Chemical Modification In The Presence Of A Sulfur Or Silicone Containing Material Patents (Class 8/128.3)
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Patent number: 8292971Abstract: The present invention relates to a method of treating fabric conditioner for washable silk products, which can provide smoothness to silk products since fabric conditioners of different kinds are mixed and treated together and decrease whiteness or prevent yellowing.Type: GrantFiled: October 27, 2008Date of Patent: October 23, 2012Inventor: Man Soo Choi
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Publication number: 20110203054Abstract: The present invention relates to a method of treating fabric conditioner for washable silk products, which can provide smoothness to silk products since fabric conditioners of different kinds are mixed and treated together and decrease whiteness or prevent yellowing.Type: ApplicationFiled: October 27, 2008Publication date: August 25, 2011Inventor: Man Soo Choi
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Publication number: 20110191963Abstract: Disclosed is a method for producing a modified animal fiber, the method includes step 1 (31, 32) of pre-oxidizing a cystine bond (—S—S— bond) present in an epidermal cell of an animal fiber to bring the cystine bond into a low oxidation state, step 2 (33) of oxidizing with ozone the pre-oxidized —S—S— bond to bring the —S—S— bond into at least one high oxidation state selected from di-, tri-, and tetra-oxidation states, and step 3 (34) of reductively cleaving the —S—S— bond in a high oxidation state. The method imparts shrink resistance and pilling resistance to an animal fiber. In the step 2 (33) ozone is microdispersed in an aqueous solution comprising an anionic surfactant having a C8-24 alkyl group, and the animal fiber is contacted with the ozone.Type: ApplicationFiled: June 23, 2010Publication date: August 11, 2011Applicant: KURASHIKI BOSEKI KABUSHIKI KAISHAInventors: Akinori Takagi, Susumu Katsuen, Kunihiro Ohshima
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Patent number: 7740664Abstract: The present disclosure provides a composition for treating keratin fibers, for example, human keratin fibers such as the hair. The present disclosure provides a composition for dyeing keratin fibers, comprising: at least one compound X and at least one compound Y, wherein at least one of the compounds X and Y is a silicone compound, wherein when X and Y are placed in contact with each other they react together via a hydrosilyation reaction, a condensation reaction, or a crosslinking reaction in the presence of at least one peroxide; and at least one alkoxysilane comprising a single silicon atom.Type: GrantFiled: December 20, 2007Date of Patent: June 22, 2010Assignee: L'oreal S.A.Inventor: Katarina Benabdillah
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Patent number: 7465321Abstract: Film, fibre, foam and adhesive materials are produced from soluble S-sulfonated keratins. Once formed, the films, fibres, foams or adhesives are treated to modify the properties of the materials, in particular to improve the wet strength of the materials. Treatments used include removal of the S-sulfonate group by treatment with a reducing agent, treatment with an acid or treatment with a common protein crosslinking agent or treatment with a reduced form of keratin or keratin protein. The films are made by solvent casting a solution of S-sulfonated keratin proteins, the foam made by freeze-drying a solution of S-sulfonated keratin proteins and the fibres made by extruding a solution of a S-sulfonated keratin protein.Type: GrantFiled: August 30, 2002Date of Patent: December 16, 2008Assignee: Keratec LimitedInventors: Robert James Kelly, Alisa Dawn Roddick-Lanzilotta, Douglas Alexander Rankin, Warren Glenn Bryson
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Patent number: 7147671Abstract: A silicone composition is provided which comprises at least one polysiloxane or siloxane oligomer functionalized with at least one amino group and at least three functional groups capable of cross-linking wherein the polysiloxane or siloxane oligomer imparts flame retardancy on a cellulose-containing substrate. Further embodiments of the present invention include a method for making and a cellulose-substrate comprising the aforementioned silicone composition.Type: GrantFiled: June 2, 2003Date of Patent: December 12, 2006Assignee: General Electric CompanyInventors: Matthew David Butts, Kathryn Ann Shaffer
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Patent number: 7090701Abstract: Methods of improving shrink-resistance of natural fibers (e.g., wool, wool fibers, animal hair, cotton), synthetic fibers (e.g., acetate, nylon, polyester, viscose rayon), or blends thereof (e.g., wool/cotton blends), or fabrics or yarns composed of natural fibers, synthetic fibers, or blends thereof, involving contacting the fibers (or fabric or yarn) with NaOH, H2O2, gluconic acid, dicyandiamide, and non-ionic surfactant (e.g., Triton X surfactant such as Triton X-100 and preferably Triton X-114), and optionally subsequently contacting the fibers (or fabric or yarn) with protease and non-ionic surfactant and optionally sodium sulfite and optionally triethanolamine and optionally polyacrylamide polymer. The methods do not utilize dichloroisocyanuric acid, chloroamines, peroxymonosulfuric acid, monoperoxyphthalic acid, permanganate, chlorine gas, sodium hypochlorite, or aminoplast resins.Type: GrantFiled: December 8, 2003Date of Patent: August 15, 2006Assignee: The United States of America as represented by the Secretary of AgricultureInventors: Jeanette M. Cardamone, Jiming Yao
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Patent number: 6827746Abstract: A process for treating a textile fabric to impart or enhance at least one property of the fabric comprising: introducing the fabric into an aqueous formaldehyde containing solution to provide a wet pickup of an effective amount of the solution by the fabric, applying to the fabric an effective amount of a catalyst for catalyzing a reaction between formaldehyde and the fabric; thereafter exposing the wet fabric to a temperature of at least about 300° F. to react the formaldehyde with the fabric to impart or enhance the property of the fabric before there is a substantial loss of formaldehyde from the exposed fabric.Type: GrantFiled: February 7, 2002Date of Patent: December 7, 2004Assignee: Strike Investments, LLCInventor: George L. Payet
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Patent number: 6803407Abstract: Described are polysiloxane compositions that are obtainable in 2 steps. The first step comprises reacting a linear organopolysiloxane which contains Si—H bonds with a compound that has a terminal C═C double bond and a polyoxyalkylene chain. This reaction is carried out in such a way that Si—H bonds are still present in the resultant product. The second step comprises adding a base or water and an acid to the resultant product. The hydrophilic properties of the resultant polysiloxane compositions can be influenced in a specific manner. The compositions are useful for treating fiber materials, especially textile fabrics. The effects obtained are notable for good durability. Further groups may be incorporated into the polysiloxanes to open up further applications.Type: GrantFiled: September 13, 2002Date of Patent: October 12, 2004Assignee: Ciba Specialty Chemicals CorporationInventors: Harald Chrobaczek, Franz Dirschl, Ralf Goretzki, Günther Tschida
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Patent number: 6691358Abstract: The invention refers to a method for an integrated treatment of cellulose pulp. The method includes the steps: providing said cellulose pulp (1), providing a determined quantity of white liquor (2) including alkali and sulphur components, providing an oxygen-containing gas, oxidizing (5) the sulphur components of the white liquor by the supply of a part of said gas in such a way that at least a part of the sulphur is present in the form of sulphate, transporting the cellulose pulp having a certain kappa number to at least one mixing device (4), and supplying the oxidized white liquor from the oxidizing step to the cellulose pulp, supplying a part of said gas to the cellulose pulp in said mixing device, mixing the cellulose pulp with the oxidized white liquor and said gas in said mixing device, and transporting the cellulose pulp from said mixing device to a delignification reactor (6) for oxygen delignification of said cellulose pulp, wherein the kappa number is reduced.Type: GrantFiled: March 15, 2002Date of Patent: February 17, 2004Assignee: AGA AktiebolagInventors: Anders Tor Jörgen Engström, Anna Tigerström
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Patent number: 6663677Abstract: Improved methods for wool whitening and garment washing are provided. More particularly, methods of the present invention employ a first reducing agent, preferably a borohydride material, and a second reducing agent, preferably a bisulfite material, to increase the brightness (whiteness) of wool and to reduce color components in certain garments, particularly denim. Methods of the present invention are particularly useful in the garment and piece goods industries.Type: GrantFiled: September 17, 2001Date of Patent: December 16, 2003Assignee: Rohm and Haas CompanyInventors: Harrie Peter Schoots, Lester Franklin Stevens, Jr.
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Patent number: 6660044Abstract: The present invention provides a fiber product-treating agent which can impart an excellent wrinkle-resistant effect and an excellent durable press effect to the fiber product capable of being heated and being hardly effected with not only during wearing but also after washing. That is, the present invention provides the treating agent for imparting the durable press configuration on a fiber product by a heating treatment with e.g. an iron, which comprises a specific amount of (i) two or more compounds forming mutually a crosslinked structure by heating and/or (ii) a compound forming a self-crosslinked structure by heating, and water, wherein the content of a nonvolatile matter is 0.01 to 30%.Type: GrantFiled: March 30, 2001Date of Patent: December 9, 2003Assignee: Kao CorporationInventors: Takako Igarashi, Koji Yui, Miki Hasegawa, Yasushi Yoshida
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Patent number: 6652599Abstract: A treatment agent for elastic polyurethane fibers comprising a dispersion in which a higher fatty acid magnesium salt is colloidally dispersed in a silicone mixture consisting of a silicone oil with a viscosity of 5×10−6−50×10−6 m2/S at 25° C. as a dispersion medium and a dispersant mainly comprising a modified silicone at a ratio by weight of the dispersion medium/the dispersant=100/0.5-100/4.5, wherein the amount of the higher fatty acid magnesium salt is 1 to 10 parts by weight per 100 parts by weight of the silicone oil.Type: GrantFiled: August 15, 2000Date of Patent: November 25, 2003Assignees: Takemoto Oil & Fat Co., Ltd., Du Pont-Toray Co., Ltd.Inventors: Yoshinobu Inuzuka, Yasushi Miyamoto, Eiji Kawanishi, Noboru Watanabe
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Patent number: 6632537Abstract: Reaction product of a composition comprising in admixture a polyisocyanate, a silicone having dimethylsiloxane segments containing one or more isocyanate-reactive group, a reactant containing one or more of an isocyanate-reactive group and one or more ionizable group, optionally an organic substance having one or more isocyanate-reactive groups and no ionizable group, and compound providing counterion for said ionizable group, wherein either the silicone, or the reactant, or both, have a single isocyanate-reactive group.Type: GrantFiled: May 29, 2001Date of Patent: October 14, 2003Inventor: A. Andrew Shores
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Patent number: 6579325Abstract: Compositions are described with organopolysiloxanes which contain crosslinked units and are further crosslinkable. The compositions further contain reaction products of diepoxides and diamines. They are useful for treating fiber materials, especially textile sheet materials, and can be applied thereto in the form of aqueous solutions or dispersions. Textiles which are 50 to 100% by weight wool and have been finished with the compositions exhibit low shrinkage and low felting tendency during washing operations.Type: GrantFiled: August 3, 2000Date of Patent: June 17, 2003Assignee: Ciba Specialty Chemicals CorporationInventors: Simpert Lüdemann, Harald Chrobaczek, Theodor Angele, Jürgen Riedmann
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Patent number: 6511928Abstract: A durable press process for rayon fiber-containing fabrics comprising treating a rayon fiber-containing fabric with an aqueous mixture containing a high concentration of formaldehyde, and a catalyst capable of catalyzing the crosslinking reaction between formaldehyde and the rayon, wherein the concentration of the formaldehyde is sufficient to produce a durable press fabric without substantially shrinkage of the treated fabric, followed by heat curing the treated fabric to produce a durable press rayon fabric without substantial shrinkage.Type: GrantFiled: September 30, 1998Date of Patent: January 28, 2003Assignee: The Procter & Gamble CompanyInventor: George L. Payet
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Patent number: 6475568Abstract: A composition is disclosed that comprises non-hydrolyzable, block, non-(AB)n type copolymers comprising units of the formula {XR2[(SiO(R1)2]xSi(R1)2R2X}, units of the formula {YO(CaH2aO)bY}, and linking groups —NR3—, wherein R1 is alkyl, R2 is a divalent organic moiety, X and Y are independently selected divalent organic groups formed by the ring opening of an epoxide, R3 is selected from the group consisting of alkyl, aryl, aralkyl, oxygen-containing alkyl, oxygen-containing aryl, and oxygen-containing aralkyl, a=2 to 4, b=2 to 100, and x=1 to 500.Type: GrantFiled: May 15, 2001Date of Patent: November 5, 2002Assignee: Crompton CorporationInventor: Anna Maria Czech
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Patent number: 6375685Abstract: A process for treating a textile fabric to impart or enhance at least one property of the fabric comprising: introducing the fabric into an aqueous formaldehyde containing solution to provide a wet pickup of an effective amount of the solution by the fabric, applying to the fabric an effective amount of a catalyst for catalyzing a reaction between formaldehyde and the fabric; thereafter exposing the wet fabric to a temperature of at least about 300° F. to react the formaldehyde with the fabric to impart or enhance the property of the fabric before there is a substantial loss of formaldehyde from the exposed fabric.Type: GrantFiled: March 15, 1999Date of Patent: April 23, 2002Assignee: The Procter & Gamble CompanyInventor: George L. Payet
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Patent number: 6258129Abstract: The present invention relates to methods of producing wool or animal hair material with improved properties such as shrink-proofed (anti-felting tendency), increased whiteness, improved dyeability, increased softness and/or reduced pilling tendency, the method comprising the steps of treating wool, wool fibers or animal hair material in a process selected from the group consisting of plasma treatment processes and the Delhey process, and subjecting the wool or animal hair material to a treatment with a proteolytic enzyme (a protease), preferably a serine protease, more preferably a subtilisin, in an amount effective for improving the properties.Type: GrantFiled: June 6, 1997Date of Patent: July 10, 2001Assignee: Novozymes A/SInventors: Lone Dybdal, Elisabeth Heine, Hartwig Hocker
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Patent number: 6242554Abstract: The invention relates to novel polyether-quaternary organosiloxanyl derivatives, to the preparation of these compounds and to their use in formulations for improving the surface properties of fabrics and fibers.Type: GrantFiled: November 11, 1999Date of Patent: June 5, 2001Assignee: TH. Goldschmidt AGInventors: Stephan Busch, Manfred Krakenberg, Peter Lersch, Stephan Stadtmüller