    Filed: April 23, 2009
    Publication date: October 29, 2009
    Inventors: Vincenzo Guida, Bruna Perfili, Luca Sarcinelli
  • Publication number: 20090092835
    Abstract: The present invention generally relates to a process for the extraction and preparation of bast fibers with high quality and high counts. The process is suitable for ramie, hemp and flax. The present invention also relates to bast fibers with high counts produced according to the process, as well as pure yarns and mixed, blended yarns made from said bast fibers.
    Type: Application
    Filed: December 16, 2008
    Publication date: April 9, 2009
    Inventor: Meirong XU
  • Patent number: 7481843
    Abstract: The present invention generally relates to a process for the extraction and preparation of bast fibers with high quality and high counts. The process is suitable for ramie, hemp and flax. The present invention also relates to bast fibers with high counts produced according to the process, as well as pure yarns and mixed, blended yarns made from said bast fibers.
    Type: Grant
    Filed: October 31, 2006
    Date of Patent: January 27, 2009
    Inventor: Meirong Xu
  • Patent number: 7462202
    Abstract: A method to safely remove foxing stains from paper and celluloid items using distilled water, sodium hypochlorite, acetic acid, sodium bicarbonate and glue size.
    Type: Grant
    Filed: July 26, 2005
    Date of Patent: December 9, 2008
    Inventors: Jeffrey Lee Kaplan, Robert Namiat
  • Publication number: 20080083071
    Abstract: Calcium hypochlorite for use in a laundry washing process. The calcium hypochlorite may be provided in a solid form such as a tablet, granule, and/or powder. The calcium hypochlorite of the present invention may also utilize a sequestering agent. Additionally, other adjunct materials may be included. The present invention also relates to a process for using calcium hypochlorite in a laundry washing process.
    Type: Application
    Filed: October 9, 2007
    Publication date: April 10, 2008
    Inventors: Mario Elmen Tremblay, Peter Robert Foley
  • Patent number: 7226486
    Abstract: Ready-to-use compositions for bleaching human keratin fibers, such as hair, comprising i) at least one anhydrous bleaching composition, in paste form, comprising at least one peroxygenated salt, at least one alkaline agent and from 1% to 35% by weight of at least one inert organic liquid, and ii) at least one oil-in-water emulsion comprising at least one first surfactant chosen from nonionic and anionic surfactants and at least one copolymer comprising (a) at least one unit derived from a salified or non-salified (meth)acrylic acid and (b) at least one unit derived from esters of (meth)acrylic acid and at least one first fatty alcohol chosen from saturated and unsaturated, linear and branched, ethoxylated C8-C30 fatty alcohols, wherein said ingredients (i) and (ii) are mixed before use; process for preparing the compositions; process for bleaching human keratin fibers using the compositions; and multicompartment devices comprising the compositions.
    Type: Grant
    Filed: January 15, 2004
    Date of Patent: June 5, 2007
    Assignee: L'Oreal S.A
    Inventor: Fréderic Legrand
  • Patent number: 7220285
    Abstract: A pulverulent composition for bleaching human keratin fibers, and more particularly the hair, comprising at least one peroxygenated salt, at least one polymer chosen from nonionic and anionic amphiphilic polymers, wherein said at least one polymer comprises at least one fatty chain; and at least one polydecene of formula C10nH[(20n)+2] in which n ranges from 3 to 9, the at least one polydecene being present in an amount by weight of less than 10% relative to the total weight of the composition. The pulverulent composition is capable of being mixed with at least one aqueous hydrogen peroxide composition having a titre of not more than 40 volumes to form stable, homogeneous, bleaching compositions that can be applied precisely and easily, and can produce a homogeneous bleaching of the hair that does not leave the hair coarse.
    Type: Grant
    Filed: April 27, 2006
    Date of Patent: May 22, 2007
    Assignee: L'Oreal S.A.
    Inventors: Frédéric Legrand, Jean-Marie Millequant
  • Patent number: 7217298
    Abstract: A composition comprising: i) at least one anhydrous bleaching composition in paste form comprising at least one peroxygenated salt, at least one alkaline agent, and from 15% to 35% by weight of at least one inert organic liquid, and ii) at least one oxidizing composition in the form of a hydrogen peroxide oil-in-water emulsion comprising at least one surfactant chosen from nonionic and anionic surfactants and at least one copolymer comprising at least one hydrophobic unit and at least one unit derived from at least one ethylenically unsaturated monomer comprising at least one sulphonic group, in free or partially or totally neutralized form. The composition may, for example, be used for bleaching human keratin fibers, such as hair. Also disclosed is a process for preparing a ready-to-use composition, comprising mixing, before use, the bleaching composition with the oxidizing composition.
    Type: Grant
    Filed: January 16, 2004
    Date of Patent: May 15, 2007
    Assignee: L'Oreal S.A.
    Inventors: Fréderic Legrand, Sylvain Kravtchenko
  • Patent number: 7109157
    Abstract: Methodologies and equipment for using a hypochlorite solution to remove menstrual fluid, underarm perspiration or other hard-to-remove stains from soft fabric articles with reduced damage to the fabric articles when compared with popular chlorine bleaches. The soft fabric articles preferably are in white, although the present invention can also be applied to articles in other colors. In one embodiment, the weight concentration ratio of the alkali metal hydroxide over the hypochlorite salt in the hypochlorite solution is no less than 1:12.5. The hypochlorite solution may contain at least 0.2% by weight of sodium hydroxide and/or have a pH of at least 11.8.
    Type: Grant
    Filed: July 3, 2003
    Date of Patent: September 19, 2006
    Inventor: Lawnie Taylor
  • Patent number: 7077869
    Abstract: The invention concerns a composition for bleaching or permanent waving of keratinous fibers, in particular human keratinous fibers and more particularly hair, comprising, in a medium suitable for bleaching or permanent waving, at least a reducing agent and furthermore at least a cationic associative polyurethane. The invention also concerns methods and devices for bleaching or permanent waving of keratinous fibers using said composition.
    Type: Grant
    Filed: November 6, 2001
    Date of Patent: July 18, 2006
    Assignee: L'Oreal S.A.
    Inventors: Frédéric Legrand, Roland De La Mettrie
  • Patent number: 7066965
    Abstract: The invention concerns bleaching composition for keratinous fibres, in particular human keratinous fibres and more particularly hair, comprising, in a medium suitable for bleaching, at least an oxidising agent and furthermore at least a cationic associative polyurethane. The invention also concerns the bleaching method and devices using said composition.
    Type: Grant
    Filed: November 6, 2001
    Date of Patent: June 27, 2006
    Assignee: L'Oreal S.A.
    Inventors: Frédéric Legrand, Roland De La Mettrie
  • Patent number: 6881299
    Abstract: Methods of bleaching mechanical pulp under alkaline conditions with hydrogen peroxide. The methods include introducing a source of magnesium ions and hydroxyl ions to a refiner. The wood particulates are refined into a pulp in the presence of the magnesium ions and hydroxyl ions, and optionally perhydroxyl ions to simultaneously refine and bleach the pulp in a refiner.
    Type: Grant
    Filed: December 9, 2003
    Date of Patent: April 19, 2005
    Assignee: North American Paper Corporation
    Inventors: Anthony Parrish, Roger O. Campbell, Raymond E. Harrison, Paul B. Mobley, Gregg McCarthy
  • Patent number: 6743332
    Abstract: A method of making bleached mechanical pulps is disclosed for pulping mills having a primary and a secondary refiner. A first step is to provide cellulosic materials, such as wood chips to refine into the pulp; the wood chips have an initial brightness level. A second step is to provide a bleaching liquor to the refining system of the pulp mill, wherein the liquor comprises an amount of hydrogen peroxide and an amount of alkali having greater than 0% to 100% magnesium hydroxide or soda ash or a combination thereof. A third step is to hold the pulp with the bleaching liquor at a temperature in the range of about 85° to about 160° C. and for about 2 to about 180 minutes. The components of the bleach liquor can be added at the first refiner or interstage between refiners.
    Type: Grant
    Filed: May 16, 2001
    Date of Patent: June 1, 2004
    Assignee: Weyerhaeuser Company
    Inventors: Kaaren K. Haynes, Roger O. Campbell, Zeecha L. Brooks, Anthony Parrish, Robert T. Hamilton
  • Patent number: 6663677
    Abstract: Improved methods for wool whitening and garment washing are provided. More particularly, methods of the present invention employ a first reducing agent, preferably a borohydride material, and a second reducing agent, preferably a bisulfite material, to increase the brightness (whiteness) of wool and to reduce color components in certain garments, particularly denim. Methods of the present invention are particularly useful in the garment and piece goods industries.
    Type: Grant
    Filed: September 17, 2001
    Date of Patent: December 16, 2003
    Assignee: Rohm and Haas Company
    Inventors: Harrie Peter Schoots, Lester Franklin Stevens, Jr.
  • Patent number: 6641618
    Abstract: Ready-to-use aqueous composition for bleaching keratin fibers, in particular, human keratin fibers, containing a combination of at least one alkaline agent, at least one peroxygenated salt, hydrogen peroxide, at least one water-soluble solvent, and at least one amphiphilic polymer chosen from nonionic and anionic amphiphilic polymers and comprising at least one fatty chain, and a process for bleaching the hair using these aqueous compositions.
    Type: Grant
    Filed: January 28, 2000
    Date of Patent: November 4, 2003
    Assignee: L'Oreal S.A.
    Inventors: Frédéric Legrand, Jean Millequant
  • Patent number: 6331192
    Abstract: The invention relates to a process for the bleaching of chemical pulp, wherein the pulp is delignified and/or bleached with chlorine dioxide or with a combination of chlorine dioxide and a per-compound, and additionally the pulp is chelated in order to bind heavy metals, such as Fe, Mn and/or Cu, to a chelate complex. The chelate complex is selected from the group made up of N-bis-[(1,2-dicarboxylethoxy)-ethyl]-amine, N-bis[(1,2-dicarboxylethoxy)-ethyl]-aspartic acid and N-tris-[(1,2-dicarboxylethoxy)-ethyl]-amine, and the alkali metal and earth-alkali metal salts of these, and the chelating treatments are carried out simultaneously by combining the chelating chemical with the pulp in the same bleaching stage as chlorine dioxide.
    Type: Grant
    Filed: June 30, 2000
    Date of Patent: December 18, 2001
    Assignee: Kemira Chemicals Oy
    Inventors: Jukka Jäkärä, Reijo Aksela, Aarto Parén, Ilkka Renvall
  • Publication number: 20010042274
    Abstract: The present invention provides a process for removal of excess dye from newly manufactured printed or dyed fabric or yarn, comprising treatment with a rinse liquor comprising at least one enzyme selected from the group consisting of enzymes exhibiting peroxidase activity or laccase activity, an oxidation agent, and at least one mediator selected from the group consisting of aliphatic, cyclo-aliphatic, heterocyclic or aromatic compounds containing the moiety >N—OH, in particular 1-hydroxybenzotriazole.
    Type: Application
    Filed: May 11, 2001
    Publication date: November 22, 2001
    Applicant: Novozymes A/S
    Inventors: Ture Damhus, Uwe Vogt, Palle Schneider
  • Patent number: 6217621
    Abstract: Matrix-dyed textiles of cellulose acetate, cellulose triacetate, silk, wool, flax, nylon, acrylic, polyethylene terephthalate, cotton, and rayon are stripped of their dyes in a dye stripping system comprising a reducing agent in an aqueous bath produced by the reaction of a bisulfite with about 0.35% or less of a borohydride by weight of the textile. The borohydride may be added to an aqueous bath already containing the bisulfite and the textile or the borohydride and bisulfite may be mixed in an add tank and the mixture added to the aqueous bath. Chelating agents, sequestering agents, fire retardants, and odor scavengers are not needed. Reclaimed textiles having superior receptivity of a new dye are provided.
    Type: Grant
    Filed: July 9, 1999
    Date of Patent: April 17, 2001
    Assignee: Morton International Inc.
    Inventors: Peter Modebelu, Harrie Schoots, Jeremy Ko
  • Patent number: 6153300
    Abstract: Recycled paper pulp having at least two different types of paper which consume widely different amounts of bleaching chemical, or mixed hardwood and soft-wood pulps, are treated in a manner that enhances distribution and redistribution of bleaching chemical to enhance uniformity of the bleaching treatment. The pulp is intensely mixed to provide a homogenous mixture of fibrous material and bleaching chemical, and then is continuously or intermittently subjected to mechanical action (such as in low intensity mixers, or by agitating pulp in a retention tank) of sufficient intensity and duration so as to enhance distribution and redistribution of a bleaching chemical. Also, recycled pulp will have cleanliness which varies significantly over time, and this is accommodated by sensing at least one of the brightness, color, or lignin content (e.g.
    Type: Grant
    Filed: April 18, 1994
    Date of Patent: November 28, 2000
    Assignee: Ahlstrom Machinery, Inc.
    Inventors: C. Bertil Stromberg, Patrick E. Sharpe, Louis O. Torregrossa, Joseph R. Phillips
  • Patent number: 6136205
    Abstract: The invention is a method for preparing a stabilized aqueous alkali or alkaline earth metal hypobromite solution. The method comprises the steps of:a. Mixing an aqueous solution of alkali or alkaline earth metal hypochlorite having from about 5 percent to about 70 percent available halogen as chlorine with a water soluble bromide ion source;b. Allowing the bromide ion source and the alkali or alkaline earth metal hypochlorite to react to form a 0.5 to 70 percent by weight aqueous solution of unstabilized alkali or alkaline earth metal hypobromite;c. Adding to the unstabilized solution of alkali or alkaline earth metal hypobromite an aqueous solution of an alkali metal sulfamate in a quantity to provide a molar ratio of alkali metal sulfamate to alkali or alkaline earth metal hypobromite is from about 0.5 to about 7; and,d. Recovering a stabilized aqueous alkali or alkaline earth metal hypobromite solution.
    Type: Grant
    Filed: May 5, 1999
    Date of Patent: October 24, 2000
    Assignee: Nalco Chemical Company
    Inventors: Anthony W. Dallmier, William F. McCoy, Shunong Yang
  • Patent number: 6024766
    Abstract: There is provided a process of desizing textiles with enzymes together with a subsequent step of deactivating any residual enzymes to prevent degradation of the textiles. There is further provided a step or removal of any residual sizing and/or decolorizing dyed garments with ozone.
    Type: Grant
    Filed: January 27, 1999
    Date of Patent: February 15, 2000
    Inventor: Eric M. Wasinger
  • Patent number: 5795487
    Abstract: The invention is a method for preparing a stabilized aqueous alkali or alkaline earth metal hypobromite solution. The method comprises the steps of:a. Mixing an aqueous solution of alkali or alkaline earth metal hypochlorite having from about 5 percent to about 70 percent available halogen as chlorine with a water soluble bromide ion source;b. Allowing the bromide ion source and the alkali or alkaline earth metal hypochlorite to react to form a 0.5 to 70 percent by weight aqueous solution of unstabilized alkali or alkaline earth metal hypobromite;c. Adding to the unstabilized solution of alkali or alkaline earth metal hypobromite an aqueous solution of an alkali metal sulfamate in a quantity to provide a molar ratio of alkali metal sulfamate to alkali or alkaline earth metal hypobromite is from about 0.5 to about 7; and,d. Recovering a stabilized aqueous alkali or alkaline earth metal hypobromite solution.
    Type: Grant
    Filed: January 3, 1997
    Date of Patent: August 18, 1998
    Assignee: Nalco Chemical Company
    Inventors: Anthony W. Dallmier, William F. McCoy
  • Patent number: 5760222
    Abstract: Bleaches, a method for bleaching substrates using these materials and detergent compositions containing same are reported. The bleaches are thiadiazole dioxide derived mono- and di- oxaziridines. Substrates such as fabrics may be bleached in an aqueous solution containing the oxaziridine.
    Type: Grant
    Filed: December 3, 1996
    Date of Patent: June 2, 1998
    Assignee: Lever Brothers Company, Division of Conopco, Inc.
    Inventor: Janet Lynn Coope
  • Patent number: 5711764
    Abstract: A composition is provided for improving decolorizing and desizing garments and fabrics with a reducing agent in a washer. A surfactant is added so as to improve wet out and to reduce the surface tension of the water.
    Type: Grant
    Filed: October 3, 1996
    Date of Patent: January 27, 1998
    Inventor: Eric M. Wasinger
  • Patent number: 5683654
    Abstract: The invention is a method for preparing a stabilized aqueous alkali or alkaline earth metal hypobromite solution. The method comprises the steps of:a. Mixing an aqueous solution of alkali or alkaline earth metal hypochlorite with a water soluble bromide ion source;b. Allowing the bromide ion source and the alkali or alkaline earth metal hypochlorite to react to form a 0.5 to 30 percent by weight aqueous solution of unstabilized alkali or alkaline earth metal hypobromite;c. Adding to the unstabilized solution of alkali or alkaline earth metal hypobromite an aqueous solution of an alkali metal sulfamate having a temperature of at least 50.degree. C. in a quantity to provide a molar ratio of alkali metal sulfamate to alkali or alkaline earth metal hypobromite is from about 0.5 to about 6; and then,d. Recovering a stabilized aqueous alkali or alkaline earth metal hypobromite solution.
    Type: Grant
    Filed: March 22, 1996
    Date of Patent: November 4, 1997
    Inventors: Anthony W. Dallmier, William F. McCoy
  • Patent number: 5571286
    Abstract: A process for shrink-proofing wool which comprises treating the wool with specific polymers and prepolymers derived from polyoxyalkyleneamines.
    Type: Grant
    Filed: July 7, 1994
    Date of Patent: November 5, 1996
    Assignee: Precision Processes (Textiles) Limited
    Inventors: David L. Connell, Anthony Szpala
  • Patent number: 5562740
    Abstract: Disclosed is a process for making reduced odor individualized, crosslinked fibers which includes the steps of providing cellulosic fibers, contacting the fibers with a solution containing a C.sub.2 -C.sub.9 polycarboxylic acid crosslinking agent, mechanically separating the fibers into substantially individual form, drying the fibers and reacting the crosslinking agent with the individualized fibers to form intrafiber crosslink bonds. The individualized cellulosic fibers are then contacted with a strong alkaline solution and strong oxidizing agent to reduce the odor and increase the brightness. Preferably, the crosslinking agent is citric acid, and preferably, between about 1.0 weight % and about 12.0 weight % of the crosslinking agent reacts to form the intrafiber crosslink bonds. Preferably, the alkaline solution is an aqueous solution of sodium hydroxide, and preferably, about 0.09 weight % of the sodium hydroxide, on a dry fiber weight basis, is applied to the crosslinked fibers.
    Type: Grant
    Filed: June 15, 1995
    Date of Patent: October 8, 1996
    Assignee: The Procter & Gamble Company
    Inventors: Jeffery T. Cook, Walter D. Daniels, Pedro A. Rodriguez, Peter A. Graef, Clifford R. Bolstad, William L. Duncan
  • Patent number: 5482514
    Abstract: The present invention relates to the addition of photosensitising compounds to woodpulps and mixtures thereof for enhancing their whiteness, brightness and chromaticity, as well as to the paper making fibres so obtained and the use thereof.
    Type: Grant
    Filed: September 9, 1993
    Date of Patent: January 9, 1996
    Assignee: Ciba-Geigy Corporation
    Inventor: Axel von Raven
  • Patent number: 5480457
    Abstract: A method for using a bleaching composition comprising a partially saturated carrier and a bleaching agent prepared by first mixing the dry carrier with the dry bleaching agent and then adding water while continuing mixing to produce a moist powder. This powder is used in a tumbler with at least partially nonsynthetic dyed fabrics to dry bleach or fade the dye from the fabrics. Specifically, the bleaching composition is a mix of potassium permanganate as the bleaching agent and diatomaceous earth as the carrier and is tumbled with the fabric to remove the dye from the fabric. The tumbling causes repeated contact with the bleaching agent and removes the dye in the fabric.
    Type: Grant
    Filed: April 27, 1994
    Date of Patent: January 2, 1996
    Assignee: Ocean Wash, Inc.
    Inventors: Glen A. Dickson, Donnie R. Gray
  • Patent number: 5366509
    Abstract: A method for bleaching a cloth dyed with an indigo dye by using a processing solution containing a bleaching agent, wherein said processing solution is an aqueous solution of a dichloroisocyanuric acid salt, is disclosed. According to the invention, the degree of bleaching can be easily controlled and, after the bleaching, neither yellowing nor deterioration of fibers occurs.
    Type: Grant
    Filed: December 11, 1992
    Date of Patent: November 22, 1994
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Masanori Ota, Masashi Nakamura, Takashi Kamiyama
  • Patent number: 5308545
    Abstract: The invention relates to pyrazoline compounds of formula ##STR1## wherein R.sub.1 is hydrogen or methyl, R.sub.2 and R.sub.3 are each independently of the other methyl, ethyl or hydroxyethyl, R.sub.4 is hydrogen or chlorine, R.sub.5 and R.sub.6 are each independently of the other hydrogen or methyl, R.sub.7 is hydrogen, methyl or phenyl, n is 0 or 1, with the proviso that, if n is 0 and R.sub.4 to R.sub.7 are hydrogen, R.sub.2 is methyl and R.sub.3 is hydroxyethyl, and X.sup..crclbar. is a C.sub.1 -C.sub.3 alkanoate, C.sub.1 -C.sub.4 alkanephosphonate, C.sub.1 -C.sub.4 alkanesulfonate, phosphite, sulfamate or glycolate anion and, if R.sub.1 is methyl, X.sup..crclbar. is also a methosulfate, chloride or bromide ion, to the preparation of said compounds, to the use thereof as fluorescent whitening agents, and to novel hydrazine intermediates of formula ##STR2## wherein R.sub.2 and R.sub.3 are methyl, ethyl or hydroxyethyl, and the acetone hydrazones and salts thereof.
    Type: Grant
    Filed: November 30, 1992
    Date of Patent: May 3, 1994
    Assignee: Ciba-Geigy Corporation
    Inventor: Hans R. Meyer