Aryl Ether Patents (Class 8/610)
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Publication number: 20020132737Abstract: The invention relates to compounds of the formula (I) 1Type: ApplicationFiled: August 29, 2001Publication date: September 19, 2002Inventors: Helmut-Martin Meier, Hans-Joachim Knackmuss, Paul-Gerhard Rieger
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Patent number: 6436153Abstract: The invention relates to a direct dye composition for keratin fibers, in particular for human keratin fibers such as the hair, comprising, in a medium which is suitable for dyeing and which is free of oxidases or oxidoreductases, at least one cationic direct dye of given formula and at least one specific polyol and/or polyol ether. Subjects of the invention are also the dyeing processes and devices/kits using the said composition.Type: GrantFiled: May 28, 1999Date of Patent: August 20, 2002Assignee: L'Oréal S.A.Inventor: Christine Rondeau
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Patent number: 6371994Abstract: The invention relates to a dye composition for keratin fibers, in particular for human keratin fibers such as the hair, comprising at least one cationic direct dye of given formula and at least glycerol and/or one specific polyol and/or polyol ether. The invention also relates to the dyeing processes and devices using this composition.Type: GrantFiled: May 28, 1999Date of Patent: April 16, 2002Assignee: L'Oreal S.A.Inventors: Gérard Lang, Jean Cotteret
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Patent number: 5968207Abstract: A process for imparting long-lasting antimicrobial properties to fabrics is disclosed which entails the diffusion of triclosan esters within each individual fiber of a textile. One preferred method is performed in a standard jet dye bath which requires a high range of temperatures to effectively color fabrics. Dyeing in this manner also involves diffusing compounds within individual fibers; thus, this manner of incorporating dyestuffs and colorants within textile fabrics provides a compatible and effective vehicle for simultaneously introducing triclosan esters within such textile fibers, also. A dye bath application is not required, however, as any procedure which allows contact between a triclosan ester derivative and a fabric at a sufficient temperature and for a sufficient time to effectuate diffusion of the ester within each individual fiber of the fabric is also contemplated within this invention.Type: GrantFiled: February 20, 1998Date of Patent: October 19, 1999Assignee: Milliken & CompanyInventor: Shulong Li
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Patent number: 5762650Abstract: A composition and a process are disclosed for imparting durable antimicrobial properties to fibrous materials. The composition contains a leveling surfactant and a water-insoluble antimicrobial compound. In one embodiment, simultaneous dyeing and antimicrobial finishing of a fibrous material is achieved using an aqueous dye bath containing the aforesaid composition.Type: GrantFiled: August 23, 1996Date of Patent: June 9, 1998Assignee: Olin CorporationInventors: Murray A. Ruggiero, Phil Magan, Thomas Edgar Robitaille, Robert P. Roth, James J. Irovando
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Patent number: 5554199Abstract: Dyeing of cellulosic substrates with reactive dyes in the presence of at least 20 g/l of sodium chloride, employing auxiliaries (E) of levelling activity, which are methylene-bridge-containing and sulpho-group-containing aromatic compounds, obtainable by condensation of defined sulphonation products with formaldehyde resp. formaldehyde-yielding compounds and optionally salt formation; (E)-contaning compositions that further contain at least one hydrotrope (H) and/or at least one sequestering agent (Q); and novel condensation products.Type: GrantFiled: November 17, 1994Date of Patent: September 10, 1996Assignee: Sandoz Ltd.Inventor: Hans-Peter Baumann
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Patent number: 5460632Abstract: The present invention relates to an acid dye-leveling composition that is useful for imparting a dye leveling characteristic to fibers prior to, or during, the fiber dyeing operation. Also described is a process for preparing the dye-leveling composition, as well as a process for using the composition in the dyeing of fibers. The composition is particularly useful for treating polyamide fibers, such as nylon, but is also suitably used in the treatment of silk, wool, and other synthetic and natural fibers. The composition is also useful as a hard surface cleaner, adhesive additive, and a leveling agent for paints.Type: GrantFiled: December 29, 1994Date of Patent: October 24, 1995Assignee: Olin CorporationInventors: Murray A. Ruggiero, Bruce A. Marien
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Patent number: 5360457Abstract: The present invention relates to an acid dye-leveling composition comprising a piperazine substituted organosulfonate that is useful for imparting a dye leveling characteristic to fibers prior to, or during, the fiber dyeing operation. Also described is a process for preparing the dye-leveling composition, as well as a process for using the composition in the dyeing of fibers. The composition is particularly useful for treating polyamide fibers, such as nylon, but is also suitably used in the treatment of silk, wool, and other synthetic and natural fibers.Type: GrantFiled: January 31, 1994Date of Patent: November 1, 1994Assignee: Olin CorporationInventors: Murray A. Ruggiero, Bruce A. Marien, Shoaib Arif, Robert P. Roth, Joseph T. Farrell, A. R. Vanover
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Patent number: 5300122Abstract: PEKK fiber is dyed with a disperse dye in an organic dye carrier.Type: GrantFiled: October 1, 1992Date of Patent: April 5, 1994Assignee: E. I. Du Pont de Nemours and CompanyInventor: David J. Rodini
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Patent number: 5259849Abstract: The invention relates to compositions, which are stable on storage, of certain benzoquinone and naphthoquinone dyestuffs in an anhydrous solvent containing a non-ionic surface-active agent.Type: GrantFiled: June 10, 1992Date of Patent: November 9, 1993Assignee: L'OrealInventors: Jean F. Grollier, Jean Cotteret
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Patent number: 5244476Abstract: The present invention relates to compounds of the general formula I ##STR1## in which R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, x and y are defined as in the description, processes for their preparation, their use for improving the light stability of polyester dyeings and a dyeing process and dye preparations.Type: GrantFiled: March 13, 1992Date of Patent: September 14, 1993Assignee: Cassella AGInventors: Joachim Schulz, Gunter Bartels
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Patent number: 5209758Abstract: The invention relates to novel pasty or solid dye melts which contain, per 1 part of a sparingly water-soluble or water-insoluble dye whose melting point is higher than 150.degree. C., 2 to less than 5 parts of a nonionic surfactant with a melting point of 25.degree.-100.degree. C. and having an HLB value of 13 to 19 or of a cationic surfactant with a melting point of 25.degree.-100.degree. C., or a mixture of said surfactants, to a process for their preparation and to the use of said melts, preferably for dyeing and printing polyester materials, to give level dyeings having a high degree of exhaustion.Type: GrantFiled: December 4, 1991Date of Patent: May 11, 1993Assignee: Giba-Geigy CorporationInventors: Rainer H. Traber, Ulrich Strahm
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Patent number: 5207802Abstract: Compounds and mixtures of compounds obtainable by condensation of sulphonation products of defined alkyl-substituted naphthalenes and sulphonation products of optionally alkyl-substituted diphenylethers with formaldehye and optionally treated with further components, are valuable interface-active compounds suitable as assistants in various application fields, in particular as dispersing or levelling agents in the dyeing with disperse dyes or as tanning-assistants or dyeing-assistants for leather.Type: GrantFiled: August 23, 1990Date of Patent: May 4, 1993Assignee: Sandoz Ltd.Inventor: Hans-Peter Baumann
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Patent number: 5096456Abstract: A process for improving the thermal and/or photochemical stability of dyeings on polyamide fibres by applying to said fibres, from an aqueous medium, water-soluble phenolic antioxidants of formula (A--Y--).sub.n Z(--W).sub.m, wherein A, Y, Z, W, m and n are as defined in claim 1.Type: GrantFiled: January 15, 1991Date of Patent: March 17, 1992Assignee: Ciba-Geigy CorporationInventors: Gerhard Reinert, Francesco Fuso
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Patent number: 5074887Abstract: Aqueous dye preparations are described which contain 15-40% by weight of dyes, 3-18% by weight of an anionic dispersant of the formula (1), 1-10% by weight of sodium lactate, 1-10% by weight of glycerol and/or propylene glycol, 0.1-5% by weight of a compound having monomer units of the general formula (2), 3-10% by weight of betaine monohydrate, 0-4% by weight of a compound having monomer units of the general formula (3) and 0.1-15% by weight of customary auxiliaries; preparations of this type have a long shelf life, are highly redispersible and do not form sediments; they are suitable in particular for the continuous dyeing of polyester textile materials or mixtures thereof with cellulose textile materials.Type: GrantFiled: October 23, 1990Date of Patent: December 24, 1991Assignee: Ciba-Geigy CorporationInventor: Zdenek Koci
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Patent number: 5009668Abstract: Mixture of dyeing assistants containing(A) an acid ester, or salts thereof, of an alkylene oxide adduct of the formula ##STR1## in which V is hydrogen or methyl, X is the acid radical of an inorganic acid containing oxygen, or the radical of an organic acid and Y is C.sub.1 -C.sub.12 alkyl, aryl or aralkyl, "alkylene" is the ethylene or propylene radical and m is 1 to 3, m.sub.1 is 1 or 2 and n is 4 to 50,(B) a nonionic surfactant containing polyglycol ether groups, and(C) an aliphatic or aromatic carboxylic acid ester, an alkylbenzene, tetralin or a mixture of these substances.The mixture of assistants is employed in the dyeing of synthetic fibre materials, in particular textile material containing polyester fibres, for increasing the rate of migration of disperse dyes.Type: GrantFiled: February 8, 1990Date of Patent: April 23, 1991Assignee: Ciba-Geigy CorporationInventors: Hans-Ulrich Berendt, Rosemarie Topfl
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Patent number: 4994089Abstract: The carrier mixture contains N-alkylphthalimides and compounds of the general formula ##STR1## in which R is C.sub.1 -C.sub.7 -alkyl; phenyl, benzyl or phenylethyl, which can be substituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkoxycarbonyl,R.sup.1 is hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.3 -alkylcarbonyloxy, hydroxyl or C.sub.1 -C.sub.4 -alkoxycarbonyl,m is 0 or 1,n is 0 or 1, m and n not being 0 at the same time.Type: GrantFiled: September 28, 1989Date of Patent: February 19, 1991Assignee: Bayer AktiengesellschaftInventors: Frank Bartkowiak, Hans Schulze, Wolf-Dieter Schroer, Gunther Boehmke, Karlhans Jakobs, Willi Schossler
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Patent number: 4976744Abstract: Concentrated solutions of cationic dyes are prepared by treating the cationic dyes, which contain as the counterions the anions customarily present during their preparation, with alkali metal salts of monocarboxylic acids and with or without complexing agents in an aqueous glycol ether medium, and separating off the organic phase, which contains the dyes in the form of their monocarboxylic acid salts.Type: GrantFiled: September 12, 1989Date of Patent: December 11, 1990Assignee: BASF AktiengesellschaftInventors: Johannes P. Dix, Guenter Hansen, Hellmut Kast
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Patent number: 4943299Abstract: Levelling agents containingI. ethers of the general formula ##STR1## in which R.sub.1 denotes alkyl, alkenyl, cycloalkyl, aryl or aralkyl,R.sub.2 denotes hydrogen or methyl,x denotes 1, 2 or 3 andy denotes 0 to 7, andII. emulsifiers and, if desired,III. carriers for the dyeing of polyesters are used for the high-temperature dyeing of polyester fibres and polyester-containing materials.Type: GrantFiled: September 22, 1988Date of Patent: July 24, 1990Assignee: Bayer AktiengesellschaftInventors: Hans Schulze, Klaus Walz, Frank Bartkowiak, Karlhans Jakobs
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Patent number: 4940469Abstract: A stable and low-foaming composition for finishing synthetic fibres which contains, based on (a)+(b)+(c)(a) 15 to 84% by weight of a sparingly water-soluble or water-insoluble dye, fluorescent whitening agent or UV absorber,(b) 15.5% to 75% by weight of one or more dispersing agents, and(c) 0.5 to 10% by weight of an alkylenediamide.Type: GrantFiled: January 30, 1989Date of Patent: July 10, 1990Assignee: Ciba-Geigy CorporationInventors: Reinhart Mockel, Roland Putzar
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Patent number: 4923481Abstract: Aqueous dispersion of a sulfonated metallizable dye containing(a) based on the total weight at least 10% of the sulfonated metallizable dye and(b) a sulfonated condensation product obtained by reacting an aromatic compound having at least two replaceable ring-positioned hydrogen atoms in any desired order with a compound of the formula ##STR1## in which X is a direct bond or oxygen, Hal is chlorine or bromine and n is 1 to 4, and sulfonation.Type: GrantFiled: December 16, 1988Date of Patent: May 8, 1990Assignee: Ciba-Geigy CorporationInventors: Roberto Galli, Ernst Tempel
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Patent number: 4911732Abstract: Improved light fastness of dyeings on textile polyester material with disperse dyes is obtainable by dyeing in the presence of certain benzophenone ether esters, some of which are novel.Type: GrantFiled: September 28, 1988Date of Patent: March 27, 1990Assignee: BASF AktiengesellschaftInventors: Peter Neumann, Dieter Wegerle, Reinhold Krallmann
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Patent number: 4886549Abstract: Specific vatting accelerators according to claims 1 and 2 are described. These can be added to a vat dye or sulfur dye composition, or to a dye bath or printing paste containing a vat dye or sulfue dye, by virtue of which an improvement of dye yield, particularly on cellulose materials, is obtained.Type: GrantFiled: March 8, 1988Date of Patent: December 12, 1989Assignee: Ciba-Geiegy CorporationInventor: Zdenek Koci
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Patent number: 4865885Abstract: This invention relates to a new process and group of products that are useful in preventing nylon and wool fibers, including carpeting and upholstery, from being permanently stained. Fibers can be permanently stained by food colors contained in foods spilled on the fiber. This new group of sulfonated phenol-formaldehyde or naphthol-formaldehyde and anionic surfactant compounds not only block the stain from the fiber but also minimizes any yellowing or discoloration of the treated fibers during the application and during the subsequent exposure to sunlight or commonly used lightfastness testing equipment.Type: GrantFiled: June 19, 1987Date of Patent: September 12, 1989Assignee: Crompton & Knowles CorporationInventors: Michel A. Herlant, Alexander S. Kirjanov, Vincent W. Bannigan, Jr.
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Patent number: 4813971Abstract: Textile materials made of natural or synthetic polyamides or mixtures thereof are dyed in the presence of a cyclic ester of sulfurous acid with an aliphatic 1,2-diol in place of a customary pH regulant.Type: GrantFiled: February 4, 1988Date of Patent: March 21, 1989Assignee: BASF AktiengesellschaftInventors: Sigismund Heimann, Michele Vescia, Attila Bereck, Hermann Sulz, Ingrid Steenken
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Patent number: 4789382Abstract: Textile polyester material is dyed with disperse dyes in the presence of specific benzophenone derivatives, some of which are novel, to improve the light fastness.Type: GrantFiled: July 10, 1987Date of Patent: December 6, 1988Assignee: BASF AktiengesellschaftInventors: Peter Neumann, Dieter Wegerle, Reinhold Krallmann
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Patent number: 4722736Abstract: A low-dusting particulate composition comprising (i) a particulate solid, especially a hydrophilic solid, such as a water-soluble dye or surfactant-treated water-insoluble dye, and (ii) an aryl hydroxypolyalkoxylate which is free from long aliphatic substituents.Type: GrantFiled: April 15, 1986Date of Patent: February 2, 1988Assignee: Imperial Chemical Industries PLCInventor: George Hull
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Patent number: 4702743Abstract: A liquid dye preparation comprising an aqueous solution containing at least 0.5% by weight of a water-soluble anionic dye and at least 0.1% by weight of a surfactant of the formula: ##STR1## wherein R represents a non-ionic substituent,m represents an integer from 0 to 3,X represents a divalent bridging atom or group,Y represents a C.sub.2-4 alkylene radical,n represents an integer of at least 2, andZ represents hydrogen, akyl, sulpho or phosphino.Type: GrantFiled: May 5, 1986Date of Patent: October 27, 1987Assignee: Imperial Chemical Industries PLCInventors: Patrick O'Callaghan, Henry R. Murton
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Patent number: 4657558Abstract: Textile fabrics formed at least partially of polyester fibers are dyed with an aqueous dyebath comprising(a) 0 to 5 g/l of thickener;(b) disperse dyestuffs in an amount sufficient to dye the fibers to the desired depth of color;(c) 2 to 100 g/l of a partially sulfated adduct of ethylene oxide with an alkyl phenyl or C.sub.8 to C.sub.16 fatty alcohols;(d) 0 to 60 g/l of nonionic or anionic surfactants; and(e) 5 to 50 g/l of at least one organic compound selected from the group consisting of aromatic nitrile ethers and ethoxylated chlorophenols.The fabrics may be continuously dyed by padding, immersing, spraying or otherwise applying the dyestuffs, steaming the fabrics in their wet condition, and subsequently washing and drying.Type: GrantFiled: September 20, 1984Date of Patent: April 14, 1987Assignee: Collins & Aikman CorporationInventor: Dieter Huxoll
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Patent number: 4581035Abstract: A waterless dye composition for apparel and other thermoplastic articles comprises a triglyceride fat or oil of the formula ##STR1## wherein acyl, acyl' and acyl" each are saturated or unsaturated substituted or unsubstituted linear alkanoyl of an even number of carbon atoms from 10-30 carbon atoms and an organic colorant.The composition can further contain one or more of:A. an aromatic polyester of the formula C.sub.6 H.sub.z' -(COOR.sub.1).sub.z, wherein z is 3, 4,5, or 6; z' is 6-z and R.sub.1 is higher alkyl;B. a cycloaliphatic diester of the formula ##STR2## wherein R is substituted or unsubstituted straight or branched chain alkyl of 4-20 carbon atoms, polyoxyalkylene of the formula HO(C.sub.x H.sub.y O).sub.n C.sub.x H.sub.y --or phosphated polyoxyalkylene of the formula(HO).sub.2 P(.dbd.O)O(C.sub.x H.sub.2x O).sub.n C.sub.x H.sub.2xor a salt thereof, wherein (C.sub.x H.sub.2x O).sub.n is (CH.sub.2 CH.sub.2 O).sub.n, (C.sub.3 H.sub.6 O).sub.n or (CH.sub.2 CH.sub.2 O).sub.p --(C.sub.3 H.sub.6 O).sub.Type: GrantFiled: November 8, 1984Date of Patent: April 8, 1986Assignee: Crucible Chemical CompanyInventor: Robert B. Wilson
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Patent number: 4525170Abstract: The invention relates to solid formulations of metal complex dyes, which formulations are obtained by dissolving or suspending at least one metal complex dye in water with the addition of an anionic dispersant or mixture of dispersants, and 1 to 20% by weight, based on the final formulation, of a non-ionic ethylene oxide adduct having a molecular weight of 200 to 5000, and optionally further ingredients, subsequently mixing the components and spray drying the solution or suspension.Such formulations are readily wettable and have a cold water dispersibility of .gtoreq.30 g/l.Type: GrantFiled: May 19, 1983Date of Patent: June 25, 1985Assignee: Ciba-Geigy CorporationInventor: Paolo Balliello
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Patent number: 4519805Abstract: Specific vatting accelerators according to claims 1 and 2 are described. These can be added to a vat dye or sulfur dye composition, or to a dye bath or printing paste containing a vat dye or sulfur dye, by virtue of which an improvement of dye yield, particularly on cellulose materials, is obtained.Type: GrantFiled: December 29, 1981Date of Patent: May 28, 1985Assignee: Ciba Geigy CorporationInventor: Zdenek Koci
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Patent number: 4490150Abstract: A process for shifting the equilibrium of disperse dyestuffs between an aqueous liquor and a textile substrate comprising adding to the aqueous liquor a compound of formula I ##STR1## wherein R.sub.1 and R.sub.2, independently, are hydrogen or C.sub.4-12 -alkyl, provided that R.sub.1 and R.sub.2 are not both hydrogen;R is a mixed chain containing from 7 to 31 ethyleneoxy and 3 to 27 propyleneoxy units,with the proviso that R contains at most a total of 34 units.Type: GrantFiled: February 3, 1983Date of Patent: December 25, 1984Assignee: Sandoz Ltd.Inventor: Juerg Heller
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Patent number: 4436522Abstract: A disperse dye composition containing:20 to 50% by weight of a water-insoluble or sparingly soluble dye; and1 to 5% by weight of a water-soluble surface active agent represented by the formula: ##STR1## wherein R.sup.1 is a hydrogen atom or an .alpha.-methylbenzyl group, R.sup.2 is a hydrogen atom or an .alpha.-methylbenzyl group, R.sup.3 is a hydrogen atom or a methyl group, R.sup.4 is a hydrogen atom, a methyl group or an .alpha.-methylbenzyl group, any one of l and n is 0 and the other is an integer of 7 to 20, and m is an integer of 0 to 5.Type: GrantFiled: December 31, 1981Date of Patent: March 13, 1984Assignee: Mitsubishi Chemical Industries LimitedInventors: Toshio Niwa, Susumu Nagashima
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Patent number: 4428750Abstract: In order to achieve lighter patterned effects on a background of a deeper color, aqueous printing pastes containing, additionally to thickeners and other conventional printing assistants, assistants which have dissolving properties for the dyestuffs at elevated temperatures and which do not attack the fibers under thermosol conditions, are applied to textile webs which have been dyed in a finished manner with suitable dyestuffs or have only been impregnated therewith, after which the goods treated in this way are subjected to a steaming process or to a dry heat treatment. In accordance with the process it is possible to effect a uniform lightening, "white discharging" or "colored discharging" of dyeings, particularly dyeings of synthetic fibers with disperse dyestuffs and also dyeings of natural fibers or mixtures thereof with disperse dyestuffs, vat dyestuffs, leuco esters thereof and developing dyestuffs.Type: GrantFiled: February 18, 1983Date of Patent: January 31, 1984Assignee: Hoechst AktiengesellschaftInventors: Walter Birke, Hans-Ulrich von der Eltz, Franz Schon, Erich Feess
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Patent number: 4397652Abstract: Described is a process for the production of negligibly dusty preparations of dyes and/or optical brighteners, which process comprises mixing an adhesive as e.g. sorbitol and a dust binding surface active agent into a mixture of dye or optical brightener and, optionally, further additives.Type: GrantFiled: January 18, 1982Date of Patent: August 9, 1983Assignee: Ciba-Geigy CorporationInventor: Konrad Neumann
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Patent number: 4373930Abstract: An aqueous dispersion of a solid, especially a disperse dyestuff or a pigment, containing, as dispersing agent, a water-soluble, non-ionic polycyclic aromatic compound having a poly(lower alkylene-oxy)chain containing from 5 to 30 lower alkylene-oxy groups. Preferred dispersing agents contain about 10 ethylene-oxy groups in the chain. The dispersions of disperse dyestuffs are especially suitable for use in aqueous print pastes based on synthetic thickening agents and the pigment dispersions are suitable for use in emulsion paints.Type: GrantFiled: September 15, 1981Date of Patent: February 15, 1983Assignee: Imperial Chemical Industries LimitedInventor: Geoffrey R. Rothwell
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Patent number: 4345910Abstract: A process for dyeing polyester fibers which do not require a carrier with disperse dyes by the exhaustion method at 20.degree.-100.degree. C. and pH 4-6, with liquor ratios of from 5:1 to 100:1, and dyeing times of from 30 to 180 minutes, wherein the dyeing is carried out in the presence of from 0.5 to 20%, based on fiber weight, of a leveling agent consisting of an adduct of a C.sub.5 -C.sub.14 -alkylphenol or C.sub.5 -C.sub.14 -alkylnaphthol with from 4 to 25 moles of ethylene oxide.Type: GrantFiled: February 10, 1981Date of Patent: August 24, 1982Assignee: BASF AktiengesellschaftInventors: Michele Vescia, Sigismund Heimann
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Patent number: 4341526Abstract: The present invention involves an improved levelling agent and a method of using it in the disperse dyeing of hydrophobic synthetic fiber materials such as polyesters and polyamides. The levelling agent enhances dye migration without substantially accelerating the exhaustion of dye onto the fabric being dyed. It is based on diaryl ethers such as ditolyl ether mixed with emulsifiers and optionally a diluent which is water or an organic solvent.It also involves a process for improving the levelness of already dyed materials by subjecting them to temperatures above the boiling point of water in the presence of diaryl ether based levelling agents.Type: GrantFiled: August 30, 1977Date of Patent: July 27, 1982Assignee: Mobay Chemical CorporationInventors: Rolf G. Kuehni, Thomas C. Cox
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Patent number: 4329176Abstract: Oxyalkylated 1,3-bis-aryl-glycerol ethers of the formula ##STR1## where R and R.sup.1 are aromatic substituents, R.sup.2 is --CH.sub.3 or --C.sub.2 H.sub.5, R.sup.3 is --H or --CH.sub.3, n is from 0 to 10 and m is from 8 to 50.The compounds of the formula I are used as emulsifiers, preferably in the preparation of print pastes.Type: GrantFiled: February 8, 1980Date of Patent: May 11, 1982Assignee: BASF AktiengesellschaftInventors: Heinz Krapf, Knut Oppenlaender, Guenter Uhl
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Patent number: 4306876Abstract: An anionic surfactant can be used for the preparation of aqueous dispersions of specific composition with a high degree of fineness of the particle sizes of primary aromatic amines free from carboxylic acid or sulfonic acid groups. Besides said aromatic amine and said anionic surfactant these aqueous dispersion contain as a dispersing agent a water-soluble condensation product containing one or several radicals of oxalkylated, hydroxy and/or carboxy group-containing aromatic compounds, which radicals are linked with one another by methylene bridges either directly or via radicals of aromatic compounds. The dispersions may further contain a polyhydric alcohol and optionally a high molecular weight polyglycol. The dispersions have a good viscosity behavior, a good stability in storage and are stable at temperatures of about -15.degree. to +50.degree. C. They can be readily and rapidly diazotized and yield residue-free diazonium salt solutions with low tendency to foam formation.Type: GrantFiled: March 7, 1980Date of Patent: December 22, 1981Assignee: Hoechst AktiengesellschaftInventor: Hasso Hertel
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Patent number: 4255152Abstract: A batchwise process for dyeing hydrophobic fibres at 110.degree. C. to 135.degree. C. with a disperse dye in the presence of an adduct of an average of 1 to 4 molar proportions of ethylene oxide, propylene oxide or styrene oxide or a combination of these oxides with 1 molar proportion of a phenol compound having the formula ##STR1## in which n is a number from 1 to 4,R.sub.1 is hydrogen, chlorine an alkyl group with 1 to 8 carbon atoms, an alkoxy group with 1 to 8 carbon atoms or an alkenyl group with 2 to 8 carbon atoms.R.sub.Type: GrantFiled: September 5, 1978Date of Patent: March 10, 1981Assignee: Ciba-Geigy CorporationInventors: Brian Hewitt, Cyril Hobday, James Jack, John F. E. Keenan
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Patent number: 4221566Abstract: This invention discloses compositions and methods for dyeing natural proteinaceous and synthetic polyamide fibers, particularly wool, silk and nylons, utilizing dye assistants effective with both acid and disperse dyes, such assistants being a synergistic combination of (a) a mixture of lower alkyl esters of toluic and benzoic acids with (b) certain other materials, none of the components in either (a) or (b) being, in themselves, effective dye assistants for both acid and disperse dyes.Type: GrantFiled: June 5, 1978Date of Patent: September 9, 1980Assignee: Velsicol Chemical CorporationInventors: Remus I. Lazar, Richard C. Reichel
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Patent number: 4209298Abstract: Compositions and methods for dyeing natural proteinaceous and synthetic polyamide fibers, particularly wool, silk and nylons, utilizing dye assistants effective with both acid and disperse dyes, such assistants being a combination of (a) dibenzyl ether with (b) a compound of the formula: ##STR1## wherein x is selected from the group consisting of hydrogen, methyl and ethyl.Type: GrantFiled: June 5, 1978Date of Patent: June 24, 1980Assignee: Velsicol Chemical CorporationInventors: Remus I. Lazar, Richard C. Reichel