Acrylate Polymer Substrate Patents (Class 8/509)
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Patent number: 5142722Abstract: A process for applying images by transfer printing disperse dyes onto furniture end pieces, especially end pieces for use in juvenile furniture. In one preferred embodiment the end piece board is first coated with a pigmented non-polyester base coat which is applied with rollers and conventionally cured. The board is then coated with a 100% polyester clear top coat which is also applied with rollers and UV cured. In a second preferred embodiment the board is coated with a pigmented polyester base coat which is either sprayed or roll coated and which may be either conventionally or UV cured. Finally a sublimation decal is transfer printed into the polyester coating using a press having heated platens and operated at about 400.degree. F. and at between 8-30 psi for between 20-40 seconds. For larger boards, a silicone pad may be attached to the upper platen of the heat press adjacent to the surface of the platen which contacts the transfer printing decal to improve image transfer for uneven presses.Type: GrantFiled: February 27, 1991Date of Patent: September 1, 1992Assignee: Rosalco, Inc.Inventor: Kenneth W. Kolb
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Patent number: 5124071Abstract: Microscopic, neutrally buoyant particles containing fluorescing compounds used for tracers of large scale turbulent flows. The particles are generated by dissolving acrylics in a solvent and mixing the solution with fluorescing dyes. This mixture is sprayed into a heated chamber where the solvent evaporates, and the solid acrylic with the imbedded dye settles on the bottom of the chamber. The dust is collected, and the particles are separated according to size using a filter. Dye residue on the particles' surface is washed leaving the dye imbedded within the particles. The particles are then used within flow fields.Type: GrantFiled: September 20, 1990Date of Patent: June 23, 1992Inventor: Joseph Katz
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Patent number: 5116884Abstract: A hydrophilic contact lens is disclosed incorporating melanin that protects the eye from harmful radiation and superoxide.Type: GrantFiled: February 16, 1990Date of Patent: May 26, 1992Assignee: Photoprotective Technology IncorporatedInventor: James M. Gallas
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Patent number: 5112883Abstract: The present invention is directed to a medium incorporating melanin for radiation protection.Type: GrantFiled: November 9, 1990Date of Patent: May 12, 1992Assignee: Photoprotective Technologies IncorporatedInventor: James M. Gallas
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Patent number: 5047447Abstract: The present invention is directed to a medium incorporating melanin for radiation protection.Type: GrantFiled: December 20, 1989Date of Patent: September 10, 1991Assignee: Photoprotecive Technologies IncorporatedInventor: James M. Gallas
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Patent number: 5036115Abstract: Melanin is used as the absorbing pigment for radiation protective eyeware. Thus, a melanin-plastic copolymer was formed by adding a catalyst (benzoyl peroxide) to the liquid monomer, diethylene glycol bis allyl carbonate (CR-39), which contained dissolved catechol (a melanin precursor); the solution was heated for one day at 50 degrees celsius and an additional two days at 65 degrees celsius and yielded an optically transparent solid plastic with amber color and with an optical absorption spectrum very close to that associated with melanin.Type: GrantFiled: March 19, 1990Date of Patent: July 30, 1991Assignee: Photoprotective Technologies, Inc.Inventor: James M. Gallas
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Patent number: 5028660Abstract: A polycarbonate resin of a copolymer of diethyleneglycol bis(allyl carbonate) with one of glycidyl acrylate and glycidyl methacrylate, its homopolymer and its copolymer, and further occasionally a copolymerizable compound can be easily modified with active amine at its surface, and the surface-modified copolymer of diethylene glycol bis(allyl carbonate) with glycidyl acrylate or methacrylate can be easily dyed with acid dye in a sharp color tone and can be used in an optical instrument demanded to have a high vividness of color.Type: GrantFiled: November 15, 1989Date of Patent: July 2, 1991Assignees: Nippon Oil and Fats Co. Ltd., PPG Industries, Inc.Inventors: Rikizo Kobashi, Shigeyuki Takase, Hiroyuki Enomoto, Yasushi Hayasaki, Toyohisa Kobayashi, Shingo Yamazaki
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Patent number: 5021068Abstract: An improvement in a process for preparing a contact lens tinted over at least a portion of its surface, having the steps of forming a tinting solution having a reactive dyestuff and applying the tinting solution to a polymeric hydrogel contact lens material, wherein the improvement comprises adding an effective amount of an ammonium or phosphonium quaternary salt to the tinting solution before the applying step.Type: GrantFiled: August 7, 1990Date of Patent: June 4, 1991Assignee: Ciba-Geigy CorporationInventors: William M. Hung, Kai C. Su
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Patent number: 4978362Abstract: A thermoplastic resin composition is provided which contains a thermoplastic resin and a colorant in the form of a polyalkyleneoxy-trifluoromethyl aniline colorant provided in said thermoplastic resin in a minor amount sufficient to provide coloration to said resin, said colorant having the formula: ##STR1## wherein R.sub.1 is selected from H, a lower alkyl group containing from 1 to about 10 carbon atoms, CH.sub.2 Cl, CH.sub.2 Br, CH.sub.2 OH, phenyl or ##STR2## wherein R.sub.4 is H or a lower alkyl group containing from 1 to about 9 carbon atoms; R.sub.2 is H, CF.sub.3, a lower alkyl group containing from 1 to about 9 carbon atoms, Cl or Br; R.sub.3 is an aromatic or heteroaromatic containing group, and n is an integer from 2 to about 75.Type: GrantFiled: October 11, 1988Date of Patent: December 18, 1990Assignee: Milliken Research CorporationInventors: Edward W. Kluger, John W. Rekers
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Patent number: 4963159Abstract: There is disclosed a method for making colored hydrophilic contact lenses. A contact lens constructed of hydrophilic polymer that is substantially devoid of the functional groups --COOH, --OH, --NH--R, wherein R is hydrogen or C.sub.1 to C.sub.8 alkyl, --NCO and epoxy is provided. At least a portion of the surface of the lens is coated with a color coat comprising at least one pigment, binding polymer having functional groups selected from at least one of --COOH, --OH, and --NH--R, wherein R is hydrogen or C.sub.1 to C.sub.8 alkyl, and an additional compound having at least two groups per molecule of --NCO. The coated lens is subjected to conditions which cause the color coat to adhere to the lens.Type: GrantFiled: July 11, 1989Date of Patent: October 16, 1990Assignee: Schering CorporationInventors: Kenneth W. Narducy, Richard L. Jahnke, Samuel Loshaek
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Patent number: 4960433Abstract: A process for the deposition of a film of an electrophoretic resin upon the surface of a substrate which comprises the steps of (i) electrophoretically depositing from a bath comprising water, a water miscible organic solvent and the resin, a film of the uncured resin upon the surface of the substrate; (ii) immersing said film in a solution of a resin additive in a solvent medium comprising water and a water miscible organic solvent, the amount of said resin additive dissolved in said solvent medium being sufficient for the absorption into the resin film of sufficient additive to impart the desired property to the cured resin film, the composition of said solvent medium being such that the requisite amount of additive can be dissolved therein and such that said desired property is imparted to said resin film while immersed in said solvent medium without significant damage to the resin fim; and (iii) curing the resin.Type: GrantFiled: July 10, 1989Date of Patent: October 2, 1990Assignee: Albright & Wilson LimitedInventor: Stanley Renton
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Patent number: 4954132Abstract: An improvement in a process for preparing a contact lens tinted over at least a portion of its surface, having the steps of forming a tinting solution having a reactive dyestuff and applying the tinting solution to a polymeric hydrogel contact lens material, wherein the improvement comprises adding an effective amount of an ammonium quaternary salt to the tinting solution before the applying step.Type: GrantFiled: March 14, 1989Date of Patent: September 4, 1990Assignee: Ciba-Geigy CorporationInventors: William M. Hung, Kai C. Su
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Patent number: 4891046Abstract: Hydrophilic contact lenses comprised of a copolymer of an hydroxyl group-containing monomer and N-vinylpyrrolidone are tinted by impregnating the lens with an aqueous solution of a dichlorotriazine reactive dye and fixing the dye in the lens by contacting the lens with an aqueous alkaline solution.Type: GrantFiled: March 15, 1984Date of Patent: January 2, 1990Assignee: CooperVision, Inc.Inventors: Joseph W. Wittmann, John M. Evans
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Patent number: 4880432Abstract: Disclosed is a process for preparing particles colored with a dye which comprises: (a) forming, by a free radical dispersion polymerization process in a nonaqueous solution, polymeric particles having attached thereto stabilizing copolymers with at least one functional group capable of undergoing a chemical reaction with a dye, the particles having an average diameter of from about 0.1 to about 20 microns; (b) adding a dye to the polymeric particles having attached thereto stabilizing copolymers; and (c) effecting a chemical reaction between the dye and the stabilizing copolymers that results in the dye becoming covalently bound to the polymeric particles. Also disclosed is a liquid electrophotographic developer composition comprising a liquid medium, a charge control agent, and colored polymeric toner particles prepared as stated above and having an average diameter of from about 0.5 to about 5 microns.Type: GrantFiled: January 11, 1988Date of Patent: November 14, 1989Assignee: Xerox CorporationInventors: Luke S. Egan, Mitchell A. Winnik, Francoise M. Winnik
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Patent number: 4880667Abstract: Described is a method for imparting a photochromic response to a synthetic plastic article, e.g., an optical lens such as a sunglass lens prepared from an allyl diglycol carbonate monomer. The method described comprises depositing a thin uniform substantially dry film of a photochromic-bearing polymeric resin onto at least one planar surface of the synthetic plastic material, heating the plastic article and resin film substantially uniformly at temperatures near to but below the melting temperature of the photochromic substance for a time sufficient to transfer a photochromic amount of the photochromic material into the subsurface region of the plastic article, and thereafter removing the photochromic-lean resin film from the planar surface(s) of the plastic article.Type: GrantFiled: October 15, 1987Date of Patent: November 14, 1989Assignee: PPG Industries, Inc.Inventor: Cletus N. Welch
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Patent number: 4857072Abstract: There is disclosed a method for making colored hydrophilic contact lenses. A contact lens constructed of hydrophilic polymer that is substantially devoid of the functional groups --COOH, --OH, --NH--R, wherein R is hydrogen or C.sub.1 to C.sub.8 alkyl, --NCO and epoxy is provided. At least a portion of the surface of the lens is coated with a color coat comprising at least one pigment, binding polymer having functional groups selected from at least one of --COOH, --OH, and --NH--R, wherein R is hydrogen or C.sub.1 to C.sub.8 alkyl, and an additional compound having at least two groups per molecule of --NCO. The coated lens is subjected to conditions which cause the color coat to adhere to the lens.Type: GrantFiled: November 24, 1987Date of Patent: August 15, 1989Assignee: Schering CorporationInventors: Kenneth W. Narducy, Richard L. Jahnke, Samuel Loshaek
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Patent number: 4842783Abstract: A fiber optic chemical sensor and the method of making it are provided, such being useful in medical, biological and industrial applications. The sensor includes an optical fiber waveguide having a photocrosslinked polymeric gel at a portion thereof, which gel is crosslinked in place and undergoes substantial volume expansion. A dye is absorbed into the gel, the dye being responsive to different degrees depending on the presence and concentration of any one of particular parameters of a fluid being monitored, such parameters being pH, oxygen concentration, carbon dioxide concentration and the like.Type: GrantFiled: September 3, 1987Date of Patent: June 27, 1989Assignee: Cordis CorporationInventor: Mark E. Blaylock
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Patent number: 4812141Abstract: A colored thermoplastic resin composition is provided which comprises a thermoplastic resin and a colorant in the form of an alkyleneoxy-substituted chromophore group provided in said thermoplastic resin in a minor amount sufficient to provide coloration to said thermoplastic resin. A process for preparing colored thermoplastic resins is also provided.Type: GrantFiled: March 17, 1988Date of Patent: March 14, 1989Assignee: Milliken Research CorporationInventors: Alan S. Baumgartner, Patrick D. Moore, Richard A. VanDahm
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Patent number: 4780103Abstract: A method for partially dyeing a plastic lens and plastic lens dyed by the method are herein disclosed, the method comprising forming a film of a nondyeable coating agent on the whole surface of the lens, cutting and removing at least part of the film and then immersing the plastic lens in a dyeing liquid to selectively dye the part of the lens from which the film is cut and removed, the method making it possible to provide a dyed lens having a clear boundary between the dyed and nondyed parts.Type: GrantFiled: February 24, 1987Date of Patent: October 25, 1988Assignee: Kabushiki Kaisha Minowa GankyoInventor: Toshiaki Minowa
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Patent number: 4780533Abstract: A disazo pigment is prepared by coupling the tetrazo compound of 3,3'-dichlorobenzidine with an acetoacetanilide compound which is other than those represented by the below-described general formula (I) and is free of water-soluble groups. In the present invention, about 0.5-50 mole % of the acetoacetanilide compound is replaced by a compound represented by the following general formula (I): ##STR1## wherein R means a methyl, ethyl, propyl or butyl group or a substituted or unsubstituted phenyl group.Type: GrantFiled: February 9, 1987Date of Patent: October 25, 1988Assignee: Dainichiseika Color & Chemicals Mfg. Co., Ltd.Inventors: Naonori Takami, Tetsuo Fukuda, Takeshi Uehara
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Patent number: 4737581Abstract: Azo compounds of the formula I ##STR1## wherein X is --H, --CH.sub.3, --CF.sub.3, --NO.sub.2, --COOR.sub.1, --NHCOR.sub.2 or --COHN.sub.2, and R.sub.1 and R.sub.2 are as defined in claim 1, are suitable for pigmenting high-molecular organic material.Type: GrantFiled: April 18, 1985Date of Patent: April 12, 1988Assignee: Ciba-Geigy CorporationInventor: Stefan Hari
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Patent number: 4732570Abstract: A colored thermoplastic resin composition is provided which comprises a thermoplastic resin and a colorant in the form of an alkyleneoxy-substituted chromophore group provided in said thermoplastic resin in a minor amount sufficient to provide coloration to said thermoplastic resin. A process for preparing colored thermoplastic resins is also provided.Type: GrantFiled: June 23, 1986Date of Patent: March 22, 1988Assignee: Milliken Research CorporationInventors: Alan S. Baumgartner, Patrick D. Moore, Richard A. VanDahm
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Patent number: 4668240Abstract: Colored contact lenses are produced by providing a contact lens constructed of polymer and coating at least a portion of the lens with coloring substance and binding polymer. The lens and binding polymers are bonded to each other by the reaction of functional groups selected from at least one of --COOH, --OH, and --NH--R, wherein R is hydrogen or alkyl, with functional groups selected from at least one of --NCO and epoxy.Type: GrantFiled: December 16, 1985Date of Patent: May 26, 1987Assignee: Schering CorporationInventor: Samuel Loshaek
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Patent number: 4664672Abstract: A process for transfer printing onto solid substrates made of plastics or having a surface layer of varnish or plastic is described. According to the invention described a sheet dye carrier at a temperature suitable for dye transfer is pressed to a preferably preheated surface and/or to a limited area of the surface to be printed by means of superatmospheric gas pressure, in particular by means of a flowing gas. Additionally the surface to be printed is maintained at a temperature below the thermoplastic range during the transfer process.Type: GrantFiled: March 10, 1986Date of Patent: May 12, 1987Assignee: Rohm GmbH Chemische FabrikInventors: Otmar Krajec, Walter Hellmann
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Patent number: 4661117Abstract: A waterless dip dye composition for non-textile and general-utility articles comprises an aromatic ester of the formula ArCOOR.sub.2, ArCOO--R.sub.1 --OOCAr or (ArCOO).sub.z --R.sub.3, wherein R.sub.1 is alkylene of 2-8 carbon atoms or polyoxyalkylene of the formula --C.sub.r H.sub.2r (OC.sub.r H.sub.2r).sub.s, in which r is 2 or 3 and s is 1 to 15; R.sub.2 is substituted or unsubstituted alkyl or alkenyl of 8-30 carbon atoms; R.sub.3 is the residue of a polyhydric alcohol having z hydroxyl groups; Ar is substituted or unsubstituted mono- or bicyclic aryl of up to 15 carbon atoms and z is 3-6, admixed with at least 0.5% by weight of a dyeing assistant agent and an organic colorant.A process for coloring non-textile and general-utility articles, fabricated from polyester, polyamide, polyurethane, acrylic, halogenated polyolefin or epoxy plastic, comprises exposing an article to the foregoing compositions, maintained at a temperature from about 100.degree. C.Type: GrantFiled: November 8, 1984Date of Patent: April 28, 1987Assignee: Crucible Chemical CompanyInventors: Robert B. Wilson, William F. Pomeroy, Louis T. Sovey, Jr.
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Patent number: 4640690Abstract: A colored thermoplastic resin composition is provided which comprises a thermoplastic resin and a colorant in the form of an alkyleneoxy-substituted chromophore group provided in said thermoplastic resin in a minor amount sufficient to provide coloration to said thermoplastic resin. A process for preparing colored thermoplastic resins is also provided.Type: GrantFiled: September 13, 1985Date of Patent: February 3, 1987Assignee: Milliken Research CorporationInventors: Alan S. Baumgartner, Patrick D. Moore, Richard A. VanDahm
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Patent number: 4581035Abstract: A waterless dye composition for apparel and other thermoplastic articles comprises a triglyceride fat or oil of the formula ##STR1## wherein acyl, acyl' and acyl" each are saturated or unsaturated substituted or unsubstituted linear alkanoyl of an even number of carbon atoms from 10-30 carbon atoms and an organic colorant.The composition can further contain one or more of:A. an aromatic polyester of the formula C.sub.6 H.sub.z' -(COOR.sub.1).sub.z, wherein z is 3, 4,5, or 6; z' is 6-z and R.sub.1 is higher alkyl;B. a cycloaliphatic diester of the formula ##STR2## wherein R is substituted or unsubstituted straight or branched chain alkyl of 4-20 carbon atoms, polyoxyalkylene of the formula HO(C.sub.x H.sub.y O).sub.n C.sub.x H.sub.y --or phosphated polyoxyalkylene of the formula(HO).sub.2 P(.dbd.O)O(C.sub.x H.sub.2x O).sub.n C.sub.x H.sub.2xor a salt thereof, wherein (C.sub.x H.sub.2x O).sub.n is (CH.sub.2 CH.sub.2 O).sub.n, (C.sub.3 H.sub.6 O).sub.n or (CH.sub.2 CH.sub.2 O).sub.p --(C.sub.3 H.sub.6 O).sub.Type: GrantFiled: November 8, 1984Date of Patent: April 8, 1986Assignee: Crucible Chemical CompanyInventor: Robert B. Wilson
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Patent number: 4494954Abstract: A uniformly colored shaped article which is resistant to discoloration and fading can be produced by immersing a shaped article, particularly a contact lens, consisting of a polymer of at least one monomer selected from the group consisting of acrylates and methacrylates in a dyeing solution prepared by dissolving a water-soluble dye in a solvent capable of swelling said polymer, to swell and color the shaped article, and then drying the swollen shaped article.Type: GrantFiled: December 15, 1982Date of Patent: January 22, 1985Assignees: Japan Synthetic Rubber Co., Ltd., Ricky Contact Lens Research Institute Inc.Inventors: Taro Suminoe, Tetsuo Ito, Yasuhiro Kiyomatsu, Takao Shimizu
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Patent number: 4469515Abstract: A process for producing monoazo or disazo pigments, which process comprises:(a) adding to a solution of a diazonium and/or tetrazonium salt of an aromatic or heterocyclic amine a solution or suspension containing 0.1-50% by weight of the theoretically required total weight of one or more coupling components, and(b) using the product from step (a) as an additive in the production of a monoazo pigment, a disazo pigment or a mixture of monoazo and disazo pigments.Compared with products produced by conventional methods, the pigments produced in the manner described above have a greater coloring strength, improved transparency, improved flow properties, and a higher degree of dispersibility.Type: GrantFiled: May 10, 1982Date of Patent: September 4, 1984Assignee: Ciba-Geigy CorporationInventors: David T. Pechey, John H. Coy
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Patent number: 4440541Abstract: A dichroic light polarizer comprising a sheet of molecularly oriented polyacrylic acid/chitosan complex having incorporated therein a dichroic dye.Type: GrantFiled: May 20, 1982Date of Patent: April 3, 1984Assignee: Polaroid CorporationInventor: Carl M. Berke
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Patent number: 4406662Abstract: A process of heat transfer printing the surface of a filled polymeric article, wherein the filled polymeric article consists essentially of an inorganic filler, preferably alumina trihydrate, and a polymer with an affinity for disperse dyes, preferably polymethyl methacrylate. A desired design is printed onto a carrier using sublimable disperse dyes. The filled polymeric article is preheated, the carrier supporting sublimable disperse dye is placed in intimate contact with the preheated article, and sufficient heat is applied to cause the dye to sublime, then diffuse into the surface of the article.Type: GrantFiled: March 5, 1982Date of Patent: September 27, 1983Assignee: E. I. Du Pont de Nemours and CompanyInventors: Joseph F. Beran, Emery J. Gorondy
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Patent number: 4341701Abstract: A process for producing monoazo or disazo pigments, which process comprises:(a) adding to a solution of a diazonium and/or tetrazonium salt of an aromatic or heterocyclic amine a solution or suspension containing 0.1-50% by weight of the theoretically required total weight of one or more coupling components, and(b) using the product from step (a) as an additive in the production of a monoazo pigment, a disazo pigment or a mixture of monoazo and disazo pigments.Compared with products produced by conventional methods, the pigments produced in the manner described above have a greater coloring strength, improved transparency, improved flow properties, and a higher degree of dispersibility.Type: GrantFiled: November 4, 1980Date of Patent: July 27, 1982Assignee: Ciba-Geigy CorporationInventors: David T. Pechey, John H. Coy
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Patent number: 4323671Abstract: Anthraquinone derivatives which, in one of their tautomeric structures, correspond to the formula ##STR1## in which A denotes an anthraquinone radical which is free from sulphonic acid groups, is optionally further substituted and preferably consists of at most 5 fused rings,m denotes a number from 1 to 4, preferably 1 or 2,R denotes a substituent andn denotes 0, 1, 2, 3 or 4,processes for their preparation, their use for pigmenting organic macromolecular substances, and the material pigmented in this manner.Type: GrantFiled: April 14, 1980Date of Patent: April 6, 1982Assignee: Bayer AktiengesellschaftInventors: Rutger Neeff, Meinhard Rolf, Walter Muller
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Patent number: 4323670Abstract: Anthraquinone-azomethine compounds of the formula ##STR1## or of the tautomeric formula ##STR2## in which A denotes an anthraquinone radical which is free from sulphonic acid groups and is optionally further substituted and which preferably consists of at most 5 fused rings,R.sub.1 denotes hydrogen, optionally substituted aryl, preferably ##STR3## hetero-aryl, cycloalkyl or C.sub.1 -C.sub.12 -alkyl, it being possible for the alkyl chain to be interrupted by oxygen or sulphur and/or to be substituted by hydroxyl groups or N(R.sub.3).sub.2 groups, --N(R.sub.3).sub.2 or ##STR4## R.sub.2 denotes a substituent, R.sub.3 denotes hydrogen, C.sub.1 -C.sub.4 -alkyl, cycloalkyl oroptionally substituted aryl,m denotes 1, 2, 3 or 4 andn denotes 0, 1, 2, 3, 4 or 5, processes for their preparation and processes for pigmenting organic macromolecular substances using the new anthraquinone-azomethine compounds.Type: GrantFiled: July 21, 1980Date of Patent: April 6, 1982Assignee: Bayer AktiengesellschaftInventors: Rutger Neeff, Meinhard Rolf, Walter Muller
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Patent number: 4319025Abstract: Anthraquinone-azomethine compounds of the formula ##STR1## or of the tautomeric formula ##STR2## or of the tautomeric formula ##STR3## in which A denotes an anthraquinone radical which is free from sulphonic acid groups and optionally further substituted and which preferably consists of at most 5 fused rings,R.sub.1 denotes hydrogen, C.sub.1 -C.sub.4 -alkyl, hydroxy-C.sub.1 -C.sub.4 -alkyl, optionally substituted phenyl, carboxyl, carboxylic acid, C.sub.1 -C.sub.4 -alkyl ester or hydroxyl,R.sub.2 denotes hydrogen, halogen, nitro, cyano, optionally substituted carbamoyl or optionally substituted sulphamoyl, sulphonic acid C.sub.1 -C.sub.4 -alkyl ester, sulphonic acid aryl ester, C.sub.1 -C.sub.4 - alkylcarbonyl, C.sub.1 -C.sub.4 -alkoxycarbonyl, optionally substituted benzoyl, alkyl or optionally substituted phenyl sulphone, or a hetero-aromatic radical, for example a radical of the formula ##STR4## or of the formula ##STR5## or of the formula ##STR6## R.sub.Type: GrantFiled: July 21, 1980Date of Patent: March 9, 1982Assignee: Bayer AktiengesellschaftInventors: Rutger Neeff, Meinhard Rolf, Walter Muller
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Patent number: 4310330Abstract: A method for the manufacture of a colored nonfogging article, which comprises bringing a nonfogging substrate containing a surfactant into contact with a dyeing solution containing a surfactant, a solvent and a coloring material, said surfactant being contained in the dyeing solution in an amount within the range of 20 to 100% by weight based on the total amount of the surfactant and the solvent.Type: GrantFiled: June 18, 1980Date of Patent: January 12, 1982Assignees: Nippon Sheet Glass Co., Ltd., Sumitomo Chemical Company, LimitedInventors: Masaaki Funaki, Motoaki Yoshida, Haruo Inatomi, Ryozo Kuriyama, Taizo Oshima
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Patent number: 4303701Abstract: A method of marking plastic lenses to selectively identify a lens by impregnating a fluorescent material into the surface of the lens so that when the lens is exposed to ultraviolet light it fluoresces.Type: GrantFiled: December 31, 1979Date of Patent: December 1, 1981Assignee: Buckbee-Mears CompanyInventors: Daniel L. Torgersen, Leon H. Fischer
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Patent number: 4286957Abstract: A process of integrating a photochromic substance, especially a spiropyran or a metal dithizonate, into a transparent substrate of polymerized organic material such as poly [ethylene glycol di-allyl di-carbonate] by thermal transfer, comprising applying the photochromic substance alone or with a solvent and/or thickening agent to the surface of a transparent organic substrate such as a lens disc, and heating until the photochromic substance is sublimed and then diffused and anchored in the organic material of the lens, preferably just beneath the surface to which it is applied. Preferably, the photochromic substance is initially carried on a temporarily support for application.Type: GrantFiled: January 10, 1979Date of Patent: September 1, 1981Assignee: Essilor International "Cie Generale d'Optique"Inventor: Lyliane Le Naour-Sene
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Patent number: 4284411Abstract: Anthraquinone derivatives which in one of their tautomeric structures correspond to the formula ##STR1## in which A denotes an anthraquinone radical which is free from sulphonic acid groups, is optionally further substituted and preferably consists of at most 5 fused rings,m is a number from 1-4 and preferably 1 or 2,R.sub.1 is hydrogen or a C.sub.1 -C.sub.4 -alkyl group andR.sub.2 is a cyano group or a radical of the formula ##STR2## or a radical of the formula ##STR3## in which formulae R.sub.3 is hydrogen, a straight-chain or branched alkyl group of a cycloalkyl radical,R.sub.4 is a substituent,n is 0, 1, 2, 3 or 4 andp is 0, 1, 2, 3, 4 or 5,processes for their preparation and their use for pigmenting organic macromolecular substances.Type: GrantFiled: July 19, 1979Date of Patent: August 18, 1981Assignee: Bayer AktiengesellschaftInventors: Rutger Neeff, Meinhard Rolf, Walter Muller
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Patent number: 4257692Abstract: A method of marking an ophthalmic lens of organic material and the lens so marked. A marking substance containing an optical brightener which is a derivative of benzoxazolyls stilbenes, or benzotriazoles is mixed with a suitable binder and solvent and applied to a surface of the lens to be marked by thermal transfer from a transfer support. The marking substance is shaped to the desired configuration either when applied to the transfer support or by a mask defining the mark or indicia to be applied. Heat is applied to the marking substance and the lens which sublimes the optical brightener which then penetrates into the organic material of the lens to be anchored therein. The resultant indicia or mark provides a permanent marking of the lens and is only visible in ultra-violet light.Type: GrantFiled: October 13, 1978Date of Patent: March 24, 1981Assignee: Essilor International "Cie Generale d'OptiqueInventor: Lyliane Le Naour-Sene
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Patent number: 4253838Abstract: Heat transfer printing sheet wherein a pattern comprising a basic dye having the poor heat transferable property, an alkaline agent having a property of increasing the heat transferable property of the basic dye and a binder is formed on a base support sheet and also a resin film through which the basic dye can be passed when the heat transfer printing is carried out, but can not be passed through when the heat transfer printing is not carried out is formed on the pattern. The resin film can be provided on the right and/or back side surfaces of the base support sheet. Heat transfer printing method using the above heat transfer printing sheet with heat under pressure.Type: GrantFiled: April 20, 1979Date of Patent: March 3, 1981Assignee: Dai Nippon Printing Co., Ltd.Inventors: Shogo Mizuno, Sumio Ishii
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Patent number: 4251582Abstract: Dyeable and dyed polymer-coatings on metal articles such as sliders, buttons, buckles, clasps, nuts, bolts, hooks, etc. include a substantial quantity of active proton acceptor groups relative to the number of polymer molecules in order to provide adequate dye pick-up.Type: GrantFiled: May 15, 1979Date of Patent: February 17, 1981Assignee: Textron Inc.Inventors: Lornie J. Bernier, Tapan K. Das
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Patent number: 4202663Abstract: Method of dye absorption into the surface of plastics is accomplished by placing polyolefin film between a dye transfer paper and a sheet of thermoplastic and applying pressure and heat thereto. The heat applied is sufficient to sublime the dyes through the film to the plastic sheet. The dyes are absorbed into the surface of the plastic with the design intact. The materials are then cooled and separated and a decorated plastic sheet or article with wear-proof design is obtained. Thermoset plastics are similarly dye penetrated in this manner during the curing thereof.In-mold dye decoration and penetration of thermoplastics and thermoset plastics are also disclosed.Further, post-pressure dye transfer to plastic sheets and plastic articles is disclosed.Type: GrantFiled: September 6, 1977Date of Patent: May 13, 1980Inventors: John M. Haigh, deceased, by Joyce E. Quinlan, administrator