Dry Heat Treatment For Penetration Patents (Class 8/470)
  • Patent number: 11490667
    Abstract: A protective lens stack comprises a base layer including a polyethylene terephthalate (PET) film containing a UV blocking additive and one or more removable lens layers stacked on top of the base layer. Each of the removable lens layers may include a PET film and a first adhesive disposed on a bottom surface of the PET film. Refractive indices of the base layer and the one or more removable lens layers may be matched to within 0.2. Each layer of the protective lens stack, including the base layer and each of the removable lens layer(s), may have less than 0.5% haze. The protective lens stack may be used as a face shield or may be surface mountable using a second adhesive disposed on a bottom surface of the PET film containing the UV blocking additive.
    Type: Grant
    Filed: June 8, 2021
    Date of Patent: November 8, 2022
    Assignee: Racing Optics, Inc.
    Inventors: Bart E. Wilson, Stephen S. Wilson
  • Patent number: 11274394
    Abstract: A coloring product for dyeing or refreshing dyes in textile materials is disclosed. The coloring product includes a flat carrier material, at least one coating applied to the carrier material, and at least one dye in the coating. The at least one dye is present in a quantity ranging from 45% by weight 98% by weight in relation to the overall quantity of the coating. The flat carrier material is a nonwoven. The coloring product may be included in a washing machine that has textile materials in an aqueous solution at a temperature of at least 20° C. over a period of at least 10 minutes.
    Type: Grant
    Filed: November 16, 2016
    Date of Patent: March 15, 2022
    Assignee: Brauns-Heitmann GmbH & Co. KG
    Inventors: Uwe Gibbels, Aline Rosenfeldt, Katja Fueser
  • Patent number: 11203211
    Abstract: A system and method for coating a lens (10) using a plurality of inkjet print bars (46) arranged in-line, includes generating, using at least one processor (54, 110) in communication with the plurality of inkjet print bars (46), at least one graphical user interface configured to facilitate the automation of the creation or selection of an image to be printed on a lens (10); generating a plurality of image layers based on the lens (10) geometry, target product, and number of print bars (46); and controlling, using the at least one processor (54, 110), at least two of the plurality of inkjet print bars (46) to print the image on the lens (10), such that each of the at least two inkjet print bars (46) prints at least one image layer of the plurality of image layers.
    Type: Grant
    Filed: April 28, 2017
    Date of Patent: December 21, 2021
    Assignee: Transitions Optical, Ltd.
    Inventors: Carlos Rodriguez, William D. Carpenter
  • Patent number: 9392801
    Abstract: The invention describes a process to produce a casing with marks and a meat product with marks. Said process starts from a casing by way of pleated tubular wrapping, where a coloring composition is impregnated on at least one sector of its surface to produce a casing with marks, which is optionally transferred to the stuffed meat product in said casing.
    Type: Grant
    Filed: May 11, 2007
    Date of Patent: July 19, 2016
    Assignee: VISCOFAN, S.A.
    Inventors: Carlos Longo Areso, Alberto Gallues Biurrun, Jose Ignacio Recalde Irurzun
  • Patent number: 8999006
    Abstract: The invention relates to a selective dyeing method used for dyeing a substrate (10), selectively within a first exposed surface portion (S1) of said substrate. For this purpose, the substrate consists of a material (2) that is impervious to a dye with the exception of the first portion of the exposed surface. In particular, the impervious material can form a layer which covers a base portion (3) of the substrate in a second portion (S2) of the exposed surface. The substrate is heated such that the dye (C) penetrates a pervious material (1) which constitutes the first portion of the exposed surface. The method is particularly useful for eliminating light diffused by the walls of a multilayer structure which is supported by means of ocular glass.
    Type: Grant
    Filed: October 15, 2010
    Date of Patent: April 7, 2015
    Assignee: Essilor International (Compagnie Generale d'Optique)
    Inventors: Samuel Archambeau, Jérôme Ballet, Jean-Paul Cano, Stéphane Perrot
  • Patent number: 8709103
    Abstract: A sublimation transfer ink to be discharged by an ink jet process contains water, a sublimation dye, and a trehalose-based compound. The amount of the trehalose-based compound in the sublimation transfer ink is preferably in the range of 3% by mass to 20% by mass, both inclusive.
    Type: Grant
    Filed: February 8, 2013
    Date of Patent: April 29, 2014
    Assignee: Seiko Epson Corporation
    Inventor: Hideki Oguchi
  • Publication number: 20140109324
    Abstract: The invention relates to a transfer paper (4) for use for transferring a print of ink onto a fabric, said transfer paper comprising: i) a base paper (2); ii) an additive (8) comprising a starch component, and a binding agent; wherein said starch component being a starch selected from the group comprising unmodified starch or a modified starch or a mixture thereof; and wherein said binding agent being a binding agent selected from the group comprising: an alkyl ketene dimer, a tall oil/fumaric acid copolymer, a styrene/acrylate copolymer and an alkenyl succinic anhydride and a mixture thereof; wherein said base paper (2) comprises an amount of said additive by being impregnated therewith; and wherein said base paper (2) having a water uptake as defined by a Cobb-45 value of 10-100 g/m2 and a having a Gurley porosity of 10-140 seconds. The present invention furthermore relates to uses of the transfer paper (4).
    Type: Application
    Filed: May 7, 2012
    Publication date: April 24, 2014
    Applicant: Beaver Paper & Graphic Media, Inc
    Inventor: Knud Villefrance Rasmussen
  • Patent number: 8425624
    Abstract: A method of dyeing an object comprising placing a sublimable dye and the object to face each other apart at a predetermined distance of 0.1 mm or more but 10 mm or less under pressure, heating the sublimable dye with a laser to sublimate it toward the object such that the deposition region of the dye is part of a to be dyed region of the object, applying the sublimable dye over the entire to be dyed region of the object by relatively moving the object with respect to the sublimation position of the dye using a moving unit and heating at least a part of the dyed region of the object to fix the dye to the region.
    Type: Grant
    Filed: July 27, 2011
    Date of Patent: April 23, 2013
    Assignee: Nidek Co., Ltd.
    Inventors: Minoru Inuzuka, Atsushi Yano
  • Patent number: 8163038
    Abstract: A low volatile sublimation printing process comprises transferring a sublimation ink solid in an unsublimed form in a desired design by means of, for example, lithographic printing machinery, onto a medium such as paper. The image then is transferred from the medium onto a desired material in which sublimation takes place at the time of transfer onto that desired material. The sublimation ink can have a total volatile content of less than 10%, and preferably may have a total volatile content of less than 5%.
    Type: Grant
    Filed: March 1, 2011
    Date of Patent: April 24, 2012
    Assignee: Superior Printing Ink Co., Inc.
    Inventors: Richard Czarnecki, Mark Finley, Joseph Kissinger, Kenneth Smith
  • Publication number: 20120073063
    Abstract: A method of transferring a dye to a composite material comprising applying the dye to a transfer media to create a colored transfer media, placing the colored transfer media into contact with the composite material, and applying, using an autoclave, at least one of heat, external pressure, vacuum pressure to infuse the dye to the composite material to create a colored composite material.
    Type: Application
    Filed: August 3, 2011
    Publication date: March 29, 2012
    Applicant: CUBIC TECH CORPORATION
    Inventors: Rowland Joseph Downs, Christopher Michael Adams, Jon Michael Holweger
  • Patent number: 8088180
    Abstract: A lens dyeing method comprising the steps of: (a) determining a print area to be formed on a dyeing base body based on information entered to dye a predetermined area of a surface of a lens to be dyed with desired hue and almost uniform color density so that the print area has a diameter larger than that of the lens surface area and the color density of the print area concentrically changes from a central portion to a peripheral portion in a stepwise or linear manner; (b) applying a dyeing ink containing a sublimable dye onto the base body to form the determined print area on one surface of the base body; and (c) placing the base body and the lens so that the print area formed surface and the lens surface area to be dyed face each other in noncontact relation under substantially a vacuum condition, and heating the base body to deposit the dye onto the lens.
    Type: Grant
    Filed: September 27, 2007
    Date of Patent: January 3, 2012
    Assignee: Nidek Co., Ltd.
    Inventors: Minoru Inuzuka, Hirokazu Hyodo
  • Patent number: 8052785
    Abstract: An indaniline dye represented by the following formula (1): wherein R1 and R2 represent an unsubstituted linear or branched alkyl group having from 2 to 5 carbon atoms; R3 represents an unsubstituted linear or branched alkyl group having from 1 to 3 carbon atoms; provided that the total number of the carbon atoms of R1, R2 and R3 is 6 or 7.
    Type: Grant
    Filed: March 28, 2008
    Date of Patent: November 8, 2011
    Assignee: FUJIFILM Corporation
    Inventors: Yoshihiko Fujie, Takashi Hoshimiya, Hisashi Mikoshiba, Naotsugu Muro
  • Patent number: 7988742
    Abstract: The present invention provides a decorative medical covering for the protective wrapping of a skin injury or an orthopedic injury. The decorative medical covering is produced by providing a strip of material of a predetermined length and a predetermined width. The material is composed of a plurality of fibers. An aesthetically pleasing image is stored onto a sublimation transferal medium. The image is transferred from the sublimation transfer medium onto the strip wherein the image is permanently incorporated into the plurality of fibers of the material.
    Type: Grant
    Filed: October 25, 2004
    Date of Patent: August 2, 2011
    Inventors: Celeste Ann Stein, Ben Jay Stein
  • Patent number: 7749287
    Abstract: The present invention refers to a process and to an equipment and machine, which allow the application of digital images to straps, webbings and belts of different kinds and sizes destined to different applications and is achieved in a way to provide the continuous transferring of digital images or a trace to straps, where the straps are manufactured with an ordinary weave or with an special weave to receive a bleaching treatment with an optical white, as well as pass by a thermo-fixation process that creates an alteration at the material properties, enabling, this way, various printings in high quality.
    Type: Grant
    Filed: December 16, 2004
    Date of Patent: July 6, 2010
    Assignee: Beltgroup Do Brasil LTDA
    Inventor: Ricardo Augusto de Lorenzo
  • Publication number: 20080078037
    Abstract: A lens dyeing method comprising the steps of: (a) determining a print area to be formed on a dyeing base body based on information entered to dye a predetermined area of a surface of a lens to be dyed with desired hue and almost uniform color density so that the print area has a diameter larger than that of the lens surface area and the color density of the print area concentrically changes from a central portion to a peripheral portion in a stepwise or linear manner; (b) applying a dyeing ink containing a sublimable dye onto the base body to form the determined print area on one surface of the base body; and (c) placing the base body and the lens so that the print area formed surface and the lens surface area to be dyed face each other in noncontact relation under substantially a vacuum condition, and heating the base body to deposit the dye onto the lens.
    Type: Application
    Filed: September 27, 2007
    Publication date: April 3, 2008
    Applicant: NIDEK CO., LTD.
    Inventors: Minoru Inuzuka, Hirokazu Hyodo
  • Patent number: 6905522
    Abstract: Dye compositions comprising, in a medium suitable for dyeing: at least one first oxidation base chosen from 4,5-diaminopyrazole derivatives of formula (I) and addition salts thereof, at least one second cationic oxidation base chosen from monobenzenic, dibenzenic and heterocyclic oxidation bases, and the addition salts thereof, comprising at least one cationic group Z chosen from aliphatic chains optionally bearing at least one ring chosen from saturated and unsaturated rings; wherein said at least one cationic group Z is linked directly to at least one benzenic ring or to at least one heterocycle of said at least one second cationic oxidation base or linked to at least one amine functional group borne by said at least one benzenic ring or said at least one heterocycle; and at least one coupler; as well as the use of this composition for dyeing keratin fibers and the dying process using this composition.
    Type: Grant
    Filed: February 11, 2003
    Date of Patent: June 14, 2005
    Assignee: L'Oreal S.A.
    Inventors: Sylvain Kravtchenko, Alain Lagrange
  • Patent number: 6793688
    Abstract: A method is described herein for imprinting an image on a soft surface typically embodied in a consumer article. The image is formed using an ink compound comprising ink and aromatic polyisocyanates, to provide improved attachment of the image to the surface using the method described herein. For imprinting a single-color image on a surface, the method typically includes providing the image on heat transfer paper, applying powder to the image, applying heat to the heat transfer paper after applying the powder, positioning the heat transfer paper with the image thereon against the surface, applying heat and pressure to the heat transfer paper against the surface to cause the heat transfer paper with the image thereon to attach to the surface, removing the heat transfer paper from the surface such that the image remains on the surface, and applying heat to the surface after removing the heat transfer paper from the surface.
    Type: Grant
    Filed: January 22, 2002
    Date of Patent: September 21, 2004
    Assignee: Logotec USA, LLC
    Inventors: Timothy G. Tyler, Ryan K. Mizell, Juan M. Figueroa
  • Patent number: 6736863
    Abstract: A dyeing method for dyeing a plastic lens, a plastic lens obtained by use of the dyeing method, and a dyeing system, a dyeing device, and a dyeing jig for a plastic lens are disclosed. The method includes a producing step of producing a print base body on which a print area is printed with a sublimatable dye by a printer under control of a computer, the printer being previously supplied with the dye; a placing step of placing the print base body and a lens to be dyed so that the print area on the base body is brought into nearly close contact with a lens surface to be dyed; and a transferring step of heating at least the print base body to sublimate the sublimatable dye of the print area, thereby transferring the dye to the lens surface to be dyed.
    Type: Grant
    Filed: February 26, 2002
    Date of Patent: May 18, 2004
    Assignee: Nidek Co., Ltd.
    Inventors: Yasuhiro Inagaki, Minoru Inuzuka
  • Patent number: 6221112
    Abstract: A polyester film can be dyed by coating the film with a layer of a dye mixture which is a suspension of at least one disperse dyestuff in a solution of a thickener in water and which has a viscosity of no more than 500 centipoise, preferably 5-50 centipoise, at ambient temperature, followed by heating to cause the dyestuff to migrate from the layer into the film. The coating process is preferably reverse gravure printing. The process can be used to prepare films which contain one or more dyestuffs in one surface region of the film and one or more different dyestuffs, for example an ultraviolet absorber, in the other surface region of the film. The dyed films show good resistance to fading when exposed to light and are useful for example as automobile window films.
    Type: Grant
    Filed: November 2, 1998
    Date of Patent: April 24, 2001
    Assignee: CP Films, Inc.
    Inventor: William Douglas Snider
  • Patent number: 5895505
    Abstract: The present invention relates to a process for printing characters or image with high durability on a fibrous sheet by a dry method, fabrics prepared by said printing process, and an apparatus for preparing said fabrics. The present invention relates to a process for preparing an information-bearing fibrous sheet, comprising the steps of temporarily forming an image such as characters or identification mark on a fibrous sheet by a dye; heating it to let the dye migrate into the fibrous sheet; and pressing another sheet material to the fibrous sheet with the image temporarily formed, with heat treatment for removing the excessive dye. The process of the present invention does not include the step of washing by water and allows dyeing with a sense of OA apparatuses. Therefore, it can be widely applied for clothing, and industrial and fashion fabric goods, etc. and expected to tempt the development of quite new applications.
    Type: Grant
    Filed: January 10, 1994
    Date of Patent: April 20, 1999
    Assignee: Toray Industries, Inc.
    Inventors: Yasumasa Yamamoto, Shiro Imai
  • Patent number: 5580410
    Abstract: A dispersed dye sublimation imaging method of a substrate includes a pre-conditioning step, before the substrate is imaged, which uses controlled heat and humidity. The pre-conditioning step, by raising the surface energy levels of the substrate and thermally stabilizing the substrate before pressured contact in the imaging zone, allows for more precise control of dye sublimation during image. Pre-conditioning also allows: the use of higher temperature dyes; the use of higher temperatures and shorter dwell times in the imaging zone; and/or the use of lower imaging temperatures. The pre-conditioning also provides for greater migration and penetration of the dispersed dye into the surface of the substrate being imaged. The shorter dwell time and thermally stabilized pre-conditioned substrate also reduces movement between the substrate and dye carrier device, which provides for increased resolution of the imaged substrate.
    Type: Grant
    Filed: December 14, 1994
    Date of Patent: December 3, 1996
    Assignee: Delta Technology, Inc.
    Inventor: Kenneth Johnston
  • Patent number: 5571289
    Abstract: Dye donor element for use according to thermal dye sublimation transfer comprising a support having thereon a dye layer comprising at least one heterocyclic hydrazono dye, wherein said dye corresponds to the general formula:A.dbd.N-N.dbd.Hetwherein A is a carbocyclic or heterocyclic coupler group or a cyclic reactive methylene system, which may carry at least one substituent, and Het is a heterocyclic nucleus, which may carry at least one substituent.
    Type: Grant
    Filed: May 23, 1995
    Date of Patent: November 5, 1996
    Assignee: AGFA-Gevaert N.V.
    Inventors: Wilhelmus Janssens, Luc Vanmaele
  • Patent number: 5468258
    Abstract: Dye donor element for use according to thermal dye sublimation transfer comprising a support having thereon a dye layer comprising at least one heterocyclic hydrazono dye, wherein said dye corresponds to the general formula:A=N-N=Hetwherein A is a carbocyclic or heterocyclic coupler group or a cyclic reactive methylene system, which may carry at least one substituent, and Het is a heterocyclic nucleus, which may carry at least one substituent.
    Type: Grant
    Filed: December 17, 1993
    Date of Patent: November 21, 1995
    Assignee: Agfa-Gevaert N.V.
    Inventors: Wilhelmus Janssens, Luc Vanmaele
  • Patent number: 5358537
    Abstract: There is disclosed a process and a composition for dyeing polymeric fibers which have limited dye sites and/or difficult to penetrate chemical structures. Briefly stated, the process comprises the steps of contacting polymeric fibers with a dye composition comprising a disperse dye and a swelling agent. The fibers in contact with said dye composition are then preferably heated to a temperature and for a time sufficient to effect dispersion of a portion of said dye into said polymeric fibers. Subsequently, the fibers are treated to remove residual dye composition.
    Type: Grant
    Filed: September 17, 1991
    Date of Patent: October 25, 1994
    Assignee: Shaw Industries, Inc.
    Inventors: David R. Kelly, Richard Castle, Christopher Bryant
  • Patent number: 5160505
    Abstract: A method and apparatus for the transfer printing of a fabric web is provided. The apparatus includes a supply station for supplying a multi-layered web comprising a web of fabric to be printed and at least one substrate having a surface provided with a sublimation ink, the substrate being disposed in intimate frictional contact with the web of fabric so that the ink-carrying surface thereof is in contact with the web surface to be printed. The apparatus further includes a printing station for maintaining a slight pressure on the multi-layered web and for applying heat thereto to thereby effect the transfer of ink from the substrate to the web of fabric. A receiving station is also provided for separating the multi-layered web into a printed web of fabric and into at least one substrate, and further for collecting the printed web and substrate following the separation thereof.
    Type: Grant
    Filed: August 3, 1990
    Date of Patent: November 3, 1992
    Assignee: Pierre L. P. M. Seveno
    Inventors: Pierre L. P. M. Seveno, Aime M. Lemire
  • Patent number: 5112361
    Abstract: A method of manufacturing a color filter for a liquid crystal cell comprises forming a plurality of patterns, each of a respective dye intermediate material, on a carrier element. The patterns of dye intermediate materials are then brought into contact with a substrate layer, supported on a glass substrate, under the application of heat and pressure. The substrate layer, such as a polyacrylonitrile layer, contains free acid groups which interact with the dye intermediate materials to form the colors of the color filter in the substrate layer. The method permits the actual formation of the colors on the substrate to be effected in a single alignment step, minimizing wastage of the relatively expensive glass substrates. Furthermore, as the dyes providing the colors of the filter are chemically part of the substrate layer, they are very resistant to leaching by the liquid crystal materials.
    Type: Grant
    Filed: January 29, 1991
    Date of Patent: May 12, 1992
    Assignee: Thorn EMI plc
    Inventors: Andrew N. Carrington, Bernard J. Green, Francis Jones, deceased
  • Patent number: 4767420
    Abstract: The transfer sheet or web is intended for the use in a heat transfer printing process of cotton, of cotton-polyester blend or of nitrogen containing textile fibers such as wool, silk or nylon.It comprises on its surface at least one organic impregnating agent which has a melting point between 60.degree. and 230.degree. C. and is no polymer, at least one water insoluble, non-subliming dyestuff, and the minimum amount of a binder. The dyestuff forms a pattern or image which is heat contact printed on said textile substrate without the use of carrier vapors or vacuum. The pattern to be heat transferred may also be prepared in an electrophotographic process using a new toner comprising particles of impregnating agent, binder and dyestuff.The pattern on the transfer support is transferred at a temperature between 160.degree. and 230.degree. C. during 30 to 60 seconds to said textile substrate. The printings obtained have very good light, rubbing and washing fastnesses; the handling is not impaired.
    Type: Grant
    Filed: January 23, 1987
    Date of Patent: August 30, 1988
    Assignee: Sicpa Holding S.A.
    Inventors: Wolfgang Mehl, Albert Amon
  • Patent number: 4764177
    Abstract: A method of making plastics molded articles having patterns of characters and/or symbols on their top and side front faces, wherein, after a transfer sheet having a top face pattern, a front side face pattern and a line of fracture surrounding the front side face pattern has been fixed above a key cap, the top face pattern of the transfer sheet is pressed against and tightly applied to a top face of the key cap by the use of a top pad whereas the front side face pattern of the transfer sheet is pressed against and tightly applied to a front side face while being cut along the line of fracture by the use of a side pad, and a pattern imparting machine convenient for use therein.
    Type: Grant
    Filed: October 27, 1986
    Date of Patent: August 16, 1988
    Assignee: Nissha Printing Co., Ltd.
    Inventors: Takao Sumi, Yoshihide Inako, Masahiro Nishida
  • Patent number: 4693915
    Abstract: A film forming method, a recording medium formed thereby, and a recording method therewith are provided. The recording medium comprises a recording layer constituted of a monomolecular film or monomolecular-layer built-up film of a clathrate complex compound comprised of a host molecule and a guest molecule, said host molecule having a hydrophilic portion, a hydrophobic portion, and a portion capable of enclosing said guest molecule.
    Type: Grant
    Filed: April 18, 1985
    Date of Patent: September 15, 1987
    Assignee: Canon Kabushiki Kaisha
    Inventors: Hiroshi Matsuda, Masahiro Haruta, Yutaka Hirai, Yukuo Nishimura, Ken Eguchi, Takashi Nakagiri
  • Patent number: 4682983
    Abstract: The transfer sheet is used for dry thermal printing of water swellable celluluse fibers with dyestuffs which are insoluble in water of 60.degree. C. The dyestuffs are difficult to evaporate and cannot be used in a conventional heat transfer printing process. They are transferred at 230.degree. C. and a contact pressure of 10.sup.4 -10.sup.6 Pa from a base paper provided with a release coating, to cellulose fibers which have been swollen with water and the swollen state of which has been preserved after drying with a polyglycol. I order to increase the penetration of dyestuffs into the textile structure, it is recommended to lower the air pressure in the transfer area down to a pressure ranging from 1 to 5.times.10.sup.4 Pa.
    Type: Grant
    Filed: March 12, 1986
    Date of Patent: July 28, 1987
    Assignee: Sicpa Holding S.A.
    Inventor: Wolfgang Mehl
  • Patent number: 4668239
    Abstract: A method of applying a dye image to a plastic member and the image bearing member thereby formed. A disperse dye having a melting point which is below the thermal deflection temperature of the plastic of the member and a vaporization point which is above said deflection temperature is applied to a surface of the member in a desired image. The dye bearing plastic is then heated to a temperature which is above the melting point of the dye and below the thermal deflection temperature of the plastic, but which is nevertheless high enough to cause some softening of said plastic. The dye is then permitted to diffuse into the plastic to provide a sharp, clear and durable image thereon.
    Type: Grant
    Filed: September 7, 1984
    Date of Patent: May 26, 1987
    Assignee: K-T, Inc.
    Inventor: David Durand
  • Patent number: 4664670
    Abstract: The transfer sheet or web is intended for the use in a heat transfer printing process of cotton, of cotton-polyester blend or of nitrogen containing textile fibers such as wool, silk or nylon.It comprises on its surface at least one organic impregnating agent which has a melting point between 60.degree. and 230.degree. C. and is no polymer, at least one water insoluble, non-subliming dyestuff, and the minimum amount of a binder. The dyestuff forms a pattern or image which is heat contact printed on said textile substrate without the use of carrier vapors or vacuum. The pattern to be heat transferred may also be prepared in an electrophotographic process using a new toner comprising particles of impregnating agent, binder and dyestuff.The pattern on the transfer support is transferred at a temperature between 160.degree. and 230.degree. C. during 30 to 60 seconds to said textile substrate. The printings obtained have very good light, rubbing and washing fastnesses; the handling is not impaired.
    Type: Grant
    Filed: December 14, 1984
    Date of Patent: May 12, 1987
    Assignee: Sicpa Holding SA
    Inventors: Wolfgang Mehl, Albert Amon
  • Patent number: 4664030
    Abstract: Simultaneous multisurface diffusion printing of indicia into the top and front surfaces of the assembled keys (39) of a keyboard (41) is disclosed. The bottom (29) of a fixture (23) supports a plurality of spring-loaded pedestals (37) for the keys (39) to be imprinted. A locator plate (27) maintains the keys (39) in a fixed position and functions as a heat shield. Positioned above the locator plate (27) is a sheet of transfer paper (61) having an array of reverse image indicia (63) which are located at positions in alignment with the top and front surfaces of the keys (39) to be imprinted. U-shaped incisions (65) allow the portion of the indicia to be imprinted on the front surface of a key to be bent away from the plane of the transfer sheet. Positioned above the locator plate (27) is a printing plate (73) having different shape protrusions (75a and 75b) to impinge on at least the two surfaces of the keys ( 39) to be imprinted.
    Type: Grant
    Filed: September 30, 1985
    Date of Patent: May 12, 1987
    Assignee: Advanced Input Devices, Inc.
    Inventors: Ronald A. Siverson, Jay A. Clark
  • Patent number: 4636223
    Abstract: When silk fabrics, pre-treated with swelling agents, are printed by heat transfer techniques, the fabric will yellow. The invention eliminates yellowing by pre-treating said silk fabrics with a liquid or solid impregnating agent, dissolved or dispersed in water, then drying the fabric, and adding before, during or after the pre-treating an optical brightening agent of the type normally used for polyester.The impregnating agent can alternatively be applied to the fabric in a water-free condition before or during dyestuff transfer, and an optical brightener may be added.It is further contemplated to use easily migrating dyestuffs which are transferred to the fabric at relatively very low temperatures, and to avoid dyestuff migration by pre-treating the silk fabric with solid impregnating agents.All these techniques produce deep and brilliant shades; the prints have excellent fastnesses.
    Type: Grant
    Filed: April 4, 1985
    Date of Patent: January 13, 1987
    Assignee: Sicpa Holding S.A.
    Inventors: Wolfgang Mehl, Albert Amon
  • Patent number: 4619665
    Abstract: Transfer sheets are provided which include a polyethylene imine as a blocking agent and which are useful in the heat transfer dye printing of various materials such as textiles. The polyethylene imine is capable of completely or partially blocking the transfer of sublimable dyes which have been imprinted on the transfer sheet while having no effect on other dyes which also have been imprinted on the transfer sheet. By using such transfer sheets, designs can be printed which are not otherwise obtainable by conventional techniques. The invention further concerns the method of making such sheets, their use in the printing of various materials, and the materials which have been so printed.
    Type: Grant
    Filed: March 11, 1985
    Date of Patent: October 28, 1986
    Assignee: Technographics Printworld, Inc.
    Inventors: Carl E. Sideman, Thomas E. Lewis, Michael T. Nowak
  • Patent number: 4599259
    Abstract: A cover film for a sublimation transfer type hard copy of the present invention is a cover film which is melt bonded by heat on the surface of a hard copy printing paper in which a picture image is formed on the surface thereof by selectively transferring a sublimation dye. The cover film includes a resinous layer containing a metal compound selected from Al, Mg, Ca and Sn. This cover film is capable of producing magenta color of high color saturation by arbitrarily controlling the coloring of reddish dye to be shifted to the blue side and can also protect the surface of the printing paper.Furthermore, the present invention relates to a cover film which is melt bonded by heat on the surface of a hard copy printing paper in which a picture image is formed on the surface thereof by selectively transferring a sublimation dye.
    Type: Grant
    Filed: June 22, 1984
    Date of Patent: July 8, 1986
    Assignee: Sony Corporation
    Inventors: Naotake Kobayashi, Tetsuya Abe, Satoru Shinohara, Yoshio Fujiwara
  • Patent number: 4587155
    Abstract: A method of applying a dye image to a plastic member and the image bearing member thereby formed. A disperse dye having a melting point which is below the thermal deflection temperature of the plastic of the member and a vaporization point which is above said deflection temperature is applied to a surface of the member in a desired image. The dye bearing plastic is then heated to a temperature which is above the melting point of the dye and below the thermal deflection temperature of the plastic, but which is nevertheless high enough to cause some softening of said plastic. The dye is then permitted to diffuse into the plastic to provide a sharp, clear and durable image thereon.
    Type: Grant
    Filed: March 15, 1985
    Date of Patent: May 6, 1986
    Assignee: Raymond Iannetta
    Inventor: David Durand
  • Patent number: 4555427
    Abstract: A heat transferable sheet to be heat transfer printed when used in combination with a heat transfer printing sheet has a receptive layer for receiving a dye transferred from the heat transfer printing sheet upon being heated, the receptive layer comprising first and second regions having respective specific properties.
    Type: Grant
    Filed: July 23, 1984
    Date of Patent: November 26, 1985
    Assignee: Dai Nippon Insatsu Kabushiki Kaisha
    Inventors: Sadanobu Kawasaki, Mineo Yamauchi, Masanori Akada
  • Patent number: 4523922
    Abstract: The viscosity of aqueous printing inks for gravure printing is adjusted by means of partially organophilic gels which contain plastics mixtures of at least one polymer swelling in water and at least one polymer not swelling in water or to an insignificant extent only, in a solvent mixture of at least two hydrophilic organic hydroxy compounds and one hydrophobic organic hydroxy compound. The printing inks prepared with the aid of the thickener mixtures of the invention contain up to 90% of water, and can be handled as textile printing pastes.Gravure printing inks on the basis of such plastics gels containing disperse dyestuffs are suitable for the manufacture of transfer printing paper sheets. Since the thickening system adjusting the viscosity contains aqueous alcohols, if any, and no solvents as usual in transfer printing inks, no special measures have to be taken with respect to flammability and explosion risks.
    Type: Grant
    Filed: April 2, 1984
    Date of Patent: June 18, 1985
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Sienling Ong, Ulrich Karsunky, Helmut Schmidt
  • Patent number: 4505975
    Abstract: In a thermal transfer-type printing method in which an image is formed on printing paper by the selective transfer thereto of disperse dye from a dye carrier of flexible sheet material in response to the selective application of thermal energy to the carrier while in contact with a surface of the printing paper, the latter is comprised of a base of cellulose fibers and resin into which the disperse dye diffuses for producing a clear definition of the image. The resin is desirably polyester or acetyl cellulose either in the form of fibers which are co-mingled with the cellulose fibers in the base of the printing paper, or in the form of a coating on a surface of the paper base.
    Type: Grant
    Filed: July 21, 1982
    Date of Patent: March 19, 1985
    Assignee: Sony Corporation
    Inventor: Osamu Majima
  • Patent number: 4456669
    Abstract: An image forming process comprising steps of arranging on a support member, in accordance with image signals, image forming particles containing dye former which develops its color in reaction with a color developing agent, heat-transferring the dye former from the particles to an image receiving substrate. After the heat-transfer step, the color developing agent is caused to adhere to the dye former heat-transferred on the image receiving substrate to provide colored images.Choice of the image receiving substrate and the color developing agent is expanded. Fogging is not caused, color purity is not lowered, and the other image receiving material is not polluted due to reevaporation of the dye former which is on the image receiving substrate and is not reacted with color developing agent.
    Type: Grant
    Filed: June 15, 1982
    Date of Patent: June 26, 1984
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Keiichi Yubakami, Yuji Takashima, Wataru Shimotsuma
  • Patent number: 4455147
    Abstract: Color yield of the coloration processes for textile and like materials, more especially of sublimable dyes applied by transfer printing, is enhanced by pretreatment of the material by deposition of 1 to 10% surfactant or other amphipathic substance. Preferred substances are cationic, anionic or non-ionic surfactants, which may be applied from aqueous solution at levels of 1 to 10% on the weight of the material. The material is dried before printing. The surfactants can be accompanied by swelling agents, catalysts or cross-linking agents. Preferred dyes for the printing stage are sublimable dyes containing chelatable groups, fibre-reactive groups or cross-linkable groups.
    Type: Grant
    Filed: March 26, 1981
    Date of Patent: June 19, 1984
    Assignees: I.W.S. Nominee Company, Limited, Commonwealth Scientific and Industrial Research Organization
    Inventors: David M. Lewis, Peter R. Brady, Peter G. Cookson, Keith W. Fincher
  • Patent number: 4454279
    Abstract: The viscosity of aqueous printing inks for gravure printing is adjusted by means of partially organophilic gels which contain plastics mixtures of at least one polymer swelling in water and at least one polymer not swelling in water or to an insignificant extent only, in a solvent mixture of at least two hydrophilic organic hydroxy compounds and one hydrophobic organic hydroxy compound. The printing inks prepared with the aid of the thickener mixtures of the invention contain up to 90% of water, and can be handled as textile printing pastes.Gravure printing inks on the basis of such plastics gels containing disperse dyestuffs are suitable for the manufacture of transfer printing paper sheets. Since the thickening system adjusting the viscosity contains aqueous alcohols, if any, and no solvents as usual in transfer printing inks, no special measures have to be taken with respect to flammability and explosion risks.
    Type: Grant
    Filed: August 15, 1983
    Date of Patent: June 12, 1984
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Sienling Ong, Ulrich Karsunky, Helmut Schmidt
  • Patent number: 4452604
    Abstract: The present invention concerns our discovery that decorative sheets and coverings comprising polyvinyl chloride and having substantially non-migratable through-color images may be prepared using cationic dyestuffs. These coverings may be prepared by providing a variety of polyvinyl chloride-containing substrates with image compositions comprising cationic dyestuffs and a suitable binder, and then treating these materials such that the cationic dyestuffs migrate into the substrate. Through-color images are obtained which are substantially non-migrating, even under severe conditions.
    Type: Grant
    Filed: October 11, 1983
    Date of Patent: June 5, 1984
    Assignee: Armstrong World Industries, Inc.
    Inventors: Ronald S. Lenox, Anne L. Schwartz, Moses Sparks, Jr.
  • Patent number: 4424091
    Abstract: A transfer sheet comprising, in laminated combination, a substrate sheet and, provided thereabove, a coloring layer of desired pattern containing a coloring agent possessing heat transferability and a resist layer of a desired pattern containing a metal compound for resist printing and a binder, the metal compound having the capability of causing the coloring layer to lose its heat transferability, either of the coloring layer and the resist layer being nearer than the other to the substrate sheet. Because of the capability of the metal compound, the resist power is very great, whereby ample resist printing effect can be obtained with only an extremely thin resist layer.
    Type: Grant
    Filed: January 28, 1981
    Date of Patent: January 3, 1984
    Assignee: Dai Nippon Insatsu Kabushiki Kaisha
    Inventors: Shogo Mizuno, Takao Suzuki, Sadanobu Kawasaki, Hideichiro Takeda
  • Patent number: 4401692
    Abstract: Transfer-printing supports, which are impregnated or printed with a formulation containing a mixture of a blue disperse dyestuff which sublimes readily and has the formula ##STR1## in which X is hydrogen or halogen, R, R.sup.1 and R.sup.2 denote alkyl with 1 to 4 carbon atoms and R.sup.3 denotes hydrogen or alkyl with 1 to 4 carbon atoms, and yellow to red disperse dyestuffs which sublime readily, give deep and fast black dyeings on polyester materials and polyester mixed materials by the heat transfer-printing process.
    Type: Grant
    Filed: July 31, 1981
    Date of Patent: August 30, 1983
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Rudolf Schickfluss, Manfred Schneider, Claus Schuster
  • Patent number: 4344765
    Abstract: The heat-transfer coloring process using sublimable disperse dyestuffs can be applied on cellulosic materials if these are treated with an aqueous preparation containing a thickening agent and an addition compound of a lower alkylene oxide onto a compound having active hydrogen atoms. If the thickener is a synthetic polymer containing carboxy group the alkylene oxide addition compound can be omitted.
    Type: Grant
    Filed: June 28, 1979
    Date of Patent: August 17, 1982
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Friedrich Reinhardt, Helmut Schmidt
  • Patent number: 4271224
    Abstract: A transfer sheet comprising, in laminated combination, a substrate sheet and, provided thereabove, a coloring layer of desired pattern containing a coloring agent possessing heat transferability and a resist layer of a desired pattern containing a metal compound for resist printing and a binder, the metal compound having the capability of causing the coloring layer to lose its heat transferability, either of the coloring layer and the resist layer being nearer than the other to the substrate sheet. Because of the capability of the metal compound, the resist power is very great, whereby ample resist printing effect can be obtained with only an extremely thin resist layer.
    Type: Grant
    Filed: February 1, 1980
    Date of Patent: June 2, 1981
    Assignee: Dai Nippon Insatsu Kabushiki Kaisha
    Inventors: Shogo Mizuno, Takao Suzuki, Sadanobu Kawasaki, Hideichiro Takeda
  • Patent number: 4269334
    Abstract: There is provided a method of printing and pleating a fabric which comprises folding the fabric into a pleat pattern and then simultaneously forming the pleat and printing the fabric by passing the fabric together with a print paper in contact with at least a portion thereof through a zone heated to a temperature sufficient to cause the print color and/or pattern to be transferred to the fabric while the folds in the fabric are simultaneously made into permanent pleats.
    Type: Grant
    Filed: March 21, 1979
    Date of Patent: May 26, 1981
    Assignee: Roldwest Limited
    Inventor: Edward Chodosh
  • Patent number: 4246331
    Abstract: An electrophotographic developer is composed of particles comprising magnetic cores which are coated with an organic substance and at least one dyestuff which passes into the vapour state at a temperature in the range of from 100.degree. to 220.degree. C. at atmospheric pressure.
    Type: Grant
    Filed: March 5, 1979
    Date of Patent: January 20, 1981
    Assignee: Sublistatic Holding SA
    Inventors: Wolfgang Mehl, Dieter Hendriks