Acid (including Direct) Dye, E.g., Sulfonated, Sulfamated, Etc. Patents (Class 8/455)
  • Patent number: 7087095
    Abstract: A hair dye composition that is particularly applicable by localized capillary action, and comprises one or more FD&C and D&C dyes, water, alcohol, Polectron 430, and a polymeric ruboff protector component for preventing ruboff of the color of the dye.
    Type: Grant
    Filed: August 6, 2002
    Date of Patent: August 8, 2006
    Assignee: HairMarker LLC
    Inventor: George Pollack
  • Patent number: 7070625
    Abstract: The objects of the present invention are an agent (A) for coloring fibers obtained by mixing two components (A1) and (A2), characterized in that component (A1) contains at least one 2-benzothiazolinone hydrazone derivative of formula (I) or a physiologically tolerated salt thereof and component (A2) contains at least one ortho-quinone of formula (II) or a para-quinone of formula (III), a method for coloring hair by use of said agent and a multicomponent kit for coloring hair.
    Type: Grant
    Filed: August 22, 2002
    Date of Patent: July 4, 2006
    Assignee: Wella AG
    Inventors: Cécile Pasquier, Gisela Umbricht, Veronique Buclin-Charrière, Sylviane Oberson, Hans-Juergen Braun
  • Patent number: 7056349
    Abstract: The invention relates to an agent for colouring fibres (A). Said agent is produced by mixing two constituents (A1) and (A2), and is characterised in that the constituent (A1) contains at least one quinonimine derivative of formula (I), and the constituent (A2) contains at least one compound from the group consisting of aromatic amines and phenols. The invention also relates to a method for colouring keratin fibres using the inventive agent.
    Type: Grant
    Filed: February 23, 2002
    Date of Patent: June 6, 2006
    Assignee: Wella AG
    Inventors: Cécile Pasquier, Veronique Buclin-Charrière, Patrick Wyss
  • Patent number: 6916343
    Abstract: A method for coloring keratin fibers is provided that includes at least two steps. In one step, the keratin fibers are treated with a pretreatment composition containing at least one substantive dye. In another step, the keratin fibers are treated with a composition containing at least one synthetic dye or synthetic dye precursor after applying the pretreatment composition.
    Type: Grant
    Filed: August 22, 2000
    Date of Patent: July 12, 2005
    Assignee: Hans Schwarzkopf GmbH & Co. KG
    Inventors: Mustafa Akram, Rolf-Werner Haubold
  • Patent number: 6916344
    Abstract: The invention relates to a direct dyeing composition for keratinic fibers, especially human keratinic fibers such as hair, containing at least one direct dye and a thickening polymer with an ether plastic skeleton, in a medium which is suitable for dyeing. The invention also relates to dyeing methods and devices for using the invention composition.
    Type: Grant
    Filed: November 10, 2000
    Date of Patent: July 12, 2005
    Assignee: L'Oreal S.A.
    Inventors: Delphine Allard, Frédéric Legrand
  • Patent number: 6908491
    Abstract: A method for color-revitalizing a color tone of hair that involves applying a color-revitalizing composition to hair previously dyed with an oxidative hair dye composition. The color-revitalizing composition, which has a color determined by the color of the oxidative hair dye composition and contains at least one direct dye, revitalizes the color tone originally obtained by after dyeing with the oxidative hair dye composition.
    Type: Grant
    Filed: October 23, 2001
    Date of Patent: June 21, 2005
    Assignee: The Andrew Jergens Company
    Inventors: Vince Fischer, Masahiko Sakai, Satoshi Onitsuka, Hajime Miyabe, Hiroshi Ikeda, David Ferguson
  • Patent number: 6905521
    Abstract: Disclosed are a cumulative hair-dyeing temporary hairdye comprising 0.01 to 3% by weight of an acid dye as a colorant, 0.1 to 10% by weight of a nonionic or anionic silicone base resin, 3 to 20% by weight of a hair-dyeing aid, 30 to 80% by weight of a lower alcohol and 5 to 50% by-weight of water and having a pH of 2 to 5 and a viscosity of 100 mPa·s or less and a production process for a cumulative hair-dyeing temporary hairdye, wherein the respective components are blended in such an order that at least a nonionic or anionic silicone base resin and a lower alcohol are mixed to prepare a vehicle, and then the other components are blended therewith and stirred.
    Type: Grant
    Filed: December 15, 2000
    Date of Patent: June 14, 2005
    Assignee: Mitsubishi Pencil Kabushiki Kaisha
    Inventor: Eiji Tsuchiya
  • Patent number: 6776803
    Abstract: A hair dye composition comprises the following ingredients (A) and (B): (A) a compound having a 5- or 6-membered lactone skeleton, and (B) an acid dye; and having a pH of from 2 to 6 and a buffer capacity not lower than 0.004 gram equivalent/L but lower than 0.2 gram equivalent/L as measured in a form of a tenfold dilute aqueous solution. This hair dye composition does not cause staining to the skin, is excellent in dyeing properties for hair, is good in the fastness to shampoo, and does not give off gas through hydrolysis in an acidic range.
    Type: Grant
    Filed: February 1, 2002
    Date of Patent: August 17, 2004
    Assignee: Kao Corporation
    Inventors: Masato Oshika, Takashi Itou, Eiichi Nishizawa, Sachiko Tajima, Takashi Mizooku
  • Patent number: 6749645
    Abstract: The object of the present invention is the use of 4-nitro-2,1,3-benzoxadiazole derivatives of general formula (I) as dye in colorants for keratin fibers such as, for example, wool, silk, furs or hair and particularly human hair In formula (I) X denotes oxygen, sulfur or NRa, Ra standing for hydrogen, a (C1-C4)-alkyl group, a monohydroxy-(C1-C4)-alkyl group, a polyhydroxy-(C2-C4)-alkyl group or a mono-(C1 C4)-alkoxy-(C1-C4)-alkyl group, R1 and R2 can be equal or different and independently of each other denote hydrogen, a halogen atom, a (C1-C4)-alkyl group, a halogen-substituted (C1-C4)-alkyl group, a (C1-C4)-alkoxy group, a nitro group or an NRbRc group, the Rb and Rc groups being equal or different and independently of each other denoting hydrogen, a (C1-C4)-alkyl group, an optionally substituted aromatic carbon ring or a (C1-C4)-alkanecarbonyl group, or Rb and Rc together with the nitrogen atom forming a heterocyclic (C3-C6) group, and Q denotes hydrogen, an aliphatic group, an aromati
    Type: Grant
    Filed: March 26, 2002
    Date of Patent: June 15, 2004
    Assignee: Wella Aktiengesellschaft
    Inventors: Cécile Pasquier, Véronique Charrière, Hans-Juergen Braun
  • Patent number: 6746492
    Abstract: A semipermanent hair dye composition comprising (A) a direct dye, (B) a hydrocarbon oil and (C) polyoxyalkylene-modified dimethyl polysiloxane. The semipermanent hair dye composition can uniformly dye hair without coloring the scalp and skin and gives the hair an excellent feel after hair coloring.
    Type: Grant
    Filed: December 20, 2001
    Date of Patent: June 8, 2004
    Assignee: Kao Corporation
    Inventors: Tetsuya Kawai, Takashi Itou
  • Patent number: 6736862
    Abstract: A composition and method for using the composition for dyeing keratin fibers. The composition consists of indole/indoline hybrid dyes and hybrid dye precursors. More particularly, the indole/indoline hybrid dyes and hybrid dye precursors correspond to formula (I): X—S—Y  (I) where X is a group derived from an indole or indoline derivative as a melanin precursor, Y is a group derived from an oxidation dye precursor of the secondary or primary intermediate type or an indole or indoline derivative as a melanin precursor; and S is a structural element which is common constituent of the groups X and Y, a direct bond or at least one spacer group. The composition may also be used to color human skin.
    Type: Grant
    Filed: July 9, 2003
    Date of Patent: May 18, 2004
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Frank Naumann, Detlef Hollenberg, Horst Hoeffkes, David Rose
  • Patent number: 6689173
    Abstract: Provided is a hair dye composition containing a direct dye (1). This hair dye composition has markedly high hair dyeing power, has less color fade over time and undergoes a small change in the color tone of the dye even after storage. wherein, R1 to R4 each represents a (substituted) C1-6 alkyl group, (substituted) alkenyl group or (substituted) aryl group or R3 and R4, when taken together with the adjacent C, form a 5 to 12 membered ring, R5 represents H, (substituted) C1-6 alkyl group, (substituted) alkenyl group, (substituted) aryl group or acyl group, X1 and X2 each represents H or halogen atom, Y1 and Y2 each represents H, (substituted) C1-6 alkyl group, (substituted) alkenyl group, (substituted) C1-6 alkoxy group or halogen atom, Z1 and Z2 each represents H, (substituted) C1-6 alkyl group, (substituted) alkenyl group, (substituted) C1-6 alkoxy group, nitro group or halogen atom, and A− represents an anion.
    Type: Grant
    Filed: June 26, 2001
    Date of Patent: February 10, 2004
    Assignee: Kao Corporation
    Inventors: Yukihiro Ohashi, Hajime Miyabe, Kenichi Matsunaga, Shintaro Totoki, Yoshinori Saito
  • Patent number: 6656228
    Abstract: A composition comprising: (a) a cationic substance; (b) an acid generator; and (c) an alkyl or a hydroxyalkyl substituted starch. Also claimed is a polyamide textile material treated with the composition, a method for ink jet printing onto a polyamide textile material which has been treated with the composition and a polyamide material printed using the method.
    Type: Grant
    Filed: January 29, 2001
    Date of Patent: December 2, 2003
    Assignee: Avecia Limited
    Inventors: Alison Sherwin, John Reginald Provost, William Albert Fern
  • Patent number: 6623531
    Abstract: The invention relates to a hair dye composition having markedly high dyeing power, less color fade over time, and undergoes a small change in the color tone of the dye even after storage.
    Type: Grant
    Filed: June 26, 2001
    Date of Patent: September 23, 2003
    Assignee: Kao Corporation
    Inventors: Yukihiro Ohashi, Hajime Miyabe, Kenichi Matsunaga
  • Patent number: 6616708
    Abstract: Provided is a hair dye composition containing a direct dye (1), (2) or (3). This hair dye composition has markedly high hair dyeing power, has less color fade over time and undergoes a small change in the color tone of the dye even after storage. wherein, R1 represents a (substituted) aryl group, R2, R4 to R6, R8 and R9 each represents H, a (substituted) C1-6 alkyl group or a (substituted) aryl group, R3 and R7 each represents a (substituted) aryl group, R10 to R12 each represents a (substituted) C1-6 alkyl or (substituted) aryl group, rings A to G each represents a benzene ring which may be substituted by a (substituted) amino group, (substituted) C1-6 alkyl group, C1-6 alkoxy group or halogen atom or may further be cyclocondensed with a benzene ring, and X− represents an anion.
    Type: Grant
    Filed: June 25, 2001
    Date of Patent: September 9, 2003
    Assignee: Kao Corporation
    Inventors: Yukihiro Ohashi, Hajime Miyabe, Kenichi Matsunaga
  • Patent number: 6616709
    Abstract: Provided is a hair dye composition containing a direct dye (1). This hair dye composition has markedly high hair dyeing power, has less color fade over time and undergoes a small change in the color tone of the dye after storage. wherein, ring A may represents a benzene ring which may have a substituent or the like, B represents an aryl or heterocyclic group, D represents N or CR4 (wherein R4 represents H or alkyl), E represents NR5, CR6R7 or CR6═CR7 (wherein R5 represents alkyl or the like, and R6 and R7 each represents H or alkyl) or, O or S, R1 represents alkyl or the like, and n stands for 0 or 1, with the proviso that at n=0, R2 and R5 form, when taken together with N—C—C, a heterocycle, or R2 is bonded to B, thereby forming a heterocycle and at n=1, R2 and R3 form, when taken together with C═D—N, a heterocycle, and X− represents an anion.
    Type: Grant
    Filed: June 25, 2001
    Date of Patent: September 9, 2003
    Assignee: Kao Corporation
    Inventors: Yukihiro Ohashi, Hajime Miyabe, Kenichi Matsunaga, Shintaro Totoki, Yoshinori Saito
  • Patent number: 6533823
    Abstract: Provided is a dye composition for keratinous fibers, which comprises (A) a hydrolyzate of a lower alkyl vinyl ether/maleic anhydride copolymer partially crosslinked with a terminal unsaturated diene compound, or a monoalkyl ester of the hydrolyzate; and (B) a dye. The dye composition for keratinous fibers according to the present invention has a stable and appropriate viscosity even in a wide pH range and even in a system containing a salt or solvent at a high concentration; and has excellent usability and dyeing properties. It is particularly suited for use with an acid dye.
    Type: Grant
    Filed: March 5, 2001
    Date of Patent: March 18, 2003
    Assignee: KAO Corporation
    Inventors: Atsushi Nakashimada, Masaki Fukuhara
  • Patent number: 6383231
    Abstract: The invention relates to a ready-to-use mixture for tinting keratin fibres, especially human keratin fibres such as hair, comprising in a support material suitable for keratin materials: a) at least one laccase-type enzyme; at least one anionic surface-active agent selected from the group made up of the acylisethionates, acyltaurates, sulfosuccinates having a special structure, acylsarcosinates having a special structure, acyl glutamates, polyoxyalkylenated carboxylic acid ethers and their salts, fatty glucamide sulfates, alkyl galactoside uronates, anionic derivatives of alkyl polyglucoside, and mixtures thereof; and (c) at least one oxidation tint. The invention also relates to the hair tinting methods using the above mixture.
    Type: Grant
    Filed: September 5, 2000
    Date of Patent: May 7, 2002
    Assignee: L'Oreal
    Inventors: Gérard Lang, Jean Cotteret
  • Patent number: 5769904
    Abstract: This invention relates to a process for the production of resists or multicolor effects on natural or synthetic polyamide fiber materials, which, to produce resists, comprises locally applying a liquid preparation wet-on-wet before or after treating the textile material with a dyeing liquor or printing paste containing at least one anionic dye, said preparation comprising one or more than one compound of formula ##STR1## wherein R.sub.1 is a straight-chain or branched C.sub.10 -C.sub.24 alkyl or alkenyl radical, R.sub.2 and R.sub.3 are each independently of the other C.sub.1 -C.sub.
    Type: Grant
    Filed: May 27, 1997
    Date of Patent: June 23, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Guy Achilles Alfons Meerschman, Jean-Pierre Troch, Serge Charles Jacques Garing
  • Patent number: 5574106
    Abstract: Addition polymers suitable for imparting stain resistance to nylon carpets and other polyamide products are formed of styrene or other ethylenically unsaturated monomer containing cyclic hydrocarbon groups, sodium vinyl sulphonate or other ethylenically unsaturated strong acid monomer, and ethylenically unsaturated weak acid monomer that is preferably acrylic acid. The proportions of the monomer are, respectively, 7 to 50%, 1 to 20% and 40 to 90% by weight.
    Type: Grant
    Filed: January 17, 1995
    Date of Patent: November 12, 1996
    Assignee: Allied Colloids Limited
    Inventor: Adrian S. Allen
  • Patent number: 5571444
    Abstract: A textile treatment composition which comprises; a textile binding agent which forms a chemical bond with the outer layer of the textile according to the formula (Ia): ##STR1## and, a barrier agent which forms a chemical bond with the textile binding agent and which increases the surface tension of the textile. Methods for treating textiles with the treatment composition, and kits comprising the components are also provided.
    Type: Grant
    Filed: January 11, 1996
    Date of Patent: November 5, 1996
    Assignee: Invicta Group Industries Pty Ltd.
    Inventors: Arthur D. Fisher, Dieter Reinehr, Jorg Binz, Sven Strunk
  • Patent number: 5443598
    Abstract: Compositions comprising(a) a cationic surfactant which per se acts as a reserving agent in the dyeing of substrates dyeable with anionic dyes, or a mixture of such surfactantsand (b) a cationic surfactant which per se acts as a retarder in the dyeing of polyacrylonitrile with cationic dyes, or a mixture of such surfactantsand which may contain further components, are eminently suitable as reserving agents for substrates dyeable with anionic dyes.
    Type: Grant
    Filed: June 17, 1992
    Date of Patent: August 22, 1995
    Assignee: Sandoz Ltd.
    Inventor: Hans-Peter Baumann
  • Patent number: 5138729
    Abstract: A system providing universal support for patients includes an articulated platform supported by a universal joint supported by a pair of hydraulic support arms, and by a pair of lesser hydraulic arms spaced from the universal joint. The platform is comprised of a plurality of relatively hinged panels which are also hydraulicly driven. Thus, the platform is capable of assuming a large number of configurations, including full sitting and standing positions. A patient cushion system includes a large plurality of cushions which are individually or severally controlled through a valve and manifold system which is computer controlled for cycling cushion pressures between high and low pressures. The sides of the bed platform have restraining members which may be lowered and hinged in toward the patient to provide access to the patient. These restraining members also provide for supplemental support of such things as a canopy or tension weight.
    Type: Grant
    Filed: January 16, 1991
    Date of Patent: August 18, 1992
    Assignee: American Life Support Technology
    Inventor: Robert Ferrand
  • Patent number: 5066535
    Abstract: A method for patterning a textile fabric in which a hydrophobic composition is uniformly applied to the surface of the fabric, and the resulting product. A high velocity water stream is used to wet areas of the fabric comprising the pattern areas. An aqueous dye is then applied uniformly to the fabric. The unfixed dye is retained by the fabric in those areas wetted by the water stream, the fabric is then treated to fix the retained dye.
    Type: Grant
    Filed: July 25, 1990
    Date of Patent: November 19, 1991
    Assignee: Milliken Research Corporation
    Inventor: Wesley D. Christie
  • Patent number: 5022891
    Abstract: The process for producing patterns on ground dye colored textile fiber pile substrates, particularly wherein the pile fibers are in the form of yarns comprised predominantly of polyamide fiber, and wherein at least some of the ground dye component is at least partially color dischargeable and selected from vat, reactive, direct, acid, premetallized or mordant dyes, the process comprising contacting selected portions of the colored pile fibers with a reducing system which optionally can contain one or more reduction resistant dye or pigment materials for in situ coloring of the substrates, the contacting being characterized by jet forcing the reducing system interstitially of the pile fibers to deposit the reducing system thereon substantially below the surface thereof, and to effect the color discharge of at least a portion of the ground dye component.
    Type: Grant
    Filed: April 30, 1990
    Date of Patent: June 11, 1991
    Assignee: Milliken Research Corporation
    Inventor: Daniel T. McBride
  • Patent number: 4859207
    Abstract: A process for dyeing textile planar fabrics made from natural or synthetic polyamides with anionic dyes by(a) locally applying a resist agent by itself or in conjunction with an anionic dye of fluorescent whitening agent,(b) subjecting the textiles to a heat treatment, and(c) carrying out ground dyeing with a dye liquor that contains a further anionic dye,which process comprises using, as resist agent, a melamine compound of formula ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are each independently phenyl or naphthyl, each of which may be substituted by halogen, hydroxy, C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkoxy, Z is an acid water-solubilizing group, and m is 1 to 6.
    Type: Grant
    Filed: July 19, 1988
    Date of Patent: August 22, 1989
    Assignee: Ciba-Geigy Corporation
    Inventors: Thys Bouwknegt, Heinz Abel
  • Patent number: 4800118
    Abstract: A light stabile composition for imparting stain resistance to polyamide fiber-containing textile articles (e.g. nylon, wool or silk carpets) comprises a halogenated (e.g. brominated or chlorinated) aryl group-containing product of the condensation polymerization of a hydroxyaryl sulfonic acid (e.g., para-hydroxyphenyl sulfonic acid), a dihydroxydiaryl sulfone (e.g., dihydroxydiphenyl sulfone) and an aldehyde (e.g., formaldehyde). The polyamide fiber-containing textile articles are converted to a stain resistant product by containing the fibers with an acidified aqueous solution of the aforesaid composition.
    Type: Grant
    Filed: November 4, 1987
    Date of Patent: January 24, 1989
    Assignee: West Point Pepperell
    Inventors: John W. Reed, Richard D. Smith
  • Patent number: 4680033
    Abstract: In the conventional discharge printing on polyamide fiber materials using acid dyes, above all, the very low wet and light fastness properties of the designs obtained in this manner are frequently an obstacle to the wide expansion of this interesting technique in practice. Applying this known patterning method for wool or nylon to resist prints made with reactive dyes being distinguished by better fastness level, does not always produce satisfactory white resist effects when, for example, sulfite compounds as the resist agent and reactive dyes having esterified .beta.-hydroxyethylsulfonyl groups as the reactive radical are taken into consideration; colored effects having a bright hue are not even possible at all in various cases.
    Type: Grant
    Filed: October 25, 1985
    Date of Patent: July 14, 1987
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Bernd Durl, Johannes Bos, Sienling Ong, Peter Raffel, Kurt Brozat
  • Patent number: 4622040
    Abstract: A continuous process for dyeing a pre-wetted carpet includes the step of printing, in one dye color, a desired pattern on the tufts, compressing those of the tufts receiving the dye in the process. The tufted printed surface of the carpet is then covered with a viscous water-soluble gum and then drops of a second dye, which is less viscous than the gum, are applied to the viscous gum-wetted tufts. Then a third dye which is substantially less viscous than the second dye is applied over the entire tufted surface of the carpet.
    Type: Grant
    Filed: June 19, 1978
    Date of Patent: November 11, 1986
    Assignee: RCA Corporation
    Inventor: David B. Nichols, Jr.
  • Patent number: 4622044
    Abstract: A continuous process for dyeing a pre-wetted carpet includes the step of applying a viscous water soluble gum layer over the tufted face of the carpet. Drops of first and second dyes less viscous than the gum are applied over the gum-wetted carpet face. A third dye which is substantially less viscous than the gum and the first and second dyes is applied over the entire tufted surface of the carpet.
    Type: Grant
    Filed: July 22, 1985
    Date of Patent: November 11, 1986
    Assignee: RCA Corporation
    Inventor: David B. Nichols, Jr.
  • Patent number: 4441884
    Abstract: The present invention relates to a process for treating a polyamide textile substrate to increase the affinity thereof for anionic dyes or to reserve the same against cationic dyes comprising applying thereto, in a weakly alkaline medium, a compound of formula I, ##STR1## wherein R is phenyl; naphthyl; (C.sub.5-6)cycloalkyl; or phenyl or naphthyl substituted by a total of up to 3 substituents selected from the group consisting of (C.sub.1-4)alkyl, chlorine and bromine (maximum of two of each of these);each of R.sub.1 and R.sub.2, independently, is (C.sub.1-4)alkyl, and X.sup..crclbar. is a non-chromophoric anion.
    Type: Grant
    Filed: November 9, 1978
    Date of Patent: April 10, 1984
    Assignee: Sandoz Ltd.
    Inventors: Hans-Peter Baumann, Urs Mosimann
  • Patent number: 4412837
    Abstract: Process for imprinting textiles made from cellulose fibers or cellulose fibers mixed with other fibers employing reactive and/or developing dyes according to the etch-resist process using printing dyes which contain per 1000 parts by weight, 10 to 100 parts by weight of one or more of the following compounds: butyl glycol, butyl diglycol, butyl triglycol, 1,2-butane diol, 2,5-hexane diol, and diethylene glycol monoethylether. This results in essentially complete penetration.
    Type: Grant
    Filed: April 30, 1982
    Date of Patent: November 1, 1983
    Assignee: BASF Aktiengesellschaft
    Inventors: Adolf Blum, Hans D. Opitz
  • Patent number: 4411666
    Abstract: A process for dyeing polyolefin fiber materials, which comprises contacting a polyolefin fiber material obtained by melt-spinning a mixture of crystalline polyolefin and 0.1 to 30% by weight based on the weight of the polyolefin of a copolymer of ethylene and an aminoalkyl acrylate compound represented by the formula, ##STR1## wherein R.sub.1 represents hydrogen atom or methyl group, R.sub.2 and R.sub.3 each represents hydrogen atom or an alkyl group having 1 to 4 carbon atoms, and n represents an integer from 1 to 4, or a blend product of the said polyolefin fiber material and a polyamide fiber material, with a dye bath containing an anionic dye and at least one carboxylic acid selected from the group consisting of benzoic acid, salicylic acid, p-chlorobenzoic acid and 5-chlorosalicylic acid.
    Type: Grant
    Filed: February 8, 1982
    Date of Patent: October 25, 1983
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Shuhei Hashizume, Sadaharu Abeta, Tadayuki Ohmae, Hajime Nishibara
  • Patent number: 4411665
    Abstract: The invention relates to a wet-on-wet dyeing process comprising(A) impregnating the substrate with an acid dyeing liquor containing an anionic dye having a K'.sub.pH6 -value.gtoreq.5(B) applying locally to the substrate at room temperature, a liquor or paste containing an alkoxylated fatty amine or polyamine having affinity for anionic dyes with a K'.sub.pH6 -value.gtoreq.5, said step (B) being carried out directly after or directly before said step (A), and(C) subsequently submitting the substrate to a heat treatment to effect fixation of the dye.
    Type: Grant
    Filed: June 26, 1981
    Date of Patent: October 25, 1983
    Assignee: Sandoz Ltd.
    Inventors: Hermann Egli, Emil Engeler
  • Patent number: 4410330
    Abstract: A process for dyeing a voluminous flat form anionic dyeable substrate, for example a carpet, comprises applying locally to said substrate one or more dyes, optical brightening agents and/or reserving agents having low migration properties followed by pre-fixation of the same, subsequently dyeing the treated substrate in a short bath with one or more dyestuffs having better migration properties, rolling up the substrate and rotating the rolled-up substrate under conditions to effect fixation of the dyestuffs.
    Type: Grant
    Filed: January 12, 1981
    Date of Patent: October 18, 1983
    Assignee: Sandoz, Ltd.
    Inventors: Hans-Peter Stakelbeck, Rudolf Sommerhalder
  • Patent number: 4351638
    Abstract: Cotton-containing toweling is dyed in a dye bath solution containing a coloring amount of at least one phosphonic acid fiber reactive dye together with sufficient acids such that the fiber reactive dye reacts with and attaches to the cotton of the toweling. The deybath-saturated toweling is passed through a high expression roll until the wet pickup is in the range of about 40-55 percent wpu, and then the toweling is heated to a temperature of at least 200 degrees F. for a time sufficient to fix the dye onto the cotton producing a fully penetrated, evenly dyed toweling. The toweling may be printed in a predetermined pattern with a print paste after passage through a high expression roll and before final heating.
    Type: Grant
    Filed: September 21, 1981
    Date of Patent: September 28, 1982
    Assignee: Burlington Industries, Inc.
    Inventors: James E. Finlayson, III, Joseph P. Holder, L. Earl Holt, Seung Y. Lee
  • Patent number: 4302202
    Abstract: A composition useful as a dyeing, fixing and leveling agent for acid dyestuffs on polyamide fibers, as a reserving agent in dyeing of polyamide-cellulosic blends with direct dyes and as an aftertreating agent for improving wet fastness and perspiration resistance of polyamides dyed with an acid dyestuff consists essentially of an aqueous solution of 60-85% by weight of solute of phenolsulfonic acid-formaldehyde condensate and 15-40% by weight of solute of an alkylene glycol of up to 3-10 carbon atoms or a polyoxyethylene or -thio glycol or molecular weight up to 1000.
    Type: Grant
    Filed: October 9, 1979
    Date of Patent: November 24, 1981
    Assignee: Northwestern Laboratories, Inc.
    Inventors: Jeffery L. Sumner, Arthur L. Tinsley
  • Patent number: 4300899
    Abstract: The present invention relates to compounds of formula I.sub.x, ##STR1## in which Y.sub.1 is (C.sub.1-6) alkoxy, Z is hydrogen, alkali metal or ammonium, andn is 1 or 2and a process for treating anionic dyeable substrates therewith to reserve the same against anionic dyes.
    Type: Grant
    Filed: February 20, 1980
    Date of Patent: November 17, 1981
    Assignee: Sandoz Ltd.
    Inventor: Hans-Rudolf Schmid
  • Patent number: 4285691
    Abstract: The present invention provides a process for dyeing an anionic dyeable substrate with reserve and/or multicolored effects, which process comprises(1) impregnating the substrate with a dyeing liquor containing an anionic dye having a K'-value.gtoreq.5(2) directly thereafter applying locally to the substrate a liquor or paste containing an alkoxylated fatty amine or polyamine having affinity for anionic dyes with a K'value.gtoreq.5 and optionally a disperse dye and/or an anionic dye or an anionic optical brightening agent with the proviso that the anionic dye or optical brightening agent has a K-value at least one unit lower than the K'value of the anionic dye used in step (1), and(3) subsequently submitting the substrate to a heat treatment to effect fixation of the dye(s) and, if used, optical brightening agent.
    Type: Grant
    Filed: January 31, 1980
    Date of Patent: August 25, 1981
    Assignee: Sandoz Ltd.
    Inventors: Hermann Egli, Emil Engeler
  • Patent number: 4222742
    Abstract: The present invention is a dyeing and/or printing process which employs as an additive a composition comprising one or more cations selected from ammonium, Group I and Group II metals of the Periodic Tables due to Mendeleef, one or more carboxylate anions and water, the ratio of the anion to the cation being in the range of 2:1 and 4:1 on a chemical equivalent basis. The additive can be incorporated into the dyeing and/or printing process at various points in the process, for example at the stages of scouring of the fabric, mordanting, levelling, exhaustion, fixing finishing, water-proofing and milling. They are less corrosive to skin, clothing, plastics and metal and hence are safer to the operative and do not promote deterioration of equipment.
    Type: Grant
    Filed: October 2, 1978
    Date of Patent: September 16, 1980
    Assignee: BP Chemicals Limited
    Inventor: David Berry