Basic Dye, Including Diphenylmethane, Triphenylmethane, Xanthene, Fluorene, Methine, Acridine, Oxazine, Phenazine, Flavylium, Naphthoperinone, Quinophthalone, Quaternary Ammonium Group, Etc., Containing Patents (Class 8/426)
  • Patent number: 11344489
    Abstract: A composition for dyeing keratin fibres comprising a. at least one azomethine compound selected from compounds (3) and (4) and b. water. The composition may be used in a process for dyeing keratin fibres or, with simultaneous or sequential application of a composition comprising one or more oxidising agents, in a process for lightening keratin fibres.
    Type: Grant
    Filed: November 21, 2019
    Date of Patent: May 31, 2022
    Assignee: BASF SE
    Inventors: Frank Bachmann, Beate Froehling, Christian Cremer, Marie-Pascale Perritaz, Volker Wendel
  • Patent number: 11273110
    Abstract: A dye for hair coloration that has a long shelf life and is excellent in heat resistance, and a method for producing the dye for hair coloration, are provided. A dye for hair coloration represented by the following general formula (1), the dye for hair coloration having a proportion of a polyatomic anion (An) or impurities derived from An of 1% by mass or less: wherein in the formula (1), D represents a cationic moiety of the dye for hair coloration; An represents a polyatomic anion; and a and b each independently represent a value of 0 to 1.
    Type: Grant
    Filed: February 25, 2021
    Date of Patent: March 15, 2022
    Assignee: HODOGAYA CHEMICAL CO., LTD.
    Inventors: Keigo Naito, Tetsuya Yoshida
  • Patent number: 10888510
    Abstract: The present invention relates to a process for dyeing keratin fibres, in particular human keratin fibres such as the hair, using one or more particular 2- or 4-azopyridinium dyes and one or more fluorescent dyes. The present invention also relates to a cosmetic composition comprising the dyes defined above, and also to a multi-compartment device containing said dyes. The present invention also relates to the use of said dyes for dyeing light keratin fibres, especially human keratin fibres such as the hair, in chestnut-brown, dark chestnut-brown, brown, brown with a glint, or even black, without using an additional dye other than those defined above.
    Type: Grant
    Filed: December 20, 2017
    Date of Patent: January 12, 2021
    Assignee: L'Oreal
    Inventors: Christian Blaise, Hervé David
  • Patent number: 10494527
    Abstract: The invention relates to cationic direct dyes of the formula I (1), wherein m and n are independently from each other 0 or 1, D is an aromatic or a cationic heteroaromatic group, which are further specified, K is an aromatic or heteroaromatic group, E1 and E2 are independently from each other ?CH— or ?N—, An is an anion and a is a number from 1 to 6 and R1 and R2 are independently from each other and further specified. The compounds show washfastness at hair-dying.
    Type: Grant
    Filed: March 18, 2016
    Date of Patent: December 3, 2019
    Assignee: BASF SE
    Inventors: Frank Bachmann, Christian Cremer, Beate Froehling, Bryan Patrick Murphy, Guiru Zhang, Peter Marte Torgerson
  • Patent number: 9790453
    Abstract: The present invention relates to polymeric shading dye and their use in laundry applications. The polymers are alkoxylated polyethylene imines and the dyes are reactive dyes.
    Type: Grant
    Filed: February 23, 2012
    Date of Patent: October 17, 2017
    Assignee: Conopco, Inc.
    Inventors: Stephen Norman Batchelor, Sheng Meng, Qingsheng Tao, Jinfang Wang
  • Patent number: 9302126
    Abstract: A polymer with good compatibility comprising one or more non-ionic water soluble monomers, such as poly(ethylene glycol)(meth)acrylate (PEGMA), is provided that is suitable for use in aerosol hair styling formulations which have improved clarity. There is also provided a hair styling composition comprising (a) one or more fully soluble polymer, and (b) a solvent mixture, and optional other ingredients.
    Type: Grant
    Filed: July 15, 2011
    Date of Patent: April 5, 2016
    Inventors: Wei Gao, Linus Linder, Miao Wang, Mark Westmeyer, Fanwen Zeng
  • Publication number: 20150101132
    Abstract: The invention relates to the dyeing of human keratin fibres, especially the hair, using cationic direct dyes bearing a particular sulf(on)ate, carboxylate, or phosph(on)ate counterion of formula (I) in which formula (I) Col(?)m, X?, m and n are as defined in the description. The invention relates to a dye composition comprising a cationic dye of formula (I), and to a process for dyeing keratin fibres such as the hair, using the said composition. Similarly, the invention relates to novel cationic compounds of formula (I) and to the uses thereof for dyeing keratin fibres. This composition makes it possible to obtain chromatic, powerful and particularly fast coloration on keratin fibres and particularly lightening coloration via an optical effect on dark hair.
    Type: Application
    Filed: May 24, 2013
    Publication date: April 16, 2015
    Inventors: Herve David, Annabelle Eudeline-Ly
  • Patent number: 8992633
    Abstract: Disclosed are compounds of formula (1) or formula (2). The compounds are useful for the dyeing of organic materials, such as keratin fibers, wool, leather, silk, cellulose or polyamides, especially keratin-containing fibers, cotton or nylon, and preferably hair, more preferably human hair. (1) (2).
    Type: Grant
    Filed: May 2, 2012
    Date of Patent: March 31, 2015
    Assignee: BASF SE
    Inventors: Sophie Marquais-Bienewald, Christian Cremer, Beate Frohling
  • Publication number: 20150027483
    Abstract: The present invention relates to azomethine-type direct dyes with a tri-aromatic unit having the following formula (I): and their use for colouring keratin fibres, particularly human keratin fibres such as the hair. The invention also relates to a composition for dyeing keratin fibres comprising, in a suitable medium for dyeing, such direct dyes. Another subject of the present invention is a method for dyeing keratin fibres using said dyeing composition. Finally the present invention also relates to precursors for these direct dyes.
    Type: Application
    Filed: December 13, 2012
    Publication date: January 29, 2015
    Applicant: L'OREAL
    Inventors: Stephane Sabelle, Madeline Leduc
  • Publication number: 20140352081
    Abstract: The present invention relates to a para-aminophenol compound of formula (I) the addition salts thereof with an acid and the solvates thereof, dye composition comprising the latter and a dyeing process.
    Type: Application
    Filed: September 13, 2012
    Publication date: December 4, 2014
    Applicant: L'OREAL
    Inventor: Aziz Fadli
  • Patent number: 8888866
    Abstract: Dyeing process using a natural dye on keratin fibers that have undergone permanent reshaping The present invention relates to a process for dyeing keratin fibers, in particular human keratin fibers such as the hair, in which: a) an aqueous alkaline composition comprising one or more alkaline agents in an amount such that the pH of the composition is greater than at least 10 is applied to the said fibers, or a reducing composition comprising one or more reducing agents and then an oxidizing composition are applied to the said fibers, b) the said fibers are optionally rinsed, c) optionally, the treatment is neutralized, and the fibers are washed with shampoo and rinsed, d) optionally, the fibers are dried or left to dry, e) a dye composition comprising, in a cosmetically acceptable medium, one or more natural dyes is applied to the said fibers, f) optionally, the fibers are washed and rinsed, g) the fibers are dried or left to dry.
    Type: Grant
    Filed: July 20, 2012
    Date of Patent: November 18, 2014
    Assignee: L'Oreal
    Inventor: Boris Lalleman
  • Patent number: 8840684
    Abstract: The invention relates to a process for dyeing and/or lightening keratin fibers such as the hair, using i) at least one cationic direct dye bearing a disulfide, thiol or protected thiol function especially of formula (I) as defined in the description and ii) water vapor. The invention also relates to the use i) of at least one cationic direct dye bearing a disulfide, thiol or protected thiol function combined with ii) water vapor, for dyeing and lightening keratin fibers, and to the use of water vapor for grafting onto keratin fibers dyes bearing a disulfide, thiol or protected thiol function. The process used and the use of thiol, protected thiol or disulfide dyes combined with water vapor makes it possible especially to obtain a long-lasting coloration on keratin fibers without the use of a reducing agent and without odor.
    Type: Grant
    Filed: December 5, 2011
    Date of Patent: September 23, 2014
    Assignee: l'oreal
    Inventor: Andrew Greaves
  • Patent number: 8834579
    Abstract: The present invention relates to an azo dye composition for hair dyeing that has an excellent performance as a dye for hair dyeing and proves negative in the Ames test, and also relates to a method for producing the composition. An object of the present invention is to develop a purification method for a dye composition for hair dyeing mainly containing an azo dye and proving negative in the Ames test, and to provide the dye composition for hair dyeing that is produced by applying the purification method and indicates negative in the Ames test. The dye composition for hair dyeing contains, as a main component, the azo dye having trimethylammonio, and the dye composition for hair dyeing is characterized in that the result of the Ames test is negative.
    Type: Grant
    Filed: March 12, 2013
    Date of Patent: September 16, 2014
    Assignee: Hodogaya Chemical Co., Ltd.
    Inventors: Masatoshi Isobe, Kenichiro Suzuki, Mitsuhiro Akiba
  • Patent number: 8808401
    Abstract: The present invention relates to a process for dyeing hair using at least one water-insoluble silicate, at least one compound of formula (I), in which Y represents a C1-C4 hydroxyalkyl group or a C1-C4 hydroxyalkyloxy radical, n denotes an integer ranging from 0 to 5, X, which may be identical or different, represents a C1-C4 alkyl radical or a halogen; and at least one hydroxylated aliphatic solvent comprising therein from 2 to 6 carbon atoms.
    Type: Grant
    Filed: December 19, 2011
    Date of Patent: August 19, 2014
    Assignee: L'Oreal
    Inventors: Boris Lalleman, Françoise Albouy
  • Patent number: 8801808
    Abstract: One subject of the present invention is a dye composition comprising benzyl alcohol, at least one C1-C4 monoalcohol and at least one anthraquinone direct dye of formula (I) or azomethine direct dye of formula (II). The composition of the invention makes it possible to obtain colorings that are intense and resistant.
    Type: Grant
    Filed: December 19, 2011
    Date of Patent: August 12, 2014
    Assignee: L'oreal
    Inventors: Boris Lalleman, Alain Lagrange
  • Patent number: 8771377
    Abstract: Hair care composition comprising a metal pyrithione, characterized by from 0.00001 to 0.005% wt. a purple or pink or red coloring component.
    Type: Grant
    Filed: February 7, 2012
    Date of Patent: July 8, 2014
    Assignee: Conopco, Inc.
    Inventors: Qunhua Cao, Amit Jayaswal, Qing Yang, Shuhong Yuan
  • Publication number: 20140157529
    Abstract: Disclosed are compounds of formula (1) or formula (2). The compounds are useful for the dyeing of organic materials, such as keratin fibers, wool, leather, silk, cellulose or polyamides, especially keratin-containing fibers, cotton or nylon, and preferably hair, more preferably human hair. (1) (2).
    Type: Application
    Filed: May 2, 2012
    Publication date: June 12, 2014
    Applicant: BASF SE
    Inventors: Sophie Marquais-Bienewald, Christian Cremer, Beate Frohling
  • Patent number: 8734530
    Abstract: An agent in foam form for coloring keratin-containing fibers, in particular human hair, under induction by atmospheric oxygen and methods for coloring keratin-containing fibers using such agent is provided. In an embodiment, the agent comprises, in a cosmetically acceptable carrier, at an alkaline pH of 8 to 10.5, (a) as a color-forming component in the form of a dye precursor of a nature-analogous dye an indole and/or indoline derivative, (b) an alkalizing agent, and (c) a propellant, the agent containing no additional oxidizing agent for the color-forming components.
    Type: Grant
    Filed: January 14, 2013
    Date of Patent: May 27, 2014
    Assignee: Henkel AG & Co. KGaA
    Inventors: Frank Janssen, Jurgen Schopgens, Sabine Babiel, Armin Wadle, Udo Erkens
  • Patent number: 8709102
    Abstract: Present invention relates to dyeing composition for keratin fibers especially human hair comprising cationic anthrachinone dye. The first object of the present invention is a dyeing composition for keratin fibers especially human hair resulting from mixing of two parts A and B wherein part A has an alkaline pH and comprises at least one cationic antraquinone dye and at least one additional dyestuff selected from direct and oxidative dyes and part B has an acidic pH and comprises at least one oxidizing agent.
    Type: Grant
    Filed: December 23, 2011
    Date of Patent: April 29, 2014
    Assignee: KAO Germany GmbH
    Inventors: Jonathan Wood, Anja Aechtner, Axel Blake
  • Publication number: 20140090186
    Abstract: The present invention is drawn to an agent and process for altering the color of keratin fibers wherein the agent comprises: (A) a color base composition containing a fatty substance having a viscosity greater than about 50 mm2/s at 40° C.; a rheology modifying polymer; and an alkalizing agent; a short alkyl chain hydroxy compound chosen from monoalcohols and polyols; a direct dye; optionally an oxidative dye precursor; and (B) optionally, an oxidizing composition comprising an oxidizing agent.
    Type: Application
    Filed: October 2, 2012
    Publication date: April 3, 2014
    Inventor: Mark Benn
  • Publication number: 20140090185
    Abstract: The present invention is drawn to an agent and process for altering the color of keratin fibers wherein the agent comprises: (A) a color base composition, containing from about 50% to about 80% by weight of a fatty substance comprising a fatty substance having a viscosity greater than about 50 mm2/s at 40° C.; and optionally, an additional fatty substance; a rheology modifying polymer; and an alkalizing agent; a short alkyl chain hydroxy compound chosen from monoalcohols and polyols; a direct dye; optionally an oxidative dye precursor; and (B) optionally, an oxidizing composition comprising an oxidizing agent.
    Type: Application
    Filed: October 2, 2012
    Publication date: April 3, 2014
    Inventor: Mark Benn
  • Patent number: 8685114
    Abstract: The invention relates to a dyeing composition comprising a fluorescent disulphide dye and to a method of dyeing keratin materials, with a lightening effect, that employs said composition. It likewise relates to new fluorescent disulphide dyes and to their uses in the lightening of keratin materials. This composition allows a particularly persistent lightening effect to be obtained.
    Type: Grant
    Filed: October 10, 2013
    Date of Patent: April 1, 2014
    Assignee: L'Oreal
    Inventors: Nicolas Daubresse, Andrew Greaves, Henri Samain
  • Publication number: 20130326826
    Abstract: The invention relates to a process for dyeing and/or lightening keratin fibres such as the hair, using i) at least one direct dye bearing a disulfide, thiol or protected-thiol function and ii) at least one sparingly or non-ethoxylated fatty alcohol, iii) at least one cationic surfactant, iv) at least one alkaline agent, and v) at least one reducing agent. The invention also relates to a composition comprising the ingredients i) to v), to the use of the combination of i), ii), iii), iv) and v) for the dyeing and/or lightening of keratin fibres, and to a multi-compartment kit comprising the ingredients i) to v). The dyeing process and the composition according to the invention especially afford a long-lasting coloration on keratin fibres, which is strong, chromatic and/or homogeneous, with or without the use of an oxidizing agent.
    Type: Application
    Filed: February 17, 2012
    Publication date: December 12, 2013
    Applicant: L'OREAL
    Inventor: Chrystel Pourille
  • Patent number: 8568491
    Abstract: The present invention relates to a cationic 4-aminoindole of general formula (I), addition salts thereof with an acid and solvates thereof: in which: R1 is a linear or branched, saturated C2-C20 alkyl radical, substituted and/or interrupted with a cationic radical. The present invention is also directed towards a process for synthesizing this cationic 4-aminoindole, to the compositions, the uses, the hair dyeing processes and the devices using this cationic 4-aminoindole.
    Type: Grant
    Filed: December 6, 2010
    Date of Patent: October 29, 2013
    Assignee: L'Oreal
    Inventor: Aziz Fadli
  • Patent number: 8562693
    Abstract: The invention relates to a dyeing composition comprising a fluorescent disulphide dye and to a method of dyeing keratin materials, with a lightening effect, that employs said composition. It likewise relates to new fluorescent disulphide dyes and to their uses in the lightening of keratin materials. This composition allows a particularly persistent lightening effect to be obtained.
    Type: Grant
    Filed: November 19, 2012
    Date of Patent: October 22, 2013
    Assignee: L'Oreal
    Inventors: Nicolas Daubresse, Andrew Greaves, Henri Samain
  • Publication number: 20130269121
    Abstract: Present invention relates to the use of a cationic anthrachinone dye for coloring keratin fibers, especially human hair, and compositions comprising the said dyestuffs. The object of the present invention is the use of dyestuff according to general structure wherein R1 is a group selected from CH3, CH2OH, C2H2OH, C4H9, C3H6OC2H5, C2H4OCH3 and C3H6OC2H4OCH3 for dyeing keratin fibers especially human hair.
    Type: Application
    Filed: December 23, 2011
    Publication date: October 17, 2013
    Applicant: KAO GERMANY GMBH
    Inventor: Dominic Pratt
  • Publication number: 20130263877
    Abstract: The present invention relates to a process for oxidative coloring keratin fibers especially human hair wherein dyeing composition comprises a cross linked copolymer. The objective of the present invention is a process for oxidative coloring hair wherein compositions A and B are mixed, composition A comprises at least one oxidative dye precursor and optionally at least one coupling agent and optionally at least one direct dye in a cosmetically acceptable medium and composition B comprises at least one oxidizing agent in a cosmetically acceptable medium, and applied onto hair and processed for 1 to 45 min at a temperature range of 20 to 45° C. and rinsed off from hair, wherein at least one of the two compositions A and B comprises a cross linked copolymer of vinylpyrrolidone, vinylimidazol, 3-methyl-1-vinylimidazolium and methacrylic acid.
    Type: Application
    Filed: December 23, 2011
    Publication date: October 10, 2013
    Applicant: KAO GERMANY GMBH
    Inventors: Jonathan Wood, Sabine Schäfer
  • Publication number: 20130255008
    Abstract: Present invention relates to dyeing composition for keratin fibers especially human hair comprising cationic anthrachinone dye. The first object of the present invention is a dyeing composition for keratin fibres especially human hair resulting from mixing of two parts A and B wherein part A has an alkaline pH and comprises at least one cationic anthraquinone dye and at least one additional dyestuff selected from direct and oxidative dyes and part B has an acidic pH and comprises at least one oxidizing agent.
    Type: Application
    Filed: December 23, 2011
    Publication date: October 3, 2013
    Applicant: KAO Germany GMBH
    Inventors: Jonathan Wood, Anja Aechtner, Axel Blake
  • Publication number: 20130255712
    Abstract: The present invention relates to processes for neutralizing relaxed hair. Still further, the present invention relates to neutralizer compositions for use on relaxed hair. Still further, the present invention relates to a system for neutralizing relaxed hair. Yet further, the invention relates to relaxed hair neutralized by the compositions and methods disclosed herein. The present invention also relates to compositions and methods to simultaneously neutralize and color relaxed hair.
    Type: Application
    Filed: August 14, 2012
    Publication date: October 3, 2013
    Inventors: Mario M. de la Guardia, JR., Tony Ray Adair
  • Patent number: 8523954
    Abstract: The present invention is drawn to a composition and method for dyeing keratinous substrates containing: (a) at least one polyamine compound comprising at least three amino groups; (b) at least one nonionic surfactant; (c) at least anionic silicone; (d) at least one dye chosen from oxidation dye precursors and direct dyes. The compositions of the present invention may optionally contain at least one thickening agent, at least one alkaline agent, at least one fatty substance, at least one salt, and at least one oxidizing agent.
    Type: Grant
    Filed: June 24, 2011
    Date of Patent: September 3, 2013
    Assignee: L'Oreal
    Inventors: Sawa Hashimoto, Nghi Van Nguyen, Siliu Tan
  • Publication number: 20130180542
    Abstract: Dicationic azo dyes of the formula (I), which are suitable for colouring keratin fibers, in particular human hair, and are in part themselves still not described in the prior art are provided. In colourations, particularly brilliant and luminous red shades are obtained. Agents for dyeing and optionally simultaneously lightening keratin fibers and methods for dyeing and optionally simultaneously lightening keratinic fibers also are provided.
    Type: Application
    Filed: March 4, 2013
    Publication date: July 18, 2013
    Applicant: HENKEL AG & CO. KGAA
    Inventor: Henkel AG & Co. KGaA
  • Publication number: 20130152314
    Abstract: The invention relates to a composition for dyeing keratin materials, and in particular human keratin fibres such as the hair, comprising at least one 2-pyrrolidone functionalized in the 4 position with an ester or amide radical, and at least one hydrophobic direct dye or a pigment; a dyeing process using this composition. Similarly, the invention relates to the use of the said pyrrolidone combined with a direct dye or a pigment for dyeing keratin materials, and especially to the use of the said pyrrolidone for improving the colour uptake onto the fibres of direct dyes that are sparingly soluble or insoluble in aqueous-alcoholic supports. The invention also relates to novel pyrrolidone derivatives. The present invention makes it possible in particular to obtain direct dyeing on keratin materials that is fast, resistant to washing, chromatic and powerful.
    Type: Application
    Filed: June 8, 2011
    Publication date: June 20, 2013
    Applicant: L'OREAL
    Inventors: Stéphane Sabelle, Madeleine Leduc, Christian Blaise
  • Publication number: 20130139328
    Abstract: The present invention relates to the reaction product of (A) a polymeric backbone with (B) A chromophore; and with (C) at least one sulfide containing compound. Very good dyeing results are obtained with this new technology.
    Type: Application
    Filed: August 15, 2011
    Publication date: June 6, 2013
    Applicant: BASF SE
    Inventors: Sophie Marquais-Bienewald, Christian Cremer, Beate Frohling
  • Publication number: 20130074276
    Abstract: The invention relates to a dyeing composition comprising a fluorescent disulphide dye and to a method of dyeing keratin materials, with a lightening effect, that employs said composition. It likewise relates to new fluorescent disulphide dyes and to their uses in the lightening of keratin materials. This composition allows a particularly persistent lightening effect to be obtained.
    Type: Application
    Filed: November 19, 2012
    Publication date: March 28, 2013
    Applicant: L'OREAL S.A.
    Inventor: L'OREAL S.A.
  • Patent number: 8328880
    Abstract: The invention relates to a dyeing composition comprising a fluorescent disulfide dye and to a method of dyeing keratin materials, with a lightening effect, that employs said composition. It likewise relates to new fluorescent disulfide dyes and to their uses in the lightening of keratin materials. The composition allows a particularly persistent lightening effect to be obtained.
    Type: Grant
    Filed: September 14, 2011
    Date of Patent: December 11, 2012
    Assignee: L'Oreal
    Inventors: Nicolas Daubresse, Andrew Greaves, Henri Samain
  • Patent number: 8268014
    Abstract: The invention relates to hair dyeing composition comprising (a) a dye of formula (1); (b) ant least one dye selected from the compounds of formulae (2); (3) and (4); wherein D is the radical of a diazo component of the formula (2a); (2b); (2c); (2d); (2f); (2g) or (2h). The invention also relates to the dyeing methods for dyeing keratinous fibers comprising such dyeing composition.
    Type: Grant
    Filed: February 19, 2010
    Date of Patent: September 18, 2012
    Assignee: BASF SE Ludwigshafen
    Inventor: Beate Fröhling
  • Patent number: 8268772
    Abstract: The present invention relates to depot preparations for the targeted release of an aldehyde together with two carboxylic acids, where the released aldehydes are organoleptic substances, specifically fragrances or flavorings, and these depot preparations are prepared by reacting aldehydes with carboxylic anhydrides.
    Type: Grant
    Filed: January 5, 2006
    Date of Patent: September 18, 2012
    Assignee: Symrise AG
    Inventors: Marcus Eh, Horst Surburg, Steffen Sonnenberg
  • Patent number: 8257448
    Abstract: The invention relates to hair dyeing composition comprising (a) a dye of formula (1); (b) a least one dye selected from the compounds of formulae (2) and (3), wherein D is the radical of a diazo component of the formula (2a) and (c) a quaternary ammonium salt selected from (c1) quaternary ammonium salts of the formula (4); (c2) imidazolium salts of the formula (5) and (c3) quaternary diammonium salts of the formula (6). The invention also relates to the dyeing methods for dyeing keratinous fibers comprising such dyeing composition.
    Type: Grant
    Filed: February 19, 2010
    Date of Patent: September 4, 2012
    Assignee: BASF SE
    Inventor: Beate Fröhling
  • Patent number: 8192505
    Abstract: The present invention concerns cosmetic compositions for coloring hair comprising at least one direct hair dye and a carrier system for the at least one direct hair dye, the use of such compositions in cosmetic formulations for coloring hair and processes for the production of the compositions.
    Type: Grant
    Filed: June 9, 2011
    Date of Patent: June 5, 2012
    Assignee: Rovi Cosmetics International GmbH
    Inventors: Monika Beyer, Dirk Teichmüller
  • Publication number: 20120110750
    Abstract: Disclosed are polymeric dyes of formula (1a), (1b), or (1c); wherein A and B, independently from each other represent a polymer backbone; X1 and X2 independently from each other are a linkage group selected from —S—, —S—S—, —N—, —N?—, —N(R5)—, —S(O)—, —SO2—, —(CH2CH2—O)1-5—, —(CH2CH2CH2—O)1-5—, —C(O)—, —C(O)O—, —OCO—, (formula II) —CON(R1)—, —C(NR1R2)2—, —(R1)NC(O)—, —C(S)R1—; which may be interrupted and/or terminated at one or both ends by one or more than one —C1C30alkylene- or —C2-C12alkenylene-; or an optionally substituted, saturated or unsaturated, fused or non-fused aromatic or nonaromatic (heterocyclic) bivalent radical optionally comprising at least one heteroatom; a saturated or unsaturated, fused or non-fused aromatic or nonaromatic bivalent radical comprising at least one heteroatom, which is optionally substituted by C1-C30alkyl, C1-C30alkoxy, C2-C12alkenyl, C5-C10aryl, C5-C10cycloalkyl, C1-C10alkyl(C5-C10arylene), hydroxy or halogen; R1 and R2 independently from each other are hydrogen; unsubst
    Type: Application
    Filed: July 15, 2010
    Publication date: May 10, 2012
    Applicant: BASF SE
    Inventors: Christian Cremer, Oliver Becherer, Beate Fröhling
  • Patent number: 8152860
    Abstract: The present invention concerns cosmetic compositions for coloring hair comprising at least one direct hair dye and a carrier system for the at least one direct hair dye, and the use of such compositions in cosmetic formulations for coloring hair. To provide a possible way with which the permanence of the bond of direct hair dyes to the hair can be improved, with the aim of direct dyes remaining on the hair for as long as possible to deliver the desired hair color in the desired quality for as long as possible, according to the invention there are proposed compositions of the aforementioned kind in which the carrier system is vesicular and comprises vesicles which are made up from hydrophobised polysaccharides and have a particle size of between 10 and 1000 nm as well as a positive surface charge with a zeta potential in the range of between 1 and 150 mV.
    Type: Grant
    Filed: June 9, 2011
    Date of Patent: April 10, 2012
    Assignee: ROVI Cosmetics International GmbH
    Inventors: Monika Beyer, Dirk Teichmüller
  • Patent number: 8137415
    Abstract: The present invention is related to an aqueous composition comprising an alkalizing agent and an aqueous emulsion of a silicone copolymer. The inventors of the present invention have surprisingly found out that a composition comprising at least one alkalizing agent and an aqueous emulsion of divinyldimethicone/dimethicone copolymer with an internal phase viscosity of more than 1×108 mm2/s measured at 0.01 Hz and at about 25° C. colors and/or permanently shapes hair excellently and improves hair shine, combability and manageability and especially hair treated with such composition has less flyaway. Additionally it has been observed that hair colored and/or permanently shaped more homogeneously from root to tips. The subject of the present invention is an aqueous composition for human hair comprising at least one alkalizing agent and an aqueous emulsion of divinyldimethicone/dimethicone copolymer with an internal phase viscosity of more than 1×108 mm2/s measured at 0.01 Hz and at about 25° C.
    Type: Grant
    Filed: October 20, 2009
    Date of Patent: March 20, 2012
    Assignee: KPSS KAO Professional Salon Services GmbH
    Inventors: Jonathan Wood, Alexandra Meuser, Mustafa Grit
  • Patent number: 8137414
    Abstract: The present invention is related to an aqueous composition comprising an alkalizing agent and a cationic polymer. The inventors of the present invention have surprisingly found out that a composition comprising at least one alkalizing agent and a cationic polymer consisting of a copolymer of vinylpyrrolidone and vinylimidazole and a homopolymer of dimethyl dially ammonium chloride colors and/or permanently shapes hair excellently and improves hair shine, combability and manageability and especially hair treated with such composition has less flyaway. Additionally it has been observed that hair colored and/or permanently shaped more homogeneously from root to tips. The object of the present invention is a composition for hair comprising at least one alkalizing agent and a cationic polymer consisting of a copolymer of vinylpyrrolidone and vinylimidazole and a homopolymer of dimethyl dially ammonium chloride. Cationic charge density of the polymer is preferably between 3 and 4 mEq/g and particularly 3.
    Type: Grant
    Filed: October 20, 2009
    Date of Patent: March 20, 2012
    Assignee: KPSS KAO Professional Salon Services GmbH
    Inventors: Jonathan Wood, Alexandra Meuser, Mustafa Grit
  • Publication number: 20120031422
    Abstract: The invention relates to a dyeing composition containing a thiol/disulphide fluorescent colorant comprising a heterocycle, and to a method for colouring keratin materials, especially keratin fibres, particularly human keratin fibres such as hair, with a lightening effect, using said composition. The invention also relates to novel thiol/disulphide fluorescent colorants and the uses thereof for lightening keratin materials. Said composition produces a lightening effect which is especially tenacious and visible on dark keratin fibres.
    Type: Application
    Filed: March 23, 2007
    Publication date: February 9, 2012
    Inventors: Andrew Greaves, Nicolas Daubresse
  • Patent number: 8105394
    Abstract: The invention relates to the dyeing of keratin fibers using azomethine direct dyes or reduced precursors of azomethine direct dyes of formula (I) and (II) obtained from 2-amino-3-hydroxypyridine. The invention relates to a dye composition comprising at least one azomethine direct dye or a reduced precursor of an azomethine direct dye, to a process for dyeing keratin fibers, using the said composition, and to their uses in the dyeing of keratin fibers. This composition allows a particularly stable and fast coloration to be obtained.
    Type: Grant
    Filed: December 9, 2008
    Date of Patent: January 31, 2012
    Assignee: L'Oreal S.A.
    Inventors: Madeleine Leduc, Stéphane Sabelle, Eric Metais, Christophe Rondot
  • Publication number: 20120017931
    Abstract: Hair dyeing composition comprising (a) a dye of formula (1) (b) at least one dye selected from the compounds of formulae (2) (3) (4) wherein D is the radical of a diazo component of the formula (2a) (2b) (2c) (2d) K is the radical of a coupling component selected from aniline derivatives; phenol derivatives; naphthalene derivative; X is —CH? —O—; —S—; or —N(R7)—; R1, R2, R3 end R4 independently from each other are hydrogen; or C1-C4alkyl; R5 and R6 independently from each other are hydrogen; C1-C4alkyl; or C1-C4alkoxy; R7 and R9 independently from each other are unsubstituted or OH—, C1-C4alkoxy-, halogen-, amino-, C1-C4-mono or -dialkylamino-substituted C1-C4alkyl; or phenyl; R8 is hydrogen; C1-C4alkyl; Cl; or nitro; R10 is hydrogen; C1-C4alkyl; Cl; nitro; amino; or C1-C4mono- or C1-C4dialkylamino; R11 is hydrogen; C1-C4alkyl; or CN; R12 is unsubstituted or OH— or CN-substituted C1-C4alkyl; R13 is hydrogen; or C1-C4alkyl; R14 and R15 independently from each other are hydrogen; C1-C4alkyl; or C1-C4alkoxy; or
    Type: Application
    Filed: February 19, 2010
    Publication date: January 26, 2012
    Applicant: BASF SE
    Inventor: Beate Fröhling
  • Publication number: 20120012128
    Abstract: Disclosed is a hair dyeing composition comprising (a) a dye of formula (1); (b) at least one dye selected from the compounds of formulae (2); wherein D is the radical of a diazo component of the formula (2a); K is the radical of a coupling component selected from aniline derivatives; phenol derivatives; and a radical of a heterocyclic coupling component; X is O—; —S—; or N(R8)—; Y is CH?; —CR15?; or N?; R1, R2, R3 and R4 independently from each other are hydrogen; or C1-C4alkyl; R5 and R6 independently from each other are hydrogen; C1-C4alkyl; or C1-C4alkoxy; R7 and R9 independently from each other are unsubstituted or OH—, C1-C4alkoxy-, halogen-, amino-, C1-C4-mono or -dialkylamino-substituted C1-C4alkyl; R8 is hydrogen; or C1-C4alkyl; R10 is hydrogen; C1-C4alkyl; or CN; R11 is unsubstituted or OH- or CN-substituted C1-C4alkyl; R12 is hydrogen; or C1-C4alkyl; R13 and R14 independently from each other are hydrogen; C1-C4alkyl; or C1-C4alkoxy; or R13 and R14 together with the nitrogen and carbon atoms joining
    Type: Application
    Filed: February 19, 2010
    Publication date: January 19, 2012
    Applicant: BASF SE
    Inventor: Beate Fröhling
  • Patent number: 8097044
    Abstract: Disclosed herein are compositions for simultaneous shaping, dyeing, and/or lightening of keratin fibers comprising at least one disulfide direct dye and at least one organic or mineral hydroxide alkaline agent. Also disclosed herein are processes for simultaneous shaping, dyeing, and/or lightening of keratin fibers using said compositions and compartmentalized devices comprising said compositions. The compositions disclosed herein may make it possible to obtain a long-lasting dyeing effect, while limiting the degradation of the keratin fibers.
    Type: Grant
    Filed: July 24, 2008
    Date of Patent: January 17, 2012
    Assignee: L'Oreal S.A.
    Inventors: Frédéric Guerin, Maxime de Boni
  • Patent number: 8088176
    Abstract: Disclosed are methods, kits and compositions for coloring the hair involving a color base composition having: at least one oxidation dye precursor, and at least 5% by weight water based on the weight of the color base composition, wherein the color base composition has a pH ranging from 2 to 12; and a developer composition made from a combination of an anhydrous oxidizer composition containing at least one oxidizing agent chosen from persulfates, perborates, percarbonates, their salts, and mixtures thereof, and a shampoo composition containing a carrier vehicle and at least 4% of at least one surfactant.
    Type: Grant
    Filed: August 28, 2009
    Date of Patent: January 3, 2012
    Assignee: L'Oreal
    Inventors: Michael DeGeorge, Jeremy Puco, Delphine Allard
  • Patent number: 8066781
    Abstract: The present disclosure relates to a composition for dyeing or lightening human keratin fibers, comprising: a cosmetically acceptable medium; at least 25% by weight of at least one fatty substance; at least one cationic polymer; at least one dye chosen from oxidation dyes and direct dyes; at least one basifying agent; and at least one oxidizing agent. The disclosure also relates to a dyeing or lightening process using it. Another subject of the disclosure is multi-compartment devices or kits for obtaining, after mixing together the compositions of the compartments, just before its application, a composition according to the disclosure.
    Type: Grant
    Filed: December 18, 2009
    Date of Patent: November 29, 2011
    Assignee: L'Oreal S.A.
    Inventors: Leïla Hercouet, Frédéric Simonet, Marie-Pascale Audousset, Philippe Rapold