Sulfonic Acid Or Salt Thereof Or Sulfonamide Patents (Class 8/676)
  • Patent number: 5085667
    Abstract: Stain-resistant nylon, especially cationic-dyeable carpet nylon, is prepared by dyeing cationic-dyeable nylon fibers with acid or premetalized dye. Lightfastness and depth of shade of an apparent value equal to acid dyeable nylons is obtained with superior stain resistance equal to commercially available solution dyed nylon carpeting.
    Type: Grant
    Filed: July 12, 1990
    Date of Patent: February 4, 1992
    Assignee: Burlington Industries, Inc.
    Inventor: William G. Jenkins
  • Patent number: 5071442
    Abstract: A process for dyeing or printing cellulosic textile fibre materials by the trichromatic technique, which process comprises dyeing or printing said materials from an aqueous liquor with at least one red or reddish brown dyeing dye of formula ##STR1## and at least one yellow or orange dyeing dye of formula ##STR2## and at least one blue dyeing dye of formula ##STR3## wherein A.sub.1, A.sub.2, (B.sub.2).sub.1-3, R.sub.1, R.sub.2, R.sub.3, (R.sub.4).sub.1-2, (X).sub.1-2, (T.sub.1).sub.1-2, (T.sub.2).sub.1-2, (Y).sub.1-3 and Z in formulae (1) to (7) are as defined in claim 1.The process of this invention is suitable for dyeing or printing cellulosic fibre materials.
    Type: Grant
    Filed: January 4, 1991
    Date of Patent: December 10, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Jean P. Luttringer, Athanassios Tzikas, Pierre Galafassi
  • Patent number: 5047067
    Abstract: A reactive dyestuff composition containing, as a dyestuff component, at least two different reactive dyestuffs which present similar color hue upon dyeing cellulose and have different reactive groups and different substantivities is disclosed. Preferably, the composition contains at least one reactive dyestuff having either a .beta.-sulfatoethyl-sulfone group or vinylsulfone group and at least one reactive dyestuff having a halogenated triazine group. The composition is suitable for dyeing cellulose fibers.
    Type: Grant
    Filed: November 23, 1988
    Date of Patent: September 10, 1991
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Koichi Miyazaki, Hachiro Hirooka
  • Patent number: 4999418
    Abstract: Disclosed are colored polyester compositions comprising a polyester having reacted therewith or copolymerized therein at least one residue of an anthraquinone compound having the formula ##STR1## wherein AQ is the residue of a 9,10-anthraquinone radical; R.sup.1 and R.sup.2 are the same or different and are unsubstituted or substituted alkyl, cycloalkyl or aryl; X is a group reactive with at least one of the functional groups of the monomers from which the polyester is prepared; and n is 1 or 2. The described anthraquinone compounds possess improved thermal stability and thus are not decomposed at the high temperatures at which polyesters are prepared. Also disclosed are shaped articles, particularly containers, fabricated from the colored polyester compositions.
    Type: Grant
    Filed: August 31, 1989
    Date of Patent: March 12, 1991
    Assignee: Eastman Kodak Company
    Inventors: James J. Krutak, Max A. Weaver, Clarence A. Coates, Jr., Samuel D. Hilbert, Wayne P. Pruett, William W. Parham
  • Patent number: 4950303
    Abstract: Water-soluble dyes are loaded on polymer microparticles having a particle size of 0.01 to 50 microns. The carrier polymer microparticles are produced by emulsion polymerizing a mixture of at least one monofunctional monomer with a crosslinking monomer in the presence of a polymerizable amino acid derivative or a hydrophilic oligomer having a plurality of amphoionic groups. Water-soluble dyes are added to the resulting emulsion. Color-loaded polymer microparticles are obtained by removing water from the emulsion followed by resuspending in an organic solvent.
    Type: Grant
    Filed: December 3, 1987
    Date of Patent: August 21, 1990
    Assignee: Nippon Paint Co., Ltd
    Inventor: Keizou Ishii
  • Patent number: 4944768
    Abstract: There are disclosed solid dye formulations which comprise at least one anionic wool dye and optional additional components as well as a mixture of an anionic dispersant and an amphoteric surfactant. Such formulations are distinguished in particular by improved solubility in water.
    Type: Grant
    Filed: February 13, 1989
    Date of Patent: July 31, 1990
    Assignee: Ciba-Geigy Corporation
    Inventors: Paolo Balliello, Otto Schilling, Beat Bruttel
  • Patent number: 4894065
    Abstract: The invention refers to a mixture of anionic dyestuffs having a skitteriness value at pH5 of 3-4 and a combinability value at pH5 of 4-5 and to a process for dyeing a fibre material comprising wool with such a mixture of dyestuffs. These mixtures of anionic dyestuffs give surface and fibre level dyeings.
    Type: Grant
    Filed: March 3, 1988
    Date of Patent: January 16, 1990
    Assignee: Sandoz Ltd.
    Inventors: Oskar Annen, Wolfgang Beck, Josef Frauenknecht
  • Patent number: 4891047
    Abstract: A process for dyeing fibers. Fibers are dyed in a dye liquor containing granules of silica gel.
    Type: Grant
    Filed: November 19, 1986
    Date of Patent: January 2, 1990
    Assignee: Director-General of the Sericultural Experiment station, Ministry of Agriculture, Forestry and Fisheries of Japan
    Inventors: Hrioshi Kato, Keiichi Komatsu
  • Patent number: 4888028
    Abstract: A water-soluble dye mixture comprising a blue anthraquinone reactive dye represented in its free acid form by the formula: ##STR1## wherein X is --CH.dbd.CH.sub.2 or --C.sub.2 H.sub.4 W wherein W is a group removable by action of alkali and from 0.2 to 5 times by weight to said anthraquinone reactive dye of a blue formazan reactive dye represented in its free acid form by the formula: ##STR2## wherein R is a hydrogen atom or a C.sub.1 -C.sub.4 alkyl group, Y is a halogen atom, --NHC.sub.2 H.sub.4 SO.sub.3 H or ##STR3## and X is --CH.dbd.CH.sub.2 or --C.sub.2 H.sub.4 W wherein W is a group removable by action of alkali.
    Type: Grant
    Filed: June 15, 1988
    Date of Patent: December 19, 1989
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Toshio Hihara, Riyouichi Sekioka
  • Patent number: 4859207
    Abstract: A process for dyeing textile planar fabrics made from natural or synthetic polyamides with anionic dyes by(a) locally applying a resist agent by itself or in conjunction with an anionic dye of fluorescent whitening agent,(b) subjecting the textiles to a heat treatment, and(c) carrying out ground dyeing with a dye liquor that contains a further anionic dye,which process comprises using, as resist agent, a melamine compound of formula ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are each independently phenyl or naphthyl, each of which may be substituted by halogen, hydroxy, C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkoxy, Z is an acid water-solubilizing group, and m is 1 to 6.
    Type: Grant
    Filed: July 19, 1988
    Date of Patent: August 22, 1989
    Assignee: Ciba-Geigy Corporation
    Inventors: Thys Bouwknegt, Heinz Abel
  • Patent number: 4840643
    Abstract: A trichromatic dye combination especially suited for the continuous dyeing of synthetic polyamide materials; the system including an acid red dye component, an acid blue dye component and an acid yellow dye component, each of said dye components being selected on the basis of minimum and compatible cold strike and compatible on tone strike rates.The trichromatic combination according to the invention dyes synthetic polyamide fibers from aqueous liquors, producing level dyeings having excellent fastness properties including good lightfastness and good ozone fastness.
    Type: Grant
    Filed: March 16, 1988
    Date of Patent: June 20, 1989
    Assignee: Crompton & Knowles Corporation
    Inventor: Jay E. Rowe
  • Patent number: 4834769
    Abstract: Dye compositions containing (a) at least one blue sulpho group-containing triphendioxazine dye and (b) at least one blue sulpho group-containing anthraquinone dye and preferably (c) lignine sulphonic acid or a salt of it and optionally (d) a non-ionic blending agent are outstandingly suitable for the level and fast dyeing of leather substrates.
    Type: Grant
    Filed: December 8, 1987
    Date of Patent: May 30, 1989
    Assignee: Sandoz Ltd.
    Inventors: Michel Dien, Herbert Holliger
  • Patent number: 4826503
    Abstract: The invention relates to a process for aftertreating cellulosic material which has been dyed with reactive or direct dyes and subsequently treated in an acid bath. The aftertreatment with a solution of an alkali metal salt or alkaline earth metal salt enhances the wetfastness properties and the tear resistance of the cellulosic material.
    Type: Grant
    Filed: October 9, 1986
    Date of Patent: May 2, 1989
    Assignee: Ciba-Geigy Corporation
    Inventor: Jean-Francois Landre
  • Patent number: 4806126
    Abstract: Process for alkali-free dyeing and printing with reactive dyes. Beforehand, the textile material is treated with a wetting agent and a reaction product of polyethyleneimine and a bifunctional alkylating agent. This is followed by dyeing with reactive dyes in a conventional manner but without the addition of alkali to fix the dyes.
    Type: Grant
    Filed: March 23, 1988
    Date of Patent: February 21, 1989
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Klaus Sternberger, Karl-Heinz Keil, Dieter Gevert, Oscar Navarrete
  • Patent number: 4773914
    Abstract: Dyestuffs which are highly suitable for use as the blue component in the trichromatic dyeing of polyamide fibre materials have the formula ##STR1## in which R.sub.1 and R.sub.2 denote alkyl, the total number of the C atoms in the radicals R.sub.1 and R.sub.2 being at least three.The dyeings obtained are distinguished, inter alia, by good ozone fastness and the absence of the catalytic fading effect.
    Type: Grant
    Filed: December 30, 1986
    Date of Patent: September 27, 1988
    Assignee: Bayer Aktiengesellschaft
    Inventors: Wolfgang Harms, Hans-Gunter Otten
  • Patent number: 4704133
    Abstract: A process for the photochemical stabilization of fibre materials made of synthetic polyamides, which comprises treating the fibre material with at least one water-soluble copper complex dye or with a mixture of copper complex compounds containing at least one copper complex dye, or containing at least one copper complex dye in combination with a water-soluble 1:2 cobalt complex dye, 1:2 chromium complex dye, or an azo, anthraquinone, nitroaryl or dioxazine dye.The fibre materials treated (dyed) by the process of the invention are distinguished by very high tear strength and elongation values after exposure to light or exposure to hot light.
    Type: Grant
    Filed: November 12, 1985
    Date of Patent: November 3, 1987
    Assignee: Ciba-Geigy Corporation
    Inventors: Gerhard Reinert, Hans U. Schutz, Gerhard Back
  • Patent number: 4702744
    Abstract: Stable, concentrated aqueous solutions of, in particular, anionic reactive dyestuffs are obtained in a comparatively simple manner by freeing from salts, preferably by means of membrane separation processes, solutions of these substances just as they are obtained in the course of synthesis, and by replacing, with the aid of ion exchangers, the cations which cause sparing solubility.
    Type: Grant
    Filed: May 27, 1986
    Date of Patent: October 27, 1987
    Assignee: Bayer Aktiengesellschaft
    Inventors: Joachim Wolff, Jochen Koll, Karlheinz Wolf, Reinhold M. Klipper, Peter M. Lange
  • Patent number: 4693727
    Abstract: Process for preparing ozone-fast dyeings on synthetic polyamide fibre materials from aqueous liquor with anthraquinone dyes which comprises using at least one anthraquinone dye which contains one or two fibre-reactive groups and one or two sulfo groups.The process according to the invention is suitable for dyeing synthetic polyamide materials producing with the monosulfoanthraquinone or disulfoanthraquinone dyes which contain one or two fibre-reactive groups level dyeings having good fastness properties, in particular good ozone fastness.
    Type: Grant
    Filed: March 18, 1986
    Date of Patent: September 15, 1987
    Assignee: Ciba-Geigy Corporation
    Inventors: James B. Bowles, Marshall White, Jr., Alois Puentener, Jean-Marie Adam, Peter Loew
  • Patent number: 4645510
    Abstract: The invention provides a process for the exhaust dyeing with a reactive dyestuff of a textile material comprising cellulosic fibres, which process comprises the step of adding to the dyebath containing the reactive dyestuff, simultaneously the salt and the alkali in specified quantities metered per unit time so as to give a substantially linear exhaustion of the dyebath.
    Type: Grant
    Filed: May 24, 1985
    Date of Patent: February 24, 1987
    Assignee: Sandoz Ltd.
    Inventors: Rolf Hasler, Francis Palacin
  • Patent number: 4629465
    Abstract: The invention relates to a process for exhaust dyeing a textile fibre substrate to obtain level dyeings, which process comprises the step of adding to the dyebath the effective amount of dyestuff or electrolyte or dyestuff and electrolyte either simultaneously or one after the other in specified quantities per cycle of the dyeing machine, metered according to a mathematical function.
    Type: Grant
    Filed: October 1, 1984
    Date of Patent: December 16, 1986
    Assignee: Sandoz Ltd.
    Inventors: Rolf Hasler, Francis Palacin
  • Patent number: 4615837
    Abstract: A propylene oxide polyadduct containing carboxyl groups, or a salt thereof, obtained from(a) an adduct of propylene oxide and an aliphatic alcohol having 3 to 10 carbon atoms which is at least trihydric,(b) an aliphatic dicarboxylic acid or the anhydride thereof having 2 to 10 carbon atoms or a mono- or di-lower alkylester of said dicarboxylic acids,(c) an aliphatic diol having an average molecular weight of at most 2,000,(d) a fatty acid having 8 to 22 carbon atoms and(e) an aromatic dicarboxylic acid or the anhydride thereof having 8 to 12 carbon atoms; it is in particular useful as dyeing assistant for the dyeing of fibrous material made of or containing wool with anionic dyes.
    Type: Grant
    Filed: November 16, 1981
    Date of Patent: October 7, 1986
    Assignee: Ciba-Geigy Corporation
    Inventors: Heinz Abel, Paul Schafer
  • Patent number: 4594075
    Abstract: A process is described for spray-drying readily water-soluble dyes and fluorescent brighteners from a saturated aqueous solution which contains undissolved dye or fluorescent brightener in a ratio between dissolved and undissolved matter of 1:9 to 9:1.The free-flowing dye or brightener granulates obtained in this process are distinguished by high bulk density, abrasion resistance and dimensional stability.
    Type: Grant
    Filed: January 22, 1985
    Date of Patent: June 10, 1986
    Assignee: Ciba-Geigy Corporation
    Inventor: Ernst Schenkenberger
  • Patent number: 4579561
    Abstract: A trichromatic dye system for the dyeing of synthetic polyamide fibers, the system including an acid red dye component, an acid blue dye component, and an acid yellow dye component, each of the dye components being compatible from a performance standpoint.
    Type: Grant
    Filed: January 9, 1985
    Date of Patent: April 1, 1986
    Assignee: Crompton and Knowles Corporation
    Inventors: Jay E. Rowe, James F. Feeman
  • Patent number: 4567171
    Abstract: A composition and a process for the production of stable, water dispersions of anionic dyestuffs, for example acid or direct dyestuffs, useful for the dyeing of organic fibers including paper. Highly concentrated, liquid dispersions of at least 15-40% by weight of dry anionic dyestuff are achieved by the use of nonionic dispersing agents and mixing or grinding in a mill until most of the undissolved dyestuff particles are smaller than 10.mu..
    Type: Grant
    Filed: March 20, 1984
    Date of Patent: January 28, 1986
    Assignee: Ciba-Geigy Corporation
    Inventor: Thomas M. Mangum
  • Patent number: 4563192
    Abstract: The invention relates to a process for dyeing synthetic polyamide fibre material with dyes or dye mixtures in the presence of a mixture of dyeing assistants, which comprises using for the dyeing of these materials an aqueous liquor which contains at least one anionic dye which, under the defined dyeing conditions, has a degree of exhaustion of at least 95% at 1/1 standard depth of shade, and a dyeing assistant mixture containing an anionic compound, a quaternary compound and a non-ionic compound, and wherein the liquor contains an alkali metal salt and an organic acid, and finishing the dyeing at pH 5-7, preferably pH 5.5-6, and at a temperature of 95.degree. to 130.degree. C.The process according to the invention is suitable for dyeing synthetic polyamide materials, producing level dyeings having good fastness properties with all types of dye or mixtures of dyes of identical or different types.
    Type: Grant
    Filed: September 14, 1984
    Date of Patent: January 7, 1986
    Assignee: Ciba-Geigy Corporation
    Inventors: Heinz Salathe, Hermann Flensberg, Harry Schaetzer
  • Patent number: 4514187
    Abstract: The present invention relates to a process for the differential dyeing of such polyamide fibres and materials containing polyamide fibres as are made of components which differ in dyeability, or mixtures of polyamide fibres, with dyes or dye mixtures, which comprises using for dyeing these materials an aqueous liquor which contains a dye of the formula ##STR1## in which A.sub.1 is hydrogen or C.sub.1-4 alkyl and R is a C.sub.2-5 -alkanoyl, C.sub.3-6 -alkenoyl, (C.sub.1-4 -alkoxy)carbonyl, phenoxycarbonyl, C.sub.1-4 -alkylsulfonyl or phenylsulfonyl radical which can be substituted in the alkyl, alkenyl, alkoxy, phenoxy or phenyl moiety, or a mixture of a dye of the formula (1) with a monosulfo-containing anthraquinone dye, and to those dyes of the formula (1) in which A.sub.1 is as defined above and R is a C.sub.1-4 -alkylsulfonyl or phenylsulfonyl radical which can be substituted in the phenyl moiety by C.sub.1-4 -alkyl.
    Type: Grant
    Filed: July 14, 1983
    Date of Patent: April 30, 1985
    Assignee: Ciba-Geigy Corporation
    Inventors: Hans U. Schutz, Helmut Raisin, Thys Bouwknegt
  • Patent number: 4501592
    Abstract: The invention relates to dyes of the formula ##STR1## wherein X is oxygen or sulfur, R is hydrogen or C.sub.1 -C.sub.4 alkyl, Y is an unsubstituted or substituted aryl radical, n is 1, 2 or 3, the benzene ring A may be substituted by halogen and the benzene rings B and D may each independently be substituted by halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or a radical of the formula --O--CH.sub.2 CH.sub.2 --O--R.sub.1, wherein R.sub.1 is hydrogen, methyl or ethyl. These dyes are suitable for dyeing or printing natural or synthetic polyamide fibres.
    Type: Grant
    Filed: August 10, 1983
    Date of Patent: February 26, 1985
    Assignee: Ciba-Geigy Corporation
    Inventors: Jean-Marie Adam, Peter Bloch
  • Patent number: 4487610
    Abstract: A cold water soluble dyestuff composition which contains(a) 30 to 90% by weight of the dye of formula I ##STR1## (b) 2 to 50% by weight of an anionic dispersant (c) 0.1 to 10% by weight of an alkylenediaminedicarboxylic, -tricarboxylic or -tetracarboxylic acid of the formula II ##STR2## wherein X is a carboxyl group or the nitrilo group, m is 1 to 3 and n is 2 to 5, or a salt thereof, and optionally further ingredients.The assistant combination of anionic dispersant and alkylenediaminedicarboxylic, -tricarboxylic or -tetracarboxylic acid imparts to the composition a cold water solubility of 30 g/l. The composition is suitable for dyeing and printing textile material, especially that made from synthetic polyamide.
    Type: Grant
    Filed: August 5, 1983
    Date of Patent: December 11, 1984
    Assignee: Ciba-Geigy Corporation
    Inventor: Dieter M/a/ usezahl
  • Patent number: 4474577
    Abstract: The present disclosure is concerned with new modifications of the dyestuff Color Index Acid Blue 324 which have significant advantages over the known form of this dyestuff. In particular, the preferred modification is much easier to isolate from an aqueous medium by filtration and the isolated product has a higher purity. The filtration proceeds much more rapidly and gives a filter residue of a much higher solids content. Furthermore, this new form of the dyestuff imparts a dramatically lower viscosity to aqueous dispersions or slurries prepared from it than are obtained using the old form of this dyestuff. These modifications are obtained by heating an aqueous dispersion or slurry of the known form of Color Index Acid Blue 324 to temperatures in excess of about 97.degree. C. and for the preferred form in the presence of a substance which reduces the surface tension between the dispersed organic dyestuff phase and the aqueous dispersing medium.
    Type: Grant
    Filed: October 26, 1983
    Date of Patent: October 2, 1984
    Assignee: Mobay Chemical Corporation
    Inventors: Charles W. Sandefur, Thomas J. Thomas
  • Patent number: 4465491
    Abstract: The solid dye preparations contain(a) 30-90 percent by weight of a water-soluble dye,(b) 1-25 percent by weight of an aliphatic aminocarboxylic acid or a salt thereof, and(c) 0-50 percent by weight of further additives.There is preferably at least 2% of anionic dispersing agent in the preparations.The preparations are particularly suitable for dyeing textile material made from cotton, polyacrylonitrile, wool or synthetic polyamide.
    Type: Grant
    Filed: July 20, 1983
    Date of Patent: August 14, 1984
    Assignee: Ciba-Geigy Corporation
    Inventors: Paolo Balliello, Paul Erzinger, Ernst Tempel
  • Patent number: 4453943
    Abstract: The invention relates to solid dye formulations which, in addition to containing at least one anionic dye, at least one anionic dispersant, a non-ionic emulsifier and optionally further ingredients, contains 0.1 to 10% by weight, based on the final formulation, of a quaternary ammonium salt of the formula I ##STR1## wherein R.sub.1 is a C.sub.8 -C.sub.20 alkyl or C.sub.8 -C.sub.20 alkenyl group, each of R.sub.2, R.sub.3 and R.sub.4 independently of one another is a C.sub.1 -C.sub.4 alkyl group, and An.sup..crclbar. is an anion.Such formulations, which have good cold water solubility, are suitable for dyeing or printing textile material e.g. of wool or polyamide.
    Type: Grant
    Filed: March 23, 1983
    Date of Patent: June 12, 1984
    Assignee: Ciba-Geigy Corporation
    Inventor: Paolo Balliello
  • Patent number: 4402701
    Abstract: Leather dyeing agents, which can be obtained by concentrating, by means of a membrane separation process, the mother liquors, which are produced in the salting-out process in the preparation of organic dyestuffs which are water-soluble or which contain groups imparting water-solubility, the mother liquors having an extinction in the absorption maximum which is .gtoreq.500, with a layer thickness of 10 cm, and by drying the concentrate, if appropriate.
    Type: Grant
    Filed: September 21, 1981
    Date of Patent: September 6, 1983
    Assignee: Bayer Aktiengesellschaft
    Inventors: Harald Gleinig, Hans-Heinz Molls, Jochen Koll, Gottfried Dick, Reinhold Hornle, Friedrich Kunert
  • Patent number: 4402704
    Abstract: The invention relates to a process for the trichromatic dyeing or printing of natural and synthetic polyamide materials with dye mixtures, in which process there is used the dye of the formula ##STR1## wherein R.sub.1 is methyl or ethyl, and R.sub.2 is cyclohexyl or phenyl, together with at least one dye of the formula ##STR2## wherein B.sub.1, B.sub.2 and E.sub.1 are hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy, and X is straight-chain or branched-chain C.sub.1 -C.sub.4 -alkyl, or straight-chain or branched-chain C.sub.2 -C.sub.4 -hydroxyalkyl, and a dye of the formula ##STR3## wherein one Y is hydrogen or methyl, and the other Y is C.sub.2 -C.sub.4 -alkanoylamino or C.sub.2 -C.sub.4 -hydroxyalkylsulfamoyl, or with a mixture of the dyes of the formulae ##STR4## where Y.sub.1 in the formula (4) is C.sub.2 -C.sub.4 -hydroxyalkylsulfamoyl, and Z is hydrogen or methyl, and Y.sub.2 in the formula (5) is C.sub.2 -C.sub.4 -alkanoylamino, Z in the formula (4) being hydrogen when Y.sub.
    Type: Grant
    Filed: February 8, 1982
    Date of Patent: September 6, 1983
    Assignee: Ciba-Geigy Corporation
    Inventors: Helmut Raisin, Dieter Mausezahl, Harry Schaetzer
  • Patent number: 4396393
    Abstract: The invention relates to a dye mixture which contains a dye of the formula ##STR1## wherein Z is hydrogen or methyl, and a dye of the formula ##STR2## Z in the formula (1) being hydrogen when the propionylamino group in the formula (2) is bound in the m-position with respect to the NH group. The dye mixture is suitable for dyeing or printing natural or synthetic polyamide materials, especially in combination with other dyes, and particularly from short liquors. The dye mixture is characterized by generally good properties, in particular by good strike properties and good solubility.
    Type: Grant
    Filed: February 8, 1982
    Date of Patent: August 2, 1983
    Assignee: Ciba-Geigy Corporation
    Inventors: Harry Schaetzer, Helmut Raisin, Dieter Mausezahl
  • Patent number: 4349349
    Abstract: An aqueous liquid dye composition containing 10 to 50 parts by weight of C.I. Reactive Blue 19, 1 to 40 parts by weight of a condensation product of formaldehyde with naphthalenesulfonic acid which may be alkylated, 0.1 to 10 parts by weight of a nonionic surfactant having an HLB of 9 to 20, and 20 to 80 parts by weight of water. This liquid dye composition has a good storage stability, and shows a sufficient solubility in an aqueous alkali liquor so that it is particularly suitable for dyeing cellulosic fibers by a one-bath pad-batch method.
    Type: Grant
    Filed: March 23, 1981
    Date of Patent: September 14, 1982
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Kiyoharu Nakatsuka, Sadaharu Abeta
  • Patent number: 4332938
    Abstract: Dyestuffs of the formula ##STR1## wherein R.sub.1 and R.sub.2 have the meaning given in the description,and their use for dyeing and printing materials containing hydroxyl groups or amide groups, such as textile fibres, filaments and fabrics of wool, silk or synthetic polyamide or polyurethane fibres, and for dyeing and printing natural or regenerated cellulose with dyeings and prints which are fast to washing. The dyeings obtained are distinguished by good fastness to light and wet processing.
    Type: Grant
    Filed: November 30, 1979
    Date of Patent: June 1, 1982
    Assignee: Bayer Aktiengesellschaft
    Inventors: Wolfgang Harms, Klaus Wunderlich, Klaus von Oertzen
  • Patent number: 4330294
    Abstract: The present invention relates to compounds of formula ##STR1## in which R.sub.1 is an aliphatic or alicyclic hydrocarbon radical,R.sub.2 is hydrogen, halogen or C.sub.1-8 alkyl,M is hydrogen or an equivalent of a non-chromophoric cationand mixtures of such compounds with the corresponding ethers, which mixtures are useful as anionic dyestuffs.
    Type: Grant
    Filed: September 26, 1980
    Date of Patent: May 18, 1982
    Assignee: Sandoz Ltd.
    Inventor: Roland Wald
  • Patent number: 4325705
    Type: Grant
    Filed: December 10, 1979
    Date of Patent: April 20, 1982
    Assignee: Bayer Aktiengesellschaft
    Inventors: Wolfgang Harms, Klaus Wunderlish, Klaus von Oertzen
  • Patent number: 4294578
    Abstract: Use of compounds which, in the form of the free acid, correspond to the formula ##STR1## in which Z represents halogen or alkylcarbonylamino with 1-4 C atoms in the alkyl radical,m is 0, 1 or 2 andn, r and s represent the numbers 0 or 1 with the proviso that the sum of n, r and s has a value of 1 or 2 and s can be 1 only if r at the same time is 0,for dyeing polymeric materials containing amide groups, material dyed in this way and colorants containing the compounds of the indicated formula.
    Type: Grant
    Filed: March 15, 1979
    Date of Patent: October 13, 1981
    Assignee: Bayer Aktiengesellschaft
    Inventors: Friedrich W. Krock, Rutger Neeff
  • Patent number: 4283195
    Abstract: A dye composition containing C.I. Reactive Blue 19 and an alkylnaphthalenesulfonic acid/formaldehyde condensate, which is very readily soluble in water and aqueous alkaline liquors and useful for dyeing natural and regenerated cellulose fibers with high color yield, particularly in accordance with a one-bath pad dyeing method.
    Type: Grant
    Filed: January 7, 1980
    Date of Patent: August 11, 1981
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Kiyoharu Nakatsuka, Sadaharu Abeta
  • Patent number: 4273553
    Abstract: Dyestuffs of the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, m, n, p and X have the meaning given in the description,and their use for dyeing and printing materials containing hydroxyl groups or amide groups, such as textile fibres, filaments and woven fabrics of wool, silk or synthetic polyamide or polyurethane fibres, and for dyeing and printing natural or regenerated cellulose in dyeings and prints which are fast to washing. Blue dyeings and prints which are fast to light and wet processing are obtained.
    Type: Grant
    Filed: October 19, 1979
    Date of Patent: June 16, 1981
    Assignee: Bayer Aktiengesellschaft
    Inventors: Wolfgang Harms, Horst Jager, Klaus von Oertzen, Klaus Wunderlich
  • Patent number: 4273720
    Abstract: The present invention relates to anionic dyestuffs of the 1-amino-4-aryl- or -4-alkylamino anthraquinone series which are unsubstituted in the 3-position and bear in the 2-position an arylalkyleneoxy group, and in which at least one aryl group bears a sulpho group, with the proviso that when the substituent in the 4-position is alkylamino such alkyl is linear, branched or cyclic and contains at least 9 carbon atoms and the sum of the carbon atoms of the alkylamino group in the 4-position and the alkylene group in the 2-position is at least 12, which dyestuffs are in the free acid or salt form.
    Type: Grant
    Filed: September 18, 1978
    Date of Patent: June 16, 1981
    Assignee: Sandoz Ltd.
    Inventor: Roland Wald
  • Patent number: 4264511
    Abstract: New anthraquinone compounds of the formula ##STR1## in which Y denotes chlorine, bromine, --O--R or ##STR2## R denotes aryl, R.sub.1 and R.sub.2 denote hydrogen, alkyl, cycloalkyl or aryl andX.sub.1 and X.sub.2 denote hydrogen, halogen or nitro,are obtained when the corresponding 2-sulphonic acids are treated with inorganic acid halides and the products are then optionally treated with alcohols or amines. The compounds I are valuable dyestuffs for dyeing polyester fibres and starting materials for the preparation of such dyestuffs.
    Type: Grant
    Filed: May 11, 1979
    Date of Patent: April 28, 1981
    Assignee: Bayer Aktiengesellschaft
    Inventors: Friedrich W. Krock, Rutger Neeff
  • Patent number: 4255151
    Abstract: In order to dye and print cellulose fibres swollen with water-miscible swelling agents or mixed fibres containing these fibres, the fibres are treated with dyestuffs which are free from sulphonic acid groups and carboxylic acid groups, of the general formula ##STR1## wherein R denotes hydrogen or optionally substituted alkyl, aryl or acyl,Hal denotes chlorine or bromine,n denotes a number from 0 to 2 and the ring B can optionally be further substituted or fused, with the proviso that if R denotes hydrogen or methyl, n must be >0 and/or B must be further substituted,and the dyestuffs are fixed by heat treatment.
    Type: Grant
    Filed: October 4, 1979
    Date of Patent: March 10, 1981
    Assignee: Bayer Aktiengesellschaft
    Inventors: Volker Hederich, Gunter Gehrke, Robert Kuth, Werner Kuhnel
  • Patent number: 4249902
    Abstract: Formulations for dyeing polyesters and polyamides, the dyestuff component of which does not tend to crystallize in the dyebath and the effluents of which can be readily degraded biologically, are obtained in an inexpensive manner when those organophilic dyestuffs which have melting points below 140.degree. C., preferably below 100.degree. C., are used and these dyestuffs are homogeneously mixed with emulsifying polar/non-polar compounds, such as, for example, fatty sulphates and sulphonates, without expensive fine comminution processes.
    Type: Grant
    Filed: May 30, 1978
    Date of Patent: February 10, 1981
    Assignee: Bayer Aktiengesellschaft
    Inventors: Winfried Kruckenberg, Karl H. Schundehutte
  • Patent number: 4244691
    Abstract: The invention relates to novel, water-soluble anthraquinone dyes which, in the form of the free acid, have the formula I ##STR1## in which X is halogen, R.sub.1 is an unbranched or branched alkyl radical having 4 to 8 carbon atoms, R.sub.2 and R.sub.3 independently of one another are an unbranched or branched alkyl radical having 1 to 4 carbon atoms, R.sub.4 is hydrogen, an unbranched or branched alkyl radical having 1 to 4 carbon atoms, a free or acylated amino group or a fibre-reactive radical bonded via an amino group, R.sub.5 is hydrogen or an unbranched or branched alkyl radical having 1 to 4 carbon atoms and R.sub.6 and R.sub.7 independently of one another are hydrogen, an unbranched or branched alkyl radical having 1-4 carbon atoms, a --SO.sub.3 H group, halogen or a radical of the formula --CH.sub.
    Type: Grant
    Filed: November 16, 1979
    Date of Patent: January 13, 1981
    Assignee: Ciba-Geigy Corporation
    Inventor: Jean-Marie Adam
  • Patent number: 4213759
    Abstract: Differential-dyeing nylon fibres are dyed or printed with a mixture of compatible dyes selected from spcified classes of yellow, orange, red and blue disulphonated or monosulphonated/monocarboxylated monoazo, disazo and anthraquinone dyes.
    Type: Grant
    Filed: November 20, 1978
    Date of Patent: July 22, 1980
    Assignee: Imperial Chemical Industries Limited
    Inventors: Denis R. A. Ridyard, Charles W. Taylor