Nontextile, Dyeing Process Or Product, Including Inorganic Fiber Patents (Class 8/506)
  • Patent number: 7431743
    Abstract: The invention relates to a colorant composition comprising humic acid and/or fulvic acid and a water soluble dye. The invention in particular relates to a colorant composition to be used for turf.
    Type: Grant
    Filed: April 1, 2004
    Date of Patent: October 7, 2008
    Assignee: Australian Agricultural Chemicals
    Inventor: Douglas John Hughes
  • Publication number: 20080196176
    Abstract: This invention relates to unsubstituted and polymeric leuco colorants for use as consumer product additives to indicate a product function by color change, to make attractive or distinctive visual effects, or to provide latent or delayed color generation. The colorants may be present in a stable, colorless state and may be transformed to an intense colored state upon exposure to certain physical or chemical changes. Alternatively, the colorants may be transformed from one color to another color upon exposure to certain physical or chemical changes. The colored form of the unsubstituted or polymeric leuco colorant may be transient, since the colorant can revert back to its colorless form or its original color after the physical or chemical activation has been removed or changed. Polymeric leuco colorants are typically comprised of at least two components: at least one leuco chromophore component and at least one polymeric component.
    Type: Application
    Filed: February 6, 2008
    Publication date: August 21, 2008
    Inventors: Eduardo Torres, Patrick D. Moore, Joe Clark
  • Publication number: 20080196177
    Abstract: This invention relates to unsubstituted and polymeric leuco colorants for use as consumer product additives to indicate a product function by color change, to make attractive or distinctive visual effects, or to provide latent or delayed color generation. The colorants may be present in a stable, colorless state and may be transformed to an intense colored state upon exposure to certain physical or chemical changes. Alternatively, the colorants may be transformed from one color to another color upon exposure to certain physical or chemical changes. The colored form of the unsubstituted or polymeric leuco colorant may be transient, since the colorant can revert back to its colorless form or its original color after the physical or chemical activation has been removed or changed. Polymeric leuco colorants are typically comprised of at least two components: at least one leuco chromophore component and at least one polymeric component.
    Type: Application
    Filed: February 6, 2008
    Publication date: August 21, 2008
    Inventors: Patrick D. Moore, Eduardo Torres
  • Publication number: 20080189879
    Abstract: Liquid colorant preparations comprising at least one pigment and at least one dye are useful for coloring cellulose polymer compounds or composites.
    Type: Application
    Filed: April 28, 2006
    Publication date: August 14, 2008
    Applicant: Basf Aktiengesellschaft
    Inventors: Andres Carlos Garcia Espino, Juliane Krusemann, Werner Peter
  • Publication number: 20080184497
    Abstract: The present invention relates to dyes of formula (1) that are soluble in organic solvents, wherein Cat+ is an organic cation, to a process for their preparation and to their use in the production of coloured plastics or polymeric colour particles, printing colorants, printing pastes and printing inks.
    Type: Application
    Filed: December 19, 2005
    Publication date: August 7, 2008
    Inventors: Thomas Ruch, Ursula Luterbacher
  • Patent number: 7387646
    Abstract: The present invention relates to a method of protecting organic material, especially from the pharmaceutical, food and nutrition sectors, from light, which method comprises applying to or incorporating in a carrier material a combination of the dye of formula (1) the dye of formula (2) and a UV absorber and, optionally, further dyes, and positioning the so-treated carrier material between the light source and the organic material to be protected
    Type: Grant
    Filed: December 13, 2004
    Date of Patent: June 17, 2008
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Joachim Jandke
  • Publication number: 20080104776
    Abstract: The present invention relates to a process for the bichromatic or the trichromatic dyeing or printing of hydroxy-group-containing or nitrogen-containing organic substrates with dye mixtures and also to such dye mixtures and hydroxy-group-containing or nitrogen- containing organic substrates dyed or printed therewith.
    Type: Application
    Filed: April 1, 2005
    Publication date: May 8, 2008
    Inventors: Rainer Nusser, Markus Gisler
  • Patent number: 7175675
    Abstract: In the method of the present invention a plastic article (e.g., a molded article of thermoplastic polycarbonate) is immersed at least partially in a dye bath which includes one or more dyes, water, at least one carrier, and at least one diol. The dye bath contains: (i) at least one dye (e.g., a static and/or photochromic dye); (ii) water; (iii) at least one carrier represented by the following general formula I, R—O—(CH2)n—OHI wherein R is a radical selected from linear or branched C1–C18 alkyl, benzyl, benzoyl and phenyl, and n is 2 or 3; and (iv) a diol selected from at least one of linear or branched C2–C20 aliphatic diols, poly(C2–C4 alkylene glycol), cycloaliphatic diols having from 5 to 8 carbon atoms in the cyclic ring, monocyclic aromatic diols, bisphenols and hydrogenated bisphenols. In an embodiment of the present invention, the carrier is ethyleneglycol butyl ether, and the diol is diethylene glycol.
    Type: Grant
    Filed: December 11, 2003
    Date of Patent: February 13, 2007
    Assignee: Bayer MaterialScience LLC
    Inventors: Robert A. Pyles, Rick L. Archey, David M. Derikart
  • Patent number: 7077874
    Abstract: The purpose of the present invention is to provide an ink for dyeing a plastic lens, capable of favorably dyeing the plastic lens by a vapor transfer dyeing method, and a method of dyeing a plastic lens by using the ink. In the present invention, an ink for dyeing a plastic lens, the ink being applied by an ink jet printer, sublimated in vacuum and deposited on the plastic lens to dye the lens, wherein the ink includes at least one sublimatable disperse dye of an anthraquinone dye, a quinophthalone dye, and an azo dye of thiazole type.
    Type: Grant
    Filed: March 6, 2002
    Date of Patent: July 18, 2006
    Assignee: Nidek Co., Ltd.
    Inventor: Minoru Inuzuka
  • Patent number: 7029502
    Abstract: The present invention relates to an azo dye of formula wherein D is the radical of a diazo component of the benzene, naphthalene, diphenyl, thiophene, benzothiazole, benzisothiazole, thiadiazole, indazole, benzotriazole, pyrazole, anthraquinone, naphthalic acid imide, chromone, phthalimide or diphenylene oxide series, R1 is an unsubstituted or substituted aryl radical and R2 is an unsubstituted or substituted aryl radical, with the exception of the compounds of formulae (1a) and (1b) to a process for its preparation and to its use in a process for the production of mass-colored plastics or polymeric color particles, and in the dyeing or printing of semi-synthetic or synthetic hydrophobic fiber materials.
    Type: Grant
    Filed: January 18, 2002
    Date of Patent: April 18, 2006
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Antoine Clément, Anton Andreoli, Urs Lauk, Athanassios Tzikas
  • Patent number: 7018430
    Abstract: The present invention relates to a method of mass-coloring synthetic materials, which comprises using at least one pigment dye of formula (1) wherein R and R1 together form a phenyl or heteroaryl radical and R2 is hydrogen, or R1 and R2 together form a phenyl or heteroaryl radical and R is hydrogen, and the rings A and B may each independently of the other be substituted by C1-C4?alkyl, C1–C4alkoxy, halogen, —COOR3, —CONHR4 and/or by —SR5, wherein R3, R4 and R5 are each independently of the others hydrogen, C1–C4alkyl, C6–C12aryl or heteroaryl, to synthetic materials colored with such pigment dyes, and to novel pigment dyes of formula (3), wherein R6 is hydrogen or bromine
    Type: Grant
    Filed: July 18, 2002
    Date of Patent: March 28, 2006
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Jean-Marie Adam, Jean-Pierre Bacher
  • Patent number: 6994736
    Abstract: Use of pigments according to formula (I) wherein the substituents have the meanings as defined in claim 1 for dyeing semisynthetic or synthetic hydrophobic fiber materials in aqueous media as well as semisynthetic or synthetic hydrophobic fiber materials dyed with such pigments.
    Type: Grant
    Filed: January 21, 2002
    Date of Patent: February 7, 2006
    Assignee: Clariant Finance (BVI) Limited
    Inventor: Helmut Sieber
  • Patent number: 6994735
    Abstract: A process for tinting a molded article is disclosed. The process entails applying by spraying or by flow coating a hot, dye-solution onto at least a portion of the surface of a molded article to obtain a tinted article and washing the tinted article. In addition to the dissolved dye, the dye solution that is substantially free of particulate matter contains an aqueous solution of a carrier and an optional emulsifier. The article is one molded of a thermoplastic molding composition. In an embodiment of the invention, the dye solution is prepared by filtering a hot aqueous solution through a bag filter that contains a dye to obtain a hot, dye-solution. In a further embodiment, activated carbon is used to purify the dye solution to obtain a dye-free aqueous solution.
    Type: Grant
    Filed: May 8, 2003
    Date of Patent: February 7, 2006
    Assignee: Bayer Materialscience LLC
    Inventors: Robert A. Pyles, David M. Derikart, Rick L. Archey, Michael Nikolakopoulos
  • Patent number: 6964689
    Abstract: The present invention relates to anthraquinone dyes of the formula (I) where R1 is hydrogen, R2 is hydrogen or CO—C2C6alkyl moiety may be substituted by carboxyl, or is (II) wherein R6 is hydrogen, C1-C4alkyl, hydroxyl, carboxyl or halogen, R7 is hygrogen, C1-C4alkyl or halogen and R8 is hydrogen or C2-C3alkyl or when R4 is halogen R8 ? may be methyl or halogen R3 is hydrogen or halogen, R4 is hydrogen or halogen and n is (0), (1) or (2), with the proviso that R3, R4, R6, R7 and R8 are not all hydrogen at one and the same time, processes for their preparation and their use for dyeing or printing hydrophobic fiber materials or for preparing colored plastics or polymeric color particles.
    Type: Grant
    Filed: December 13, 2001
    Date of Patent: November 15, 2005
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Peter Sutter, Peter Aeschlimann
  • Patent number: 6949127
    Abstract: A process of dyeing a molded article is disclosed. The process entails immersing at least a portion of the article in a dyeing bath, retaining the portion in the bath for a period of time sufficient to allow an amount of dye to diffuse into the article, and removing said article from the bath. The molded article comprises a polymeric resin such as (co)polyester, (co)polycarbonates, acrylonitrile-butadiene-styrene, polyamide, polyurethane, polyalkyl(meth)-acrylate, allyldiglycol carbonate and styrene copolymers. The dyeing bath contains in addition to dye, water, a plasticizing agent and a leveling agent.
    Type: Grant
    Filed: March 9, 2004
    Date of Patent: September 27, 2005
    Assignee: Bayer MaterialScience LLC
    Inventors: Robert A. Pyles, Rick L. Archey
  • Patent number: 6942705
    Abstract: The invention provides a method of effectively dyeing a thermoplastic resin plastic lens in any desired color tone and density as well as a colored plastic lens made by the method. The method involves dipping a thermoplastic resin plastic lens in a dyeing liquid containing one or more disperse dyes and one or more monocyclic monoterpenes.
    Type: Grant
    Filed: March 21, 2003
    Date of Patent: September 13, 2005
    Assignee: Hoya Corporation
    Inventors: Kazuo Inoue, Misa Mishna, Masahiro Nakagawa
  • Patent number: 6929368
    Abstract: The method comprises: a) placing in contact at least one principal surface of the colourless articles of the set with a solution of a fluorescent material for a sufficient time to allow penetration of the fluorescent material under the principal surface of the article; b) irradiation of the impregnated articles by means of radiation which activates the fluorescence of the fluorescent material; and c) selection of the articles in the set into two sub-sets of which the first is composed of those articles of the set which show a homogeneous fluorescence of their principal surfaces under irradiation and the second is composed of those articles of the set which show a non-homogeneous fluorescence of their principal surfaces under irradiation. Application: to opthalmic lenses.
    Type: Grant
    Filed: October 5, 2001
    Date of Patent: August 16, 2005
    Assignee: Essilor International Compagnie Generale d'Optique
    Inventors: Gilles Massey, Jean-Claude Dauguet
  • Patent number: 6923836
    Abstract: The present application relates to a process for preparing dyed plastics or polymeric dye particles characterized in that it comprises mixing a high molecular weight organic material with a coloristically effective amount of at least one dye of the formula where R1 is hydrogen, hydroxyl or a radical —NHCO—R6, where R6 is C1-C6alkyl or unsubstituted or C1-C4alkyl- or halogen-substituted phenyl, R2 is hydrogen, hydroxyl or a radical W—R7, where W is —NHCO— or —S— and R7 is C1-C6alkyl or unsubstituted or C1-C4alkyl- or halogen-substituted phenyl, R3 is hydrogen, R4 is hydrogen or hydroxyl, R5 is hydrogen, or R3 and R4 combine to form the radical of the formula, where the rings A and B may independently bear further substituents.
    Type: Grant
    Filed: December 13, 2001
    Date of Patent: August 2, 2005
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Rainer Hildebrand, Peter Sutter
  • Patent number: 6911055
    Abstract: The invention concerns a method which comprises irradiating at least one face of an article with UV radiation, causing the article to be photodegraded over a thickness of at least 1 ?m and contacting the irradiated face of the article with a coloring agent, so as to diffuse the coloring agent in the entire thickness of the photodegraded surface layer of the article. The invention is useful for optical and ophthalmologic articles.
    Type: Grant
    Filed: May 12, 2004
    Date of Patent: June 28, 2005
    Assignee: Essilor International Compagnie General d'Optique
    Inventor: Gilles Baillet
  • Patent number: 6897413
    Abstract: A device that utilizes an improved method to heat dyes to color plastic lenses and filters.
    Type: Grant
    Filed: March 29, 2004
    Date of Patent: May 24, 2005
    Assignee: Brain Power Incorporated
    Inventor: Herbert A. Wertheim
  • Patent number: 6893472
    Abstract: The present invention relates to a process for dyeing or printing manufactured natural polymer or synthetic hydrophobic fiber materials, characterized in that it comprises using dyes of the formula (I), where R1 is hydrogen, hydroxyl or a radical —NHCO—R6, where R6 is C1-C6alkyl or unsubstituted or C1-C4alkyl- or halogen-substituted phenyl, R2 is hydrogen, hydroxyl or a radical W—R7, where W is —NHCO— or —S— and R7 is C1C6alkyl or unsubstituted or C1-C4alkyl- or halogen-substituted phenyl, R3 is hydrogen, R4 is hydrogen or hydroxyl, R5 is hydrogen, halogen, methoxy, phenoxy or phenylthio, or R3 and R4 combine to form the radical of the formula (II), where the rings A and B may independently bear further substituents, to the use of these dyes for trichromatic dyeing of manufactured natural polymer or synthetic hydrophobic fiber materials and mass dyeing of plastics materials and to producing solid on-tone combinations of plastics material and manufactured natural polymer or synthetic fiber material.
    Type: Grant
    Filed: December 13, 2001
    Date of Patent: May 17, 2005
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Rainer Hildebrand, Peter Sutter
  • Patent number: 6840621
    Abstract: A dyeing system for a lens includes a color measuring device (1) for measuring a color of a colored lens (4a, 4b) used as a sample lens to obtain color data thereof; a determination unit (50) for determining data for dyeing based on the obtained color data; a printer (60) for applying dyes to a base substrate (61) to be used for dyeing; a control part (51) for controlling the printer (60) to adjust application amounts of dyes onto the base substrate (61) based on the determined dyeing data.
    Type: Grant
    Filed: September 25, 2002
    Date of Patent: January 11, 2005
    Assignee: Nidek Co., Ltd.
    Inventor: Minoru Inuzuka
  • Patent number: 6797016
    Abstract: Concentrated dye compositions (P) which are solutions of y % by weight of at least one anionic dye (A) in a solution of x % by weight of benzyl alcohol (B) in water, and z % by weight of at least one formulation additive (F), in which x is a number in the range from 0.5 to 4, y is a number in the range from 5 to 35 and z is a number in the range from 0 to 2, and are essentially free from alcohols other than (B) and from solvents or solubilizers other than water and (B) are distinguished by their surprisingly good stability and can be used for any desired dyeing methods for which the respective dyes (A) themselves can be employed, be it for the dyeing of fibre material or be it, in particular, for the coloring of non-fibrous substrates.
    Type: Grant
    Filed: May 17, 2002
    Date of Patent: September 28, 2004
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Georg Schöfberger, Klaus Körte, Jürgen Geiwiz
  • Publication number: 20040123403
    Abstract: The present invention relates to pyrifone azo dyes of formula (1), wherein A is the radical of a diazo component of the benzene, naphthalene, diphenyl, azobenzene, thiophene, benzothiazole, benzoisothiazole, thiadiazole, indazole, benzotriazole, pyrazole, anthraquinone, naphttholic acid imide, chromone, phthalimide or diphenylene oxide series, R1 is hydrogen, unsubstituted or hydroxyl- or phenyl-substituted C1-C6alkyl, it being possible for the alkyl chain to be interrupted from C3 upwards by one or more oxygen atoms, or has the meanings of R2, R2 is a radical of formulae (2), (3), (4), (5), (6), or (7), wherein B is a bridging member, R4 is alkyl or aryl, R5 and R6 are each independently of the other alkyl, aryl or heteroaryl and A is as defined for formula (1), or R1 and R2 toghether with the nitrogen atom in NR1R2 form a heterocyclic ring, Y is cyano, —CONH2 or CH2SO3H, and n is an integer from 2 to 6, to a process for their preparation and to their use in the production coloured plastics or polymeri
    Type: Application
    Filed: September 5, 2003
    Publication date: July 1, 2004
    Inventors: Athanassions Tzikas, Urs Lauk, Romeo Dreier, Antoine Clement
  • Publication number: 20040123404
    Abstract: The present invention is a thickened dye composition and method of applying same to a paper web that produces colored or patterned paper having good bleed resistance. The dye composition of the invention includes a binder; a dye; a thickener selected from the group consisting of polyvinylpyrrolidone homopolymers, polyvinylpyrrolidone copolymers, and mixtures thereof, and water. The present invention also includes colored or patterned papers prepared using this dye composition.
    Type: Application
    Filed: December 15, 2003
    Publication date: July 1, 2004
    Inventors: James A. Deckers, Stephen S. Jose, Michael T. Jennings
  • Patent number: 6749646
    Abstract: A process for tinting of articles molded from a polymeric resin is disclosed. Preferably, the article is molded from polycarbonate and the process entails immersing the molded article in a dye bath that contains water, dye, a carrier and an optional surfactant. The carrier is a compound conforming to R1[—O—(CH2)n]mOR2  (i) wherein R1 and R2 independently denote H or C1-18 alkyl, benzyl, benzoyl or phenyl radical which may be substituted in the aromatic ring by alkyl and or halogen, preferably R1=butyl, R2=H, n is 2 or 3 and m is 2 to 35. The method is especially useful in the manufacture of tinted lenses.
    Type: Grant
    Filed: November 7, 2001
    Date of Patent: June 15, 2004
    Assignee: Bayer Polymers LLC
    Inventors: Robert A. Pyles, Rick L. Archey
  • Publication number: 20040107517
    Abstract: The present invention refers to dyestuffs of the formula I 1
    Type: Application
    Filed: July 1, 2003
    Publication date: June 10, 2004
    Inventors: Warren James Ebenezer, Werner Russ
  • Patent number: 6736863
    Abstract: A dyeing method for dyeing a plastic lens, a plastic lens obtained by use of the dyeing method, and a dyeing system, a dyeing device, and a dyeing jig for a plastic lens are disclosed. The method includes a producing step of producing a print base body on which a print area is printed with a sublimatable dye by a printer under control of a computer, the printer being previously supplied with the dye; a placing step of placing the print base body and a lens to be dyed so that the print area on the base body is brought into nearly close contact with a lens surface to be dyed; and a transferring step of heating at least the print base body to sublimate the sublimatable dye of the print area, thereby transferring the dye to the lens surface to be dyed.
    Type: Grant
    Filed: February 26, 2002
    Date of Patent: May 18, 2004
    Assignee: Nidek Co., Ltd.
    Inventors: Yasuhiro Inagaki, Minoru Inuzuka
  • Patent number: 6733543
    Abstract: A process of dyeing a molded article is disclosed. The process entails immersing at least a portion of the article in a dyeing bath, retaining the portion in the bath for a period of time sufficient to allow an amount of dye to diffuse into the article, and removing said article from the bath. The molded article comprises a polymeric resin such as (co)polyester, (co)polycarbonates, acrylonitrile-butadiene-styrene, polyamide, polyurethane, polyalkyl(meth)acrylate, allyldiglycol carbonate and styrene copolymers. The dyeing bath contains in addition to dye, water, a plasticizing agent and a leveling agent.
    Type: Grant
    Filed: March 26, 2002
    Date of Patent: May 11, 2004
    Assignee: Bayer Polymers LLC
    Inventors: Robert A. Pyles, Rick L. Archey
  • Publication number: 20040074017
    Abstract: The invention relates to a process for protecting reduction-sensitive dyes in the course of dyeing or printing fiber materials with dyes using a compound of the formula (I) or a mixture thereof 1
    Type: Application
    Filed: August 8, 2003
    Publication date: April 22, 2004
    Inventor: Martin Stumpf
  • Patent number: 6699976
    Abstract: A polyazo compound or salt thereof covering the region of from 500 to 580 nm and manifesting high initial polarization ability and represented by the following formulae (I) or (II): wherein, A represents a phenyl having sulfo and/or carboxyl and optionally having a lower alkyl or lower alkoxy, or a naphthyl having 1 to 3 sulfos, R1 to R6 represent hydrogen, lower alkyl or alkoxy, m and n each independently represent 0 or 1, R7 represents hydrogen or sulfo, D and E each independently represents —NHCO— or —N═N—, G represents —CH2—, alkylene having 2-4 carbon atoms, phenylene or —CH═CH—, and R8 represents sulfo, carboxyl or lower alkoxycarbonyl; is provided.
    Type: Grant
    Filed: July 5, 2002
    Date of Patent: March 2, 2004
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Toru Ashida, Yoshiteru Ohta, Narutoshi Hayashi
  • Publication number: 20040034949
    Abstract: A process for producing a colouring agent (masterbatch) for colouring a polymer is provided, comprising the step of mixing a plastics material, carbon black and waste print powder. The maximum proportion of waste print powder is preferably 50%. The process enables waste print powder to be recycled in a useful manner, thereby addressing the environmental problem of waste print powder pollution.
    Type: Application
    Filed: April 3, 2003
    Publication date: February 26, 2004
    Inventors: George Leopold Archer, John Stewart Holmes, Neville Hugh McKay
  • Patent number: 6696553
    Abstract: Water-soluble dyes of the formula in which R1 is hydrogen, hydroxyl, C1-4-alkyl, C1-4-alkoxy, halogen or SO3M, R2 is hydrogen, C1-4-alkyl or C3-6-cycloalkyl, B is the radical of a carbocyclic, heterocyclic or methylene-active non-cyclic coupling component having at least two optionally fused carbocyclic rings, and M is hydrogen or a non-chromophoric cation, the ring A has no further substituents or is substituted with from one to four of the following substituents: C1-4-alkyl, C1-4-alkoxy, halogen, —NO2, —COOM and, —SO3M, and the group —N═N—B is bonded to position 3 or 4 of the ring A, with the proviso that the molecule contains at least two —SO3M groups, are suitable for dyeing or colouring non-fibrous substrates, in particular anodized aluminium or water-soluble plastic compositions.
    Type: Grant
    Filed: November 16, 2001
    Date of Patent: February 24, 2004
    Assignee: Clariant Finance (BVI) Limited
    Inventor: Klaus Körte
  • Patent number: 6669338
    Abstract: The method of using a tablet or coated tablet to introduce tint concentrate, UV absorbers, decolorant, conditioner and other optical chemistry into the dyebaths used for tinting plastic ophthalmic non-contact spectacle lenses and optical filters.
    Type: Grant
    Filed: January 15, 2002
    Date of Patent: December 30, 2003
    Assignee: Brain Power Incorporated
    Inventors: Herbert A. Wertheim, William F. Moore
  • Patent number: 6656231
    Abstract: A dyeing method of dyeing a plastic lens includes: a step of placing the lens in a predetermined position in a vacuum vapor-deposition device; a step of placing a base body to be used for a dyeing operation in the vapor-deposition device, the base body being applied with dyeing solutions each containing a dissolved or fine-grained dispersed sublimatable dye to form a dye application area on the base body, and the base body being arranged so that the dye application area faces the lens without contact therewith; a step of heating the base body under vacuum in the vapor-deposition device, thereby sublimating the dye of the dye application area to vapor-deposit the sublimated dye on the lens; and a step of heating the lens on which the dye has been vapor-deposited at changing heating temperatures, thereby fixing the dye on the lens.
    Type: Grant
    Filed: January 29, 2001
    Date of Patent: December 2, 2003
    Assignee: Nidek Co., Ltd.
    Inventor: Minoru Inuzuka
  • Patent number: 6652602
    Abstract: A process for the continuous dyeing of plastic films, such as polyethylene terephthalate, is characterized by passing the film through a dye bath comprised of dye stuffs dissolved, suspended or dispersed in a liquid carrier comprised at least in part of a polymer, preferably a polyol, having at least one free hydroxyl group and a molecular weight within the range of from about 200 to about 600. The hydrogen bonding provided by the hydroxyl group, together with the high molecular weight and high boiling point of the polyol, mitigate against migration of the dye stuff out of the film, i.e., fading of the film, and impart long lasting color fastness to the film. Rapid diffusion of the dye bath into the film is enhanced by thermal and ultrasonic energization of the bath.
    Type: Grant
    Filed: December 21, 2001
    Date of Patent: November 25, 2003
    Assignee: N.V. Bekaert S.A.
    Inventors: Xiaoming Yang, Raymond B. Turner
  • Patent number: 6641621
    Abstract: A method has been disclosed for preparing a co-precipitated microcrystalline dye dispersion, the absorption spectrum of which exceeds the summoned spectra of individually dispersed dyes, which comprises, as consecutive preparation steps: adding to one vessel, an amount of at least one pentamethine oxonol-type barbituric acid filter dye having ionizable sites in its molecular structure; adding thereto an aqueous alkaline solution in an amount sufficient to completely dissolve the said filter dye while stirring the solution thus formed; adding in another vessel, to an amount of at least one pyrrole type filter dye, an amount of water, followed by adding of an aqueous alkaline solution and a surfactant; followed, after having completely dissolved (under stirring conditions) the said pyrrole type filter dye, by adding to the solution thus formed in the other vessel, the solution formed in the one vessel; adding an aqueous acidic solution up to a pH of less than 3.
    Type: Grant
    Filed: March 4, 2002
    Date of Patent: November 4, 2003
    Assignee: Agfa-Gevaert
    Inventors: Kris Viaene, Jan Gilleir, Geert De Roover
  • Publication number: 20030182737
    Abstract: The invention provides a method of effectively dyeing a thermoplastic resin plastic lens in any desired color tone and density as well as a colored plastic lens made by the method. The method involves dipping a thermoplastic resin plastic lens in a dyeing liquid containing one or more disperse dyes and one or more monocyclic monoterpenes.
    Type: Application
    Filed: March 21, 2003
    Publication date: October 2, 2003
    Applicant: HOYA CORPORATION
    Inventors: Kazuo Inoue, Misa Mishina, Masahiro Nakagawa
  • Patent number: 6620931
    Abstract: Process for phase conversion of a methyl-substituted, benzimidazolone-fused dioxazine pigment of composition C22H12Cl2N6O4 having the formula (1) or of an isomer or tautomer thereof, which comprises treating the pigment of formula (1) with certain organic solvents. In the course of this phase conversion, 4 novel crystal polymorphs are formed which are called phases II, IV, V and VI and are characterized by means of their X-ray powder diagrams. The novel polymorphs are of low solubility and feature good fastness properties and violet colorations. The novel crystal polymorphs are suitable for pigmenting coating materials, plastics, printing inks, aqueous or solvent-based pigment preparations, electrophotographic toners and developers, powder coating materials, inks, preferably inkjet inks, and color filters, and for coloring seed.
    Type: Grant
    Filed: October 22, 2001
    Date of Patent: September 16, 2003
    Assignee: Clariant GmbH
    Inventors: Martin U. Schmidt, Peter Kempter, Roland Born
  • Publication number: 20030110580
    Abstract: A process for dyeing certain textile fibers, utilizing vat acid dyeing and specific additional (second) reducing agents such as &agr;-hydroxyalkylsulfinic acids, their salts and 1,2,4-trithiolane, resulting in excellent depth of shade and washfastness, is provided.
    Type: Application
    Filed: August 20, 2002
    Publication date: June 19, 2003
    Inventors: Stephen M. Burkinshaw, Samit N. Chevli, Michael O. Hunt, Lee D. Jones, David M. Lewis, David J. Marfell
  • Patent number: 6554873
    Abstract: A dyeing method of dyeing a plastic lens includes: a step of placing the lens in a predetermined position in a vacuum vapor-deposition device; a step of placing base bodies to be used for a dyeing operation in the vapor-deposition device, each of the base bodies being applied with dyeing solutions each containing a dissolved or fine-grained dispersed sublimatable dye to form a dye application area on each base body, and the base bodies being arranged in opposite positions to each other with respect to the lens so that the dye application area faces each surface of the lens without contact therewith; and a step of heating the base bodies by heat sources under vacuum in the vapor-deposition device, thereby sublimating the dye of the dye application areas to vapor-deposit the sublimated dye on the lens.
    Type: Grant
    Filed: January 29, 2001
    Date of Patent: April 29, 2003
    Assignee: Nipek Co., Ltd.
    Inventors: Minoru Inuzuka, Masanori Uetani
  • Publication number: 20030070927
    Abstract: Methods and reagents for fluorescent analysis of serum proteins separated by electrophoresis. This assay allows for the immediate quantitation of resolved proteins in biological materials. The electrophoresed sample is treated with a fixative composition and stained using an ANS-based stain solution. No pre-stain washing or post-stain washing and drying is required. The fluorescent serum protein assay allows for automation of serum protein analyses.
    Type: Application
    Filed: September 20, 2002
    Publication date: April 17, 2003
    Inventors: Mark E. Merchant, Philip A. Guadagno, Debra Linn Hicks, Suzan Sha Robinson
  • Patent number: 6533825
    Abstract: Dibenzonaphthyrone of formula (I) wherein A1 and A2 independently of each other are unsubstituted or mono- to tetra-substituted o-C6-C18arylene, with the proviso that formula (I) does not represent a dibenzonaphthyrone of the formula The invention further relates to processes for the preparation thereof, to the use thereof for colouring/pigmenting high-molecular-weight organic material and to substance compositions comprising dibenzonaphthyrones.
    Type: Grant
    Filed: June 13, 2001
    Date of Patent: March 18, 2003
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Peter Nesvadba, Joachim Jandke
  • Patent number: 6515123
    Abstract: The invention is directed to carbamate group containing non chloranil based triphendioxazine compounds useful as pigments which are readily convertible into the corresponding triphendioxazine pigments without carbamate.
    Type: Grant
    Filed: February 9, 2001
    Date of Patent: February 4, 2003
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Bansi Lal Kaul, Bruno Piastra, Pascal Steffanut
  • Patent number: 6512115
    Abstract: The invention relates to a process for preparing triphendioxazine compounds by cyclizing the intermediates (IV) in the presence of manganese oxide and sulfuric acid to form compounds of the general formula (I) a process for condensing compounds of the general formula (II) with compounds of the general formula (III) to form the chlorine-free intermediates (IV) and also compounds of the general formula (IV).
    Type: Grant
    Filed: March 6, 2001
    Date of Patent: January 28, 2003
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Bansi Lal Kaul, Bruno Piastra, Pascal Steffanut
  • Publication number: 20030000028
    Abstract: The invention provides a colorant for use in tinting contact lenses in which the binding polymer used is capable of forming an interpenetrating polymer network with the lens material. When the colorants of the invention are applied to uncured lens material that is subsequently cured, the binding polymer forms an interpenetrating polymer network with the lens material embedding the colorant within the lens material resulting in a stable, tinted lens.
    Type: Application
    Filed: December 20, 2001
    Publication date: January 2, 2003
    Inventors: Frank F. Molock, Khaled Chehab, James D. Ford, Ture Kindt-Larsen, Craig W. Walker, Joe M. Wood, Julieann E. Weber, Gary L. Collins
  • Patent number: 6464733
    Abstract: Plastic articles, especially plastic optical lenses are tinted by immersing the plastic article in an aqueous dispersion of tinting agent and exposing the dispersion and immersed article to microwave radiation to bring the dispersion to ebullition; the ebullition is maintained for at least 2 seconds with transfer of tinting agent from the dispersion to the article to tint the article; the tinted article is removed from the dispersion and rinsed with water. The method achieves tinting in significantly shorter times than conventional methods and employs water-based dispersions thereby avoiding emission of vapors of organic solvents.
    Type: Grant
    Filed: February 23, 2001
    Date of Patent: October 15, 2002
    Inventor: Christophe U. Ryser
  • Patent number: 6454975
    Abstract: Bulk yarns having improved elasticity and recovery and methods for their manufacture are described. A first embodiment of the invention involves providing a solution-dyed multifilament yarn of polybutylene terephthalate (PBT) and a multifilament yarn of a second thermoplastic polymer to an air jet texturizer such that the PBT component forms a core and the other yarn forms a plurality of loops and coils extending outwardly from the core. In addition to a high degree of elasticity and recovery, the composite yarn also has a low amount of shrinkage, which enables the yarns to be used in the production of woven fabrics without significant losses in fabric yield. Another embodiment of the invention involves false twisting a multifilament PBT yarn and a second multifilament yarn as individual threadlines to impart crimp thereto, then entangling the two components together using an air interlacing jet, to produce a bulk yarn having high elasticity and recovery.
    Type: Grant
    Filed: May 31, 2000
    Date of Patent: September 24, 2002
    Assignee: O'Mara Incorporated
    Inventors: J. Joseph O'Mara, Jr., Anthony Nesbitt Dotson
  • Patent number: 6375865
    Abstract: Substantially transparent compositions that block electric-arc energy. A process of making the compositions comprise blending an IR/optical dye with a substrate material and subjecting the blend to curing conditions. Products manufactured from the composition ablate upon impact of electric-arc energy.
    Type: Grant
    Filed: August 11, 1999
    Date of Patent: April 23, 2002
    Assignee: Paulson Manufacturing Corporation
    Inventors: Roy Victor Paulson, Elihu Hoagland, IV
  • Publication number: 20020040511
    Abstract: Plastic articles, especially plastic optical lenses are tinted by immersing the plastic article in an aqueous dispersion of tinting agent and exposing the dispersion and immersed article to microwave radiation to bring the dispersion to ebullition; the ebullition is maintained for at least 2 seconds with transfer of tinting agent from the dispersion to the article to tint the article; the tinted article is removed from the dispersion and rinsed with water. The method achieves tinting in significantly shorter times than conventional methods and employs water-based dispersions thereby avoiding emission of vapors of organic solvents.
    Type: Application
    Filed: February 23, 2001
    Publication date: April 11, 2002
    Inventor: Christophe U. Ryser