Five-membered Hetero Ring Having Two Or More Ring Hetero Atoms Of Which At Least One Is Nitrogen Patents (Class 8/570)
  • Patent number: 8864849
    Abstract: The present specification provides for an agent for coloring keratinic fibers. The agent includes, a cosmetic carrier, a compound of formula (I), R1 and R2 independently of one another denote hydrogen, a C1-C6 alkyl group, a C2-C6 alkenyl group, a hydroxyl group, a halogen, a C1-C6 alkoxy group, an amino group, a nitro group, an acetyl amino group, or a sulfonamide group; or when in ortho-position to one another, form a 5- or 6-membered, saturated or unsaturated ring, which optionally include further heteroatoms.
    Type: Grant
    Filed: May 6, 2014
    Date of Patent: October 21, 2014
    Assignee: Henkel AG & Co. KGaA
    Inventors: Wibke Gross, Ralph Nemitz, Melanie Moch, Astrid Kroos, Antje Gebert
  • Patent number: 8864848
    Abstract: The invention relates to agents for coloring keratinic fibers, in particular human hair, including in a cosmetic carrier at least one compound of the formula (I). The structures the of the general formula (I) have a heterocycle A which bears a quaternary nitrogen atom and thus a positive charge. The invention furthermore relates to the use of these novel azo dyes in agents for coloring hair and to the dyes themselves.
    Type: Grant
    Filed: May 5, 2014
    Date of Patent: October 21, 2014
    Assignee: Henkel AG & Co. KGAA
    Inventors: Wibke Gross, Ralph Nemitz, Melanie Moch
  • Patent number: 8821592
    Abstract: An agent for the oxidative dyeing of keratinous fibers is provided. The agent contains, as a developer-type oxidation dye precursor, a compound of Formula (I) that carries at least one cationic charge in Y.
    Type: Grant
    Filed: May 29, 2012
    Date of Patent: September 2, 2014
    Assignee: Henkel AG & Co. KGaA
    Inventors: Wibke Gross, Ralph Nemitz, Astrid Kroos
  • Patent number: 8623101
    Abstract: There is provided a coloring composition containing at least a first coloring material and at least a second coloring material, in which the first coloring material is a compound represented by the following Formula (Y), the second coloring material is, for example, the following compound 8, and the mass ratio of the content (% by mass) of the second coloring material in the composition to the content (% by mass) of the first coloring material in the composition is 0.001 to 1.0. Formula (Y) In Formula (Y), a plurality of M each independently represent a hydrogen atom or a cation, and when M represents a cation, M represents a Li+ ion, a Na+ ion, a K+ ion or a NH4+ ion.
    Type: Grant
    Filed: June 28, 2013
    Date of Patent: January 7, 2014
    Assignee: FUJIFILM Corporation
    Inventors: Keiichi Tateishi, Yoshihiko Fujie, Youichirou Takeshima
  • Patent number: 8597373
    Abstract: The invention relates to a process for dyeing keratin fibers, in which said fibers are treated: ? with a composition (A) comprising i) one or more indole or indoline compounds; ii) one or more metal salts; iii) hydrogen peroxide or one or more systems that generate hydrogen peroxide; and then ? with a composition (B) comprising iv) one or more basifying agents. The invention also relates to a hair dyeing process for obtaining better colorations, which are more uniform, chromatic and remanent and which do not impair the cosmetic properties of keratin fibers.
    Type: Grant
    Filed: June 13, 2011
    Date of Patent: December 3, 2013
    Assignee: L'Oreal
    Inventors: Frédéric Guerin, Gilles Genain, Patrick Choisy
  • Patent number: 8551191
    Abstract: Dicationic azo dyes of the formula (I), which are suitable for coloring keratin fibers, in particular human hair, and are in part themselves still not described in the prior art are provided. In colorations, particularly brilliant and luminous red shades are obtained. Agents for dyeing and optionally simultaneously lightening keratin fibers and methods for dyeing and optionally simultaneously lightening keratinic fibers also are provided.
    Type: Grant
    Filed: March 4, 2013
    Date of Patent: October 8, 2013
    Assignee: Henkel AG & Co. KGaA
    Inventors: Wibke Gross, Helmut Giesa, Astrid Kroos
  • Patent number: 8366792
    Abstract: The subject of the present invention is dye composition for keratin fibers, comprising, in suitable dyeing medium, a coupler of formula (I) or addition salts thereof with an acid a particular cationic or noncationic aminopyrazolopyridine derivative. The composition of the present invention makes it possible in particular to obtain a coloring with varied, intense and/or chromatic, aesthetic and relatively nonselective shades which are highly resistant to the various attacks to which the hair may be subjected.
    Type: Grant
    Filed: August 11, 2010
    Date of Patent: February 5, 2013
    Assignee: L'OREAL
    Inventors: Anne-Marie Couroux, Aziz Fadli
  • Patent number: 8268015
    Abstract: Use of a composition comprising hydrogen peroxide in a cosmetic vehicle allows gentle discoloring of permanently colored, keratinous fibers which have been colored with a specific coloring composition. The coloring composition used for coloring the fibers comprises, in a cosmetic vehicle, a combination of at least one CH-acidic compound with at least one reactive carbonyl compound. The discoloring composition contains preferably between 0% and 15% by weight of hydrogen peroxide and has the effect, in particular in a working time of 5 to 20 minutes even without the use of organic peroxo compounds and in the absence of inorganic persalts, of effective color removal with simultaneous gentle treatment of the fibers.
    Type: Grant
    Filed: June 16, 2011
    Date of Patent: September 18, 2012
    Assignee: Henkel AG & Co. KGaA
    Inventors: Doris Oberkobusch, Wibke Gross, Laura Stephan
  • Patent number: 8268014
    Abstract: The invention relates to hair dyeing composition comprising (a) a dye of formula (1); (b) ant least one dye selected from the compounds of formulae (2); (3) and (4); wherein D is the radical of a diazo component of the formula (2a); (2b); (2c); (2d); (2f); (2g) or (2h). The invention also relates to the dyeing methods for dyeing keratinous fibers comprising such dyeing composition.
    Type: Grant
    Filed: February 19, 2010
    Date of Patent: September 18, 2012
    Assignee: BASF SE Ludwigshafen
    Inventor: Beate Fröhling
  • Patent number: 8257448
    Abstract: The invention relates to hair dyeing composition comprising (a) a dye of formula (1); (b) a least one dye selected from the compounds of formulae (2) and (3), wherein D is the radical of a diazo component of the formula (2a) and (c) a quaternary ammonium salt selected from (c1) quaternary ammonium salts of the formula (4); (c2) imidazolium salts of the formula (5) and (c3) quaternary diammonium salts of the formula (6). The invention also relates to the dyeing methods for dyeing keratinous fibers comprising such dyeing composition.
    Type: Grant
    Filed: February 19, 2010
    Date of Patent: September 4, 2012
    Assignee: BASF SE
    Inventor: Beate Fröhling
  • Patent number: 8097044
    Abstract: Disclosed herein are compositions for simultaneous shaping, dyeing, and/or lightening of keratin fibers comprising at least one disulfide direct dye and at least one organic or mineral hydroxide alkaline agent. Also disclosed herein are processes for simultaneous shaping, dyeing, and/or lightening of keratin fibers using said compositions and compartmentalized devices comprising said compositions. The compositions disclosed herein may make it possible to obtain a long-lasting dyeing effect, while limiting the degradation of the keratin fibers.
    Type: Grant
    Filed: July 24, 2008
    Date of Patent: January 17, 2012
    Assignee: L'Oreal S.A.
    Inventors: Frédéric Guerin, Maxime de Boni
  • Patent number: 7988740
    Abstract: The invention relates to colorant compositions for the oxidative dyeing of keratin fibers comprising radical scavengers in the dyeing composition. The invention also relates to methods for reducing color formation outside of the keratin fiber during oxidative dyeing comprising using such compositions.
    Type: Grant
    Filed: April 20, 2010
    Date of Patent: August 2, 2011
    Assignee: The Procter & Gamble Company
    Inventors: Guiru Zhang, Bryan Patrick Murphy, Jennifer Mary Marsh, Richard Marc Dahlgren
  • Patent number: 7985266
    Abstract: The invention relates to colorant compositions for the oxidative dyeing of keratin fibers comprising an inhibiting system of radical scavengers and chelants in the dyeing composition. The invention also relates to methods for reducing color formation outside of the keratin fiber during oxidative dyeing comprising using such colorant compositions.
    Type: Grant
    Filed: April 20, 2010
    Date of Patent: July 26, 2011
    Assignee: The Procter & Gamble Company
    Inventors: Guiru Zhang, Bryan Patrick Murphy, Jennifer Mary Marsh, Richard Marc Dahlgren
  • Patent number: 7931697
    Abstract: The present disclosure relates to a composition for dyeing keratin fibers, comprising, in a suitable medium, at least one first oxidation base chosen from 2,3-diamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one and the addition salts thereof; and at least one second oxidation base chosen from 4,5-diamino-1-(?-hydroxyethyl)pyrazole and the addition salts thereof. The present disclosure also relates to a process for dyeing keratin fibers using the composition of the present disclosure, the use of this composition for dyeing keratin fibers, and also a method for making the composition of the present disclosure.
    Type: Grant
    Filed: November 6, 2009
    Date of Patent: April 26, 2011
    Assignee: L'Oreal S.A.
    Inventors: Gautier Deconinck, Jean-Baptiste Saunier, Patricia Desenne
  • Patent number: 7927382
    Abstract: Provided is a ready-to-use composition for the oxidation dyeing of keratin fibers, and for example human keratin fibers such as the hair, comprising: A) at least one fatty substance present in the ready-to-use composition in an amount of greater than or equal to 25% by weight relative to the total weight of the ready-to-use composition, B) at least one oxidation base chosen from 4,5-diaminopyrazoles and the acid addition salts thereof, C) at least one additional dye precursor other than the at least one oxidation base defined in B), D) at least one oxidizing agent, and optionally E) at least one alkaline agent. Also provided is a process comprising applying to the keratin fibers for a period of time sufficient to develop the desired coloring, the ready-to-use composition.
    Type: Grant
    Filed: December 18, 2009
    Date of Patent: April 19, 2011
    Assignee: L'Oreal S.A.
    Inventors: Marie-Pascale Audousset, Isabelle Schlosser
  • Patent number: 7896931
    Abstract: The present invention relates to a hair dye composition containing a dissociative azo dye which has high dyeing power, is capable of imparting a vivid color to the hair firmly, has excellent fastness to light, shampooing, sweat, friction, and heat, and fades less with the passage of time because the dye is stable against an alkali agent or an oxidizing agent and does not decompose during hair dyeing; and a hair dyeing method using the hair dye composition.
    Type: Grant
    Filed: June 27, 2008
    Date of Patent: March 1, 2011
    Assignees: Kao Corporation, FUJIFILM Corporation
    Inventors: Masakazu Yamaguchi, Osamu Takiguchi, Masaaki Tsukase, Yasuhiro Ishiwata
  • Patent number: 7892295
    Abstract: A disperse dye of formula (I): Wherein R1 and R2 independently are each (C1-C4)-alkyl, OH or (C1-C4)-alkoxy-substituted (C1-C4)-alkyl; R3 and R4 independently are each hydrogen or methyl; one of A and B is cyano and the other is —COOX; and X is (C2-C12)-alkyl, O-interrupted (C2-C12)-alkyl, (C3-C4)-alkenyl or phenyl-(C1-C4)-alkyl. The invention also relates to the preparation of the dye and the use of the dye.
    Type: Grant
    Filed: August 1, 2008
    Date of Patent: February 22, 2011
    Assignee: DyStar Colours Deutschland GmbH
    Inventor: Hartwig Jordan
  • Patent number: 7892294
    Abstract: Provided herein is a method for dyeing keratin fibers, comprising applying to the keratin fibers, at least one composition comprising at least one compound chosen from compounds of leuco type of formula (I), dyes of azomethine type containing a pyrazolopyridine unit of formula (II) corresponding to the compounds of formula (I), mesomeric forms, isomers and tautomers thereof, and also acid-addition salts thereof and solvates thereof:
    Type: Grant
    Filed: April 28, 2010
    Date of Patent: February 22, 2011
    Assignee: L'oreal S.A.
    Inventors: Aziz Fadli, Stéphane Blais
  • Patent number: 7887601
    Abstract: Disclosed herein is at least one compound chosen from compounds of leuco type of formula (I), dyes of azomethine type comprising a pyrazolopyridine unit of formula (II) corresponding to the compounds of formula (I), mesomeric forms, isomeric and tautomeric forms thereof, acid-addition salts thereof and solvates thereof:
    Type: Grant
    Filed: April 28, 2010
    Date of Patent: February 15, 2011
    Assignee: L'Oreal S.A.
    Inventors: Aziz Fadli, Stéphane Blais
  • Patent number: 7871445
    Abstract: The present disclosure relates to a dye composition for keratin fibers, such as keratin fibers, for example the hair, comprising, in a medium suitable for dyeing: at least one nonionic derivative of cellulose comprising at least one hydrophobic substituent containing from 8 to 30 carbon atoms; at least one oxidation base chosen from diaminodiazacyclopentene derivatives; and at least one oxidation coupler; and a process for dyeing keratin fibers using such a composition.
    Type: Grant
    Filed: November 10, 2008
    Date of Patent: January 18, 2011
    Assignee: L'Oreal S.A.
    Inventor: Marie-Pascale Audousset
  • Patent number: 7857864
    Abstract: Disclosed herein is a composition for the dyeing of keratin fibers, for example, human keratin fibers such as the hair, comprising at least one 3-amino pyrazolo-[1,5-a]-pyridine derivative or one of its addition salts and a method employing this derivative. The composition of the present disclosure makes it possible to obtain coloration in various shades that is powerful, chromatic, and aesthetic, with low selectivity and with good resistance to various aggressive factors to which the hair may be subjected, such as shampoos, the light, sweat and permanent shaping.
    Type: Grant
    Filed: October 9, 2009
    Date of Patent: December 28, 2010
    Assignee: L'Oreal S.A.
    Inventors: Aziz Fadli, Laurent Vidal, Stéphane Sabelle
  • Patent number: 7850742
    Abstract: Compositions for the oxidative dyeing of keratin fibers, comprising a medium suitable for dyeing and at least one 3-substituted pyrazole keratin dyeing compound and derivatives thereof. A method for oxidative dyeing of keratin fibers, comprising applying such compositions in the presence of an oxidizing agent, for a period sufficient to develop the desired coloration.
    Type: Grant
    Filed: May 11, 2009
    Date of Patent: December 14, 2010
    Assignee: The Procter & Gamble Company
    Inventors: Richard Marc Dahlgren, William David Laidig, Mu-ill Lim, Bryan Patrick Murphy, Guiru Zhang
  • Patent number: 7828858
    Abstract: Disclosed are mixtures of sulfide dyes and dyeing compositions comprising mixtures of sulfide dyes. The dye mixtures are useful for the dyeing of organic materials, such as keratin fibers, preferably human hair.
    Type: Grant
    Filed: September 13, 2006
    Date of Patent: November 9, 2010
    Assignee: Ciba Corporation
    Inventors: Christian Cremer, Victor Paul Eliu, Beate Fröhling, Olof Wallquist
  • Patent number: 7824449
    Abstract: A hair dye composition containing a triazene dissociative direct dye represented by general formula (1): A-N?N—NH-B (1) wherein A and B are each a monocyclic or a bicyclic aromatic heterocyclic group that may have a substituent or a monocyclic or a bicyclic aryl group that may have a substituent and contain none of a carboxy group, a sulfo group and a quaternary ammonium group; and A and B each bind to a triazene-1,3-diyl group represented by —N?N—NH— via a carbon atom within A and B each. A and B may be the same or different.
    Type: Grant
    Filed: April 25, 2008
    Date of Patent: November 2, 2010
    Assignees: Kao Corporation, FUJIFILM Corporation
    Inventors: Miyuki Hayama, Osamu Takiguchi, Yoshimasa Tate, Masaaki Tsukase
  • Patent number: 7803198
    Abstract: Provided is a hair dye comprising 0.1 to 3.0% by weight of at least one of aqueous acid dyes and a resin comprising a terpolymer constituted from a vinyl cyclic amide, an acrylic acid derivative and a quaternary derivative of acrylic acid, wherein a content of the resin is 0.1 to 2.5% by weight in terms of a solid content; and the hair dye further comprises 1.0 to 20% by weight of a hair dyeing auxiliary agent, 20 to 60% by weight of a lower alcohol and 20 to 60% by weight of water and has a pH of 2 to 4.
    Type: Grant
    Filed: February 12, 2008
    Date of Patent: September 28, 2010
    Assignee: Mitsubishi Pencil Company, Limited
    Inventors: Takashi Umeno, Keiichiro Takachiyo, Hiroaki Koyama
  • Patent number: 7794509
    Abstract: Disclosed are tricationic dye compounds, useful for dyeing hair, wool, leather, silk, cellulose or polyamides. The dye compounds are of formula (1), where the groups are as defined in the specification and claims.
    Type: Grant
    Filed: June 4, 2007
    Date of Patent: September 14, 2010
    Assignee: Ciba Corporation
    Inventors: Christian Cremer, Olof Wallquist, Victor Paul Eliu, Kishor Ramachandra Nivalkar
  • Patent number: 7731760
    Abstract: Disclosed are certain oxazine disulfide dyes useful for the dyeing of organic materials, such as keratin fibers, preferably human hair.
    Type: Grant
    Filed: September 27, 2006
    Date of Patent: June 8, 2010
    Assignee: Ciba Corporation
    Inventors: Christian Cremer, Olof Wallquist
  • Patent number: 7727287
    Abstract: The present disclosure relates to a novel dye composition for the dyeing and/or lightening of keratin materials, such dye comprising a hemicyanin styryl chromophore thiol or disulfide dye of formula (I) or (II): the organic or mineral acid salts thereof, optical isomers and geometric isomers thereof, and the solvates thereof such as hydrates. The present disclosure further relates to a dyeing process with a lightening effect on keratin materials, in particular keratin fibers, including human keratin fibers such as the hair, using said composition. This composition makes it possible to obtain a coloring with a lightening effect which is particularly resistant and visible on dark keratin fibers.
    Type: Grant
    Filed: September 19, 2008
    Date of Patent: June 1, 2010
    Assignee: L'Oreal S.A.
    Inventors: Andrew Greaves, Nicolas Daubresse
  • Patent number: 7678158
    Abstract: Compositions for dyeing keratin fibers comprise (a) at least one keratin dyeing compound selected from aromatic systems which comprise at least one boronic acid or boronic ester moiety and which are capable of forming upon oxidation a nucleophile or an electrophile, (b) at least one additional keratin dyeing compound selected from the group consisting of auxiliary developers and auxiliary couplers, and (c) a cosmetically suitable medium. Methods for oxidatively dyeing keratin fibers comprise the steps of applying such compositions in the presence of an oxidizing agent and rinsing the hair. A hair coloring product in kit form comprises a first separately packaged container comprising a composition as described above and a second separately packaged container comprising an oxidizing agent.
    Type: Grant
    Filed: February 12, 2009
    Date of Patent: March 16, 2010
    Assignee: The Procter & Gamble Company
    Inventors: Mu'lll Lim, Guiru Zhang, Margaret Popp, Bryan Patrick Murphy
  • Patent number: 7662193
    Abstract: Provided is a hair dye composition containing a dissociative direct dye (1): (wherein Ar represents an aromatic group or heterocyclic aromatic group which may have a substituent, Ar? represents an aromatic group which may be substituted by an alkyl group or an electron drawing group, or a specific heterocyclic aromatic group, and W represents an electron drawing group); or salt thereof.
    Type: Grant
    Filed: February 3, 2006
    Date of Patent: February 16, 2010
    Assignees: Kao Corporation, Fujifilm Corporation
    Inventors: Kenichi Matsunaga, Hiromi Saimiya, Dominic Pratt, Yasuhiro Ishiwata
  • Patent number: 7658770
    Abstract: The present invention relates to agents for coloring keratin fibers which comprise at least one cationic azodye of the general formula (I).
    Type: Grant
    Filed: February 26, 2009
    Date of Patent: February 9, 2010
    Assignee: The Procter & Gamble Company
    Inventors: Cécile Pasquier, Eric Tinguely, Markus Speckbacher, Annik Marguet, Hans-Jürgen Braun
  • Patent number: 7658771
    Abstract: The present invention relates to agents for coloring keratin fibers which comprise at least one cationic azodye of the general formula (I).
    Type: Grant
    Filed: February 26, 2009
    Date of Patent: February 9, 2010
    Assignee: The Procter & Gable Company
    Inventors: Cécile Pasquier, Eric Tinguely, Markus Speckbacher, Annik Marguet, Hans-Jürgen Braun
  • Patent number: 7655052
    Abstract: Disclosed herein is the use, in the coloring of keratinous fibers, for example human keratinous fibers, such as the hair, of a composition comprising at least one compound chosen from the compounds of formula (I) comprising a cyclic group G including a ring H capable of opening, the dyes corresponding to the compounds of formula (I) wherein the ring H is open and the addition salts thereof: and a method for treating keratinous fibers employing this composition.
    Type: Grant
    Filed: March 20, 2008
    Date of Patent: February 2, 2010
    Assignee: L'Oreal S.A.
    Inventors: Alain Lagrange, Frédéric Guerin
  • Patent number: 7651538
    Abstract: A hair dye composition containing an azo dye (1) or a salt thereof, (wherein R1 to R4 represents H, aliphatic hydrocarbon group, aryl group, halogen atom, acyl group, cyano group, acylamino group, or the like, wherein R1 and R2, and/or R3 and R4 may be coupled to form a 5- or 6-membered ring; X represents C or N, with the proviso that when X represents C, n stands for 1, and when X represents N, n stands for 0; A1, A2, A3 and A4 each represents N or represents C substituted by Y or having H, with the proviso that at least one of A1, A2, A3 and A4 is a nitrogen atom; and Y represents a substituent with the proviso that m stands for an integer from 0 to 3).
    Type: Grant
    Filed: February 10, 2006
    Date of Patent: January 26, 2010
    Assignees: Kao Corporation, Fujifilm Corporation
    Inventors: Masakazu Yamaguchi, Dominic Pratt, Yasuhiro Ishiwata
  • Patent number: 7648536
    Abstract: Disclosed herein are methods for coloring keratinous fibers comprising applying to the fibers a dyeing composition comprising at least one aminopyrazolopyridine base, said coloring method being performed without the addition of chemical oxidizing agents.
    Type: Grant
    Filed: May 9, 2008
    Date of Patent: January 19, 2010
    Assignee: L'Oreal S.A.
    Inventors: Jean-Baptiste Saunier, Aziz Fadli
  • Patent number: 7641703
    Abstract: Disclosed herein is the use, in the coloring of keratinous fibers, such as human keratinous fibers, such as the hair, of a composition comprising at least one compound chosen from the compounds of formula (I) comprising a cyclic group G including a ring H capable of opening, the dyes corresponding to the compounds of formula (I) wherein the ring H is open, and the addition salts thereof: and a method for treating keratinous fibers employing this composition.
    Type: Grant
    Filed: March 20, 2008
    Date of Patent: January 5, 2010
    Assignee: L'Oreal S.A.
    Inventors: Frédéric Guerin, Alain Lagrange
  • Patent number: 7635394
    Abstract: Disclosed herein is a composition for the dyeing of keratin fibers, for example, human keratin fibers such as the hair, comprising at least one 3-amino pyrazolo-[1,5-a]-pyridine derivative or one of its addition salts and a method employing this derivative. The composition of the present disclosure makes it possible to obtain coloration in various shades that is powerful, chromatic, and aesthetic, with low selectivity and with good resistance to various aggressive factors to which the hair may be subjected, such as shampoos, the light, sweat and permanent shaping.
    Type: Grant
    Filed: November 9, 2006
    Date of Patent: December 22, 2009
    Assignee: L'Oreal S.A.
    Inventors: Aziz Fadli, Laurent Vidal, Stéphane Sabelle
  • Patent number: 7585332
    Abstract: The present invention relates to compositions for dyeing keratin fibers, and in particular human keratin fibers such as the hair, comprising at least one compound of styryl or imine type containing a heterocycle and at least one thiol compound. The present invention makes it possible in particular to obtain a chromatic and fast coloration of keratin fibers, especially with respect to shampooing. Moreover, the color obtained is visible even on dark hair without necessarily using an oxidizing composition. The invention also makes it possible to obtain a coloration which, under certain conditions, does not stain.
    Type: Grant
    Filed: October 15, 2007
    Date of Patent: September 8, 2009
    Assignee: L'Oreal S.A.
    Inventor: Grégory Plos
  • Patent number: 7582123
    Abstract: The present disclosure relates to a composition for coloring keratin fibers which comprises, in an appropriate dyeing medium, at least one compound chosen from leuco compounds of formula (I), azomethine dyes with a pyrazolinone unit of formula (II), their mesomeric forms, acid addition salts and solvates thereof: and dyeing methods and multicompartment devices for use thereof.
    Type: Grant
    Filed: June 19, 2008
    Date of Patent: September 1, 2009
    Assignee: L'Oreal S.A.
    Inventors: Aziz Fadli, Eric Metais
  • Patent number: 7582122
    Abstract: Disclosed herein is a mixed cationic direct dye comprising at least one anthraquinone chromophore and at least one cationic chromophore chosen from cationic azo chromophores and cationic hydrazone chromophores, wherein the at least one anthraquinone chromophore is bound to the at least one cationic chromophore by means of at least one linkage. Also disclosed herein is a dyeing composition comprising at least one mixed cationic direct dye. Further disclosed herein is a method of dyeing of keratin fibers, for example, keratin fibers, comprising applying said dyeing composition to the keratin fibers. Still further disclosed herein is a multi-compartment kit comprising at least one compartment comprising at least one dye composition and at least one second compartment comprising at least one oxidizing agent.
    Type: Grant
    Filed: August 28, 2006
    Date of Patent: September 1, 2009
    Assignee: L'Oreal S.A.
    Inventors: Nicolas Daubresse, Andrew Greaves
  • Patent number: 7578855
    Abstract: The present disclosure relates to a composition for the dyeing of keratin fibers, such as the hair, comprising at least oneoxidation base chosen from cationic 3-amino pyrazolo-[1,5-a]-pyridine derivatives and addition salts thereof, and a method employing this composition. The present disclosure also relates to cationic 3-amino pyrazolo-[1,5-a]-pyridine derivatives and the addition salts thereof.
    Type: Grant
    Filed: November 9, 2006
    Date of Patent: August 25, 2009
    Assignee: L'Oréal S.A.
    Inventor: Aziz Fadli
  • Patent number: 7578856
    Abstract: Disclosed herein are compositions for dyeing keratinous fibers comprising, in an appropriate dyeing medium, at least one aminopyrazolopyridine oxidation base chosen from those of formula (I), wherein it is understood that at least one of the groups R?1, and R?2 is chosen from cationic radicals; at least one coupler and at least one C4-C30 polyol. Dyeing methods and multi-compartment devices for use thereof.
    Type: Grant
    Filed: May 9, 2008
    Date of Patent: August 25, 2009
    Assignee: L'Oreal S.A.
    Inventor: Jean-Baptiste Saunier
  • Patent number: 7569079
    Abstract: The present disclosure relates to polycationic monochromophoric hydrazone compounds of following formula (I): wherein W1 is a heteroaromatic radical comprising 5 or 6 ring members, optionally condensed with an aromatic ring comprising 6 ring members, comprising a quaternized nitrogen atom and optionally another heteroatom which may or may not be identical to nitrogen; X, which may or may not be identical, is a nitrogen atom or a CR2 group; Z is a cationic group comprising at least one quaternized nitrogen atom. 1The present disclosure also relates to a composition for dyeing human keratin fibers comprising the polycationic compounds disclosed herein, and to a dyeing process using the composition of the present disclosure, and ever further to multicompartment device.
    Type: Grant
    Filed: April 14, 2008
    Date of Patent: August 4, 2009
    Assignee: L'Oreal S.A.
    Inventors: Hervé David, Nadège Murguet
  • Patent number: 7559956
    Abstract: A subject-matter of the present invention is the use, in the direct dyeing of keratinous fibers, of at least one direct dye and of a specific cationic hydrotropic agent of formula: in which X represents CH or N+R6 with R6 representing a C1-C10 alkyl, R1 represents either a hydrogen or a C1-C10 alkyl, if X represents N+R6, or (CH2)nN+R3R4R5 with R3, R4 and R5, which are identical or different, representing a C1-C10 alkyl and n representing an integer between 0 and 12, if X represents CH; R2 represents a C1-C4 alkyl; p has a value 0 or 1; the electrical neutrality of the compound being provided by a cosmetically acceptable anion or a mixture of cosmetically acceptable anions. The invention likewise relates to a dyeing composition comprising at least one dye and such a cationic hydrotrope and to colouring processes employing this dyeing composition.
    Type: Grant
    Filed: May 17, 2007
    Date of Patent: July 14, 2009
    Assignee: L'Oreal S.A.
    Inventors: Maxime De Boni, Alain Lagrange
  • Patent number: 7553337
    Abstract: The present invention has for an object agents for the simultaneous brightening and coloring of keratin fibers—particularly hair—which are characterized in that (a) they contain an oxidant and (b) at least one thiazolium dye of formula (I) and that (c) they have a basic pH
    Type: Grant
    Filed: November 16, 2005
    Date of Patent: June 30, 2009
    Assignee: Wella AG
    Inventors: Cecile Pasquier, Caroline Kiener, Hans-Juergen Braun
  • Patent number: 7537620
    Abstract: The present invention has for an object agents for dyeing keratin fibers, characterized in that they contain at least one thiazoliumazo dye of general formula (I).
    Type: Grant
    Filed: November 16, 2004
    Date of Patent: May 26, 2009
    Assignee: Wella AG
    Inventors: Cecile Pasquier, Caroline Kiener, Hans-Juergen Braun
  • Patent number: 7534273
    Abstract: The present application relates to cationic pyrazolone dyes of the general formula (I), and to coloring agents for keratin fibers comprising these dyes.
    Type: Grant
    Filed: May 18, 2005
    Date of Patent: May 19, 2009
    Assignee: Wella AG
    Inventors: Markus Speckbacher, Hans-Juergen Braun
  • Patent number: 7531008
    Abstract: The present disclosure relates to the use of a direct dye as an agent for lightening keratin fibers, such as, for example, human keratin fibers, and/or as an agent for coloring the said fibers. The disclosure also relates to a composition comprising, in a cosmetically acceptable medium, at least the direct dye. The disclosure also relates to a process for treating keratin fibers, including human keratin fibers, using the abovementioned composition, and also to a device comprising it. Finally, the disclosure relates to the use of the composition according to the disclosure as a coloring agent and/or as an optical lightening agent for the fibers.
    Type: Grant
    Filed: November 30, 2006
    Date of Patent: May 12, 2009
    Assignee: L'Oreal S.A.
    Inventor: Alain Lagrange
  • Patent number: 7527654
    Abstract: The present invention relates to a process for dyeing keratin fibers, in particular human keratin fibers such as the hair, using a dye composition comprising at least one dye of styryl or imine type in the presence of a revealing composition comprising at least one optionally substituted (hetero) aromatic compound of weak acid type. The present invention makes it possible in particular to obtain a chromatic and fast coloration of keratin fibers, which is visible even on dark hair without prior lightening. The invention also makes it possible to obtain a coloration which, under certain conditions, does not stain.
    Type: Grant
    Filed: October 12, 2007
    Date of Patent: May 5, 2009
    Assignee: L'Oreal S.A.
    Inventor: Grégory Plos
  • Patent number: 7517368
    Abstract: The present invention has for an object agents for coloring keratin fibers and containing at least one indolylthiazoliumazo dye of general formula (I)
    Type: Grant
    Filed: November 26, 2004
    Date of Patent: April 14, 2009
    Assignee: Wella AG
    Inventors: Cecile Pasquier, Veronique Buclin, Nadia Duc-Reichlin, Caroline Kiener, Hans-Juergen Braun