Paradiaminobenzene Dye Patents (Class 8/410)
  • Patent number: 7988737
    Abstract: Provided is a ready-to-use composition for the oxidation dyeing of keratin fibers, and for example of human keratin fibers such as the hair, comprising: A) at least one fatty substance present in an amount of greater than or equal to 25% by weight relative to the total weight of the ready-to-use composition, at least one of the at least one fatty substance being chosen from fatty amides and fatty acid esters, B) at least one dye precursor, C) at least one oxidizing agent and optionally D) at least one alkaline agent. Also provided is a method of dyeing of keratin fibres, comprising applying a ready-to-use composition to the keratin fibres for a sufficient time to develop the desired coloration.
    Type: Grant
    Filed: December 18, 2009
    Date of Patent: August 2, 2011
    Assignee: L'Oreal S.A.
    Inventors: Leïla Hercouet, Frédéric Simonet, Franck Clement, Marie-Pascale Audousset, Isabelle Schlosser
  • Patent number: 7988738
    Abstract: Provided herein is a process for dyeing keratin materials, comprising: applying to said keratin materials a dyeing composition, comprising, a direct emulsion (A) comprising at least one fatty substance other than fatty acids present in an amount greater than 25% by weight; at least one surfactant; at least one alkaline agent; at least one colored or coloring entity chosen from direct dyes and oxidation dyes; and water in an amount greater than 5% by weight relative to the total weight of the direct emulsion (A); and a composition (B) comprising at least one oxidizing agent.
    Type: Grant
    Filed: December 18, 2009
    Date of Patent: August 2, 2011
    Assignee: L'Oreal S.A.
    Inventors: Leïla Hercouet, Anne-Laure Bernard, Dominique Bordeaux
  • Patent number: 7976584
    Abstract: The invention relates to a keratin fiber dyeing composition comprising, in a suitable medium, at least one dye that is selected from among direct dyes and dye precursors, said cosmetic medium containing water and at least one propylene glycol derivative having formula R1(OC3H6)nOR2 (I). The inventive composition can be used to obtain strong color while retaining the softness of the treated hair.
    Type: Grant
    Filed: April 27, 2006
    Date of Patent: July 12, 2011
    Assignee: L'Oreal S.A.
    Inventors: Maxime De Boni, Alain Lagrange
  • Patent number: 7972387
    Abstract: The present disclosure relates to a composition for dyeing keratin fibers such as the hair, which comprises, in a suitable medium, at least one oxidation base, optionally at least one coupler and at least one polyoxyethylenated sorbitan ester with a number of moles of ethylene oxide of less than or equal to 10. Such a composition makes it possible to conserve a strong coloration, while at the same time limiting the discomfort that may be experienced on the scalp at the time of application of the dye composition or after this application.
    Type: Grant
    Filed: August 11, 2006
    Date of Patent: July 5, 2011
    Assignee: L'Oreal S.A.
    Inventors: Marie-Pascale Audousset, Christine Rondeau
  • Patent number: 7959687
    Abstract: The present disclosure relates to a hair dyeing process comprising dyeing the hair by applying to the hair at least one dyeing composition comprising at least one dye precursor; rinsing the hair; and post-treating the hair by applying to the hair at least one aqueous composition comprising at least 30% of water and at least 20% of at least one organic silicon compound chosen from the silanes that comprise one silicon atom and the siloxanes that comprise two or three silicon atoms, wherein the least one organic silicon compound also comprises at least one basic chemical functional group and at least one hydroxyl group or hydrolysable group per molecule.
    Type: Grant
    Filed: April 29, 2010
    Date of Patent: June 14, 2011
    Assignee: L'Oreal, S.A.
    Inventors: Delphine Charrier, Marie-Pascale Audousset, Leïla Hercouet
  • Patent number: 7947088
    Abstract: The present disclosure relates to a composition for dyeing keratin fibers, comprising, in a suitable medium, at least one first oxidation base chosen from 2,3-diamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one and the addition salts thereof; at least one second oxidation base chosen from 4,5-diamino-1-(?-hydroxyethyl)pyrazole and the addition salts thereof; and at least one coupler chosen from 2-chloro-6-methyl-3-aminophenol and the addition salts thereof. The present disclosure also relates to a process for dyeing keratin fibers using the composition of the present disclosure, the use of this composition for dyeing keratin fibers, and also a method for making the composition of the present disclosure.
    Type: Grant
    Filed: November 6, 2009
    Date of Patent: May 24, 2011
    Assignee: L'Oreal S.A.
    Inventors: Gautier Deconinck, Jean-Baptiste Saunier, Patricia Desenne
  • Patent number: 7947089
    Abstract: The present disclosure relates to a method of coloring or lightening of human keratin fibers in the presence of an oxidizing agent, comprising the application of an anhydrous cosmetic composition comprising at least one fat, and at least one surfactant, an oxidizing composition, a composition comprising at least one inorganic base. It also relates to a kit with several compartments, in which a first compartment comprises the aforementioned anhydrous cosmetic composition, a second compartment comprises an oxidizing composition and a third compartment comprises a composition comprising at least one inorganic base and optionally at least one dye.
    Type: Grant
    Filed: December 18, 2009
    Date of Patent: May 24, 2011
    Assignee: L'Oreal S.A.
    Inventors: Leïla Hercouet, Alain Lagrange
  • Patent number: 7931697
    Abstract: The present disclosure relates to a composition for dyeing keratin fibers, comprising, in a suitable medium, at least one first oxidation base chosen from 2,3-diamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one and the addition salts thereof; and at least one second oxidation base chosen from 4,5-diamino-1-(?-hydroxyethyl)pyrazole and the addition salts thereof. The present disclosure also relates to a process for dyeing keratin fibers using the composition of the present disclosure, the use of this composition for dyeing keratin fibers, and also a method for making the composition of the present disclosure.
    Type: Grant
    Filed: November 6, 2009
    Date of Patent: April 26, 2011
    Assignee: L'Oreal S.A.
    Inventors: Gautier Deconinck, Jean-Baptiste Saunier, Patricia Desenne
  • Patent number: 7931698
    Abstract: Provided is a ready-to-use composition for the oxidation dyeing of keratin fibers, and for example of human keratin fibers such as the hair, comprising, A) at least one fatty substance other than fatty acids present in the ready-to-use composition in an amount of greater than or equal to 25% by weight relative to the total weight of the ready-to-use composition, B) at least one polymeric thickener, C) at least one dye precursor, D) at least one oxidizing agent and E) at least one alkaline agent wherein at least one of the at least one alkaline agent is an organic amine. Also provided is a method of dyeing keratin fibers, comprising applying the ready-to-use composition to the keratin fibers for a sufficient time to develop the desired coloration.
    Type: Grant
    Filed: December 18, 2009
    Date of Patent: April 26, 2011
    Assignee: L'Oreal S.A.
    Inventors: Frédéric Simonet, Luc Nicolas-Morgantini, Irène Fonseca, Leïla Hercouet, Marie-Pascale Audousset, Jean-Marc Ascione, Florence Laurent
  • Patent number: 7927382
    Abstract: Provided is a ready-to-use composition for the oxidation dyeing of keratin fibers, and for example human keratin fibers such as the hair, comprising: A) at least one fatty substance present in the ready-to-use composition in an amount of greater than or equal to 25% by weight relative to the total weight of the ready-to-use composition, B) at least one oxidation base chosen from 4,5-diaminopyrazoles and the acid addition salts thereof, C) at least one additional dye precursor other than the at least one oxidation base defined in B), D) at least one oxidizing agent, and optionally E) at least one alkaline agent. Also provided is a process comprising applying to the keratin fibers for a period of time sufficient to develop the desired coloring, the ready-to-use composition.
    Type: Grant
    Filed: December 18, 2009
    Date of Patent: April 19, 2011
    Assignee: L'Oreal S.A.
    Inventors: Marie-Pascale Audousset, Isabelle Schlosser
  • Patent number: 7927383
    Abstract: The present disclosure relates to a composition for dyeing or lightening human keratin fibers, comprising: a cosmetically acceptable medium; at least 25% by weight of at least one fatty substance different from fatty acids; from 1% to 10% by weight of at least one nonionic surfactant comprising ethylene oxide in an amount ranging from 10 mol to 80 mol; at least one dye chosen from oxidation dyes and direct dyes; at least one basifying agent; and at least one oxidizing agent. The disclosure also relates to a dyeing or lightening process using it. Another subject of the disclosure is multi-compartment devices or kits for obtaining, after mixing together the compositions of the compartments, just before its application, a composition according to the disclosure.
    Type: Grant
    Filed: December 18, 2009
    Date of Patent: April 19, 2011
    Assignee: L'Oreal S.A.
    Inventors: Leïla Hercouet, Frédéric Simonet, Marie-Pascale Audousset, Isabelle Schlosser
  • Patent number: 7927380
    Abstract: The disclosure relates to a composition for the oxidation dyeing of keratin fibers comprising: A) at least one fatty substance wherein the at least one fatty substance is present in an amount greater than or equal to 25% by weight relative to the total weight of the composition; B) at least one oxidation base chosen from diaminopyrazolones and acid-addition salts thereof; C) at least one additional dye precursor other than the oxidation base in B); D) at least one oxidizing agent; and optionally E) at least one alkaline agent.
    Type: Grant
    Filed: December 18, 2009
    Date of Patent: April 19, 2011
    Assignee: L'Oreal S.A.
    Inventors: Marie-Pascale Audousset, Isabelle Schlosser
  • Patent number: 7918903
    Abstract: The present disclosure relates to a composition for the oxidation dyeing of keratin fibers, for example human keratin fibers such as the hair, comprising: at least one fatty substance present in an amount greater than or equal to 20% by weight relative to the total weight of the composition; at least one oxidation base chosen from N,N-(?-hydroxyethyl)-para-phenylenediamines and the addition salts thereof with an acid, at least one dye precursor different than the at least one oxidation base chosen from N,N-(?-hydroxyethyl)-para-phenylenediamines and the addition salts thereof with an acid, at least one oxidizing agent, and optionally at least one alkaline agent. The disclosure also relates to a dyeing or lightening process using it. Another aspect of the disclosure is multi-compartment devices or kits for obtaining, after mixing together the compositions of the compartments, just before its application, a composition according to the disclosure.
    Type: Grant
    Filed: December 18, 2009
    Date of Patent: April 5, 2011
    Assignee: L'Oreal, S.A.
    Inventors: Marie-Pascale Audousset, Isabelle Schlosser
  • Patent number: 7918900
    Abstract: Disclosed herein is a process for the predictable coloring of keratinous fibers, for example, human keratinous fibers, such as the hair, comprising applying to the fibers a first composition comprising at least one oxidation base derived from diamino-N,N-dihydropyrazolone and at least one coupler, mixed with a second composition chosen from “fundamental” and/or “golden fundamental” and/or “golden” compositions.
    Type: Grant
    Filed: June 20, 2007
    Date of Patent: April 5, 2011
    Assignee: L'Oreal S.A.
    Inventors: François Cottard, Jean-Marc Ascione
  • Patent number: 7909889
    Abstract: The present invention provides a method of lightening and/or coloring human keratin fibers that employs: at least one substantially anhydrous or aqueous composition (A) comprising at least one fat free of carboxylic acid groups and at least one surfactant, at least one substantially anhydrous or aqueous composition (B) comprising at least one specific aminotrialkoxysilane or aminotrialkenyloxysilane compounds, and at least one aqueous composition (C) comprising at least one oxidizing agent. In addition, the present invention provides a three-compartment device appropriate for the implementation of this method.
    Type: Grant
    Filed: April 29, 2010
    Date of Patent: March 22, 2011
    Assignee: L'Oreal S.A.
    Inventors: Delphine Charrier, Marie-Pascale Audousset, Leila Hercouet
  • Patent number: 7905926
    Abstract: Disclosed are methods and kits for coloring the hair involving a color base composition comprising at least one primary dye intermediate, and a developer composition comprising an oxidizing agent chosen from persulfates, perborates, percarbonates, and mixtures thereof. Preferably, the color base composition and developer composition are substantially free of an oxidation catalyst.
    Type: Grant
    Filed: July 3, 2008
    Date of Patent: March 15, 2011
    Assignee: L'Oréal
    Inventors: Michael DeGeorge, Jeremy Puco, Delphine Allard, Gilles Genain
  • Patent number: 7905925
    Abstract: Disclosed herein is an aqueous dye composition for dyeing keratin fibers, for example, human keratin fibers such as the hair, comprising, in a suitable dyeing medium: (a) at least one oxidizing agent, (b) at least one water-insoluble oxygenated organic non-dyeing compound, present in an amount of at least 30% by weight relative to the total weight of the dye composition, and (c) at least one oxidation dye precursor and/or at least one direct dye. Also disclosed herein is a process for dyeing human keratin fibers, for example, the hair, comprising applying such a composition to the keratin fibers.
    Type: Grant
    Filed: August 24, 2006
    Date of Patent: March 15, 2011
    Assignee: L'Oreal S.A.
    Inventors: Sylvain Kravtchenko, Claude Dubief
  • Patent number: 7905927
    Abstract: The present disclosure provides a method of lightening and/or coloring human keratin fibers comprising applying to the keratin fibers * at least one first composition comprising at least one fat, at least one nonionic surfactant, at least one specific aminotrialkoxy silane or aminotrialkenyloxy silane compound, and applying * at least one second composition comprising at least one oxidizing agent. It also provides a multiple-compartment device in which at least one compartment comprises the above-mentioned at least one first composition and at least one other compartment comprises the at least one oxidizing composition.
    Type: Grant
    Filed: April 29, 2010
    Date of Patent: March 15, 2011
    Assignee: L'Oreal, SA
    Inventor: Leïla Hercouet
  • Patent number: 7875084
    Abstract: The present disclosure relates to a dye composition for keratin fibers, including human keratin fibers such as the hair, comprising, in a medium suitable for dyeing: (A) at least one nonionic derivative of cellulose comprising at least one hydrophobic substituent containing from 8 to 30 carbon atoms; (B) at least one nonionic, nonhydrophobic polymer of the hydroxyalkylcellulose type; and (C) at least one oxidation dye. The present disclosure also relates to a process for dyeing keratin fibers using such a composition; and also to a device that uses this composition for dyeing keratinous fibers.
    Type: Grant
    Filed: November 10, 2008
    Date of Patent: January 25, 2011
    Assignee: L'Oreal S.A.
    Inventor: Marie-Pascale Audousset
  • Patent number: 7871445
    Abstract: The present disclosure relates to a dye composition for keratin fibers, such as keratin fibers, for example the hair, comprising, in a medium suitable for dyeing: at least one nonionic derivative of cellulose comprising at least one hydrophobic substituent containing from 8 to 30 carbon atoms; at least one oxidation base chosen from diaminodiazacyclopentene derivatives; and at least one oxidation coupler; and a process for dyeing keratin fibers using such a composition.
    Type: Grant
    Filed: November 10, 2008
    Date of Patent: January 18, 2011
    Assignee: L'Oreal S.A.
    Inventor: Marie-Pascale Audousset
  • Patent number: 7857864
    Abstract: Disclosed herein is a composition for the dyeing of keratin fibers, for example, human keratin fibers such as the hair, comprising at least one 3-amino pyrazolo-[1,5-a]-pyridine derivative or one of its addition salts and a method employing this derivative. The composition of the present disclosure makes it possible to obtain coloration in various shades that is powerful, chromatic, and aesthetic, with low selectivity and with good resistance to various aggressive factors to which the hair may be subjected, such as shampoos, the light, sweat and permanent shaping.
    Type: Grant
    Filed: October 9, 2009
    Date of Patent: December 28, 2010
    Assignee: L'Oreal S.A.
    Inventors: Aziz Fadli, Laurent Vidal, Stéphane Sabelle
  • Patent number: 7811336
    Abstract: The present disclosure relates to compositions for dyeing keratinous fibers, for example human keratinous fibers, such as hair, wherein the compositions comprise, in a medium appropriate for dyeing, at least one oxidation base, at least one coupler, at least one aminated silicone, and monoethanolamine, wherein the at least one aminated silicone has a weight-average molecular weight (Mw) of greater than or equal to 75,000 g/mol, and monoethanolamine is present in an amount ranging from 1 to 10% by weight relative to the total weight of the composition. The present disclosure also relates to methods of dyeing keratinous fibers using said compositions and devices comprising the compositions.
    Type: Grant
    Filed: May 7, 2008
    Date of Patent: October 12, 2010
    Assignee: L'Oreal S.A.
    Inventors: Marie-Pascale Audousset, Christine Rondeau
  • Patent number: 7776107
    Abstract: A new class of chemical entities chosen from aminoindolizines of formula (I), acid addition salts thereof, and solvates thereof: their use for dyeing keratin fibers, including human keratin fibers such as the hair; dyeing compositions comprising such chemical entities; and to kits containing compositions comprising those chemical entities.
    Type: Grant
    Filed: December 22, 2008
    Date of Patent: August 17, 2010
    Assignee: L'Oreal S.A.
    Inventors: Laurent Vidal, Eric Metais, Aziz Fadli, Alan Katritzky
  • Patent number: 7771491
    Abstract: Compositions for the oxidation dyeing of keratin fibers, for example of human keratin fibers such as the hair, containing, in a medium suitable for dyeing: a) at least one oxidation dye, b) at least one associative polymer chosen from non-ioninc, anionic, and amphoteric polymers, c) at least one nonionic cellulose-based compound not comprising a C8-C30 fatty chain, and d) at least one cationic polymer with a charge density of greater than 1 meq/g and not comprising a C8-C30 fatty chain.
    Type: Grant
    Filed: December 21, 2007
    Date of Patent: August 10, 2010
    Assignee: L'Oreal S.A.
    Inventors: Frédéric Simonet, Luc Nicolas-Morgantini, François Cottard, Christine Rondeau
  • Patent number: 7771492
    Abstract: Compositions for oxidation dyeing of keratin fibers, in particular human keratin fibers such as hair, comprising, in a dyeing medium, at least one oxidation dye, at least one thickening polymer comprising at least one fatty chain and at least one fatty alcohol chosen from monoglycerolated and polyglycerolated fatty alcohols. Processes comprising such oxidation dyeing compositions.
    Type: Grant
    Filed: February 23, 2009
    Date of Patent: August 10, 2010
    Assignee: L'Oreal S.A.
    Inventors: François Cottard, Christine Rondeau
  • Patent number: 7766977
    Abstract: The present disclosure relates to a composition for dyeing keratin fibers, for example, human keratin fibers such as the hair, comprising at least one first oxidation base chosen from 2,3-diamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one and the addition salts thereof, at least one second oxidation base chosen from para-phenylenediamines, at least one coupler chosen from meta-aminophenols and at least one oxidizing agent, the pH of the composition ranging from 5.5 to 7.5. The present disclosure makes it possible to obtain a coloration on keratin fibers with tints in red, coppery or mahogany tones that are sufficiently visible on natural or dyed hair and uniform from the roots to the ends.
    Type: Grant
    Filed: November 30, 2007
    Date of Patent: August 3, 2010
    Assignee: L'Oreal S.A.
    Inventors: François Cottard, Florence Laurent
  • Patent number: 7749285
    Abstract: A process for coloring and permanently shaping keratin fibers especially human hair comprising applying to the human hair: (a) an aqueous coloring composition based on at least one oxidative dye precursor and optionally at least one coupling substance but not comprising any direct dye is mixed with a composition comprising at least one oxidizing agent and applied onto hair and rinsed off from hair with water after processing 5 to 45 min at a temperature of 20 to 45° C.
    Type: Grant
    Filed: July 18, 2008
    Date of Patent: July 6, 2010
    Assignee: KPSS-KAO Professional Salon Services GmbH
    Inventors: Bernd Nöcker, Jonathan Wood, Kornelia Weiβbach, Horst Kubatz
  • Patent number: 7722682
    Abstract: Disclosed herein is a composition for the oxidation dyeing of keratin fibers, for example human keratin fibers, such as the hair, comprising, in a medium suitable for dyeing, a) at least one oxidation dye; b) at least one fatty alcohol; c) at least one associative polymer; and d) at least one compound chosen from fatty acid esters and metal oxides.
    Type: Grant
    Filed: March 7, 2008
    Date of Patent: May 25, 2010
    Assignee: L'Oreal S.A.
    Inventors: François Cottard, Christine Rondeau
  • Patent number: 7699897
    Abstract: The disclosure relates to compositions and methods of using the compositions to color hair. The composition contains at least one polyamine, at least one acid, at least one water-insoluble ingredient, at least one hair colorant, solvent and optionally at least one auxiliary ingredient. The methods for coloring involve contacting hair with the composition of the disclosure.
    Type: Grant
    Filed: September 14, 2007
    Date of Patent: April 20, 2010
    Assignee: L'Oreal
    Inventors: Nghi Van Nguyen, David W. Cannell, Sawa Hashimoto, Cynthia Espino
  • Patent number: 7695525
    Abstract: The present invention relates to compositions for the oxidative dyeing of keratin fibres, comprising a medium suitable for dyeing and a compound 2-(amino or substituted amino)-3,5-substituted phenol compounds according to the Formula (I), as defined herein.
    Type: Grant
    Filed: August 16, 2005
    Date of Patent: April 13, 2010
    Assignee: The Procter & Gamble Company
    Inventors: Philip David Bolton, Robert Wayne Glenn
  • Patent number: 7695526
    Abstract: A composition for the oxidation dyeing of keratin fibers, for example, human keratin fibers, such as hair, comprising, in a medium suitable for dyeing, a) at least one oxidation dye, b) at least one fatty alcohol, c) at least one associative polymer, and d) at least one C14-C30 alkyl sulphate; as well as the process for using this composition and multicompartment kits comprising the composition.
    Type: Grant
    Filed: October 11, 2007
    Date of Patent: April 13, 2010
    Assignee: L'Oreal S.A.
    Inventors: Luc Nicolas-Morgantini, Frédéric Simonet, Christine Rondeau, François Cottard
  • Patent number: 7691155
    Abstract: Disclosed herein is a composition for the oxidation dyeing of keratin fibers, for example of human keratin fibers, such as the hair, containing, in a medium that is suitable for dyeing, a) at least one oxidation dye, b) at least one associative polymer, and c) at least one aminosilicone, wherein the at least one aminosilicone/at least one associative polymer weight ratio is greater than or equal to 1.
    Type: Grant
    Filed: July 7, 2008
    Date of Patent: April 6, 2010
    Assignee: L'Oreal S.A.
    Inventors: François Cottard, Christine Rondeau
  • Patent number: 7678157
    Abstract: A subject-matter of the present invention is the use, in the coloring of keratinous fibers, of a specific anionic hydrotropic agent of formula: in which X represents CH or N, n represents an integer ranging from 0 to 12, R1 represents COOM or SO3M, R2 represents a hydroxyl or a C1-C4 alkyl, R3 represents hydrogen or a C1-C4 alkyl, R2 and R3 can together form a ring and M represents hydrogen or one or more inorganic cations providing the electrical neutrality of the compound of formula (I). The invention likewise relates to a dyeing composition comprising at least one dye and such an anionic hydrotrope and to coloring processes employing this dyeing composition.
    Type: Grant
    Filed: May 17, 2007
    Date of Patent: March 16, 2010
    Assignee: L'Oreal S.A.
    Inventors: Maxime De Boni, Alain LaGrange
  • Patent number: 7651537
    Abstract: The present disclosure relates to a composition for dyeing keratin fibers, comprising 2,3-diamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one as first oxidation base, 6-chloro-2-methyl-5-aminophenyl as first coupler and a substituted meta-aminophenol of given formula as second coupler, it being understood that the at least one first oxidation base and the at least one first coupler are present in a mole ratio of less than 1.5, the at least one first oxidation base and the at least one second coupler are present in a mole ratio of greater than 1, and the molar amount of the at least one first oxidation base is greater than or equal to 2.5×10?3 mol per 100 g of composition. One aspect of the present disclosure makes it possible to obtain a strong, very chromatic, aesthetic, sparingly selective and/or fast coloration of keratin fibers in coppery shades. Further, the present disclosure makes it possible to obtain a strong coloration at a neutral pH.
    Type: Grant
    Filed: June 20, 2007
    Date of Patent: January 26, 2010
    Assignee: L'Oreal S.A.
    Inventors: François Cottard, Patricia Desenne
  • Patent number: 7651536
    Abstract: Disclosed herein is a composition for dyeing keratin fibers, comprising at least one first oxidation base chosen from 2,3-diamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one and the addition salts thereof, at least one second coupler chosen from para-phenylenediamine, para-tolylenediamine, and the addition salts thereof, and at least one coupler chosen from substituted meta-aminophenols, wherein the first coupler/first oxidation base mole ratio is greater than 1, the first oxidation base/second oxidation base mole ratio ranges from 0.5 to 1.5, and the molar amount of the first oxidation base is greater than or equal to 2.5×10?3 mol per 100 g of composition. Also disclosed herein is a dyeing process comprising applying such a composition to the keratin fibers. The compositions of the present disclosure may make it possible to obtain a strong, aesthetic, sparingly selective, and/or fast coloration of keratin fibers in visible deep red shades.
    Type: Grant
    Filed: June 20, 2007
    Date of Patent: January 26, 2010
    Assignee: L'Oreal S.A.
    Inventors: François Cottard, Patricia Desenne
  • Patent number: 7651539
    Abstract: Disclosed herein are compositions for dyeing keratin fibers, for example human keratin fibers such as the hair, comprising 2,3-diamino-6,7-dihydro-1H,5H-pyrazolo[1,2 -a]pyrazol-1-one or an addition salt thereof, at least one oxidation base, at least one coupler, at least one surfactant chosen from oxyalkylenated or glycerolated fatty alcohols, anionic surfactants of sulfate or sulfonate type and amphoteric surfactants of betaine type, and at least one oxidizing agent, the pH of the composition ranging from 5.5 to 7.5. The compositions disclosed herein make it possible to obtain coloration on keratin fibers with tints in red, coppery or mahogany tones that are sufficiently visible on natural or dyed hair and/or uniform from the roots to the ends.
    Type: Grant
    Filed: November 30, 2007
    Date of Patent: January 26, 2010
    Assignee: L'Oreal S.A.
    Inventors: François Cottard, Florence Laurent, Delphine Allard
  • Patent number: 7645303
    Abstract: The subject of the invention is a composition for the oxidation dyeing of human keratinous fibers and in particular hair comprising, in a cosmetically acceptable medium based on water and at a basic pH, at least one oxidation dye and an alkalinizing agent consisting of sodium metasilicate and aqueous ammonia, and the dyeing method using this composition.
    Type: Grant
    Filed: April 11, 2003
    Date of Patent: January 12, 2010
    Assignee: L'Oreal S.A.
    Inventors: François Cottard, Christine Rondeau
  • Patent number: 7641702
    Abstract: o-Aminophenol derivatives of the general formula (I) or physiologically compatible, water-soluble salts thereof, in which X is oxygen, sulfur or N—R4; R1, R2, R3 may be identical or different and, independently of one another, are hydrogen, a halogen atom, a cyano group, a C1-C4-alkoxy group, a C1-C6-alkyl group, a C1-C4-alkyl thioether group, a mercapto group, a nitro group, a trifluoromethane group, a —C(O)H group, a —C(O)CH3 group, a —C(O)CF3 group, an —Si(CH3)3 group, a C1-C4-hydroxyalkyl group or an aminomethyl group; R4 is hydrogen, a C1-C6-alkyl group, a C1-C4-hydroxy-alkyl group, a phenyl group or an acetyl group; and colorants containing said compounds for keratin fibers.
    Type: Grant
    Filed: May 18, 2005
    Date of Patent: January 5, 2010
    Assignee: Wella AG
    Inventors: Laurent Chassot, Hans-Juergen Braun
  • Patent number: 7635394
    Abstract: Disclosed herein is a composition for the dyeing of keratin fibers, for example, human keratin fibers such as the hair, comprising at least one 3-amino pyrazolo-[1,5-a]-pyridine derivative or one of its addition salts and a method employing this derivative. The composition of the present disclosure makes it possible to obtain coloration in various shades that is powerful, chromatic, and aesthetic, with low selectivity and with good resistance to various aggressive factors to which the hair may be subjected, such as shampoos, the light, sweat and permanent shaping.
    Type: Grant
    Filed: November 9, 2006
    Date of Patent: December 22, 2009
    Assignee: L'Oreal S.A.
    Inventors: Aziz Fadli, Laurent Vidal, Stéphane Sabelle
  • Patent number: 7608116
    Abstract: The present disclosure relates to oxidation dye compositions comprising, in an aqueous medium suitable for dyeing, at least one oxidation dye, ammonia, and at least one mesomorphic phase present in an amount greater than or equal to 10% by weight, relative to the weight of the composition. The present disclosure also relates to the process for preparing the compositions, as well as ready-to-use compositions for oxidation dyeing of keratin fibers, and multi-compartment kits for oxidation dyeing of keratin fibers, wherein at least one compartment contains the dye composition. Another aspect of the present disclosure is an oxidizing composition comprising a mesomorphic phase.
    Type: Grant
    Filed: December 23, 2003
    Date of Patent: October 27, 2009
    Assignee: L'Oreal S.A.
    Inventors: Luc Nicolas-Morgantini, Jean-Marc Petit
  • Patent number: 7601180
    Abstract: The present invention relates to the use, for the dyeing with lightening effect of human keratin substances, and in particular of human keratin fibres such as the hair, of a composition comprising at least one fluorescent cyanine dye. The present invention allows human keratin substances to be both dyed and at the same time lightened without detriment to said substances. The fluorescent dyes employed in the context of the invention also have high tinctorial affinity for keratin substances and good properties of resistance towards external agents, and especially towards shampoos.
    Type: Grant
    Filed: January 11, 2007
    Date of Patent: October 13, 2009
    Assignee: L'Oreal S.A.
    Inventors: Andrew Greaves, Nicolas Daubresse
  • Patent number: 7597720
    Abstract: The present invention relates to oxidizing hair colorant compositions comprising selected oxidative hair dyes and diethylene-triamine-penta-(methylenephosphonic acid). The compositions provide improved hair color tonality, root to tip evenness and reduced wash fade over time.
    Type: Grant
    Filed: October 27, 2008
    Date of Patent: October 6, 2009
    Assignee: The Procter & Gamble Company
    Inventor: Jennifer Mary Marsh
  • Patent number: 7594936
    Abstract: This application relates to a dye composition for dyeing keratin fibers, for example human keratin fibers, such as hair, comprising, in an appropriate dyeing medium, at least one aldehyde precursor, at least one enzyme able to generate an aldehyde from the at least one aldehyde precursor and at least one heteroaromatic hydrazone. This application also concerns a method for dyeing keratin fibers using the dye composition, and a dye “kit” containing the dye composition.
    Type: Grant
    Filed: July 3, 2003
    Date of Patent: September 29, 2009
    Assignee: L'Oreal S.A.
    Inventors: Hervé Burgaud, Rui Pereira, Béatrice Belcour-Castro
  • Patent number: 7582121
    Abstract: Disclose herein is a composition for dyeing keratin fibers, for example, human keratin fibers such as the hair, comprising at least one oxidation base chosen from diamino-N,N-dihydropyrazolones and addition salts thereof, at least one coupler, and at least one heterocyclic direct dye. Also disclosed herein is a method for dyeing keratin fibers comprising applying a composition of the present disclosure to the keratin fibers. The compositions and methods of the present disclosure may make it possible to obtain fast coloration of keratin fibers that is resistant to light and/or to washing.
    Type: Grant
    Filed: May 31, 2006
    Date of Patent: September 1, 2009
    Assignee: L'Oreal S.A.
    Inventor: Leïla Hercouet
  • Patent number: 7578856
    Abstract: Disclosed herein are compositions for dyeing keratinous fibers comprising, in an appropriate dyeing medium, at least one aminopyrazolopyridine oxidation base chosen from those of formula (I), wherein it is understood that at least one of the groups R?1, and R?2 is chosen from cationic radicals; at least one coupler and at least one C4-C30 polyol. Dyeing methods and multi-compartment devices for use thereof.
    Type: Grant
    Filed: May 9, 2008
    Date of Patent: August 25, 2009
    Assignee: L'Oreal S.A.
    Inventor: Jean-Baptiste Saunier
  • Patent number: 7578855
    Abstract: The present disclosure relates to a composition for the dyeing of keratin fibers, such as the hair, comprising at least oneoxidation base chosen from cationic 3-amino pyrazolo-[1,5-a]-pyridine derivatives and addition salts thereof, and a method employing this composition. The present disclosure also relates to cationic 3-amino pyrazolo-[1,5-a]-pyridine derivatives and the addition salts thereof.
    Type: Grant
    Filed: November 9, 2006
    Date of Patent: August 25, 2009
    Assignee: L'Oréal S.A.
    Inventor: Aziz Fadli
  • Patent number: 7569079
    Abstract: The present disclosure relates to polycationic monochromophoric hydrazone compounds of following formula (I): wherein W1 is a heteroaromatic radical comprising 5 or 6 ring members, optionally condensed with an aromatic ring comprising 6 ring members, comprising a quaternized nitrogen atom and optionally another heteroatom which may or may not be identical to nitrogen; X, which may or may not be identical, is a nitrogen atom or a CR2 group; Z is a cationic group comprising at least one quaternized nitrogen atom. 1The present disclosure also relates to a composition for dyeing human keratin fibers comprising the polycationic compounds disclosed herein, and to a dyeing process using the composition of the present disclosure, and ever further to multicompartment device.
    Type: Grant
    Filed: April 14, 2008
    Date of Patent: August 4, 2009
    Assignee: L'Oreal S.A.
    Inventors: Hervé David, Nadège Murguet
  • Patent number: 7559957
    Abstract: Disclosed herein is a composition for the oxidation dyeing of keratin fibers, for example, human keratin fibers such as the hair, comprising, in a medium that is suitable for dyeing, at least one oxidation dye and at least one polymer comprising a repetition of: (i) from 45 mol % to 60 mol % of at least one unit derived from a monomer of acrylamide type, (ii) at least one unit derived from a monomer of dialkyldiallylammonium halide type, and (iii) at least one unit derived from a monomer of vinylcarboxylic acid type, wherein the mole ratio of the amount of the at least one unit derived from a monomer of dialkyldiallylammonium halide type to the amount of the at least one unit derived from a monomer of vinylcarboxylic acid type is greater than or equal to 1. The composition disclosed herein makes it possible to prevent or reduce the phenomenon of static electricity at the surface of the hair, while at the same time maintaining good rheological and dyeing properties.
    Type: Grant
    Filed: August 10, 2007
    Date of Patent: July 14, 2009
    Assignee: L'Oreal S.A.
    Inventors: François Cottard, Gautier Deconinck
  • Patent number: 7559958
    Abstract: Disclosed herein is a composition for the oxidation dyeing of keratinous fibers, for example, human keratinous fibers, such as the hair, comprising, in a medium appropriate for dyeing, at least one oxidation dye and at least one polymer comprising the repetition of: (i) at least one unit derived from a monomer of acrylamide type, (ii) at least one unit derived from a monomer of dialkyldiallylammonium halide type, and (iii) at least 50 mol % of at least one unit derived from a monomer of vinylcarboxylic acid type. The composition disclosed is easily and rapidly removed during the rinsing stage while retaining good rheological and dyeing properties.
    Type: Grant
    Filed: August 10, 2007
    Date of Patent: July 14, 2009
    Assignee: L'Oreal S.A.
    Inventors: François Cottard, Gautier Deconinck
  • Patent number: RE41549
    Abstract: Dyes, containing N-benzyl-p-phenylenediamine derivatives of the general formula (I) or their physiologically compatible salts, for keratin fibers, and new N-benzyl-p-phenylenediamine derivatives.
    Type: Grant
    Filed: March 19, 2001
    Date of Patent: August 24, 2010
    Assignee: Wella AG
    Inventors: Laurent Chassot, Hans-Juergen Braun