Polymeric Additive Patents (Class 8/552)
  • Patent number: 8444716
    Abstract: A soluble solid hair coloring article having zwitterionic direct dye and one or more soluble porous solids containing nonionic surfactant, cationic surfactant, or a mixture thereof, such that the one or more soluble porous solids have a density of from about 0.03 g/cm3 to about 0.15 g/cm3; and methods of applying the soluble solid hair coloring article to hair.
    Type: Grant
    Filed: May 23, 2012
    Date of Patent: May 21, 2013
    Assignee: The Procter & Gamble Company
    Inventors: Timothy James Felts, Guiru Zhang, Jorge Max Sunkel, Bryan Patrick Murphy
  • Patent number: 8439981
    Abstract: A soluble solid hair coloring article having anionic direct dye and one or more soluble porous solids containing nonionic surfactant, anionic surfactant, or a mixture thereof, such that the soluble porous solid has a density of from about 0.03 g/cm3 to about 0.15 g/cm3; and methods of applying the soluble solid hair coloring article to hair.
    Type: Grant
    Filed: May 23, 2012
    Date of Patent: May 14, 2013
    Assignee: The Procter & Gamble Company
    Inventors: Timothy James Felts, Guiru Zhang, Jorge Max Sunkel, Bryan Patrick Murphy
  • Patent number: 8430935
    Abstract: A multi-component packaging unit includes a first container containing a color changing preparation comprising, in a cosmetic carrier, a color-changing component and a second container packaged separately from the first container and containing an oxidizing agent preparation. The oxidizing agent preparation comprises at least two phases separated from one another. A first phase has an aqueous phase that comprises, in a cosmetically acceptable carrier, a chemical oxidizing agent and an anionic polymeric thickener chosen from homo- and copolymers of acrylic acid and methacrylic acid. A second phase has a hydrophobic phase that comprises an oil chosen from paraffin oil, liquid carboxylic acid esters of C2 to C8 monoalkanol with a mono- or dicarboxylic acid, and combinations thereof.
    Type: Grant
    Filed: September 13, 2012
    Date of Patent: April 30, 2013
    Assignee: Henkel AG & Co. KGAA
    Inventors: Konstantin Goutsis, Frank Janssen, Marc Krippahl
  • Patent number: 8425622
    Abstract: A soluble solid hair coloring article having cationic direct dye and one or more soluble porous solids containing nonionic surfactant, cationic surfactant, or a mixture thereof, such that the one or more soluble porous solids have a density of from about 0.03 g/cm3 to about 0.15 g/cm3; and methods of applying the soluble solid hair coloring article to hair.
    Type: Grant
    Filed: May 23, 2012
    Date of Patent: April 23, 2013
    Assignee: The Procter & Gamble Company
    Inventors: Timothy James Felts, Guiru Zhang, Jorge Max Sunkel, Bryan Patrick Murphy
  • Patent number: 8425623
    Abstract: Thickened oxidative preparations are provided herein. In one embodiment, a cosmetic agent for changing the color of keratinic fibers is provided. The cosmetic agent includes a preparation (M1) containing a color-changing component and an oxidizing agent preparation (M2) containing in an aqueous, cosmetic carrier at least hydrogen peroxide as a chemical oxidizing agent and an anionic, polymeric thickener selected from crosslinked or uncrosslinked polyacrylic acid polymers. The cosmetic agent has a viscosity of about 5 to about 100 Pa s. The cosmetic agent is prepared directly before use by blending preparation (M1) with oxidizing agent preparation (M2).
    Type: Grant
    Filed: September 13, 2012
    Date of Patent: April 23, 2013
    Assignee: Henkel AG & Co. KGAA
    Inventors: Konstantin Goutsis, Frank Janssen, Marc Krippahl
  • Patent number: 8419808
    Abstract: The present invention relates to a dye compound represented by the following formula (I), or a salt thereof: wherein R1, R2, R3, R4, D1, D2, B, and n are defined the same as the specification, and also relates to a photoelectric component using the same. The dye compound of the present invention is suitable for Dye-Sensitized Solar Cell (DSSC). Hence, the photoelectric characteristics of the DSSC can be improved by using the dye compound of the present invention.
    Type: Grant
    Filed: November 2, 2011
    Date of Patent: April 16, 2013
    Assignee: Everlight USA, Inc.
    Inventors: Ming-si Wu, Wei-Cheng Tang
  • Publication number: 20130084461
    Abstract: The invention provides a process for preparing organic nanoparticles comprising the steps of: (a) preparing a solution comprising an unsaturated polyester and/or a vinyl ester resin, an initiator and a hydrophobic monomer; (b) emulsifying the solution obtained in step (a) in an aqueous phase; and thereafter (c) curing the emulsified solution. The invention further provides organic nanoparticles obtainable by the process according to the invention; various uses of said nanoparticles; and paper, dye compositions and toner compositions comprising said nanoparticles.
    Type: Application
    Filed: November 29, 2012
    Publication date: April 4, 2013
    Applicant: DSM IP ASSETS B.V.
    Inventor: DSM IP ASSETS B.V.
  • Publication number: 20130074935
    Abstract: Disclosed and claimed herein is an aqueous dye dispersion for making a dye sensitized electronic device having, a water insoluble dye, an alkalizing agent, a surfactant; and water. The water insoluble dye has at least one acid group and the aqueous dye dispersion is substantially free of volatile organic solvents, co-solvents and diluents. Further disclosed and claimed is a method of making a photoelectronic device using the claimed aqueous dye dispersion.
    Type: Application
    Filed: September 23, 2011
    Publication date: March 28, 2013
    Applicant: WARNER BABCOCK INSTITUTE FOR GREEN CHEMISTRY
    Inventors: John C. Warner, Michael S. Viola
  • Patent number: 8403999
    Abstract: Disclosed herein is a device having one or more compartments, for dyeing keratin fibers, wherein a first compartment contains a dye composition free of oxidizing agent, comprising at least one hair dye and at least one polycondensate of ethylene oxide and propylene oxide, and optionally a second compartment contains an oxidizing composition. Also disclosed is an agent for dyeing and/or bleaching keratin fibers, obtained by mixing a composition A comprising at least one alkaline agent with a composition B comprising at least one oxidizing agent, compositions A and/or B comprising at least one fatty substance free of carboxylic acid groups, at least one polycondensate of ethylene oxide and propylene oxide, and a system of nonionic surfactants, with a weighted HLB of greater than or equal to 8, the amount of fatty substance being greater than 20% of the total weight of the dyeing and/or bleaching agent.
    Type: Grant
    Filed: December 13, 2010
    Date of Patent: March 26, 2013
    Assignee: L'Oreal
    Inventors: Leila Hercouet, Marie Giafferi, Liliane Gaillard, Alain Lagrange, Gautier Deconinck, Arnaud Hucher
  • Publication number: 20130067664
    Abstract: A polyurethane derivative and a composition thereof are disclosed. The polyurethane derivative of the present invention has a structure of formula (I). The polyurethane derivative and the composition thereof can be used for increasing light fastness.
    Type: Application
    Filed: September 18, 2012
    Publication date: March 21, 2013
    Applicant: EVERLIGHT CHEMICAL INDUSTRIAL CORPORATION
    Inventor: Everlight Chemical Industrial Corporation
  • Patent number: 8388698
    Abstract: The present invention is drawn to a composition and method for dyeing keratinous substrates containing: (a) at least one polyamine compound comprising at least three amino groups; (b) at least one nonionic surfactant; (c) at least one compound chosen from an alkyl ether carboxylic acid, an alkyl ether carboxylate, a fatty acid having from about 6 to about 40 carbon atoms, and mixtures thereof; (d) at least one dye chosen from oxidation dye precursors and direct dyes. The compositions of the present invention may optionally contain at least one thickening agent, at least one alkaline agent, at least one fatty substance, at least one salt, and at least one oxidizing agent.
    Type: Grant
    Filed: October 19, 2011
    Date of Patent: March 5, 2013
    Assignee: L'Oreal
    Inventors: Sawa Hashimoto, Nghi Van Nguyen, Tan Siliu
  • Patent number: 8378083
    Abstract: This invention relates to bis-azo colorants for use as bluing agents, laundry care compositions comprising bis-azo colorants that may serve as bluing agents, processes for making such bluing agents and laundry care compositions and methods of using the same. The bluing agents are generally comprised of at least two components: at least one chromophore component and at least one polymeric component. These bluing agents are advantageous in providing a whitening effect to fabrics, while not building up over time and causing undesirable blue discoloration to the treated fabrics.
    Type: Grant
    Filed: October 22, 2010
    Date of Patent: February 19, 2013
    Assignee: Milliken & Company
    Inventors: Robert L. Mahaffey, Jr., Xiaoyong Michael Hong, Eduardo Torres, Dominick J Valenti, Gregory S Miracle
  • Patent number: 8349025
    Abstract: The present invention relates to a process for oxidative coloring keratin fibers especially human hair wherein dyeing compositions are thickened with a selected thickener. The objective of the present invention is a process for oxidative coloring hair wherein compositions A and B are mixed wherein composition A comprises at least one oxidative dye precursor and optionally at least one coupling agent and optionally at least one direct dye in a cosmetically acceptable medium and composition B comprises at least one oxidizing agent in a cosmetically acceptable medium, and applied onto hair and processed for 5 to 45 min at a temperature range of 20 to 45° C. and rinsed off from hair, wherein at least one of the two compositions A and B comprises a thickening polyurethane polymer.
    Type: Grant
    Filed: December 15, 2010
    Date of Patent: January 8, 2013
    Assignee: Kao Germany GmbH
    Inventors: Jonathan Wood, Alexandra Hullmann, Sandra Schmelz, Martin Uellner
  • Patent number: 8349022
    Abstract: A two-part hair dye composed of a first part containing an alkali agent, a second part containing hydrogen peroxide, and a non-aerosol foamer container for discharging a liquid mixture of the first part and the second part in the form of a foam, the liquid mixture containing the following components (A) and (B): (A) a polymer or copolymer containing 70% or more mole fraction of diallyldimethyl quaternary ammonium salt monomer, and (B) an N-acylamino acid salt, an N-acyl-N-alkylamino acid salt, or an ether carboxylic acid salt, wherein, an equivalent ratio of the anion site of the component (B) to the cation site of the component (A) (anion/cation) is more than 1, and a viscosity of the liquid mixture at 25° C. is 1 to 300 mPa·s.
    Type: Grant
    Filed: March 9, 2010
    Date of Patent: January 8, 2013
    Assignee: Kao Corporation
    Inventors: Makoto Iijima, Naohiro Ando, Takashi Matsuo, Yuko Nobuto
  • Patent number: 8343238
    Abstract: A process for altering the appearance of hair, the process comprising the steps of (a) providing a composition for dyeing and reducing curl and/or frizziness of hair, said composition comprising, in a cosmetically acceptable carrier: (i) at least one non-hydroxide base; (ii) at least one protein denaturant different from (a)(i); (iii) at least one dye chosen from oxidative dye precursors; (iv) at least one thickening agent; (v) optionally, at least one alkoxysilane comprising at least one solubilizing functional group; and (vi) optionally, at least one fatty substance; (b) contacting the hair with the composition in (a) to form treated hair; (c) smoothing the treated hair using a combination of heat and means for physically smoothing hair to form smoothed hair; (d) optionally, shampooing the smoothed hair; and (e) rinsing the smoothed hair.
    Type: Grant
    Filed: December 30, 2011
    Date of Patent: January 1, 2013
    Inventors: Gloria Lopez, Jeremy Puco
  • Patent number: 8343237
    Abstract: The present invention provides a composition for treating keratin fibers, and especially human keratin fibers such as the hair, which comprises, in a cosmetically acceptable medium, one or more alkanolamines, one or more amino acids and one or more associative polymers. The present invention likewise provides methods of bleaching and/or coloring keratin fibers, and also multiple-compartment devices or kits for the implementation of these methods.
    Type: Grant
    Filed: December 17, 2008
    Date of Patent: January 1, 2013
    Assignee: L'Oreal
    Inventors: Frédéric Legrand, Jean-Marc Ascione
  • Patent number: 8337569
    Abstract: Disclosed are polymeric dyes of formula (1a), (1b), or (1c); wherein the substituents and variables are defined in the claims and specification. The dyes are distinguished by their depth of shade and their good fastness properties to washing, such as, for example, fastness to light, shampooing and rubbing.
    Type: Grant
    Filed: July 15, 2010
    Date of Patent: December 25, 2012
    Assignee: BASF SE
    Inventors: Christian Cremer, Oliver Becherer, Beate Fröhling
  • Patent number: 8324338
    Abstract: An oligomer removing agent for polyester-based fiber materials comprises a polyester copolymer which is obtained by polycondensation of a dibasic acid component containing 15-65 mol % of a sulfonate group-containing dibasic acid and a dihydric alcohol component containing polyethylene glycol with a molecular weight of 900-3500, and which has a 200° C. melt viscosity of 5000-23,000 mPa·s and has 10-40 mass % polyoxyethylene chains in the molecule. The oligomer removing agent is able to overcome the problems caused by deposition of polyester oligomers, when added to the dyeing bath in a dyeing step for polyester fiber materials or for fiber materials that are composites thereof with other fiber materials.
    Type: Grant
    Filed: January 21, 2011
    Date of Patent: December 4, 2012
    Assignee: Nicca Chemical Co., Ltd.
    Inventors: Masaaki Hosoda, Masatoshi Hayashi
  • Patent number: 8292973
    Abstract: A hair colorant composition being essentially free of surfactant and having a specific perfume system for the hair colorant composition, where the hair colorant composition is capable of forming a foamed hair colorant composition.
    Type: Grant
    Filed: April 25, 2012
    Date of Patent: October 23, 2012
    Assignee: The Procter & Gamble Company
    Inventors: Jose Maria Velazquez, Sebastian Karol Galazka, Brandon Scott Lane, Firoj Vohra, Elizabeth H. Agostino, George Scott Kerr, Robert Drennan Lewis, Christopher Gerald Donner
  • Patent number: 8292972
    Abstract: An oxidative hair colorant composition to be dispensed from a manually-actuable, non-aerosol dispenser as a foam. The oxidative hair colorant composition contains a foam stabilizing agent and is essentially free of surfactant.
    Type: Grant
    Filed: April 25, 2012
    Date of Patent: October 23, 2012
    Assignee: The Procter & Gamble Company
    Inventors: Brandon Scott Lane, Firoj Vohra, Sebastian Karol Galazka, Karen Michelle Nally, Elizabeth H. Agostino, George Scott Kerr, Robert Drennan Lewis, Mark Thomas Lund, Shawn David McConaughy, Edward Dewey Smith, III, Christopher Gerald Donner
  • Publication number: 20120246842
    Abstract: A dyed fibrous material comprising a plurality of textile fibers, particularly cotton fibers, and a polymer bonded to the fibers and to a disperse dye material to affix the dye material to the fibrous material.
    Type: Application
    Filed: March 30, 2012
    Publication date: October 4, 2012
    Applicant: CELANESE INTERNATIONAL CORPORATION
    Inventors: Harrie P. Schoots, Carissa Vidlak, David Lunsford
  • Patent number: 8257447
    Abstract: Compositions for treating keratin fibers comprising, in a cosmetically acceptable medium, at least one alkanolamine, at least one amino acid, and at least one cationic polymer. Also provided are methods of bleaching and/or coloring keratin fibers and multiple-compartment devices or kits for the implementation of these methods.
    Type: Grant
    Filed: December 17, 2008
    Date of Patent: September 4, 2012
    Assignee: L'Oreal S.A.
    Inventors: Frédéric Legrand, Jean-Marc Ascione
  • Patent number: 8236063
    Abstract: Agent for oxidative coloring of keratinic fibers comprising a specific combination of non-ionic emulsifiers with a differing degree of ethoxylation and a specific combination of interfacially active substances comprising at least one anionic, at least one zwitterionic and at least one amphoteric surfactant. The agents provide good coloring characteristics while simultaneously protecting against damage to human hair. In particular the agents allow for colors with high color intensity and an improved gray coverage. The agents also provide significant advantages with regard to viscosity stability during storage and use and an improvement in shear sensitivity.
    Type: Grant
    Filed: November 8, 2011
    Date of Patent: August 7, 2012
    Assignee: Henkel AG & Co. KGaA
    Inventors: Anja Reichert, Irmgard Bender, Mechtild Grunwald, Astrid Kleen
  • Patent number: 8221508
    Abstract: Polymeric dye comprising oligo and polypeptides selected from natural or synthetic aminoacids bearing at least one covalently bounded cationic dye. Very good dyeing results on human hair are obtained with these dyes.
    Type: Grant
    Filed: December 4, 2009
    Date of Patent: July 17, 2012
    Assignee: BASF SE
    Inventors: Sophie Marquais-Bienewald, Christian Cremer, Olof Wallquist, Xian-Zhi Zhou, Barbara Wagner
  • Patent number: 8206464
    Abstract: Disclosed are cationic polymeric dye with a hue value of h=210° to 330° comprising: a) a polymer backbone, b) a residue of an organic dye, and c) optionally colorless organic groups, wherein (b) and (c) are covalently bound to the polymer backbone (a), and wherein the cationic charges can independently be part of the dye or the colorless organic groups. The dyes are distinguished by their depth of shade and their good fastness properties to washing, such as, for example, fastness to light, shampooing and rubbing.
    Type: Grant
    Filed: January 7, 2009
    Date of Patent: June 26, 2012
    Assignee: BASF SE
    Inventors: Christian Cremer, Sophie Marquais-Bienewald, Olof Wallquist, Beate Fröhling
  • Patent number: 8187339
    Abstract: A hair colorant composition being essentially free of surfactant and having a specific perfume system for the hair colorant composition, where the hair colorant composition is capable of forming a foamed hair colorant composition.
    Type: Grant
    Filed: December 17, 2010
    Date of Patent: May 29, 2012
    Assignee: The Procter & Gamble Company
    Inventors: Jose Maria Velazquez, Sebastian Karol Galazka, Brandon Scott Lane, Firoj Vohra, Elizabeth H. Agostino, George Scott Kerr, Robert Drennan Lewis, Christopher Gerald Donner
  • Patent number: 8187338
    Abstract: An oxidative hair colorant composition to be dispensed from a manually-actuable, non-aerosol dispenser as a foam. The oxidative hair colorant composition contains a foam stabilizing agent and is essentially free of surfactant.
    Type: Grant
    Filed: December 17, 2010
    Date of Patent: May 29, 2012
    Assignee: The Procter & Gamble Company
    Inventors: Brandon Scott Lane, Firoj Vohra, Sebastian Karol Galazka, Karen Michelle Nally, Elizabeth H. Agostino, George Scott Kerr, Robert Drennan Lewis, Mark Thomas Lund, Shawn David McConaughy, Edward Dewey Smith, III, Christopher Gerald Donner
  • Publication number: 20120128752
    Abstract: The invention relates to a method of manufacturing multi-phase microparticles. The method comprises dissolving at least three different polymers in a volatile organic solvent to obtain a first solution. The first solution comprises at least two cloud points, wherein the second cloud point is higher than the first cloud point. Viscosity of the first solution and the first and second cloud point are selected such that the at least three different polymers are immiscible with each other in the first solution. The first solution is dispersed into an aqueous continuous phase which comprises a surfactant to obtain an emulsion. The volatile organic solvent is evaporated from the emulsion. The total concentration of the at least three different polymers together in the emulsion before evaporation is below the first cloud point, or is above the first cloud point and below the second cloud point or is above the second cloud point.
    Type: Application
    Filed: June 7, 2010
    Publication date: May 24, 2012
    Applicant: NANYANG TECHNOLOGICAL UNIVERSITY
    Inventors: Say Chye Joachim Loo, Wei Li Lee
  • Patent number: 8137415
    Abstract: The present invention is related to an aqueous composition comprising an alkalizing agent and an aqueous emulsion of a silicone copolymer. The inventors of the present invention have surprisingly found out that a composition comprising at least one alkalizing agent and an aqueous emulsion of divinyldimethicone/dimethicone copolymer with an internal phase viscosity of more than 1×108 mm2/s measured at 0.01 Hz and at about 25° C. colors and/or permanently shapes hair excellently and improves hair shine, combability and manageability and especially hair treated with such composition has less flyaway. Additionally it has been observed that hair colored and/or permanently shaped more homogeneously from root to tips. The subject of the present invention is an aqueous composition for human hair comprising at least one alkalizing agent and an aqueous emulsion of divinyldimethicone/dimethicone copolymer with an internal phase viscosity of more than 1×108 mm2/s measured at 0.01 Hz and at about 25° C.
    Type: Grant
    Filed: October 20, 2009
    Date of Patent: March 20, 2012
    Assignee: KPSS KAO Professional Salon Services GmbH
    Inventors: Jonathan Wood, Alexandra Meuser, Mustafa Grit
  • Patent number: 8137414
    Abstract: The present invention is related to an aqueous composition comprising an alkalizing agent and a cationic polymer. The inventors of the present invention have surprisingly found out that a composition comprising at least one alkalizing agent and a cationic polymer consisting of a copolymer of vinylpyrrolidone and vinylimidazole and a homopolymer of dimethyl dially ammonium chloride colors and/or permanently shapes hair excellently and improves hair shine, combability and manageability and especially hair treated with such composition has less flyaway. Additionally it has been observed that hair colored and/or permanently shaped more homogeneously from root to tips. The object of the present invention is a composition for hair comprising at least one alkalizing agent and a cationic polymer consisting of a copolymer of vinylpyrrolidone and vinylimidazole and a homopolymer of dimethyl dially ammonium chloride. Cationic charge density of the polymer is preferably between 3 and 4 mEq/g and particularly 3.
    Type: Grant
    Filed: October 20, 2009
    Date of Patent: March 20, 2012
    Assignee: KPSS KAO Professional Salon Services GmbH
    Inventors: Jonathan Wood, Alexandra Meuser, Mustafa Grit
  • Patent number: 8137413
    Abstract: An aqueous oxidative coloring composition for keratin fibers has at least one oxidative dye precursor and optionally at least one coupling agent and an aqueous emulsion of divinyldimethicone/dimethicone copolymer with an internal phase viscosity of more than 1×108 mm2/s measured at 0.01 Hz and at about 25° C. and at least one alkyl ether or ester or amine alkyl amine or quaternary ammonium compound.
    Type: Grant
    Filed: October 20, 2009
    Date of Patent: March 20, 2012
    Assignee: KPSS KAO Professional Salon Services GmbH
    Inventors: Jonathan Wood, Alexandra Hullmann, Mustafa Grit
  • Patent number: 8133285
    Abstract: Described are hair colorant compositions comprising an aqueous dispersion comprising an ethylene acrylic acid copolymer, and optionally a metallocene catalyzed polyolefin. an aqueous dispersion comprising a metallocene catalyzed polyolefin and an ethylene acrylic acid copolymer, and methods of reducing hair damage from hair colorants, comprising including an aqueous dispersion comprising a metallocene catalyzed polyolefin and an ethylene acrylic acid copolymer in the hair colorant.
    Type: Grant
    Filed: March 22, 2011
    Date of Patent: March 13, 2012
    Inventors: Susan L. Jordan, Curtis Schwartz
  • Patent number: 8118880
    Abstract: A natural coloring composition for coloring materials, and methods of its use. The coloring composition comprises a natural precursor aromatic ring molecule such as L-DOPA that is oxidatively oligomerized or polymerized in the presence of arginine and an activator, such as a salt or an enzyme, wherein the L-DOPA and the amino acid form a specific non-covalent interaction. The natural coloring composition can also include a buffer, colorant, stabilizer, and/or thickening agent, and can comprise one or two inactive solutions that are combined to form an active coloring composition.
    Type: Grant
    Filed: November 15, 2010
    Date of Patent: February 21, 2012
    Assignees: Warner Babcock Institute for Green Chemistry, LLC, John Masters Organic Hair Care, Inc.
    Inventors: John C. Warner, Emily J. Stoler
  • Patent number: 8118883
    Abstract: Disclosed are polymeric dyes obtained by the reaction of (a) a basic polycondensate with (b) an electrophilic dye of formula (2) P—X—Ya+ Ana+; wherein the basic polycondensate (a) is obtained by the reaction of (a1) an amine of formula (I) in the presence of an anhydrous solvent with an ammonium salt (a2) with a cyanamide: Wherein P, X, Y, a+, a, a1, a2, An, R1, R2, R3, R4, R5, R6 and A are defined in the claims and in the disclosure. The present invention also relates to compositions comprising these polymeric dyes, to a process for their use for dyeing of organic materials, such as keratin fibers, wool, leather, silk, cellulose or polyamides.
    Type: Grant
    Filed: January 7, 2009
    Date of Patent: February 21, 2012
    Assignee: BASF SE
    Inventors: Sophie Marquais-Bienewald, Christian Cremer, Olof Wallquist, Robert Hochberg
  • Patent number: 8119778
    Abstract: A reversible thermochromic system comprising a) a compound of the formula (I) or a tautomer thereof (I) wherein R1 is C1-C18alkyl, C2-C18alkenyl, C3-C12cycloalkyl, C3-C12cycloalkyl substituted by 1, 2 or 3 C1-C4alkyl; or C7-C12phenylalkyl; R2 and R3 are hydrogen or R2 and R3 together form a group —CH?CH—CH?CH—; and R4 is hydrogen, —NO2, —SO2—R1 or (4-nitrophenyl)azo; and b) a compound containing a group of the formula (II).
    Type: Grant
    Filed: June 20, 2007
    Date of Patent: February 21, 2012
    Assignee: BASF SE
    Inventors: Walter Fischer, Abdel-Ilah Basbas, Martin Brunner, Rolf Benz, Manuele Vitali
  • Patent number: 8118882
    Abstract: Disclosed are cationic oligomeric dye, comprising a low molecular weight polyamine comprising the repeating units (1a) or (1b), wherein at least 90% of the polyamine molecules are selected from tetramines, pentamines and hexamines; and R is the residue of a cationic dye, which is covalently bonded, optionally via a linker, to the nitrogen atoms of the polyamine; or hydrogen; wherein the polyamine repeating units (1a) and (1b) comprise at least one carionic dye residue; and n is a number from 3-12. The dyes are distinguished by their depth of shade and their good fastness properties to washing, such as, for example, fastness to light, shampooing and rubbing.
    Type: Grant
    Filed: January 7, 2009
    Date of Patent: February 21, 2012
    Assignee: BASF SE
    Inventors: Christian Cremer, Sophie Marquais-Bienewald, Olof Wallquist
  • Patent number: 8118884
    Abstract: The subject of the present disclosure relates to compositions for dyeing or lightening human keratin fibers, comprising: (a) at least 25% by weight of at least one fatty substance; (b) at least one amphoteric polymer; (c) at least one basifying agent; and (d) at least one oxidizing agent. The present disclosure also relates to a dyeing or lightening processes using the composition, and two- and three-compartment devices which make it possible to obtain a composition according to the present disclosure, after mixing of the compositions of the compartments just before application of the composition according to the present disclosure.
    Type: Grant
    Filed: December 22, 2010
    Date of Patent: February 21, 2012
    Assignee: L'Oreal S.A.
    Inventors: Jean-Marc Ascione, Jean Cotteret
  • Patent number: 8110010
    Abstract: Agents for coloring keratin-containing fibers, in particular human hair, that contain encased oxidation dye precursor products. More-uniform coloring, which is independent of which strands are wetted first or last with the coloring product, is thereby ensured. The casing of the oxidation dye precursor products is made up of an encapsulating material made of methacrylic-acid, methacrylic acid-ester, or vinyl-acetate homo- or copolymers, or shellac, as well as at least one release agent. Contact time is equalized over time and shortened overall, resulting in a reduction in hair damage due to excessively long contact times. A method for manufacturing coloring agents for keratinic fibers, containing coated particles is also provided.
    Type: Grant
    Filed: June 20, 2011
    Date of Patent: February 7, 2012
    Assignee: Henkel AG & Co. KGaA
    Inventors: Carolin Welz, Hartmut Manneck, Astrid Kleen, Mustafa Akram
  • Patent number: 8105393
    Abstract: Compositions and methods relating to the use of pigment compositions are revealed, which can be used to impart color to hair. For instance, treatment formulations that include a pigment-functionalized cationic polymer can be utilized. In some particular instances, a plurality of serially applied treatment formulations is used to improve the characteristics of hair coloring. In addition, other formulations or treatments, such as one or more sealing compositions, or a final coating formulation can also be used to impart other desired characteristics such as treatment durability. Other components of various formulations/compositions are also discussed. Processes for using such compositions/formulations are disclosed. Along with the compositions, kits can be assembled where various compositions/formulations are compartmentalized for storage until the time for application.
    Type: Grant
    Filed: May 11, 2010
    Date of Patent: January 31, 2012
    Assignee: Boston Cosmetics, LLC
    Inventors: Noah A. Suddaby, David S. Soane, Michael C. Berg, Daniel A. Bercovici
  • Patent number: 8097045
    Abstract: Disclosed are olymeric dye of formula (1a), (1b), (1c), A and B, independently from each other represent a polymer backbone; X1 and X2 independently from each other are a linkage group selected from —C1-C30alkylene- or —C2-C12alkenylene-, which is interrupted and/or terminated at one or both ends by one or more than one —S—, —N—, —N?—, —N(R5)—, —S(O)—, —SO2—, —(CH2CH2—O)1-5—, —(CH2CH2CH2—O)1-5—, —C(O)—, —C(O)O—, —OCO—, (II), —CON(R1)—, —C(NR1R2)2—, —(R1)NC(O)—, —C(S)R1—; or an optionally substituted, saturated or unsaturated, fused or non-fused aromatic or nonaromatic (heterocyclic) bivalent radical optionally comprising at least one heteroatom; a saturated or unsaturated, fused or non-fused aromatic or nonaromatic bivalent radical comprising at least one heteroatom, which is optionally substituted by C1-C30alkyl, C1-C30alkoxy, C2-C12alkenyl, C5-C10aryl, C5-C10cycloalkyl, C1-C10alkyl(C5-C10arylene), hydroxy or halogen; R1 and R2 independently from each other are hydrogen; unsubstituted or substituted, straigh
    Type: Grant
    Filed: January 7, 2009
    Date of Patent: January 17, 2012
    Assignee: BASF SE
    Inventors: Sophie Marquais-Bienewald, Christian Cremer, Olof Wallquist, Beate Fröhling
  • Patent number: 8097046
    Abstract: Disclosed herein is an aqueous dye composition for dyeing keratin fibers, for example, human keratin fibers such as the hair, comprising, in a suitable dyeing medium: (a) at least one oxidizing agent, (b) at least one water-insoluble oxygenated organic non-dyeing compound, present in an amount of at least 30% by weight relative to the total weight of the dye composition, and (c) at least one oxidation dye precursor and/or at least one direct dye. Also disclosed herein is a process for dyeing human keratin fibers, for example, the hair, comprising applying such a composition to the keratin fibers.
    Type: Grant
    Filed: February 9, 2011
    Date of Patent: January 17, 2012
    Assignee: L'Oreal S.A.
    Inventors: Sylvain Kravtchenko, Claude Dubief
  • Patent number: 8092552
    Abstract: The present invention provides a dyeing composition comprising, in a cosmetically acceptable medium, one or more oxidation dyes, aqueous ammonia, ammonium chloride and one or more additives selected from ceramides, silicas, ascorbic acid and/or its salts, fatty acids and/or salts thereof, alkanolamines and/or salts thereof, crosslinked homopolymers of acrylic acid, copolymers of dialkyldiallylammonium chloride and acrylic acid, and particular cationic polymers, or mixtures thereof. It likewise provides a method of colouring human keratin fibres, employing the said composition in the presence of a composition comprising one or more oxidizing agents. The invention further provides a multiple-compartment device appropriate to the implementation of the said method, comprising in a first compartment a dyeing composition according to the invention and in another compartment a composition comprising one or more oxidizing agents.
    Type: Grant
    Filed: March 27, 2009
    Date of Patent: January 10, 2012
    Assignee: L'Oreal S.A.
    Inventors: Caroline Goget, François Cottard, Florence Laurent, Jean-Marc Ascione
  • Patent number: 8088178
    Abstract: A hair cosmetic composition used for dyeing, bleaching, or destaining hair contains a fatty acid ester, a linear-chain higher fatty acid, polyethylene glycol having a number average molecular weight of 6,000 or more, an alkaline agent, and an oxidizing agent. The fatty acid ester is an ester of a fatty acid having a carbon number of 10 or less and an alcohol.
    Type: Grant
    Filed: May 28, 2010
    Date of Patent: January 3, 2012
    Assignee: Hoyu Co., Ltd.
    Inventors: Yuki Sasao, Yasue Yamazaki
  • Patent number: 8088177
    Abstract: A hair cosmetic composition used for dyeing, bleaching, or destaining hair contains diglycerin, 1,3-butylene glycol, and polyethylene glycol having a number average molecular weight of 10,000 or more.
    Type: Grant
    Filed: May 28, 2010
    Date of Patent: January 3, 2012
    Assignee: Hoyu Co., Ltd.
    Inventors: Yuki Sasao, Yasue Yamazaki
  • Patent number: 8088179
    Abstract: A hair cosmetic composition used for dyeing, bleaching, or destaining hair contains amino-modified silicone, dimethicone, and polyethylene glycol having a number average molecular weight of 10,000 or more.
    Type: Grant
    Filed: May 28, 2010
    Date of Patent: January 3, 2012
    Assignee: Hoyu Co., Ltd.
    Inventors: Yuki Sasao, Yasue Yamazaki
  • Patent number: 8066781
    Abstract: The present disclosure relates to a composition for dyeing or lightening human keratin fibers, comprising: a cosmetically acceptable medium; at least 25% by weight of at least one fatty substance; at least one cationic polymer; at least one dye chosen from oxidation dyes and direct dyes; at least one basifying agent; and at least one oxidizing agent. The disclosure also relates to a dyeing or lightening process using it. Another subject of the disclosure is multi-compartment devices or kits for obtaining, after mixing together the compositions of the compartments, just before its application, a composition according to the disclosure.
    Type: Grant
    Filed: December 18, 2009
    Date of Patent: November 29, 2011
    Assignee: L'Oreal S.A.
    Inventors: Leïla Hercouet, Frédéric Simonet, Marie-Pascale Audousset, Philippe Rapold
  • Publication number: 20110265273
    Abstract: The present invention discloses a modifier for modifying the polyester fiber as well as preparation method and application of the same. The modifier contains ethylene glycol, two-hydroxy-end polyether, dimethyl terephthalate, two-polyether-end modified organosilicon, and metal acetate catalyst. A two-step continuous production process is adopted. The first step is esterification; that is, ethylene glycol, two-hydroxy-end polyether, dimethyl terephthalate, and two-polyether-end organosilicon are added into a reactor, and have an esterification reaction in the presence of the catalyst. In the second step, the materials produced by the esterification is transported to a polymerizer, and have a polymerization reaction under the conditions of high temperature, vacuum and catalyst, producing the high molecular weight polyester/polyether/organosilicon terpolymer with a molecular weight of 1000˜50000 as the desired modifier.
    Type: Application
    Filed: May 5, 2011
    Publication date: November 3, 2011
    Applicant: DUPLUS CHEMICAL CO., LTD. OF ZHANGJIAGANG CITY
    Inventor: Jinhui CHEN
  • Patent number: 8043385
    Abstract: The present invention relates to a dyeing composition comprising, in a medium appropriate for dyeing: A) one or more specific cationic cellulose ether (s), B) one or more metasilicate (s), and C) one or more benzene, heterocyclic or naphthalene oxidation dye (s). The present invention also relates to a method for dyeing keratinous fibers employing such a composition and to the use of this composition for dyeing of keratinous fibers.
    Type: Grant
    Filed: July 17, 2008
    Date of Patent: October 25, 2011
    Assignee: L'Oreal S.A.
    Inventor: Marie-Pascale Audousset
  • Patent number: 8038733
    Abstract: A composition and system for use in coloring hair and improving color retention properties in colored hair is described. The composition of the present invention preferably includes hair dye and a copolymer of isobutylmethacrylate and silicone grafted acrylate in isoparaffin, whereby these components are combined in an aqueous based, or alternatively, a nonaqueous based solution. The system includes the step of applying the hair coloring solution to the hair.
    Type: Grant
    Filed: August 31, 2009
    Date of Patent: October 18, 2011
    Assignee: Farouk Systems, Inc.
    Inventor: Ali D. Ghannad
  • Patent number: 8034127
    Abstract: The present invention relates to hair coloring and hair bleaching compositions comprising at least one oxidizing agent, a specified gel network thickener system comprising a specified tertiary system, a cationic polymer and a mica and or titanium oxide. The compositions surprisingly provide improved hair colorant and bleaching compositions which deliver lift, lightening and color, whilst minimizing damage which are easy to manufacture and which improve adhesion of the composition to the hair roots.
    Type: Grant
    Filed: September 17, 2010
    Date of Patent: October 11, 2011
    Assignee: The Procter & Gamble Company
    Inventors: Andrei Sergeevich Bureiko, Juergen Schmenger