Fluorescent Dye, E.g., Stilbene, Benzimidazole, Benzoxazole, Benzothiazole, Pyrazoline Dye, Etc., Optical Brightner Or Bluing Agent Patents (Class 8/648)
  • Patent number: 7425222
    Abstract: A process for improving the sun protection factor (SPF) of cellulosic fibre materials and blends thereof, which comprises contacting said materials with at least one compound of the formula (1) in which M is hydrogen, an alkali metal atom, ammonium or a cation formed from an amine; R1 and R1? independently of each other are hydrogen, hydroxy, optionally substituted alkyl, 4-morpholinyl, —NH—R3, —N(R3)2 or —O—R3, wherein R3is optionally substituted alkyl or optionally substituted aryl, R2 is a group of formula (2) wherein X is —O— or —NH— and R4 is C1-C4-alkyl which carries at least one hydrophilic substituent and R2? has the meaning of R1 or R2.
    Type: Grant
    Filed: February 11, 2002
    Date of Patent: September 16, 2008
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Georges Metzger, Jean-Jacques Donzé, Hans Kramer, Serge Hauger, Volker Papendick, Michael Milde, Ted Deisenroth, Rainer Hans Traber, Ullrich Menge, Hauke Rohwer
  • Patent number: 7407519
    Abstract: A process for improving the sun protection factor (SPF) of cellulosic fibre materials and blends thereof, which comprises contacting said materials with at least one compound of the formula (1) in which M is hydrogen, an alkali metal atom, ammonium or a cation formed from an amine; R1 and R1? independently of each other are —NH—R3, —N(R3)2 or —O—R3, wherein R3 is aryl substituted by —CO—X—R5, wherein X is O or NH and R5 is optionally substituted C1-C4-alkyl, R2 is a group of formula —O—R4 wherein R4 is hydroxy alkyl, alkoxy alkyl or hydroxy alkoxy alkyl, and R2? has the meaning of R1 or R2.
    Type: Grant
    Filed: January 5, 2007
    Date of Patent: August 5, 2008
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Georges Metzger, Fabienne Cuesta
  • Patent number: 7377946
    Abstract: The invention relates to a composition comprising, in a cosmetically acceptable medium, at least one particular fluorescent dye. The invention also relates to a process for treating keratin fibres, in particular human keratin fibres, using this composition, and also to a device comprising it. Finally, the invention relates to the use of the composition according to the invention as a lightening agent or as a colouring agent for the said fibres.
    Type: Grant
    Filed: July 8, 2004
    Date of Patent: May 27, 2008
    Assignee: L'Oréal
    Inventors: Luc Gourlaouen, Andrew Greaves, Grégory Plos
  • Patent number: 7329289
    Abstract: The present patent application relates to the use of triarylmethane derivatives as direct dyes in a dye composition for keratin fibres, in particular human keratin fibres such as the hair, or for the manufacture of such compositions. The present patent application also relates to a dye composition for dyeing keratin fibres, in particular human keratin fibres such as the hair, comprising, in a suitable dyeing medium, at least one particular triarylmethane-based direct dye. The present patent application also relates to a process for dyeing keratin fibres, in particular human keratin fibres such as the hair, using the dye composition according to the invention.
    Type: Grant
    Filed: June 1, 2005
    Date of Patent: February 12, 2008
    Assignee: L'Oréal, S.A.
    Inventors: Alain Lagrange, Frédéric Guerin
  • Patent number: 7300474
    Abstract: The claimed liquid formulations contain an organic acid and a branched mono- or di-alcohol. The addition of the alcohol improves the storage stability of the liquid formulations.
    Type: Grant
    Filed: February 20, 2003
    Date of Patent: November 27, 2007
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Gerhard Zirkenbach, Alexander Lerch
  • Patent number: 7270771
    Abstract: The present invention relates to a fluorescent whitening agent comprising a mixture of two symmetrically and one asymmetrically substituted triazinylaminostilbene disulphonic acids, novel asymmetrically substituted derivatives, a process for their preparations and use of the mixture for whitening synthetic or natural organic materials, especially paper and for the fluorescent whitening and improvement of sun protection factors of textile materials.
    Type: Grant
    Filed: June 24, 2003
    Date of Patent: September 18, 2007
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Fabienne Cuesta, Georges Metzger, Roland Naef, Peter Rohringer, Rainer Hans Traber
  • Patent number: 7261744
    Abstract: Disclosed herein are a method of dyeing or coloring, with a lightening effect, a human keratin material comprising applying a composition comprising, in a cosmetically acceptable medium, at least one fluorescent compound and at least one optical brightener; a composition comprising, in a cosmetically acceptable medium, at least one fluorescent compound and at least one optical brightener which are both soluble in the medium; and a device using such a composition comprising at least two compartments, wherein at least one comprises, in a cosmetically acceptable medium, a composition comprising at least one fluorescent compound and at least one optical brightener and optionally at least one additional ingredient chosen from direct dyes, oxidation bases and couplers, and at least one other compartment comprises a composition comprising at least one oxidizing agent.
    Type: Grant
    Filed: December 23, 2003
    Date of Patent: August 28, 2007
    Assignee: L'Oreal S.A.
    Inventors: Luc Gourlaouen, Florent Pastore
  • Patent number: 7262160
    Abstract: Enhanced UV blocking is provided to clothing by washing the clothing in a composition including a UV blocking dye and at least one additional water-soluble material which serves as a matrix and/or a dispersant for the dye in the washing machine. The dye is initially in the form of a solid tablet or pellet preferably also containing a disintegrant, or inside a water-soluble envelope. When placed in the washing machine with the clothing and the washing water, the pellet or tablet disintegrates and dissolves releasing the UV protectant dye to the clothing.
    Type: Grant
    Filed: June 3, 2004
    Date of Patent: August 28, 2007
    Inventor: Robert H. Black
  • Patent number: 7250064
    Abstract: The disclosure relates to a composition comprising at least one fluorescent dye and at least one non-associative thickening polymer, to processes using such a composition, and to devices comprising such a composition. The disclosure also relates to processes and methods for dyeing human keratin materials, for example artificially dyed or pigmented hair and dark skin, with a lightening effect, using compositions comprising at least one fluorescent dye and at least one non-associative thickening polymer.
    Type: Grant
    Filed: April 1, 2004
    Date of Patent: July 31, 2007
    Assignee: L'Oreal S.A.
    Inventors: Grégory Plos, Luc Gourlaouen
  • Patent number: 7247174
    Abstract: The present invention provides novel bis-triazinylaminostilbene amphoteric fluorescent whitening agents, comprising both individual components and mixtures thereof, a process for their preparation, intermediates useful for their prepartion and use of the fluorescent whitening agents for the fluorescents whitening of paper.
    Type: Grant
    Filed: November 11, 2003
    Date of Patent: July 24, 2007
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Goetz Scheffler, Peter Rohringer, Ian John Fletcher
  • Patent number: 7238213
    Abstract: Disclosed are novel compositions and methods employing cyclic nucleotide-gated channels and fluorescence dyes and other indicators in detecting changes of intracellular cAMP levels, for instance in response to the stimulation of G-protein-coupled receptors. CNG mutants comprising one or more pore mutations that enhance sensitivity to cAMP and decrease divalent cation-mediated blockage are used in a variety of assays, including detection of the G-protein-coupled receptor activity. Also disclosed are novel dye quencher formulations that are particularly suited for cell-based assays of protein interactions.
    Type: Grant
    Filed: November 1, 2004
    Date of Patent: July 3, 2007
    Assignee: Atto Bioscience
    Inventors: Yong Yao, Liang Cao, Jianming Lu, Isabel Llorente
  • Patent number: 7217296
    Abstract: The invention relates to a cosmetic dyeing composition that is used to lighten human keratinous matter and, more specifically, artificially colored or pigmented hair and dark skin. The inventive composition comprises at least one flourescent dye. The invention also relates to the methods using said composition.
    Type: Grant
    Filed: September 24, 2002
    Date of Patent: May 15, 2007
    Assignee: L'Oreal S.A.
    Inventors: Florent Pastore, Luc Gourlaouen, Alain Lagrange
  • Patent number: 7208018
    Abstract: Disclosed herein are compositions comprising at least one fluorescent dye and at least one particular associative polymer, processes using this composition, and a device therefor. Further disclosed herein is the use of a composition comprising at least one fluorescent dye and at least one particular associative polymer for dyeing a human keratin material, such as artificially dyed or pigmented hair and dark skin, with a lightening effect.
    Type: Grant
    Filed: April 1, 2004
    Date of Patent: April 24, 2007
    Assignee: L'Oreal
    Inventors: Luc Gourlaouen, Henri Samain
  • Patent number: 7204860
    Abstract: Disclosed herein are compositions comprising at least one fluorescent dye and at least one polyol, processes using this composition and a device therefor. Further disclosed herein is the use of a composition for dyeing a human keratin material, such as artificially dyed or pigmented hair and dark skin, with a lightening effect, comprising at least one fluorescent dye and at least one polyol.
    Type: Grant
    Filed: April 1, 2004
    Date of Patent: April 17, 2007
    Assignee: L'Oreal
    Inventors: Grégory Plos, Luc Gourlaouen
  • Patent number: 7198650
    Abstract: The present disclosure relates to a method of dyeing human keratin materials with a lightening effect with a composition comprising, in a cosmetically acceptable medium, at least one fluorescent dye that is soluble in the cosmetically acceptable medium and at least one surfactant chosen from amphoteric surfactants and nonionic surfactants. The present disclosure also relates to compositions comprising at least one particular fluorescent dye that is soluble in the cosmetically acceptable medium and at least one surfactant chosen from amphoteric surfactants and nonionic surfactants, and also to processes using these compositions, and devices for these compositions.
    Type: Grant
    Filed: April 1, 2004
    Date of Patent: April 3, 2007
    Assignee: L'Oreal S.A.
    Inventors: Chrystel Pourille-Grethen, Grégory Plos
  • Patent number: 7198731
    Abstract: The present invention relates to the use of compounds of formula (I) wherein all substituents are as defined in the claims as optical brighteners as well as to new mixtures of optical brighteners.
    Type: Grant
    Filed: November 18, 2002
    Date of Patent: April 3, 2007
    Assignee: Clariant Finance (BVI) Limited
    Inventor: Andrew Clive Jackson
  • Patent number: 7195650
    Abstract: A process for dyeing keratin fibers that have previously undergone a permanent reshaping process, comprising applying at least one composition comprising, in a cosmetically acceptable medium, at least one fluorescent dye that is soluble in the medium. The use of the at least one composition may makes it possible to dye a human keratin material, and further, for example, artificially dyed or pigmented hair, with a lightening effect.
    Type: Grant
    Filed: April 1, 2004
    Date of Patent: March 27, 2007
    Assignee: L'Oreal S.A.
    Inventors: Grégory Plos, Henri Samain
  • Patent number: 7195651
    Abstract: The present disclosure relates to a cosmetic composition comprising at least one fluorescent dye comprising at least one fluorescent compound, and at least one cationic polymer with a charge density of at least 1 meq/g; processes that incorporate this cosmetic composition and to a kit comprising this cosmetic composition. The present disclosure also relates to the process for dyeing human keratin materials, including artificially dyed or pigmented hair and dark skin, with a lightening effect, comprising applying to the keratin materials a cosmetic composition comprising at least one fluorescent dye comprising at least one fluorescent compound and at least one cationic polymer with a charge density of at least 1 meq/g.
    Type: Grant
    Filed: April 1, 2004
    Date of Patent: March 27, 2007
    Assignee: L'Oreal S.A.
    Inventors: Grégory Plos, Henri Samain
  • Patent number: 7192471
    Abstract: Fluorescent pigment compounds comprising aryl-ureido benzoxazinone compounds of the general formula (I): wherein R1 is an substituted or unsubstituted aryl group, R2 and R3 are each independently selected from an H atom, an alkyl group, an alkoxy group, an alkylcarboxy group and a halogen atom, X is a carbon or sulfur atom and n is an integer of 1 or more. Many of the compounds of this class produce a yellow, generally deep yellow, emission at wavelengths of about 560 to about 585 nm when excited by an appropriate UV source. These compounds produce fluorescence making them useful as fluorescent pigments, those compounds providing emission wavelengths within the range of from about 560 to about 585 or higher when excited by a UV source are particularly useful. Those compounds having this emission spectra for the compounds makes these compounds particularly useful as pigments in security applications, particularly as pigments for use in security inks and fibers.
    Type: Grant
    Filed: September 24, 2004
    Date of Patent: March 20, 2007
    Assignee: Honeywell International Inc.
    Inventors: Thomas Potrawa, Joachim Schulz
  • Patent number: 7192454
    Abstract: The invention relates to a composition comprising at least one fluorescent dye and at least one particular sequestering agent, and also to processes and a device for using these compositions. The invention similarly relates to the use of a composition comprising at least one particular fluorescent dye and at least one particular sequestering agent, to dye with a lightening effect human keratin materials and more particularly artificially dyed or pigmented hair, and colored skin.
    Type: Grant
    Filed: April 1, 2004
    Date of Patent: March 20, 2007
    Assignee: L'Oreal S.A.
    Inventors: Grégory Plos, Luc Gourlaouen
  • Patent number: 7186278
    Abstract: The present disclosure relates to compositions comprising at least one soluble fluorescent dye and at least one compound comprising an acid functional group, and to processes using this composition. It likewise relates to a method of using compositions comprising, in a cosmetically acceptable medium, at least one soluble fluorescent dye and at least one compound comprising an acid functional group for dyeing human keratin materials, such as artificially dyed and/or pigmented hair and dark skin, with a lightening effect.
    Type: Grant
    Filed: April 1, 2004
    Date of Patent: March 6, 2007
    Assignee: L'Oreal S.A.
    Inventors: Grégory Plos, Luc Gourlaouen
  • Patent number: 7150764
    Abstract: A composition comprising at least one fluorescent dye and at least one insoluble conditioning agent; and processes and multicompartment kits comprising the composition. This disclosure also relates to the use of this composition for dyeing a human keratin material, and, for example, artificially dyed or pigmented hair and/or dark skin, with a lightening effect.
    Type: Grant
    Filed: April 1, 2004
    Date of Patent: December 19, 2006
    Assignee: L'Oreal S.A.
    Inventors: Grégory Plos, Henri Samain
  • Patent number: 7147673
    Abstract: Disclosed herein is a composition comprising at least one fluorescent dye and at least one insoluble polyorganosiloxane conditioning polymer, processes using this composition, and a device. Further disclosed herein is the use of compositions comprising at least one fluorescent dye and at least one insoluble polyorganosiloxane conditioning polymer, for dyeing human keratin materials, for example artificially dyed and/or pigmented hair and dark skin, with a tightening effect.
    Type: Grant
    Filed: April 1, 2004
    Date of Patent: December 12, 2006
    Assignee: L'Oreal S.A.
    Inventors: Grégory Plos, Henri Samain
  • Patent number: 7145010
    Abstract: Tert-alkylphenoxy-substituted polycyclic compounds of the general formula I where P is a conjugated polycyclic radical which is stable to bases and nucleophiles, optionally bears aryl substituents and contains no group from the group consisting of —CO—NH—CO—, —COOH and —CO—O—CO—; R is C1–C8-alkyl, whose carbon chain may be interrupted by one or more groups selected from the group consisting of —O—, —S—, —NR1—, —CO— and/or —SO2— and which may be monosubstituted or polysubstituted by C1–C6-alkoxy or by a 5- to 7-membered heterocyclic radical which is attached via a nitrogen atom and may contain further heteroatoms and be aromatic; C5–C8-cycloalkyl whose carbon chain may be interrupted by one or more groups selected from the group consisting of —O—, —S—, —NR1—, —CO— and/or —SO2— and which may be monosubstituted or polysubstituted by C1–C6-alkyl; R1 is hydrogen or C1–C6-alkyl; Hal is chlorine and/or bromine; m is from 0 to 15; n is from 1 to 16, subject to the proviso that the sum m+n is ?16, are prepared a
    Type: Grant
    Filed: March 20, 2002
    Date of Patent: December 5, 2006
    Assignee: BASF Aktiengesellschaft
    Inventors: Arno Boehm, Willi Helfer, Georg Beck, Matthias Krieger, Peter Erk
  • Patent number: 7108913
    Abstract: The present invention provides a highly reflective fluorescent polymer composition comprising a benzoxzolyl naphthalene optical brightener and a polymeric substrate support material formed into three dimensional articles or fibers. The enhanced light reflectivity of the instant compositions occurs over a wavelength range of from about 400 to 700 nanometers. The fiber embodiment comprises a body or support portion made of a flexible and durable thermoplastic material which is at least partially translucent and bis(benzoxazolyl)napthalenes optical brightener molecularly dispersed throughout the polymeric body potion of the fiber. The fibers are fluorescent to a UV source and can be effectively utilized for artificial hair for toy dolls as well as for various other textile applications.
    Type: Grant
    Filed: May 9, 2005
    Date of Patent: September 19, 2006
    Assignee: Mattel, Inc.
    Inventors: Abimael Cordova, Jason Kroskrity
  • Patent number: 7019134
    Abstract: Water soluble, amphoteric optical brighteners (W) comprising at least one brightener-characteristic radical X which contain at least one anionic substituent and covalently linked over at least one tertiary amino group Z to at least one non-chromophoric, essentially aliphatic, polyquaternary ammonium-hydrocarbon radical Y containing more than one quaternary ammonium group and in which each hydrocarbon radical is optionally interrupted by and/or substituted with one or more further heteroatoms, have surprising brightening properties, especially in papermaking, and in the form of their aqueous solutions are of notable stability.
    Type: Grant
    Filed: December 19, 2000
    Date of Patent: March 28, 2006
    Assignee: Clariant Finance (BVI) Limited
    Inventors: John Martin Farrar, Andrew Clive Jackson
  • Patent number: 6994734
    Abstract: An aqueous liquid composition characterized by containing an alkali salt, an alkali metal salt, an alkali earth metal salt or an ammonium salt of a compound represented by the following formula (1). in the form of free acid in an amount of 10–40 mass % and inorganic salt in an amount of 1.1–10 mass % can easily be produced without a desalting process or the like which has been included in a conventional process and it has an excellent storage stability and excellent fluorescent brightening effect.
    Type: Grant
    Filed: March 20, 2002
    Date of Patent: February 7, 2006
    Assignee: Nippon Kayaku Kabushiki Kaisha
    Inventors: Toru Yamaguchi, Nobutaka Yamamoto
  • Patent number: 6989360
    Abstract: Aqueous textile fiber degreasing agents (WE) essentially consisting of (A) at least one amine oxide of the average formula ?as defined in claim 1, (B) at least one hexanediol, (C) at least one secondary, branched or cyclic hexanol, (D) at least one aminosurfactant of the average formula ?as defined in claim 1 and (E) water, and optionally at least one formulation additive (F), their production and use, particularly under alkaline conditions, in textile goods production.
    Type: Grant
    Filed: July 9, 2002
    Date of Patent: January 24, 2006
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Bernard Danner, Francis Palacin
  • Patent number: 6964993
    Abstract: A paper coating slip contains a polymer dispersed with polyvinyl alcohol as protective colloid in water (abbreviated to PVA-dispersed polymer).
    Type: Grant
    Filed: May 19, 2004
    Date of Patent: November 15, 2005
    Assignee: BASF Aktiengesellschaft
    Inventors: Reinhold J. Leyrer, Harutyun Hanciogullari
  • Patent number: 6936078
    Abstract: The invention relates to a fluorescent brightener pigment and the use of said pigment, which is derived from formaldehyde, for improving the whiteness of paper or textiles, or for incorporation in detergent compositions.
    Type: Grant
    Filed: June 12, 2001
    Date of Patent: August 30, 2005
    Assignees: Ciba Specialty Chemicals Corp., Albemarle Corporation
    Inventors: Peter Bischof, Christiane Hutter, Claudio Puebla
  • Patent number: 6929667
    Abstract: A method for the fluorescent whitening of cotton in a discontinuous process comprising contacting the cotton, I an aqueous bath having a pH value of 6 or less, with one or more compounds of the Formula (I) wherein R1 represents an —SO2R3, —SOR3, CO2M, —CO2R3, —CONR3R4, —CN or —NO2 substituent, R2 is —NH2, —NH(C1-C4alkyl), —N(C1-C4alkyl)2, —NH(C2-C4hydroxyalkyl), —N(C2-C4hydroxyalkyl)2, —NH(C1-C4alkoxy)(C1-C4alkyl), —N[(C1-C4alkoxy)(C1-C4alkyl)]2, NHC2—C4alkylsulphonic acid, morpholineo, piperidino pyrrolidino, an amino acid or amino acid amide residue from which a hydrogen atom on the amino group has been removed, —OC1-C4alkyl or —OC1-C4hydroxyalkyl, R3 and R4 each, independently, represent hydrogen, C1-C4alkyl, C2-C4hydroxyalkyl or C1-C4alkoxyC1-C4alkyl and M is H, Na, Li, K, Ca, Mg, ammonium, or ammonium that is mono-, di-, tri- or tetrasubsituted by C1-C4alkyl, C2-C4hydroxyalkyl or a mixture thereof, some of which are new
    Type: Grant
    Filed: July 12, 2001
    Date of Patent: August 16, 2005
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Fabienne Cuesta, Dieter Reinehr, Hans Kramer, Georges Metzger, Bernd Wockenfuss
  • Patent number: 6890454
    Abstract: The invention relates to an optical brightener mixture (W) comprising optical brighteners (A) of formula (Ia), and (B) of formula (Ib) and optionally (C) of formula (Ic) as defined herein, their concentrated aqueous solutions (S), their production and their use.
    Type: Grant
    Filed: January 8, 2002
    Date of Patent: May 10, 2005
    Assignee: Clariant Finance (BVI) Limited
    Inventors: John Martin Farrar, Andrew Clive Jackson, Alec Stewart Tindal
  • Patent number: 6866687
    Abstract: The present invention provides a bleaching composition comprising iodine.
    Type: Grant
    Filed: September 25, 2003
    Date of Patent: March 15, 2005
    Assignee: Unilever Home & Personal Care USA, a division of Conopco, Inc.
    Inventor: Stephen Norman Batchelor
  • Patent number: 6860906
    Abstract: Described is a process for preparing concentrated solutions or suspensions of anionic organic compounds which comprises a) acidifying an aqueous solution or suspension of an anionic organic compound containing salts and/or impurities to a pH of 4.5 or less, if the pH is above this value, so that b) the anionic organic compound is water-insoluble and precipitates in the form of the free acid, c) bringing the suspension to a salt content below 2% by weight, based on the total weight of the retentate, by means of ultrafiltration with a membrane having pore diameters of from 0.001 to 0.02 ?m, and d) optionally washing out the salts with water having a pH below 4,5, e) optionally carrying out acid-free washing with water thereafter, and then f) concentrating, so that the amount of anionic organic compound is 5-50% by weight, and g) if desired, bringing the anionic organic compound into solution by adding an appropriate base.
    Type: Grant
    Filed: May 21, 2001
    Date of Patent: March 1, 2005
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Jacek Malisz, Adolf Käser, Rainer Kaufel, Holger Lautenbach, Elke Polley, Martina Hoffmann
  • Patent number: 6858044
    Abstract: Use of (PA) water-dispersible or colloidally soluble polyamides which contain hydrophilic polyalkylene glycol ether chains in the skeletal structure as wet-acting lubricants in the treatment of textile piece goods in rope or tubular form with a textile treatment agent (T) by exhaust methods from aqueous liquor under conditions which would otherwise in the textile substrate favor the formation of transport folds and/or the occurrence of friction in or on the substrate, particularly as wet-acting lubricants in the dyeing of polyamides in the jet, the corresponding wet-acting lubricants, certain polyamide preparations and certain polyamides, and their production.
    Type: Grant
    Filed: September 21, 2000
    Date of Patent: February 22, 2005
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Bernard Danner, Francis Palacin
  • Patent number: 6835333
    Abstract: Combinations of at least two individual colorant compounds that provide effective toning (or bluing) to combat yellowing within polyester articles (such as bottles, containers, and the like) are provided. Such a novel toner combination permits effective neutralization of yellowness while also providing highly desirable low haze and increased brightness due to a sharp absorption peak within the needed range of wavelengths (e.g., from about 565 to 590 nm) and a narrow half-height band width. Furthermore, such a combination of compounds is preferably liquid in nature and may thus be incorporated within an added ultraviolet absorber solution or shelf-stable dispersion to facilitate addition within target polyesters at various stages of production. The inventive combination bluing agent accords effective neutralization of UV absorber yellowing as well. Methods of production and liquid UV absorber/individual bluing agent formulations are also encompassed within this invention.
    Type: Grant
    Filed: May 7, 2002
    Date of Patent: December 28, 2004
    Assignee: Milliken & Company
    Inventors: Todd E. Danielson, Jason Sprinkle, Daniel Connor, Donnie Hyder
  • Publication number: 20040214941
    Abstract: A paper coating slip contains a polymer dispersed with polyvinyl alcohol as protective colloid in water (abbreviated to PVA-dispersed polymer).
    Type: Application
    Filed: May 19, 2004
    Publication date: October 28, 2004
    Applicant: BASF Aktiengesellschaft
    Inventors: Reinhold J. Leyrer, Harutyun Hanciogullari
  • Patent number: 6783698
    Abstract: The present invention relates to a mixture of fluorescent whitening agents comprising 20 to 70% by weight of a compound of formula (1), 30 to 80% of a compound of formula (2) and 0.1 to 10% of a compound of formula (3), compositions containing the mixture and the user of the compositions for whitening synthetic fibers, in particular, polyester.
    Type: Grant
    Filed: April 23, 2002
    Date of Patent: August 31, 2004
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Dieter Reinehr, Hanspeter Sauter, Hans Kramer, Werner Schreiber
  • Publication number: 20040111812
    Abstract: An aqueous liquid composition characterized by containing an alkali salt, an alkali metal salt, an alkali earth metal salt or an ammonium salt of a compound represented by the following formula (1).
    Type: Application
    Filed: September 18, 2003
    Publication date: June 17, 2004
    Inventors: Toru Yamaguchi, Nobutaka Yamamoto
  • Patent number: 6743588
    Abstract: A compound represented by the formula 1, a salt, hydrate, solvate or stereoisomer thereof.
    Type: Grant
    Filed: January 11, 2002
    Date of Patent: June 1, 2004
    Assignee: Tosoh Corporation
    Inventors: Takumi Tokunaga, Takahiko Ishiguro, Ryuichi Horie
  • Publication number: 20040083561
    Abstract: Aqueous dispersion comprising at least one U.V.
    Type: Application
    Filed: September 23, 2003
    Publication date: May 6, 2004
    Inventors: Jurg Heller, Jean-Luc Mura
  • Publication number: 20040074021
    Abstract: The invention relates to an optical brightener mixture (W) comprising optical brighteners (A) of formula (Ia), and (B) of formula (Ib) and optionally (C) of formula (Ic) as defined herein, their concentrated aqueous solutions (S), their production and their use.
    Type: Application
    Filed: June 25, 2003
    Publication date: April 22, 2004
    Inventors: John Martin Farrar, Andrew Clive Jackson, Alec Stewart Tindal
  • Patent number: 6723846
    Abstract: The present invention relates to compounds having formula (1): wherein each R1 represents, independently, a linear C1-C4-alkylene residue which is unsubstituted or substituted by hydroxy, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-hydroxy- or alkoxy-alkoxy, —OCOM, —OCOC1-C4-alkyl, or an amino acid residue from which a hydrogen atom on the amino group has been removed; each R2 represents, independently, a linear C1-C4-alkylene residue which is unsubstituted or substituted by hydroxy, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-hydroxy- or alkoxy-alkoxy, —OCOM, —OCOC1-C4-alkyl, —CO2M, CO2C1-C4-alkyl SO3M or phenoxy which is unsubstituted or substituted by halogen, C1-C4-alkyl or C1-C4-alkoxy, —CO2M or CO2C1-C4-alkyl, NH3 or mono- or disubstituted amino; or phenyl which is unsubstituted or substituted by 1 to 3 SO3M, SO2NHC1-C4-alkyl, —SO2NH2, —CO2M, —CO2M, —CO2C1-C4-alkyl, —CONH2, —CONHC1-C4-alkyl, —NHCOC1-C4-alkyl or mono- or disubstituted amino groups;
    Type: Grant
    Filed: March 6, 2002
    Date of Patent: April 20, 2004
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Georges Metzger, Serge Hauger, Fabienne Cuesta, Christophe Bulliard, Peter Rohringer, Marc Roger Grienenberger
  • Patent number: 6723256
    Abstract: Aqueous dispersions (U) containing: (A) a UV-light-absorbing textile treatment agent and (B) a dispersant system containing (BX) a non-ionogenic, polymeric, hydrophilic dispersant or a mixture of such dispersants and (BY) a non-ionogenic or anionic, vinyl-polymeric, hydrophilic thickener or a mixture of such thickeners, and optionally at least one of the following further components: (BZ) at least one non-ionogenic or anionic surfactant other than (BX) (BW) at least one dispersing auxiliary other than (BY). (C) by-products and/or concomitants (D) at least one formulation additive and (E) at least one agent for setting the pH are particularly stable and are very useful for the UV-active finishing of textile material.
    Type: Grant
    Filed: February 23, 2001
    Date of Patent: April 20, 2004
    Assignee: Clariant Finance (BVI) Limited
    Inventor: Jürg Heller
  • Patent number: 6719906
    Abstract: A process for the preparation of concentrated solutions or suspensions of anionic organic compounds is described, which process comprises a) acidifying an aqueous solution or dispersion of an anionic organic compound that comprises salts and/or impurities to a pH of 4.5 or less, if the pH is above that value, so that the anionic organic compound becomes insoluble in water and precipitates out in the form of the free acid, b) bringing the suspension obtained from the previous step to a salt content below 2% by weight, based on the total weight of retentate, by means of ultra-filtration with a ceramic membrane or an acid-resistant organic membrane having a pore size of from 1 to 20 nm, and c) optionally washing out of the salts with water at a pH of less than 4.
    Type: Grant
    Filed: April 26, 2002
    Date of Patent: April 13, 2004
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Jacek Malisz, Adolf Käser, Rainer Kaufel, Holger Lautenbach, Elke Polley, Martina Hoffmann
  • Patent number: 6719922
    Abstract: The present invention relates to a mixture of fluorescent whitening agents comprising 20 to 70% by weight of a compound of formula (1), 30 to 80% of a compound of formula (2) and 0.5 to 5% of a compound of formula (3), compositions containing the mixture and the use of the compositions for whitening synthetic fibers, in particular polyester.
    Type: Grant
    Filed: July 8, 2002
    Date of Patent: April 13, 2004
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Dieter Reinehr, Hanspeter Sauter, Hans Kramer, Werner Schreiber
  • Patent number: 6712862
    Abstract: Granular compacts (G) of a mixture of (A) at least one water-soluble dye or optical brightener, and (B) extender and, optionally, (C) at least one hydrophilic surfactant and/or (D) further additives, additionally containing (E) a dust-binding oil, are low-dust dry formulations of high bulk density which feature good dissolution, transportation and storage properties and are outstandingly suitable for the dyeing of the respective substrates.
    Type: Grant
    Filed: May 1, 2000
    Date of Patent: March 30, 2004
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Roland Grimm, Claude Haldimann, Werner Schumann
  • Patent number: 6706879
    Abstract: The invention relates to fluorescent dyes. More particularly, the invention relates to fluorescent cyanine dyes, and especially to water soluble fluorescent cyanine dyes that contain additional sites for attachment to biomolecules. The invention provides a group of novel, water soluble fluorescent cyanine dyes that have distinct fluorescence characteristics that permit their use in any assay or method suited to water soluble fluorescent dyes, and especially to assays requiring a plurality of distinguishable fluorescent markers. The invention further relates to nucleotides, nucleosides, polynucleotides and polypeptides labeled with novel fluorescent cyanine dyes according to the invention, and methods of using them.
    Type: Grant
    Filed: February 28, 2002
    Date of Patent: March 16, 2004
    Assignee: Stratagene
    Inventors: Jack Anderson, Jeffrey Carl Braman
  • Patent number: 6689391
    Abstract: The present invention discloses a process of extraction, purification and characterization of a non-polar fluorescent dye from a marine echinoderm Holothuria scabra, compositions containing the dye and various applications of the dye, said dye is a natural, cell permeant, nontoxic and environmentally friendly non-polar fluorescent dye.
    Type: Grant
    Filed: March 28, 2002
    Date of Patent: February 10, 2004
    Assignee: Council of Scientific & Industrial Research
    Inventors: Usha Goswami, Anutosh Ganguly
  • Patent number: 6632526
    Abstract: An improved method of making a series of bead or microsphere or particle populations characterized by subtle variation in a proportion or ratio of at least two fluorescent dyes distributed within a single bead of each population is provided. These beads, when excited by a single excitation light source are capable of giving off several fluorescent signals simultaneously. A set containing as many as 64 distinct populations of multicolored, fluorescent beads is provided and when combined with analytical reagents bound to the surface of such beads is extremely useful for multiplexed analysis of a plurality of analytes in a single sample. Thus, methods of staining polymeric particles, the particles themselves, and methods of using such particles are claimed.
    Type: Grant
    Filed: October 14, 1998
    Date of Patent: October 14, 2003
    Assignee: Luminex Corporation
    Inventors: Don J. Chandler, Van S. Chandler, Beth A. Lambert, Janet J. Reber, Stacie L. Phipps