Paper Patents (Class 8/119)
  • Patent number: 7914646
    Abstract: Oxidative compositions and processes that preserve and enhance the brightness and improve color of pulp or paper when applied during different stages of the papermaking process are identified. The oxidative composition and method maintains and/or enhances brightness, prevents yellowing, and enhances the performance of paper products. Used in combination with optical brighteners and/or chelants the oxidative agents produce a synergistic effect not previously identified in the paper process.
    Type: Grant
    Filed: July 21, 2006
    Date of Patent: March 29, 2011
    Assignee: Nalco Company
    Inventors: Prasad Y. Duggirala, Sergey M. Shevchenko, Katherine M. Broadus
  • Patent number: 7019134
    Abstract: Water soluble, amphoteric optical brighteners (W) comprising at least one brightener-characteristic radical X which contain at least one anionic substituent and covalently linked over at least one tertiary amino group Z to at least one non-chromophoric, essentially aliphatic, polyquaternary ammonium-hydrocarbon radical Y containing more than one quaternary ammonium group and in which each hydrocarbon radical is optionally interrupted by and/or substituted with one or more further heteroatoms, have surprising brightening properties, especially in papermaking, and in the form of their aqueous solutions are of notable stability.
    Type: Grant
    Filed: December 19, 2000
    Date of Patent: March 28, 2006
    Assignee: Clariant Finance (BVI) Limited
    Inventors: John Martin Farrar, Andrew Clive Jackson
  • Patent number: 6890454
    Abstract: The invention relates to an optical brightener mixture (W) comprising optical brighteners (A) of formula (Ia), and (B) of formula (Ib) and optionally (C) of formula (Ic) as defined herein, their concentrated aqueous solutions (S), their production and their use.
    Type: Grant
    Filed: January 8, 2002
    Date of Patent: May 10, 2005
    Assignee: Clariant Finance (BVI) Limited
    Inventors: John Martin Farrar, Andrew Clive Jackson, Alec Stewart Tindal
  • Patent number: 6723846
    Abstract: The present invention relates to compounds having formula (1): wherein each R1 represents, independently, a linear C1-C4-alkylene residue which is unsubstituted or substituted by hydroxy, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-hydroxy- or alkoxy-alkoxy, —OCOM, —OCOC1-C4-alkyl, or an amino acid residue from which a hydrogen atom on the amino group has been removed; each R2 represents, independently, a linear C1-C4-alkylene residue which is unsubstituted or substituted by hydroxy, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-hydroxy- or alkoxy-alkoxy, —OCOM, —OCOC1-C4-alkyl, —CO2M, CO2C1-C4-alkyl SO3M or phenoxy which is unsubstituted or substituted by halogen, C1-C4-alkyl or C1-C4-alkoxy, —CO2M or CO2C1-C4-alkyl, NH3 or mono- or disubstituted amino; or phenyl which is unsubstituted or substituted by 1 to 3 SO3M, SO2NHC1-C4-alkyl, —SO2NH2, —CO2M, —CO2M, —CO2C1-C4-alkyl, —CONH2, —CONHC1-C4-alkyl, —NHCOC1-C4-alkyl or mono- or disubstituted amino groups;
    Type: Grant
    Filed: March 6, 2002
    Date of Patent: April 20, 2004
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Georges Metzger, Serge Hauger, Fabienne Cuesta, Christophe Bulliard, Peter Rohringer, Marc Roger Grienenberger
  • Patent number: 6607813
    Abstract: A security document is provided comprising a finished cellulosic substrate having at least one transparentized portion formed therein. The transparentized portion comprises a transparentizing composition that is applied so as to define an area of increased transparency in the substrate. The area of increased transparency includes at least one thin line and resembles a simulated security thread. The transparentizing composition can be applied to form thin lines in a variety of configurations on one or both sides of the substrate.
    Type: Grant
    Filed: August 23, 2001
    Date of Patent: August 19, 2003
    Assignee: The Standard Register Company
    Inventors: David E. Washburn, Harry A. Seifert, Watson L. Gullett, Rajendra Mehta
  • Patent number: 6331626
    Abstract: The present invention provides a hydrate of the 4,4′-di-triazinylamino-2,2′-di-sulfostilbene compound having the formula: in which M and M1 independently represent hydrogen, an alkaline-, an alkaline earth metal or ammonium, x is a number within the range of from 1 to 30, and the crystal form of the hydrate (I) being characterised by an X-ray diffraction pattern which is essentially as set out in the accompanying FIGS. 1 to 11; or a mixture containing one or more of the hydrates of the 4,4′-di-triazinylamino-2,2′-di-sulfostilbene compound having the formula (I); processes for the preparation of the new hydrates; and the use of the new hydrates for the preparation of concentrated aqueous formulations of fluorescent whitening agents.
    Type: Grant
    Filed: September 21, 2000
    Date of Patent: December 18, 2001
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Peter Rohringer, André Geoffroy, Andreas Burkhard, Erwin Marti, Werner Schreiber, Josef Zelger
  • Patent number: 6294682
    Abstract: The invention concerns solutions of alkoxides containing titanium and/or zirconium and/or hafnium and magnesium and/or calcium and/or strontium and/or barium of general formula (I): [MII(OR)2-y(OR1)y]n.[MIV(OR1)4-z(OR)2], in which: MII means magnesium and/or calcium and/or strontium and/or barium; MIV titanium and/or zirconium and/or hafnium; R is an alkyl group with 1 to 18 carbon atoms; R1 is an alkyl group with 1 to 18 carbon atoms, y has a value of between 0 to 2; z has a value of 0 and 4; and n is a number between 0.001 and 3, with the exception that n cannot be 1 when y is 2 and z is 0, or when y is 0 and z is 4. The invention further concerns the production of these alkoxides and their use.
    Type: Grant
    Filed: June 19, 2000
    Date of Patent: September 25, 2001
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Hartwig Rauleder, Burkhard Standke, Michael Horn, Hans-Joachim Kotzsch, Hans-Gunther Srebny
  • Patent number: 6241780
    Abstract: This invention relates to a method for strengthening a cellulosic substrate by treating the substrate with a formaldehyde-free curable aqueous composition and curing the composition. The cellulosic substrates include, for example, paper oil- and air-filter stock, rayon nonwoven wipes, cellulosic laminating stock, cotton woven fabrics, and wood flakes suitable to be consolidated into flakeboard.
    Type: Grant
    Filed: February 27, 1995
    Date of Patent: June 5, 2001
    Assignee: Rohm and Haas Company
    Inventors: Charles Thomas Arkens, Scott Lind Egolf, Robert David Gleim, Oscar Hsien-Hsiang Hsu, Kenneth John Wiesinger
  • Patent number: 6153122
    Abstract: The present invention provides a hydrate of the 4,4'-di-triazinylamino-2,2'-di-sulfostilbene compound having the formula: ##STR1## in which M and M.sub.1 independently represent hydrogen, an alkaline-, an alkaline earth metal or ammonium, x is a number within the range of from 1 to 30, and the crystal form of the hydrate (I) being characterized by an X-ray diffraction pattern which is essentially as set out in the accompanying FIGS. 1 to 11; or a mixture containing one or more of the hydrates of the 4,4'-di-triazinylamino-2,2'-di-sulfostilbene compound having the formula (I); processes for the preparation of the new hydrates; and the use of the new hydrates for the preparation of concentrated aqueous formulations of fluorescent whitening agents.
    Type: Grant
    Filed: May 19, 1998
    Date of Patent: November 28, 2000
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Peter Rohringer, Andre Geoffroy, Andreas Burkhard, Erwin Marti, Werner Schreiber, Josef Zelger
  • Patent number: 6080208
    Abstract: The present invention provides new stilbene compounds which are useful as fluorescent whitening agents (FWAs), imparting high whiteness levels to textile fibre material treated with them, and which also impart a high sun protection factor (SPF) to textile fibre material treated with them. The present invention also concerns a method of imparting a high whiteness level and a high sun protection factor to textile fibre material, especially cotton, polyamide and wool, comprising treating the textile material with the new compounds.
    Type: Grant
    Filed: December 22, 1998
    Date of Patent: June 27, 2000
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Dieter Reinehr, Georges Metzger, Hanspeter Sauter
  • Patent number: 5718728
    Abstract: This invention relates to a method for strengthening a cellulosic substrate by treating the substrate with a formaldehyde-free curable aqueous composition and curing the composition. The cellulosic substrates include, for example, paper oil- and air-filter stock, rayon nonwoven wipes, cellulosic laminating stock, cotton woven fabrics, and wood flakes suitable to be consolidated into flakeboard.
    Type: Grant
    Filed: August 26, 1996
    Date of Patent: February 17, 1998
    Assignee: Rohm and Haas Company
    Inventors: Charles Thomas Arkens, Scott Lind Egolf, Robert David Gleim, Oscar Hsien-Hsiang Hsu, Kenneth John Wiesinger
  • Patent number: 5238648
    Abstract: A hermetic enclosure assembly, having utility for preservational storage and/or display of objects susceptible to degradation by exposure conditions such as ultraviolet radiation, visible light, oxygen, humidity, microbial, fungal, and insect species, internal acidity and external acidic gases, and the like. The enclosure assembly includes a gas-impervious housing, a mounting base, and a back cover plate, with an oxygen indicating means in communication with an interior volume of the enclosure assembly, and a slow vapor-released deacidification medium being arranged for dispersing deacidification medium vapor into the interior volume of the enclosure assembly. Also disclosed is an appertaining method of preservationally and protectively enclosing an object for storage and/or display. The invention has particular utility in the storage and/or display of cellulosic objects, which are especially susceptible to embrittlement and decay at low pH conditions, in exposure to visible light, oxygen, and moisture.
    Type: Grant
    Filed: June 3, 1992
    Date of Patent: August 24, 1993
    Inventor: Irwin Kremen
  • Patent number: 5219524
    Abstract: An article preservation system and method includes an acid-containing article which is contacted with an alkaline substrate material and an artificial atmosphere which is substantially free of gaseous oxygen. The article, alkaline substrate material and artificial atmosphere are hermetically sealed within an interior of a container, at least a portion of the container being at least partially transparent so as to permit viewing of the article from outside the container.
    Type: Grant
    Filed: May 7, 1991
    Date of Patent: June 15, 1993
    Assignee: Everseal Preservation Labs., Inc.
    Inventor: Creed M. Evans, II
  • Patent number: 5055354
    Abstract: Transparentized paper, free of residual solvent, is fabricated by coating a web of paper with a solvent-free transparentizing medium, allowing the medium to remain on the paper for a period of time sufficient to saturate part but not all of the thickness of the web, removing the excess transparentizing medium and storing the paper for a period of time sufficient to equilibrate the concentration of transparentizing medium in the thickness of the web. Also included are solvent-free transparentized papers produced by this method.
    Type: Grant
    Filed: July 27, 1989
    Date of Patent: October 8, 1991
    Assignee: Phomat Reprographics, Inc.
    Inventor: David R. Simcoke
  • Patent number: 4137046
    Abstract: A transparent cellulosic paper is produced by coating or impregnating a cellulosic paper with an organic solvent solution containing a compound having a weight-average molecular weight of 200 to 2,000 and having at least two isocyanate groups in a molecule or with an organic solvent solution containing, in addition to said compound, at least one compound selected from the group consisting of an aliphatic monohydric alcohol having 6 to 18 carbon atoms and a nonionic surface active agent to the polyethylene glycol type having one hydroxyl group in a molecule, the ratio OH/NCO in the solution being less than 1; removing said organic solvent; and allowing the coated or impregnated paper to harden by aging.
    Type: Grant
    Filed: October 4, 1976
    Date of Patent: January 30, 1979
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Takashi Koike, Masahiro Amano
  • Patent number: 4065256
    Abstract: A shaped article of hydrophobic synthetic polymer is graft polymerized uniformly and economically in a high yield, and consequently is endowed with various advantageous properties, when it is treated in an aqueous emulsified dispersion having dispersed in water an hydrophobic radical polymerization initiator, an organic solvent which is liquid at normal room temperature, naphthalene and an unsaturated monomer containing in the molecular unit thereof at least one double bond capable of radical polymerization.
    Type: Grant
    Filed: February 2, 1976
    Date of Patent: December 27, 1977
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Kikuji Igeta, Masakatsu Ohguchi