With Aminophenol Dye Patents (Class 8/412)
  • Patent number: 7150765
    Abstract: A liquid dye composition, free of fatty acids and fatty acid salts, comprising at least one oxidation base and 2-methyl-1,3-propanediol; a ready-to-use composition comprising the liquid dye composition and at least one oxidizing agent; a process for dyeing human keratin fibers using the liquid dye composition; and a device comprising the liquid dye composition.
    Type: Grant
    Filed: July 12, 2004
    Date of Patent: December 19, 2006
    Assignee: L'Oreal S.A.
    Inventor: Patricia Desenne
  • Patent number: 7147672
    Abstract: A composition for the oxidation dyeing of keratin fibers, for example, human keratin fibers such as hair, comprising, in an appropriate dyeing medium, at least one oxidation dye, at least one fatty acid chosen from C10–C14 fatty acids and at least one cationic poly(vinyllactam) and dyeing methods and devices using the composition.
    Type: Grant
    Filed: October 21, 2003
    Date of Patent: December 12, 2006
    Assignee: L'Oreal S.A.
    Inventors: François Cottard, Christine Rondeau
  • Patent number: 7141079
    Abstract: The invention concerns an oxidation dyeing composition for keratinous fibers, and in particular human keratinous fibers such as hair comprising, in a medium suited for dyeing: as first coupling agent at least a 3,5-diaminopyridine derivative suitably selected; and as second coupling agent at least a meta-phenylenediamine, and/or one of its addition salts with an acid; and at least an oxidation base such as para-phenylenediamine and/or one of its addition salts with an acid. The invention also concerns the dyeing method using said composition.
    Type: Grant
    Filed: April 11, 2001
    Date of Patent: November 28, 2006
    Assignee: L′Oreal
    Inventor: Marie-Pascale Audousset
  • Patent number: 7132001
    Abstract: The object of the present patent application are 3-aminophenol derivatives of formula (I) or the physiologically compatible, water-soluble salts thereof and colorants based on a developer-coupler combination containing these compounds.
    Type: Grant
    Filed: January 8, 2003
    Date of Patent: November 7, 2006
    Assignee: Wella AG
    Inventors: Gisela Umbricht, Franco Jose Rosato, Hans-Juergen Braun
  • Patent number: 7128764
    Abstract: The object of the present patent application are 3-aminophenol derivatives of formula (I) or the physiologically tolerated, water-soluble salts thereof wherein R denotes a heterocyclic aromatic 5-membered ring of formula (Ia) and colorants based on a developer-coupler combination and containing these compounds.
    Type: Grant
    Filed: April 24, 2002
    Date of Patent: October 31, 2006
    Assignee: Wella AG
    Inventors: Cècile Pasquier, Patrick Wyss, Hans-Juergen Braun
  • Patent number: 7125428
    Abstract: 1,3-Dihydroxybenzene derivatives of general formula (I) or (Ia) or physiologically tolerated, water-soluble salts thereof wherein R?1 denotes a substituted pyridyl group, a pyrimidyl group, a group of formula (IIa) or (IIIa) and the dyeing agents for keratin fibers containing these compounds.
    Type: Grant
    Filed: January 28, 2002
    Date of Patent: October 24, 2006
    Assignee: Wella AG
    Inventors: Laurent Chassot, Hans-Juergen Braun
  • Patent number: 7122061
    Abstract: The present invention has for an object compounds of formula (I) and colorants containing these 4-aminobiphenyl-3-ol derivatives of general formula (I) for dyeing keratin fibers, particularly hair, wherein R1 and R2 independently of each other denote hydrogen, a halogen atom, a cyano group, a hydroxyl group, a C1–C4-alkoxy group, a C2–C4-hydroxyalkoxy group, a C1–C6-alkyl group, a nitro group, a trifluoromethyl group, a —C(O)H group, a —C(O)CH3 group, a —C(O)CF3 group, an —Si(CH3)3 group or a C1–6-hydroxyalkyl group or R1 and R2 together form an —O—CH2—O— bridge.
    Type: Grant
    Filed: May 13, 2003
    Date of Patent: October 17, 2006
    Assignee: Wella AG
    Inventors: Laurent Chassot, Hans-Juergen Braun
  • Patent number: 7101405
    Abstract: The invention concerns an oxidation dyeing composition for keratinous fibers, in particular human keratinous fibers, and more particularly hair, comprising, in a medium suitable for oxidation dyeing, at least an oxidation colouring agent, and furthermore at least a cationic associative polyurethane. The invention also concerns dyeing methods and devices using said composition.
    Type: Grant
    Filed: November 6, 2001
    Date of Patent: September 5, 2006
    Assignee: L'Oreal S.A.
    Inventors: Franç is Cottard, Roland De La Mettrie
  • Patent number: 7077871
    Abstract: Described is a method of reducing transcutaneous passage of an orthodiphenol oxidation dye by adding a catalytic system of Mn(II) or Zn(II) salt or oxide and at least one alkaline or alkaline earth hydrogenocarbonate to the orthodiphenol oxidation dye composition.
    Type: Grant
    Filed: April 9, 2003
    Date of Patent: July 18, 2006
    Assignee: L'Oreal
    Inventors: Frank Dreher, Francis Pruche
  • Patent number: 7077872
    Abstract: The object of the present patent application are agents for dyeing keratin fibers based on a developer-coupler combination and characterized in that they contain at least one 3-aminophenol derivative of formula (I) or a physiologically compatible, water-soluble salt thereof wherein R1 denotes a group of the formula ?or a group of the formula ?as well as novel 3-aminophenol derivatives.
    Type: Grant
    Filed: April 24, 2002
    Date of Patent: July 18, 2006
    Assignee: Wella AG
    Inventors: Cècile Pasquier, Patrick Wyss, Hans-Juergen Braun
  • Patent number: 7074244
    Abstract: A sequential method for dyeing hair which comprises: contacting the hair with a substantially inactive dye precursor mixture containing at least one primary intermediate and an optional coupler for a period of time, followed by applying a means for aligning the hair and distributing the oxidative dye precursors uniformly, followed by contacting the hair with a developer mixture capable of oxidizing the hair dye precursors to react and form hair color molecules.
    Type: Grant
    Filed: July 3, 2003
    Date of Patent: July 11, 2006
    Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.
    Inventors: Alexander C. Chan, Padmaja Prem, Katherine Jacobs-Dube, John Brian Bartolone
  • Patent number: 7074243
    Abstract: N-benzyl-m-phenylenediamine derivatives of general formula (I) or the physiologically tolerated, water-soluble salts thereof and dyeing agents for keratin fibers containing these compounds.
    Type: Grant
    Filed: February 2, 2002
    Date of Patent: July 11, 2006
    Assignee: WELLA AG
    Inventors: Laurent Chassot, Hans-Juergen Braun
  • Patent number: 7070628
    Abstract: Hair dyeing composition on the basis of an oxidation dyestuff precursor reacting with peroxide, comprising at least one developing and/or coupling substance selected from the group a) 3-chloro-p-aminophenol and b) 2-methyl-4-methoxy-5-aminophenol, 2-methyl-4-methoxy-5-hydroxyethyl amino-phenol and/or 2-methoxy-5-aminophenol, and c) Para-phenylenediamine, para-toluylenediamine, 2,6-dimethyl-para-phenylene diamine, 2-hydroxymethyl-para-phenylenediamine, 2-hydroxyethyl-para-phenylenediamine, 2-n-propyl-para-phenylenediamine, 2-isopropyl-para-phenylenediamine, N-(?-hydroxy-propyl)-para-phenylenediamine, N,N-bis(?-hydroxyethyl)-para-phenylenediamine, N-methoxyethyl-para-phenylenediamine and/or 5-chloro-2-hydroxyethyl-para-phenylenediamine or the water-soluble salts thereof
    Type: Grant
    Filed: June 19, 2003
    Date of Patent: July 4, 2006
    Assignee: KPSS-Kao Professional Salon Services GmbH
    Inventors: Heribert Lorenz, Klaus Kaffenberger
  • Patent number: 7070627
    Abstract: Hair dyeing composition on the basis of an oxidation dyestuff precursor reacting with peroxide, comprising at least one developing and/or coupling substance selected from the group a) 3-chloro-p-aminophenol and b) 2-Methyl-5-?-hydroxypropyl aminophenol, 2-methyl-5-methyl-aminophenol and/or 2-methyl-5-ethyl aminophenol and c) para-phenylenediamine, para-toluylenediamine, 2,6-dimethyl-para-phenylenediamine, 2-hydroxymethyl-para-phenylenediamine, 2-hydroxyethyl-para-phenylenediamine, 2-n-propyl-para-phenylenediamine, 2-isopropyl-para-phenylenediamine, N-(?-hydroxypropyl)-para-phenylenediamine, N,N-bis(?-hydroxyethyl)-para-phenylenediamine, N-methoxyethyl-para-phenylenediamine and/or 5-chloro-2-hydroxyethyl-para-phenylenediamine or the water-soluble salts thereof.
    Type: Grant
    Filed: June 19, 2003
    Date of Patent: July 4, 2006
    Assignee: KPSS-Kao Professional Salon Services GmbH
    Inventors: Heribert Lorenz, Klaus Kaffenberger
  • Patent number: 7070630
    Abstract: Primary intermediates for hair coloring compositions for oxidative dyeing of hair are compounds of the formula (1): wherein R1 and R2 are each independently selected from hydrogen atoms, a C1 to C5 alkyl or hydroxyalkyl group, or R1 and R2 together with the nitrogen atom to which they are attached form a 5 or 6 member cyclic ring optionally containing one or more additional atoms selected from O, N or S atoms, and n is equal to 1 or 2, with the proviso that when n is equal to 2 only one of R1 and R2 may be hydrogen.
    Type: Grant
    Filed: May 3, 2004
    Date of Patent: July 4, 2006
    Assignee: The Procter & Gamble Company
    Inventors: Mu-Ill Lim, Yuh-Guo Pan
  • Patent number: 7066968
    Abstract: The present invention relates to a 2-step methods, and compositions for providing more vibrant, natural and long-lasting color to hair and at the same time reducing hair fiber damage associated with alternative current methods. In the first step the hair is contacted for a period of time with a dye precursor mixture containing specific oxidative hair dye precursors under conditions where these dyes are substantially inactive. Color is then developed in a second step by contacting the hair with a mixture of a peroxide compound and a persulfate salt. Surprisingly the 2-step method leads to considerable “lift” or lightening without negatively impacting the coloring ability of the oxidative dye. The invention also relates to kits providing the means to accomplish these steps.
    Type: Grant
    Filed: March 2, 2004
    Date of Patent: June 27, 2006
    Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.
    Inventors: Alexander C Chan, Stella Arcella, John Brian Bartolone, Allan Robert Burger
  • Patent number: 7060107
    Abstract: Compositions for oxidation dyeing keratin fibers, such as human keratin fibers like hair, comprising, in a dyeing medium, (1) at least one oxidation dye, and (2) a combination comprising at least one cyclohomopolymer of dialkyldiallylammonium and at least one other particular quaternary polyammonium. Processes comprising such oxidation dyeing compositions.
    Type: Grant
    Filed: January 2, 2001
    Date of Patent: June 13, 2006
    Assignee: L'Oreal S.A.
    Inventors: Cécile Bebot, Christine Rondeau, François Cottard, Francoise Boudy
  • Patent number: 7060111
    Abstract: A sequential method for dyeing hair which comprises: contacting the hair with a substantially inactive dye precursor mixture containing at least one primary intermediate and an optional coupler having at least 50% of the molecules comprising these precursors are in their non-anionic form, for a period of time, followed by contacting the hair with a developer mixture capable of oxidizing the hair dye precursors to react and form hair color molecules.
    Type: Grant
    Filed: July 3, 2003
    Date of Patent: June 13, 2006
    Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.
    Inventors: Alexander C. Chan, Padmaja Prem, John Brian Bartolone
  • Patent number: 7060112
    Abstract: The invention relates to a composition for oxidation dyeing of keratinous fibers, and in particular human keratinous fibers, such as hair, comprising, in a medium appropriate for dyeing, at least one oxidation base, 2-amino-4-N-(?-hydroxyethyl)aminoanisole as coupler, and at least an enzyme of the laccase type, as well as the dyeing method using this composition.
    Type: Grant
    Filed: April 19, 2004
    Date of Patent: June 13, 2006
    Assignee: L'Oreal
    Inventors: Gérard Lang, Jean Cotteret
  • Patent number: 7056354
    Abstract: The invention concerns compounds derived from diaminopyrazole of formula (I), wherein: Ar is a 5- or 6-membered heteroaromatic radical capable of being condensed with one or several heteroaromatic cycles each comprising 5 or 6 members, and their physiologically acceptable addition salts with and acid.
    Type: Grant
    Filed: July 9, 2002
    Date of Patent: June 6, 2006
    Assignee: L'Oreal
    Inventors: Thilo Fessmann, Eric Terranova
  • Patent number: 7018428
    Abstract: Disclosed herein is a process for the preparation of a dyeing composition intended for dyeing keratinous fibers comprising percolating pressurized steam through a suitable pulverulent compound, as well as a device for packaging such a compound and a dyeing process using such a dyeing composition.
    Type: Grant
    Filed: July 25, 2003
    Date of Patent: March 28, 2006
    Assignee: L'Oreal
    Inventors: Jean-François Grollier, Roland De La Mettrie, François Cottard
  • Patent number: 7014663
    Abstract: The invention concerns compounds derived from diaminopyrazole of formula (I), wherein: R1 is a linear or branched radical selected among C2, C3, C4 aminoalkyl radicals or C2, C3, C4 aminoalkenyl radicals, or one of the physiologically acceptable salts thereof. The invention also concerns compositions containing said compound for dyeing keratinous fibers and the method using said compositions.
    Type: Grant
    Filed: July 9, 2002
    Date of Patent: March 21, 2006
    Assignee: L'Oreal
    Inventors: Thilo Fessmann, Eric Terranova
  • Patent number: 7004981
    Abstract: A hair-coloring method comprises coloring hair having virgin hair portions and already-colored hair portions, wherein: (A) the virgin hair portions are colored with an oxidative hair-coloring agent (I) comprising an oxidative dye, ammonia and hydrogen peroxide and having an ammonia concentration of 0.2 to 3.0% by weight and a hydrogen peroxide concentration of 2.5 to 5.0% by weight, and (B) the already-colored hair portions are colored with an oxidative hair-coloring agent (II) comprising an oxidative dye, ammonia and hydrogen peroxide and having an ammonia concentration of 0.1 to 1.5% by weight and a hydrogen peroxide concentration of 0.01 to 2.0% by weight. Hair having virgin hair portions and already-colored hair portions can be colored in a uniform color tone over the whole hair.
    Type: Grant
    Filed: September 26, 2002
    Date of Patent: February 28, 2006
    Assignee: Arimino Co., Ltd.
    Inventors: Satoshi Yagioka, Shoji Machida, Hiroyasu Daigo
  • Patent number: 6997961
    Abstract: Dyeing agents for keratin fibers, containing N-heteroarylmethyl-m-phenylenediamine derivatives of general formula (I) or the salts thereof and new N-heteroarylmethyl-m-phenylenediamine derivatives.
    Type: Grant
    Filed: October 18, 2001
    Date of Patent: February 14, 2006
    Assignee: Wella AG
    Inventors: Laurent Chassot, Hans-Juergen Braun
  • Patent number: 6991660
    Abstract: Hair dyeing composition on the basis of an oxidation dyestuff precursor reacting with peroxide, comprising at least one developing and/or coupling substance selected from the group a) 3-chloro-p-aminophenol and/or 2-chloro-p-aminophenol, b) 2-methyl-5-aminophenol, 2-methyl-5-hydroxyethyl aminophenol, 2-methyl-5-?-hydroxypropyl aminophenol, 2-methyl-5-methyl aminophenol, 2-methyl-5-ethyl aminophenol, 2-methoxy-5-aminophenol, 2-methyl-4-methoxy-5-aminophenol and/or 2-methyl-4-methoxy-5-hydroxyethyl aminophenol and c) 1-methoxy-2,4-diaminobenzene, 1-?-hydroxyethyloxy-2,4-diaminobenzene, 1-(1,2-dihydroxypropyloxy)-2,4-diaminobenzene, 1-methoxy-2-amino-4-?-hydroxyethyl aminobenzene, 1,3-bis-(2,4-diaminophenoxy)-propane, 2,4-diamino-5-methyl-phenetol and/or 1-?-hydroxyethyloxy-5-methyl-2,4-diaminobenzene.
    Type: Grant
    Filed: August 18, 2003
    Date of Patent: January 31, 2006
    Assignee: KPSS-Kao Professional Salon Services GmbH
    Inventors: Heribert Lorenz, Klaus Kaffenberger, Bernd Noecker, Ruediger Wilz
  • Patent number: 6939382
    Abstract: The present, invention relates to novel 4,5-diaminopyrazole derivatives, to a composition for the oxidation dyeing of keratin fibers, and in particular of human keratin fibers, comprising, as oxidation base, at least one such derivative, and also to an oxidation dyeing process using this composition.
    Type: Grant
    Filed: January 6, 2003
    Date of Patent: September 6, 2005
    Assignee: L'Oreal S.A.
    Inventors: Thilo Fessmann, Eric Terranova
  • Patent number: 6908493
    Abstract: Couplers for hair coloring compositions for oxidative dyeing of hair are compounds of the formula (1): where R1 and R2 are each individually selected from a hydrogen atom, a C1 to C3 alkyl group, a C1 to C5 mono or dihydroxyalkyl group; phenyl or benzyl optionally substituted with an alkoxy group, or R1 and R2 together with the nitrogen atom to which they are attached form a piperazine, piperidine, imidazole, or morpholine ring.
    Type: Grant
    Filed: May 7, 2004
    Date of Patent: June 21, 2005
    Assignee: The Procter & Gamble Company
    Inventors: Mu-Ill Lim, Yuh-Guo Pan, James S. Anderson
  • Patent number: 6849766
    Abstract: 1,4-Diamino-2-alkenylbenzene derivatives of general formula (I) or physiologically tolerated water-soluble salts thereof as well as agents for oxidative dyeing of fibers, containing these compounds.
    Type: Grant
    Filed: September 10, 2001
    Date of Patent: February 1, 2005
    Assignee: Wella Aktiengesellschaft
    Inventors: Laurent Chassot, Hans-Juergen Braun
  • Patent number: 6840965
    Abstract: The object of the invention are p-aminophenol derivatives of general formula (I) or physiologically tolerated, water-soluble salts thereof and oxidative coloring preparations based on a developer-coupler combination containing at least one p-aminophenol derivative of formula (I).
    Type: Grant
    Filed: March 9, 2001
    Date of Patent: January 11, 2005
    Assignee: Wella Aktiengesellschaft
    Inventors: Laurent Chassot, Hans-Juergen Braun
  • Patent number: 6840966
    Abstract: The invention relates to a ready-to-use composition for the oxidation dyeing of keratin fibres, and in particular human keratin fibres such as the hair, comprising, in a medium which is suitable for dyeing, para-phenylenediamine as first oxidation base, at least one para-aminophenol as second oxidation base, 2-methyl-5-N-(?-hydroxyethyl)aminophenol as coupler and at least one enzyme of 2-electron oxidoreductase type in the presence of at least one donor for the said enzyme, and to the dyeing process using this composition.
    Type: Grant
    Filed: August 22, 2003
    Date of Patent: January 11, 2005
    Assignee: L'Oreal S.A.
    Inventors: Roland De La Mettrie, Jean Cotteret, Arnaud De Labbey, Mireille Maubru
  • Patent number: 6835212
    Abstract: The agent for dyeing keratin fibers contains one or more aryl and/or benzyl alcohols, one or more oxidizing enzymes, especially vanillyl oxidase, derivatives of vanillyl oxidase or galactose oxidase, and a nucleophilic compound that forms a dye for dyeing keratin fibers in the presence of the alcohols and enzymes. A method for dyeing keratin fibers with this agent is also disclosed. Two-component kits for performing the method of dyeing keratin fibers include a first compenent (A) and a second component (B) separate from the first component. The first component (A) includes the nucleophilic compound, the alcohol and optionally the oxidizing enzyme. The second component (B) includes the oxidizing enzyme when it is not included in the first component or more alcohol.
    Type: Grant
    Filed: July 18, 2002
    Date of Patent: December 28, 2004
    Assignee: Wella Aktiengesellschaft
    Inventors: David Rozzell, Guido Sauter, Hans-Juergen Braun
  • Patent number: 6821302
    Abstract: Compositions and methods for achieving permanent hair color change which composition includes a mixture of: a) a composition A which comprises: i) at least one oxidation hair dye precursor; ii) a metal cyanate selected from the group consisting of KOCN, NaOCN, LiOCN, Ca(OCN)2, Mg(OCN)2, Zn(OCN)2 and mixtures thereof which comprises a cyanate ion at about 0.1 to about 2.5%; and iii) an alkalizing agent; b) and a composition B which comprises: i) an oxidizing compound; wherein the mixture of composition A and composition B has a pH of about 7 to about 11; are described.
    Type: Grant
    Filed: November 1, 2002
    Date of Patent: November 23, 2004
    Assignee: Unilever Home & Personal Care USA, Division of Conopco, Inc.
    Inventors: Van Au, Stephen Alan Madison, John Brian Bartolone
  • Patent number: 6818022
    Abstract: A hair dyeing composition which comprises the following ingredients: (a) of an alkalizing amine; (b) a multicomponent protective agent comprising a phosphated fatty alcohol, a hydrophobic agent and an alkyl ester of glucose; (c) a non-ionic surfactant; (d) a dye; and (e) water.
    Type: Grant
    Filed: June 10, 2002
    Date of Patent: November 16, 2004
    Assignee: Combe Inc.
    Inventor: Jack Massoni
  • Patent number: 6811573
    Abstract: Colorants for keratin fibers containing 1,3-diamino-4-heteroarylbenzene derivatives of general formula (I) or the physiologically tolerated salts thereof as well as novel 1,3-diamino-4-heteroarylbenzene derivatives.
    Type: Grant
    Filed: June 26, 2002
    Date of Patent: November 2, 2004
    Assignee: Wella Aktiengesellschaft
    Inventors: Laurent Chassot, Hans-Juergen Braun
  • Patent number: 6800098
    Abstract: The invention relates to an oxidation dye composition for keratinic fibers, especially for human keratinic fibers such as hair, containing at least one oxidation dye and a thickening polymer with a plastic ether skeleton, in a medium which is suitable for dyeing. The invention also relates to the dyeing method and devices for using the inventive composition.
    Type: Grant
    Filed: August 7, 2002
    Date of Patent: October 5, 2004
    Assignee: L'Oreal, S.A.
    Inventors: Delphine Allard, Frédéric Legrand
  • Patent number: 6776802
    Abstract: Couplers for hair coloring compositions for oxidative dyeing of hair are compounds of formula (1): wherein X is selected from halogen; R3 is selected from the group consisting of C1 to C2 alkyl and hydroxyethyl; and R, R1 and R2 are each independently selected from C1 to C22 alkyl or C1 to C22 mono or dialkyl groups, or two of R, R1 and R2 together with the the nitrogen atom to which they are attached form a C3 to C6 cycloaliphatic or a C3 to C14 aromatic group, the cycloaliphatic or aromatic group optionally containing in their rings one or more hetero atoms selected from O, S and N atoms.
    Type: Grant
    Filed: November 16, 2001
    Date of Patent: August 17, 2004
    Assignee: The Procter & Gamble Company
    Inventors: Mu-Ill Lim, Yuh-Guo Pan
  • Patent number: 6770103
    Abstract: A method for permanently dyeing hair is provided which includes subjecting the hair to a number of treatments, having a set time interval between each two consecutive such treatments, and wherein each treatment comprises contacting the hair for a period from about 5 seconds to about 3 minutes with a recently made mixture of an alkaline and an acidic composition, followed by a rinsing step. A shampoo or conditioner base is present in the alkaline and acidic compositions.
    Type: Grant
    Filed: March 5, 2002
    Date of Patent: August 3, 2004
    Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.
    Inventors: Jitendra Patel, Gerald Patrick Newell, Margie Fowler
  • Patent number: 6758867
    Abstract: A method for permanently dyeing hair which comprises subjecting said hair to a number of treatments, having a set time interval between each two consecutive such treatments, wherein each treatment comprises steps a.) and b.) below: a.) contacting said hair, for a period of about 5 seconds to about 5 minutes with a recently made mixture of: part ai: oxidative dye intermediates in a shampoo base at alkaline pH and wherein part ai optionally has about 0.01 to about 5.0% of a conditioning agent; and part ai optionally has about 0.01 to about 10.0% of a structurant; part aii: an oxidative compound in a shampoo base at acidic pH and wherein part ai optionally has about 0.01 to about 5.0% of a conditioning agent; and part ai optionally has about 0.01 to about 10.0% of a structurant; with the proviso that at least one of part ai and part aii has about 0.01 to about 5.0% of a conditioning agent; and part aii optionally has about 0.01 to about 10.0% of a structurant; b.
    Type: Grant
    Filed: December 28, 2001
    Date of Patent: July 6, 2004
    Assignee: Unilever Home & Personal Care USA, Division of Conopco, Inc.
    Inventors: Jitendra Patel, Gerald Patrick Newell, Elizabeth Kim, Fe P Pascual, Margie Fowler
  • Patent number: 6758866
    Abstract: Hair coloring compositions which comprise: (A) non-nitrogenous chelating agents from the group consisting of polyphosphate; phosphonates; hydroxycarboxylates; polyacrylates; zeolite; and mixtures thereof; (B) an oxidative dye primary intermediate; and (C) an oxidative dye coupler; (D) and water  are described. The present invention also relates to a method for coloring hair which comprises contacting said hair with a hair coloring composition as described above.
    Type: Grant
    Filed: December 21, 2001
    Date of Patent: July 6, 2004
    Assignee: Unilever Home & Personal Care USA, Division of Conopco, Inc.
    Inventors: Jiang Yang, John Brian Bartolone, Gabriela Wis-Surel, Alexander C Chan
  • Patent number: 6752839
    Abstract: Compositions for oxidation dyeing of keratin fibers, and in particular of human keratin fibers such as the hair, comprising, in a medium which is suitable for dyeing, at least one heterocyclic oxidation base chosen from pyrazoles, certain pyrimidines, pyrazolopyrimidines and the acid addition salts thereof, and at least one coupler chosen from 2-substituted 5-aminoalkylphenol derivatives and the acid addition salts thereof, as well as dyeing processes using these compositions.
    Type: Grant
    Filed: October 20, 2000
    Date of Patent: June 22, 2004
    Assignee: L'Oreal
    Inventors: Florent Pastore, Alain Lagrange
  • Patent number: 6743263
    Abstract: The present invention relates to a composition for coloring keratinaceous fibers and a method of using the same. The composition of the present invention contains (a) at least one pyrimidine derivative and (b) at least one compound selected from an m-phenylene derivative, an m-aminophenol derivative, a pyridine derivative, a resorcinol derivative, a methylenedioxybenzene derivative, or 3,4-diaminobenzoic acid or combinations thereof. The method of the present invention includes applying the coloring composition to keratin-containing fibers and subsequently rinsing the coloring composition from the fibers.
    Type: Grant
    Filed: October 31, 2001
    Date of Patent: June 1, 2004
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Horst Hoeffkes, Doris Oberkobusch, David Rose, Melanie Hitz
  • Patent number: 6743264
    Abstract: A method for treating hair which comprises: first contacting said hair with a substantially inactive mixture of oxidative hair dye precursors; and allowing said mixture to remain in said hair for a period of about 30 seconds to about 60 minutes; followed by contacting said hair with a developer to achieve long lasting hair color change, is described.
    Type: Grant
    Filed: February 14, 2002
    Date of Patent: June 1, 2004
    Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.
    Inventors: Padmaja Sarojini, John Brian Bartolone, Alexander C. Chan
  • Patent number: 6743265
    Abstract: A method for permanently dyeing hair which comprises subjecting said hair to a number of treatments, having a set time interval between each two consecutive such treatments, wherein each treatment comprises steps a.) and b.) below: a.) contacting said hair, for a period of about 5 seconds to about 5 minutes with a recently made mixture of: part ai: dye intermediates in water with a gelling agent at alkaline pH part aii an oxidizing compound such as hydrogen peroxide in water at acidic pH; b.) rinsing said mixture from said hair with water; and wherein said number of treatments is between about 2 to about 30; and wherein said set time interval between each two consecutive treatments is between about 8 hours and 30 days.
    Type: Grant
    Filed: March 13, 2002
    Date of Patent: June 1, 2004
    Assignee: Unilever Home & Personal Care USA division of Conopco, Inc.
    Inventors: Jitendra Patel, Frank Jones
  • Patent number: 6740127
    Abstract: The preparation for dyeing keratin fibers contains, in a cosmetic carrier, a combination of at least one 4,5-diaminopyrazole derivative of formula (I), or a physiologically compatible salt thereof. in which R is an alkyl group, a monohydroxyalkyl group, a polyhydroxyalkyl group, a monoaminoalkyl group, a polyaminoalkyl group, an unsubstituted benzyl group or a substituted benzyl group substituted with a halogen, an alkyl group or an alkoxy group; and at least one phenylurea derivative of formula (II), or a physiologically compatible salt thereof, in which R1 represents a hydroxyl or alkoxy group and R2 represents a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, a hydroxyalkyl group or polyhydroxyalkyl group, each with up to 6 carbon atoms. A method of hair dyeing with this preparation is described.
    Type: Grant
    Filed: November 16, 2001
    Date of Patent: May 25, 2004
    Assignee: Wella Aktiengellschaft
    Inventors: Gabriele Friess, Iris Bahnmueller
  • Patent number: 6736861
    Abstract: A method for permanently dyeing hair which comprises subjecting said hair to a number of treatments, having a set time interval between each two consecutive such treatments, wherein each treatment comprises steps a.) and b.) below: a.) contacting said hair, for a period of about 5 seconds to about 5 minutes with a recently made mixture of: i.) an alkaline composition comprising a dye intermediate in a shampoo base or in a conditioner base; and ii.) an acidic composition comprising an oxidating compound in a shampoo base or in a conditioner base; b.) rinsing said mixture from said hair with water; with the proviso that when a conditioner base is present in a.) i.) above, an independently selected conditioner base is also present in a.) ii.) above; and when a shampoo base is present in a.) i.) above, an independently selected shampoo base is also present in a.) ii.
    Type: Grant
    Filed: July 17, 2002
    Date of Patent: May 18, 2004
    Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.
    Inventors: Jitendra Patel, Gerald Patrick Newell
  • Patent number: 6736862
    Abstract: A composition and method for using the composition for dyeing keratin fibers. The composition consists of indole/indoline hybrid dyes and hybrid dye precursors. More particularly, the indole/indoline hybrid dyes and hybrid dye precursors correspond to formula (I): X—S—Y  (I) where X is a group derived from an indole or indoline derivative as a melanin precursor, Y is a group derived from an oxidation dye precursor of the secondary or primary intermediate type or an indole or indoline derivative as a melanin precursor; and S is a structural element which is common constituent of the groups X and Y, a direct bond or at least one spacer group. The composition may also be used to color human skin.
    Type: Grant
    Filed: July 9, 2003
    Date of Patent: May 18, 2004
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Frank Naumann, Detlef Hollenberg, Horst Hoeffkes, David Rose
  • Patent number: 6736860
    Abstract: A method for permanently dyeing hair which comprises subjecting said hair to a number of treatments, having a set time interval between each two consecutive such treatments, wherein each treatment comprises steps a.) and b.) below: a.) contacting said hair, for a period of about 5 seconds to about 5 minutes with a recently made mixture of: part ai: dye intermediates in water and fatty alcohol at alkaline pH, part aii: an oxidizing compound such as hydrogen peroxide in water at acidic pH b.) rinsing said mixture from said hair with water; and wherein said number of treatments is between about 2 to about 30; and wherein said set time interval between each two consecutive treatments is between about 8 hours and 30 days.
    Type: Grant
    Filed: March 12, 2002
    Date of Patent: May 18, 2004
    Assignee: Unilever Home & Personal Care USA division of Conopco, Inc.
    Inventors: Jitendra Patel, Gerald Patrick Newell, Margie Fowler, Elizabeth Kim, Fe P Pascual
  • Patent number: 6726729
    Abstract: A method for permanently dyeing hair which comprises subjecting said hair to a number of treatments, having a set time interval between each two consecutive such treatments, wherein each treatment comprises steps a.) and b.) below: a.) contacting said hair, for a period of about 5 seconds to about 5 minutes with a recently made mixture of: part ai: oxidative dye intermediates in a shampoo base at alkaline pH and wherein part ai optionally has about 0.01 to about 5.0% of a conditioning agent; part aii: an oxidative compound in a shampoo base at acidic pH and wherein part ai optionally has about 0.01 to about 5.0% of a conditioning agent; with the proviso that at least one of part ai and part aii has about 0.01 to about 5.0% of a conditioning agent; b.) rinsing said mixture from said hair with water; and wherein said number of treatments is between about 2 to about 30; and wherein said set time interval between each two consecutive treatments is between about 8 hours and 30 days.
    Type: Grant
    Filed: December 28, 2001
    Date of Patent: April 27, 2004
    Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.
    Inventors: Jitendra Patel, Gerald Patrick Newell, Elizabeth Kim, Fe P Pascual, Margie Fowler
  • Patent number: 6723136
    Abstract: A composition for coloring keratin fibers comprises, a physiologically acceptable medium and an efficacious quantity of at least one coloring material precursor selected from the compounds containing at least one aromatic ring having at least two hydroxyl groups borne by two adjacent carbon atoms of the aromatic ring, an efficacious quantity of at least one oxidation base of the para or ortho type selected from the aromatic amines, and an efficacious quantity of a catalytic system comprising a first constituent selected from the group consisting of salts and oxides of Mn(II) and/or Zn(II) and their mixtures, and a second constituent selected from the group consisting of alkali hydrogen carbonates, alkaline earth hydrogen carbonates and their mixtures. Keratin fibers may be colored by the application of this composition thereto.
    Type: Grant
    Filed: December 4, 2001
    Date of Patent: April 20, 2004
    Assignee: L'Oreal
    Inventor: Francis Pruche
  • Patent number: 6709468
    Abstract: A method for permanently dyeing hair which comprises subjecting said hair to a number of treatments, having a set time interval between each two consecutive such treatments, wherein each treatment comprises steps a.) and b.) below: a.) contacting said hair, for a period of about 5 seconds to about 5 minutes with a recently made mixture of: i) part ai dye intermediates in water at alkaline pH with quaternary ammonium compounds; ii) part aii an oxidizing compound such as hydrogen peroxide in water at acidic pH; b.) rinsing said mixture from said hair with water; and wherein said number of treatments is between about 2 to about 30; and wherein said set time interval between each two consecutive treatments is between about 8 hours and 30 days.
    Type: Grant
    Filed: March 7, 2002
    Date of Patent: March 23, 2004
    Assignee: Unilever Home & Personal Care USA
    Inventors: Jitendra Patel, Gerald Patrick Newell, Elizabeth Kim, Fe P Pascual, Margie Fowler