Carbonyl Bonded Directly To Nitrogen Patents (Class 8/696)
  • Patent number: 9023118
    Abstract: The present invention relates to new azo dyes, a process for their preparation, and their use for dyeing or printing fibrous materials, to produce materials with brownish shades.
    Type: Grant
    Filed: November 29, 2011
    Date of Patent: May 5, 2015
    Assignee: Kemira OYJ
    Inventors: Helmut-Martin Meier, Christof Heide, Klaus-Günter Strumpf, Thomas Hübbe
  • Patent number: 8911509
    Abstract: Reactive dye mixtures comprising at least one red dyeing dye and at least one blue, yellow, orange or brown dyeing dye and their use in methods for the dichromatic or trichromatic dyeing or printing of cellulosic fiber materials are described. The reactive dye mixtures yield dyeings or prints having good reproducibility and good all-round fastness properties.
    Type: Grant
    Filed: January 13, 2011
    Date of Patent: December 16, 2014
    Assignee: Huntsman International LLC
    Inventors: Athanassios Tzikas, Georg Roentgen, Marco Casartelli, Remo Codemo, Jean-Francois Landre
  • Patent number: 8906116
    Abstract: The present invention relates to dye mixtures which comprise at least one dye of the formula (I) and at least one dye of the formula (II) in which R1, R2, R3, and X are defined as stated in claim 1, to processes for their preparation, and to their use.
    Type: Grant
    Filed: January 30, 2012
    Date of Patent: December 9, 2014
    Assignee: DyStar Colours Distribution GmbH
    Inventors: Adrian Murgatroyd, Clemens Grund, Klaus-Wilfried Wanken, Hartwig Jordan
  • Patent number: 8821592
    Abstract: An agent for the oxidative dyeing of keratinous fibers is provided. The agent contains, as a developer-type oxidation dye precursor, a compound of Formula (I) that carries at least one cationic charge in Y.
    Type: Grant
    Filed: May 29, 2012
    Date of Patent: September 2, 2014
    Assignee: Henkel AG & Co. KGaA
    Inventors: Wibke Gross, Ralph Nemitz, Astrid Kroos
  • Publication number: 20140196224
    Abstract: The present disclosure relates to a dye of formula (1a) and also to a process for its preparation and to its use in the dyeing or printing of semi-synthetic and, especially, synthetic hydrophobic fibre materials, more especially textile materials.
    Type: Application
    Filed: March 18, 2014
    Publication date: July 17, 2014
    Applicant: Huntsman International LLC
    Inventors: Antoine Clement, Alfons Arquint, Urs Lauk
  • Patent number: 8668746
    Abstract: Present invention relates to a two part coloring composition for hair with improved dyeing and conditioning properties of hair. The object of the present invention a two part hair dyeing composition consisting of Parts A and B which are mixed immediately before application onto hair wherein Part A is based on at least one hair dye and comprising further at least one amino acid surfactant and Part B is an aqueous composition and comprising at least one oxidizing agent and at least one cationic or cationizable surfactant, wherein parts A and/or B comprises additionally at least one oil.
    Type: Grant
    Filed: December 23, 2011
    Date of Patent: March 11, 2014
    Assignee: KAO Germany GmbH
    Inventors: Martin Uellner, Alexander Meuser, Sandra Schmelz, Diana Bauer
  • Patent number: 8636813
    Abstract: Present invention relates to a dyeing composition for hair with improved dyeing and conditioning properties of hair. The object of the present invention a composition for dyeing hair based on at least one hair dye and comprising at least one amino acid surfactant and at least one natural oil.
    Type: Grant
    Filed: December 23, 2011
    Date of Patent: January 28, 2014
    Assignee: Kao Germany
    Inventors: Martin Uellner, Alexandra Meuser, Sandra Schmelz, Diana Bauer
  • Publication number: 20130174358
    Abstract: The present invention provides a treatment composition comprising a hydrophobic dye.
    Type: Application
    Filed: September 14, 2012
    Publication date: July 11, 2013
    Applicant: The Sun Products Corporation
    Inventors: Stephen Norman Batchelor, Jayne Michelle Bird
  • Patent number: 8101731
    Abstract: The present invention relates to novel yellow anionic dyes, a process for their preparation, certain novel intermediates necessary for their preparation and the use of these dyes for dyeing natural or synthetic materials, in particular, paper. The dyes are of formula (14), (15) or (16) in which R1 represents hydrogen, C1-C4alkyl, C1-C4alkoxy or SO3H, R2 represents SO3H or CO2H, R3 represents hydrogen, C1-C4alkyl, halogen, hydroxy, C1-C4alkoxy, carboxy, NH2 or NHC1-C4alkyl, R3a represents hydrogen or NH2 and A1 and A2, independently of the other, is selected from the group consisting of an acetoacetylated amine, a derivative of barbituric acid, a 2,4,6-triaminopyrimidine derivative, a pyridone derivative, an aminopyrazole or a pyrazolone derivative and a benzoic acid derivative, or A1 and A2, each one independently of the other, represent a certain phenol residue.
    Type: Grant
    Filed: March 29, 2010
    Date of Patent: January 24, 2012
    Inventors: Michael Lennartz, Adolf Käser, Sandra Weiss
  • Publication number: 20110078863
    Abstract: The present invention relates to dyes of formula wherein R1 is 2-methoxyethyl, 2-ethoxyethyl or 2-(2-ethoxyethoxy)ethyl, R2 is C1-C8alkyl which is unsubstituted or substituted by one or more hydroxy groups, halogen atoms, C1-C4alkoxy groups, C2-C8alkoxyalkoxy groups, C1-C4alkyl-COO— groups or C1-C4alkyl-OCO— groups, R3 is methyl, hydroxy, halogen, —NH—SO2—R5 or —NH—CO—R6, wherein R5 is methyl or ethyl and R6 is methyl, ethyl, methoxymethyl or 2-methoxyethyl, and R4 is ethyl or n-propyl, and also to a process for their preparation and to their use in the dyeing or printing of semi-synthetic and, especially, synthetic hydrophobic fibre materials, more especially textile materials.
    Type: Application
    Filed: December 9, 2010
    Publication date: April 7, 2011
    Applicant: Huntsman International LLC
    Inventors: Antoine CLÉMENT, Alfons ARQUINT, Urs LAUK
  • Publication number: 20110027548
    Abstract: Use of the customary dyes for the type of fibre in question and using the customary dyeing and/or printing processes for the type of fibre in question for minimally reducing, retaining or increasing the NIR reflectance, preferably increasing the NIR reflectance, in the region of electromagnetic radiation of wavelength 700 nm to 1100 nm of textile material in relation to the undyed and untreated textile material, characterized in that metal-free dyes are used.
    Type: Application
    Filed: March 27, 2009
    Publication date: February 3, 2011
    Applicants: CLARIANT FINANCE (BVI) LIMITED, SCHOELLER TECHNOLOGIES AG
    Inventors: Rainer Nusser, Martin Leiler, Roland Lottenbach, Hans-Juergen Huebner
  • Patent number: 7875706
    Abstract: Disperse dyes of the general formula (I) where D is a diazo component derived from a substituted or unsubstituted aromatic amine, K is an aromatic radical of the formula and the substituents are each as defined in the first claim. Further described are the preparation and the use of the dyes according to the invention.
    Type: Grant
    Filed: December 2, 2004
    Date of Patent: January 25, 2011
    Assignee: Clariant Finance (BVI) Limited
    Inventor: Robert Egli
  • Patent number: 7723494
    Abstract: The present invention relates to novel yellow anionic dyes, a process for their preparation, certain novel intermediates necessary for their preparation and the use of these dyes for dyeing natural or synthetic materials, in particular, paper.
    Type: Grant
    Filed: January 4, 2008
    Date of Patent: May 25, 2010
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Michael Lennartz, Adolf Käser, Sandra Weiss
  • Publication number: 20100112304
    Abstract: Mixture comprising at least one compound of formula (I) and at least one compound of formula (II) where the substituents are each as defined in the claims, and use of these mixtures for colouring hydrophobic synthetic materials.
    Type: Application
    Filed: December 31, 2005
    Publication date: May 6, 2010
    Inventor: Helmut Sieber
  • Publication number: 20090123711
    Abstract: Dye of the formula (I) where Ra is —C6H5-substituted C1-C4-alkyl, Rb is methoxy or ethoxy Rc is methyl or ethyl, its preparation and also the use of this dye in dye mixtures.
    Type: Application
    Filed: June 7, 2006
    Publication date: May 14, 2009
    Inventor: Helmut Sieber
  • Patent number: 7341607
    Abstract: The present invention relates to novel yellow anionic dyes, a process for their preparation, certain novel intermediates for their preparation and the use of these dyes for dyeing natural or synthetic materials, in particular, paper.
    Type: Grant
    Filed: May 27, 2003
    Date of Patent: March 11, 2008
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Michael Lennartz, Adolf Käser, Sandra Weiss
  • Patent number: 7282070
    Abstract: A reactive dye composition having satisfactory reproducibility, leveling, washing off and toughness under balanced affinity and reactivity, and improving Right First Time success ratio, for dyeing a cellulose fiber or fiber materials containing the cellulose fiber. The reactive dye composition comprising: (a) at least one reactive red dyestuff selected from the group consisting of the following formulas, the component (a) is present in an amount ranging from 1% to 99% by weight, and (b) at least one yellow reactive dyestuff selected from the group consisting of the following Color Index: C.I. Reactive Yellow 145 and C.I. Reactive Yellow 176, and at least one blue reactive dyestuff selected from the group consisting of the following Color Index: C.I. Reactive Blue 194, C.I. Reactive Blue 221 and C.I. Reactive Blue 222, the component (b) is present in an amount ranging from 99% to 1% by weight.
    Type: Grant
    Filed: October 19, 2005
    Date of Patent: October 16, 2007
    Assignee: Everlight USA, Inc.
    Inventors: Wen-Jang Chen, Chien-Yu Chen, Bao-Kun Lai, Ya-Chi Tseng
  • Patent number: 7169909
    Abstract: The present invention relates to dyes of formula (I) wherein R1 is C1–C12alkyl or —CnH2n—(OCH2CH2)m—OR3, n being a number from 2 to 8, m being a number from 0 to 4 and R3 being C1–C12alkyl, C6–C24aryl or C6–C24aralkyl, R2 is methyl, ethyl, n-propyl, n-butyl, 2-methoxyethyl or 2-ethoxyethyl, X is halogen and Y is hydrogen, chlorine or bromine, and to the process for the preparation thereof and to the use thereof in dyeing or printing semi-synthetic and especially synthetic hydrophobic fiber materials, more especially textile materials
    Type: Grant
    Filed: December 8, 2003
    Date of Patent: January 30, 2007
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Antoine Clément, Alfons Arquint, Urs Lauk
  • Patent number: 7156907
    Abstract: The present invention is drawn to multimeric dyes, ink-jet inks, and systems that can be used to print images having good water fastness and humid fastness, as well as good color characteristics. Specifically, a multimeric dye for ink-jet printing can comprise a first dye molecule chemically coupled to a second dye molecule through a linker group, wherein the multimeric dye is stable in the presence of interfering metals. These multimeric dyes can be used to form ink-jet inks and can be used in printing systems in accordance with embodiments of the present invention.
    Type: Grant
    Filed: October 22, 2003
    Date of Patent: January 2, 2007
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventor: Larrie A Deardurff
  • Patent number: 7101983
    Abstract: The present invention relates to novel dyestuffs of formula (I) wherein the substituents have the meanings defined in the claims, the production of such dyestuffs, the use of these dyestuffs and material dyed or printed by such dyestuffs.
    Type: Grant
    Filed: April 2, 2002
    Date of Patent: September 5, 2006
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Robert Egli, Oliver Eich, Knut Göke
  • Patent number: 7087731
    Abstract: The present invention relates to dyes of formula wherein R1 is hydrogen, methyl or —BHCO—C1–C4alkyl, R2 is C1–C4alkyl, it being possible for the alkyl chain, from C2 upwards, optionally to be interrupted by an oxygen atom, and R3 has, independent of R2, any of the meanings of R2, and to the process for the preparation thereof and to the use thereof in dyeing or printing semi-synthetic and especially synthetic hydmophobic fiber materials, especially textile materials.
    Type: Grant
    Filed: January 29, 2002
    Date of Patent: August 8, 2006
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Antoine Clément, Jean-Claud Wilhelm, Alfons Arquint, Urs Lauk
  • Patent number: 7060807
    Abstract: Monoazo dyestuffs of the general formula (1) wherein R1, R2, R3 and n are as defined in claim 1, method for their preparation and a method for colouring a synthetic textile material or fiber blend thereof using such dyestuffs.
    Type: Grant
    Filed: September 22, 2004
    Date of Patent: June 13, 2006
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventor: Kiyoshi Himeno
  • Patent number: 7012137
    Abstract: The present invention relates to dyes of formula (I) wherein R is hydrogen or bromine, R1 is hydrogen, methyl or —NHCO—C1–C4alkyl, R2 is C1–C4alkyl substituted by C1–C4alkoxy and R3 has, independently of R2, any of the meanings of R2, and to the process for the preparation thereof and to the use thereof in dyeing or printing semi-synthetic and especially synthetic hydrophobic fiber materials, especially textile materials.
    Type: Grant
    Filed: January 29, 2002
    Date of Patent: March 14, 2006
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Antoine Clément, Jean-Claude Wilhelm, Alfons Arquint, Urs Lauk
  • Patent number: 6746525
    Abstract: A compound comprising a disazo chromaphore and an optionally substituted acyl group linked together through a —SO2—NH— group, inks comprising these compounds, ink jet printer cartridges containing these inks and their use in ink jet printing.
    Type: Grant
    Filed: March 18, 2002
    Date of Patent: June 8, 2004
    Assignee: Avecia Limited
    Inventor: Mark Robert James
  • Patent number: 6555664
    Abstract: The present invention relates to dyes of formula wherein R is methyl or butyl, R1 is hydrogen, halogen, cyano or nitro, R2 is halogen or cyano, R3 is hydrogen, halogen, C1-C4alkyl or C1-C4alkoxy, R4 is hydrogen, C1-C4alkyl, halogen, CF3 or —NHCOR7 wherein R7 is C1-C4alkyl, R5 is C1-C6alkyl that is unsubstituted or substituted by hydroxy, cyano, acyloxy,  or by phenoxy, x being a number from 0 to 4 and it being possible for the alkyl chain, from C2 upwards, optionally to be interrupted by one or more oxygen atoms, or is a radical of formula —CH2CH2—O—COR8, of formula  or of formula  and R6 is a radical of formula —CH2CH2—O—COR8 or of formula  R8 and R9 each independently of the other being C1-C4alkyl and R10 being hydrogen or C1-C4alkyl, or, when R is methyl, R5 and R6 are each independently of the other C1-C4alkyl, with the proviso that when R is n-butyl and
    Type: Grant
    Filed: June 28, 2001
    Date of Patent: April 29, 2003
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Urs Lauk, Antoine Clément, Romeo Dreier, Alfons Arquint
  • Patent number: 6388057
    Abstract: A water-insoluble monoazo dye represented by the following structural formula [I] having a crystal modification characterized by an X-ray diffraction pattern (CuK&agr;) showing one strong peak at a diffraction angle (2&thgr;) of 11.1±0.1° and also four intermediate peaks at 8.1±0.1°, 21.8±0.1°, 23.1±0.1° and 25.2±0.1°.
    Type: Grant
    Filed: August 31, 2001
    Date of Patent: May 14, 2002
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventors: Toshio Hihara, Hiroshi Inoue, Yousuke Takahashi
  • Patent number: 6120561
    Abstract: Process for the preparation of low-salt liquid dyestuff preparations, characterized in that they are obtained by:a) diazotization of an aromatic amine,b) 2-fold coupling of the diazo component obtained according to a) to I-acid-urea, in the presence of an inorganic base and in the absence of an organic base,c) desalination and, if appropriate, concentration by means of a pressure permeation of the reaction mixture obtained according to b), so that an inorganic salt content of less than 1% by weight is achieved.
    Type: Grant
    Filed: April 17, 1997
    Date of Patent: September 19, 2000
    Assignee: Bayer Aktiengesellschaft
    Inventors: Peter Wild, Volker Paulat, Wolfgang Frank, Shaun Murphree
  • Patent number: 6121352
    Abstract: The present invention relates to dye mixtures comprising at least one compound of the formula (I) ##STR1## and at least one compound of the formula (II) ##STR2## where the substituents are each as defined in the description part, which are highly useful for dyeing and printing hydrophobic synthetic material.
    Type: Grant
    Filed: March 18, 1999
    Date of Patent: September 19, 2000
    Assignee: Dystar Textifarben GmbH & Co.
    Inventors: Manfred Hoppe, Kiyoshi Himeno, Ryouichi Sekioka
  • Patent number: 6007586
    Abstract: The present invention describes a process for dyeing or printing fiber material by the pigment dyeing or pigment printing process, which comprises applying to the fiber material, and subsequently fixing, a dyeing liquor or a print paste comprising at least one dye of the formulaD--(X).sub.n (1)in whichD is a radical of an insoluble organic dye of the phthalocyanine, perinone, indigoid, thioindigoid, dioxazine, diketopyrrolopyrrole, isoindolinone, perylene, quinacridone, metal complex, monoazo, disazo, trisazo or anthraquinone series, X is a hydrophilic polar radical, and n is 1, 2 or 3, and at least one pigment dye binder, and also, if desired, further auxiliaries.
    Type: Grant
    Filed: June 17, 1998
    Date of Patent: December 28, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Peter Aeschlimann, Paul Herzig
  • Patent number: 5868802
    Abstract: Disclosed is a disperse dye composition comprising dyes of Formulae (I) and (II). ##STR1## Z.sub.1 is a halogen atom; R.sub.1 is a C.sub.1-4 alkyl group or a hydrogen atom; X.sub.1 and Y.sub.1 each are independently a chlorine atom or a bromine atom; R.sub.2 is a C.sub.1-4 alkyl group or a phenyl group. Using the composition, composite hydrophobic fiber materials can be dyed evenly, and the dyed materials have excellent color fastness.
    Type: Grant
    Filed: April 17, 1997
    Date of Patent: February 9, 1999
    Assignee: Nippon Kayaku Co., Ltd.
    Inventors: Yoshiki Akatani, Yasuo Shirasaki, Yasuo Murakami
  • Patent number: 5718730
    Abstract: Anthraquinone dyes of the formula ##STR1## in which R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 independently of one another are hydrogen or are substituted or unsubstituted C.sub.1 -C.sub.12 alkyl,X.sub.1 and X.sub.2 independently of one another are chlorine or fluorine,B.sub.1 is a C.sub.2 -C.sub.12 alkylene radical which is unsubstituted or substituted by hydroxyl, sulfo or sulfato and is uninterrupted or is interrupted by oxygen; or is a cyclohexylene radical,C.sub.1 -C.sub.4 alkylene-cyclohexylene radical, cyclohexylene-C.sub.1 -C.sub.4 alkylene radical,C.sub.1 -C.sub.4 alkylene-cyclohexylene-C.sub.1 -C.sub.4 alkylene radical or cyclohexylene-methylene-cyclohexylene radical which is unsubstituted or is substituted in the cyclohexylene ring by C.sub.1 -C.sub.4 alkyl; or is a C.sub.1 -C.sub.4 alkylene-phenylene radical,phenylene-C.sub.1 -C.sub.4 alkylene radical or C.sub.1 -C.sub.4 alkylene-phenylene-C.sub.1 -C.sub.4 alkylene radical which is unsubstituted or is substituted in the phenylene ring by C.
    Type: Grant
    Filed: October 31, 1996
    Date of Patent: February 17, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Bernhard Muller
  • Patent number: 5688288
    Abstract: A disperse dye composition comprising one or more dyes represented by the formula: ##STR1## wherein X represents a chlorine or bromine atom; Y a hydrogen atom or an alkoxy or alkoxyalkoxy group; and each of R.sub.1 and R.sub.2 independently a hydrogen atom, a linear or branched unsubstituted or substituted alkyl group, an allyl group or a cycloalkyl group, provided that each of the alkyl and alkoxy groups has 1 to 4 carbon atoms, anda dye represented by the formula: ##STR2## wherein Y represents an alkoxy or alkoxyalkoxy group; each of R.sub.1 and R.sub.2 independently a hydrogen atom, a linear or branched unsubstituted or substituted alkyl group, an allyl group or a cycloalkyl group, and R.sub.3 an alkyl group, provided that each of the alkyl and alkoxy groups has 1 to 4 carbon atoms.
    Type: Grant
    Filed: December 17, 1996
    Date of Patent: November 18, 1997
    Assignee: Nippon Kayaku Kabushiki Kaisha
    Inventors: Yoshiki Akatani, Yasuo Murakami, Hiroyuki Matsumoto, Kiyoko Tanaka
  • Patent number: 5639282
    Abstract: The present invention relates to a process for dyeing polyester or polyester-containing textile materials at pH 8 to pH 11, characterized in that one or more monoazo dyestuffs of the general formula I ##STR1## wherein D is a substituted phenyl radical of the general formula II ##STR2## or 5,6-dichlorobenzothiazol-2-yl6,7-dichlorobenzothiazol-2-yl6-chlorobenzothiazol-2-yl5-nitrobenzothiazol-2-yl6-nitrobenzothiazol-2-yl6-methylsulphonylbenzothiazol-2-yl or5-nitrobenzoisothiazol-3-ylandx.sup.1, x.sup.2, x.sup.3, x.sup.4, y.sup.1, y.sup.2, y.sup.3, r.sup.1, r.sup.2 and r.sup.3 are as defined in claim 1, are employed.
    Type: Grant
    Filed: December 14, 1995
    Date of Patent: June 17, 1997
    Assignee: Dystar Japan, Ltd.
    Inventor: Ulrich Buhler
  • Patent number: 5607502
    Abstract: A process has been found for dyeing and printing pater, wood, plastic or metal, in which dyestuffs which, in the form of the free acid, correspond to the formula (I) ##STR1## wherein A denotes a phenol radical which is optionally substituted by alkyl or cycloalkyl andn represents 0 or 1,are employed.
    Type: Grant
    Filed: October 19, 1995
    Date of Patent: March 4, 1997
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karin Hassenruck, Peter Wild, Martin Michna
  • Patent number: 5601622
    Abstract: Anthraquinone dyes of the formula ##STR1## in which R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 independently of one another are hydrogen or are substituted or unsubstituted C.sub.1 -C.sub.12 alkyl,X.sub.1 and X.sub.2 independently of one another are chlorine or fluorine,B.sub.1 is a C.sub.2 -C.sub.12 alkylene radical which is unsubstituted or substituted by hydroxyl, sulfo or sulfato and is uninterrupted or is interrupted by oxygen; or is a cyclohexylene radical, C.sub.1 -C.sub.4 alkylene-cyclohexylene radical, cyclohexylene-C.sub.1 -C.sub.4 alkylene radical, C.sub.1 -C.sub.4 alkylene-cyclohexylene-C.sub.1 -C.sub.4 alkylene radical or cyclohexylene-methylene-cyclohexylene radical which is unsubstituted or is substituted in the cyclohexylene ring by C.sub.1 -C.sub.4 alkyl; or is a C.sub.1 -C.sub.4 alkylene-phenylene radical, phenylene-C.sub.1 -C.sub.4 alkylene radical or C.sub.1 -C.sub.4 alkylene-phenylene-C.sub.1 -C.sub.
    Type: Grant
    Filed: October 11, 1995
    Date of Patent: February 11, 1997
    Assignee: Ciba-Geigy Corporation
    Inventor: Bernhard M uller
  • Patent number: 5595575
    Abstract: A blue disperse dye mixture comprising a monoazo dye of the following formula (1) and at least one azo dye selected from the group consisting of dyes of the following formulas (2), (3), (4) and (5): ##STR1## wherein each of the variables is defined in the specification.
    Type: Grant
    Filed: November 8, 1995
    Date of Patent: January 21, 1997
    Assignee: DyStar Japan Ltd.
    Inventors: Kiyoshi Himeno, Toshio Hihara, Ryouichi Sekioka
  • Patent number: 5569309
    Abstract: A dye composition containing at least one turquoise blue monoazo dye of the formula (I): ##STR1## and at least one additional dye which is at least one yellow monoazo dye of the formula (II): ##STR2## or at least one blue anthraquinone dye of the formula (III): ##STR3## or at least one navy blue dye of the formula (IV): ##STR4##
    Type: Grant
    Filed: May 19, 1995
    Date of Patent: October 29, 1996
    Assignee: Dystar Japan Ltd.
    Inventors: Toshio Hihara, Kiyoshi Himeno
  • Patent number: 5505742
    Abstract: A method for dyeing hydrophobic fibers black, wherein a mixed black dye is used which comprises a blue color component containing at least 70 wt % of a disperse dye of the following formula (I): ##STR1## wherein X is a chlorine atom or a bromine atom, and R is a methyl group or an ethyl group.
    Type: Grant
    Filed: December 20, 1994
    Date of Patent: April 9, 1996
    Assignee: Dystar Japan Ltd.
    Inventors: Kiyoshi Himeno, Kazuhisa Konishi, Ryouichi Sekioka
  • Patent number: 5496380
    Abstract: A dispersed dye composition which is (A) a combination of blue dye composition (1) and red dye composition (2); (B) a combination of blue dye composition (1) and yellow dye composition (3); or (C) a combination of blue dye composition (1), red dye composition (2) and yellow dye composition (3); wherein blue dye composition (1) consists of from 35 to 55 weight percent of a compound of Formula (I), from 35 to 55 weight percent of a compound of Formula (II) and from 2 to 20 weight percent of a compound of Formula (III); red dye composition (2) consists of at least one red dye selected from the group of compounds of Formulas (IV-1) and (IV-2); and yellow dye composition (3) consists of at least one dye within the scope of the compound of Formula (V).
    Type: Grant
    Filed: May 18, 1995
    Date of Patent: March 5, 1996
    Assignee: Dystar Japan Ltd.
    Inventors: Hideaki Imafuku, Takashi Fujita, Toshikazu Tamiya, Kuniko Kira
  • Patent number: 5494492
    Abstract: A disperse dye composition comprising compounds of the formulae (I) and (II): ##STR1## wherein each of R.sup.1 and R.sup.5 is a methyl group or an ethyl group, and each of R.sup.2, R.sup.3 and R.sup.4 is a C.sub.1-5 alkyl group, wherein the weight ratio of the compound of the formula (I) to the compound of the formula (II) is within a range of from 95:5 to 5:95.
    Type: Grant
    Filed: October 6, 1994
    Date of Patent: February 27, 1996
    Assignee: Dystar Japan Ltd.
    Inventors: Kiyoshi Himeno, Kazuhisa Konishi, Ryouichi Sekioka
  • Patent number: 5431699
    Abstract: Dye mixtures containa) one or more azo dyes of the formula I ##STR1## where Y.sup.1 is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.4 -alkoxy or unsubstituted or substituted C.sub.1 -C.sub.8 -alkanoylamino or C.sub.3 - or C.sub.4 -alkenylamino orY.sup.2 and Y.sup.3 are each hydrogen or unsubstituted or substituted C.sub.1 -C.sub.6 -alkylb) the azo dye of the formula II ##STR2## where L is allyl which may be partially replaced by or may furthermore be hydrogen andc) optionally, an azo dye of the formula III and/or IV as described in the specification.
    Type: Grant
    Filed: January 28, 1994
    Date of Patent: July 11, 1995
    Assignee: BASF Aktiengesellschaft
    Inventors: Arno Lange, Uwe Nahr, Walter Sieber, Volker Walther
  • Patent number: 5174792
    Abstract: The invention relates to mixtures of monoazo dyes, which are characterized in that they consist of one or more dyes of the general formula I ##STR1## and one or more dyes of the general formula II ##STR2## where R.sup.1 is methyl, ethyl, n-propyl or i-propyl,R.sup.2 is ethyl or n-propyl,m is 2 or 3 andn is 1 or 2, with the proviso that m+n is 4,processes for preparing same and the use thereof for dyeing and printing hydrophobic fibre materials and blends thereof with natural fibre materials.
    Type: Grant
    Filed: August 12, 1991
    Date of Patent: December 29, 1992
    Assignee: Cassella Aktiengesellschaft
    Inventors: Hirotsugu Tsumura, Ulrich Buhler, Reinhard Kuhn, Margareta Boos
  • Patent number: 5169404
    Abstract: Use of water-insoluble monoazo dyestuffs of the formula I ##STR1## wherein R.sup.1 denotes alkyl having 1 to 6 C atoms, cyclopentyl, cyclohexyl, fluorine, chlorine, bromine, alkoxy having 1 to 4 C atoms or trifluoromethyl,R.sup.2 denotes alkyl having 1 to 7 C atoms andR.sup.3 and R.sup.4 independently of one another denote alkyl having 1 to 4 C atoms,for the sublimation transfer process.
    Type: Grant
    Filed: February 21, 1991
    Date of Patent: December 8, 1992
    Assignee: Cassella AG
    Inventors: Ulrich Buhler, Erika Kunz, Josef Ritter
  • Patent number: 5092906
    Abstract: The invention relates to a dye mixture containing a dye of the formula ##STR1## in which R.sub.1 is methyl or ethyl and at least one dye of the formulae (2) to (4) ##STR2## in which R.sub.2 is halogen, benzoylamino which is unsubstituted or substituted in the phenyl ring by halogen, 1-azacycloheptane-N-sulfonyl or ##STR3## in which R.sub.5 is C.sub.1 -C.sub.8 alkyl or phenyl which is unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl, and R.sub.6 is hydrogen, or R.sub.5 and R.sub.6 are C.sub.1 -C.sub.8 alkyl, R.sub.3 is hydrogen, halogen or C.sub.1 -C.sub.8 alkyl, and R.sub.4 is hydrogen or halogen, ##STR4## in which D is substituted or unsubstituted phenyl, thiophenyl or benzothiazolyl, R.sub.7 is C.sub.1 -C.sub.8 alkyl, R.sub.8 is substituted or unsubstituted C.sub.1 -C.sub.8 alkyl, and R.sub.9 is hydrogen or C.sub.1 -C.sub.4 alkyl, and ##STR5## in which R.sub.10 is C.sub.1 -C.sub.4 alkyl. The dye mixture is extinguished by generally good properties, in particular by good exhaustion.
    Type: Grant
    Filed: November 19, 1990
    Date of Patent: March 3, 1992
    Assignee: Ciba-Geigy Corporation
    Inventor: Dieter Mausezahl
  • Patent number: 5071443
    Abstract: The dyestuff mixture contains at least one dyestuff of the formula I ##STR1## and at least one dyestuff of the formula II ##STR2## wherein X and Y denote chlorine or bromine,R.sup.1 and R.sup.5 denote methyl or ethyl,R.sup.2 and R.sup.6 denote methyl, ethyl, n-propyl or i-propyl andR.sup.3, R.sup.4, R.sup.7 and R.sup.8 denote, for example, C.sub.1 - to C.sub.11 -alkyl, in the weight ratio of I:II=(5 to 95):(95 to 5), and is, for example, outstandingly suitable for dyeing synthetic fibres.
    Type: Grant
    Filed: March 5, 1990
    Date of Patent: December 10, 1991
    Assignee: Cassella Aktiengesellschaft
    Inventors: Ulrich Buhler, Hubert Kruse, Manfred Hahnke, Margareta Boos, Reinhard Kuhn
  • Patent number: 5038415
    Abstract: A disperse dye composition comprising (a) a pyridone monoazo compound of the formula (I), ##STR1## wherein X.sup.1 and X.sup.2 are each hydrogen, halogen, alkyl, alkoxy or others, and R.sup.1 is alkyl, alkenyl, cycloalkyl, phenyl or anilino, and (b) a pyridone monoazo compound of the formula (II). ##STR2## wherein X.sup.3 and X.sup.4 are each hydrogen, halogen, alkyl, alkoxy or others, and R.sup.2 is alkyl, alkenyl, cycloalkyl, phenyl or anilino, optionally together with (c) a quinophthalone compound of the formula (III), ##STR3## wherein Y is hydrogen or bromine, and the ring A is unsubstituted or substituted benzene or naphthalene ring, which is useful as a yellow dye component for dyeing or printing hydrophobic fiber materials with superior dye bath stability and level dyeing property.
    Type: Grant
    Filed: January 9, 1990
    Date of Patent: August 13, 1991
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Yasuyoshi Ueda, Junichi Sekihachi, Takashi Omura, Hideo Hattori, Kiyoharu Nakatsuka
  • Patent number: 5034016
    Abstract: Dyed denim cotton yarns capable of meeting the market demand for color jeans can be provided by immersing denim cotton yarns in a dye bath containing a dye or dye composition comprising a specific indirubin derivative(s), a specific quinophthalone derivative(s) and/or an indigo dye, squeezing and air-oxidizing the dyed yarns, and repeating a series of these steps.
    Type: Grant
    Filed: May 24, 1989
    Date of Patent: July 23, 1991
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Hitoshi Koshida, Tetsuo Sakagawa, Takayuki Nakayama, Hiroshi Suwa, Masao Imai, Akio Karasawa
  • Patent number: 5032140
    Abstract: A reactive dye represented by the formula (I), ##STR1## wherein R represents --NH.sub.2 or --NHC.sub.2 H.sub.4 SO.sub.3 M, and M's independently represent Li.sup..sym., Na.sup..sym., K.sup..sym. or .sup..sym. NH(C.sub.2 H.sub.4 OH).sub.3, provided that at least one of M's represents Li.sup..sym. or .sup..sym. NH(C.sub.2 H.sub.4 OH).sub.3. This reactive dye easily gives a stable liquid composition and is useful to dye cellulosic or polyamide fibers.
    Type: Grant
    Filed: October 24, 1989
    Date of Patent: July 16, 1991
    Assignee: Nippon Kayaku Kabushiki Kaisha
    Inventors: Nobuyuki Yamanaka, Kazuo Hanawa, Eiichi Ogawa
  • Patent number: 4963160
    Abstract: An ultraviolet radiation absorbing agent for bonding to an ocular lens, wherein the agent has the formula: ##STR1## wherein A and B are ultraviolet radiation absorbing components which are either identical to or are dissimilar to each other.
    Type: Grant
    Filed: March 14, 1989
    Date of Patent: October 16, 1990
    Assignee: Ciba-Geigy Corporation
    Inventors: William M. Hung, Kai C. Su
  • Patent number: RE33908
    Abstract: Synthetic fiber materials are effectively colored by dyeing or printing with a dyestuff mixture containing at least two separate dyestuffs (I) and (II) in a weight ratio of (I):(II) of from (20 to 99):(80 to 1) wherein:(I) is at least one dyestuff of the formula ##STR1## and (II) is at least one dyestuff of the formula ##STR2## in which X and Y are the same or different and each is independently chloro and bromo:R.sup.1 and R.sup.
    Type: Grant
    Filed: February 19, 1991
    Date of Patent: May 5, 1992
    Assignee: Cassella Aktiengesellschaft
    Inventors: Horst Tappe, Hubert Kruse, Reinhard Kuhn, Albert Bode, Margareta Boos