Dye In Specified Form Other Than Mere Powder Patents (Class 8/526)
  • Patent number: 4332588
    Abstract: By the slow stepwise heating up of an aqueous suspension of the crystallographically amorphous dye of the formula ##STR1## which dye is unstable to dyeing, to a temperature of 90.degree.-100.degree. C. with a halting point at 40.degree.-60.degree. C., this dye can be transformed completely into the crystalline .alpha.-modification.The novel dye modification can be easily converted, without increase of viscosity, into thinly liquid formulations which are readily pourable, which form no sediment, and which are excellently suitable for producing printing pastes, for example for printing polyester fabric.
    Type: Grant
    Filed: December 31, 1980
    Date of Patent: June 1, 1982
    Assignee: Ciba-Geigy Corporation
    Inventors: Peter Eugster, Stefan Koller
  • Patent number: 4329144
    Abstract: By suspension of the melt of the known crystallographically amorphous dye of the formula ##STR1## which is unstable to dyeing, in water at a temperature of 90.degree. to 130.degree. C., this dye can be caused to crystallize. There is obtained a crystalline granulate in which the dye is completely in the novel .epsilon.-modification.The novel dye modification is stable in dispersion under dyeing conditions, and has no tendency to flocculate.
    Type: Grant
    Filed: December 15, 1980
    Date of Patent: May 11, 1982
    Assignee: Ciba-Geigy Corporation
    Inventors: Peter Eugster, Stefan Koller
  • Patent number: 4327999
    Abstract: It is possible by heating at temperatures of between 65.degree. and 200.degree. C. to convert the known .alpha.-modification of the azo dye of the formula ##STR1## which is unstable to dyeing, completely into the .beta.-modification which is stable to dyeing. The modification transformation can be performed either with the solid dye or with a suspension thereof in an organic, preferably aromatic, solvent.The novel dye modification is stable in dispersion under dyeing conditions, and shows no tendency to flocculate.
    Type: Grant
    Filed: December 31, 1980
    Date of Patent: May 4, 1982
    Assignee: Ciba-Geigy Corporation
    Inventors: Stefan Koller, Peter Eugster, Suresh C. Agarwal
  • Patent number: 4319880
    Abstract: The invention relates to a novel crystallographic modification (".beta.-modification") being stable under dyeing conditions of the dyestuff of the formula ##STR1## which is characterized by an X-ray diffraction pattern as shown in FIG. 1 with characteristic reflexes at the following glance angles .theta. (CuK.sub..alpha. radiation) with the relative intensities:______________________________________ .phi. 3.71 6.62 7.85 8.6 9.43 10.51 11.8 12.57 relat. 67 44 34 36 60 60 46 100 intensity ______________________________________to processes for their manufacture and to their use for dyeing fibrous materials of cellulose esters or of synthetic linear polyesters or blended fabrics of these polyesters and wool or rayon.
    Type: Grant
    Filed: May 23, 1980
    Date of Patent: March 16, 1982
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Konrad Opitz, Rudolf Schickfluss
  • Patent number: 4315043
    Abstract: A method of coating an organic dye composition with an inert coating material, such as an epoxy resin, is disclosed which improves the mechanical properties of the organic dye particles and enables the production of pour-castable colored smoke-producing compositions of high solids loading.
    Type: Grant
    Filed: September 22, 1980
    Date of Patent: February 9, 1982
    Assignee: Her Majesty the Queen in Right of Canada, as represented by the Minister of National Defence
    Inventors: Joseph E. G. Couture, Joseph N. A. Roy
  • Patent number: 4293543
    Abstract: A process and composition for coloring substances and tissues containing keratin, by means of an agent or co-reactant having a ketone or aldehyde function. An amino-acid, in particular a thio-amino-acid, is contacted with the substance to be colored. The composition can be in the form of a solution or a suspension containing the amino-acid, applicable separately from or together with the co-reactant of known type based on a ketone or aldehyde. The invention is useful in cosmetics, for tanning the skin or coloring the hair or nails. It is also applicable to the coloration of various articles, in particular hair in general, feathers, horn, shell etc.
    Type: Grant
    Filed: October 2, 1980
    Date of Patent: October 6, 1981
    Assignee: Societe Nationale Elf Aquitaine
    Inventors: Jean-Marie Cotte, Philippe Potin
  • Patent number: 4286959
    Abstract: The invention seeks to provide a free-flowing formulation of one or more disperse dyes, with which packages can be dyed homogeneously by the HT process without filtering out of the dye, and which is suitable for the thermosol dyeing process. According to the invention such a formulation comprises one or more disperse dyes (a) enclosed in a matrix of one or more polymers (b) which are soluble, or colloidally soluble, both in water and in an organic solvent, in the form of a solid solution in a state of molecular dispersion or of extremely fine subdivision so that in an X-ray spectrum the dye appears amorphous.The formulations may contain additional assistants conventionally present when dyeing hydrophobic fibers. The formulations contain the disperse dye in an extremely fine state of subdivision. Because of the latter, the formulations give level package dyeings, without filtration of the dye, and very level dyeings when used by the thermofixing process.
    Type: Grant
    Filed: March 8, 1979
    Date of Patent: September 1, 1981
    Assignee: BASF Aktiengesellschaft
    Inventors: Dieter Horn, Ewald Daubach, Erwin Hahn, Herbert Uhrig, Richard Hoene, Herbert Naarmann
  • Patent number: 4285692
    Abstract: Process for the production of granular mixtures of vat dyestuffs and/or disperse dyestuffs, characterized in that liquid or pasty, finished formulations of two or more vat dyestuffs and/or disperse dyestuffs are spray-dried together to form granules.
    Type: Grant
    Filed: October 4, 1979
    Date of Patent: August 25, 1981
    Assignee: Bayer Aktiengesellschaft
    Inventors: Willy Schiwy, Jurgen Schulze, Ferdinand Hummes, Peter Schulze, Reinhold Hornle, Hans-Heinz Molls, Harry Orttmann
  • Patent number: 4269729
    Abstract: Microcapsules having walls formed from polyvinyl alcohol are prepared by dispersing a substantially water insoluble nuclear material in an aqueous solution of a polyvinyl alcohol polymer, which solution has a cloud point, phase separating and depositing a concentrated aqueous solution of the polyvinyl alcohol polymer as a separated phase around said nuclear material from the bulk continuous phase by maintaining the temperature of the system above the cloud point of the aqueous polyvinyl alcohol polymer solution, and subjecting the phase separated solution to conditions which substantially solidify or gel said polyvinyl alcohol polymer in said concentrated aqueous solution of said separated phase around said nuclear material but which do not substantially solidify or gel the polyvinyl alcohol in the diluted aqueous solution of the continuous phase.
    Type: Grant
    Filed: July 23, 1979
    Date of Patent: May 26, 1981
    Assignee: Kuraray Co., Ltd.
    Inventors: Hitoshi Maruyama, Koichi Kajitani, Makoto Shiraishi
  • Patent number: 4244836
    Abstract: Microcapsules having a shell consisting of water-soluble polyvinyl alcohol and containing a liquid, water-in-soluble material are obtained by dispersing a liquid, water-insoluble phase of a substance, substance mixture or substance solution in an aqueous phase of polyvinyl alcohol obtained by partial hydrolysis of polyvinyl acetate and having a degree of hydrolysis of from 72 to 99 mol % and dehydrating the dispersion to obtain the capsules in powder form.
    Type: Grant
    Filed: February 5, 1979
    Date of Patent: January 13, 1981
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Heinz Frensch, Rudolf Heinrich, Konrad Albrecht
  • Patent number: 4235597
    Abstract: Non-dusty, free-flowing granules of textile processing agents for solvent application, which granules contain at least one textile processing agent, optionally together with a dispersing agent and/or further auxiliaries, dissolved in an organic carrier which is solid at room temperature and which is soluble in halogenated hydrocarbon, as well as a process for the production of these granules.
    Type: Grant
    Filed: November 11, 1976
    Date of Patent: November 25, 1980
    Assignee: Ciba-Geigy Corporation
    Inventor: Gerhard Reinert
  • Patent number: 4224179
    Abstract: A process for the preparation of a solution or suspension of liposomes in an aqueous medium comprising the steps of dispersing a first aqueous liquid in an essentially water-insoluble solvent in the presence of a compound of the formula XY wherein X is a hydrophilic lipophobic group and Y is a lipophilic hydrophobic group to form a dispersion of liposome precursors in the solvent, the precursors consisting of small vesicles of the first aqueous liquid surrounded by a monomolecular film of compound XY, emulsifying the liposome precursors in a second aqueous medium in the presence of a compound of the formula ZW wherein Z is a hydrophilic group and W is a hydrophobic group to thereby form a solution or suspension of liposomes in the second aqueous medium, said liposomes consisting of the first aqueous liquid surrounded by a bimolecular film of the structure XY-WZ and removing the water-insoluble solvent prior to after said emulsification.
    Type: Grant
    Filed: August 4, 1978
    Date of Patent: September 23, 1980
    Assignee: Battelle Memorial Institute
    Inventor: Michel Schneider
  • Patent number: 4222740
    Abstract: A coloration method for textiles using chemically formed gels is disclosed. The method provides considerable freedom for making color designs and precise pattern prints, and can be used with conventional dyeing and printing equipment. In one embodiment of this invention, gelled regions are formed by separately applying a gelable composition containing alginic acid or an alginic acid derivative and a gelling agent composition to a textile material, and then over-dyeing the material, the gelled regions serving as dye resist regions.
    Type: Grant
    Filed: March 5, 1979
    Date of Patent: September 16, 1980
    Assignee: Armstrong Cork Company
    Inventors: Walter J. Bohrn, William A. Moggio
  • Patent number: 4216112
    Abstract: Pressure-sensitive microcapsules containing a solvent composition for use in carbonless copy systems for use in the absence of a halogenated solvent consisting essentially of a combination of a mono-alkyl naphthalene, wherein said alkyl group contains from 1 to 3 carbon atoms per molecule and a di-alkyl naphthalene, wherein each of said alkyl groups in said di-alkyl naphthalene contains from 2 to 4 carbon atoms per molecule, said mono-alkyl naphthalene being present in an amount between about 25 and about 40 percent by weight of the alkylated naphthalenes present in the solvent, and an isocyanate cross-linking agent.
    Type: Grant
    Filed: September 21, 1977
    Date of Patent: August 5, 1980
    Assignee: Champion International Corporation
    Inventors: David N. Vincent, Cheng H. Chang
  • Patent number: 4211527
    Abstract: Described is a process for dyeing polyester materials, or mixtures thereof with other fibres, by the exhaust method from an aqueous liquor, in which process the liquor contains at least 0.2 percent by weight, relative to the material, of at least one alkaline-earth metal salt, aluminium salt or organic ammonium salt of a mono- or polyvalent aliphatic organic acid or of a mono- or polyvalent inorganic acid. Preferably calcium chloride or magnesium chloride are used.
    Type: Grant
    Filed: December 9, 1977
    Date of Patent: July 8, 1980
    Assignee: Ciba-Geigy Corporation
    Inventor: Jean P. Luttringer
  • Patent number: 4202815
    Abstract: Process for the preparation of concentrated formulations, which can be dispersed in aqueous media, in the form of free-flowing, low-dusting powders or granules starting from active substances which are sparingly soluble to insoluble in water, such as pigments, dyestuffs, optical brighteners, and other related types of additives.
    Type: Grant
    Filed: March 20, 1978
    Date of Patent: May 13, 1980
    Assignee: Rohner AG Pratteln
    Inventor: Jacques Wegmann