Cellulose Ester Or Ether Patents (Class 8/921)
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Patent number: 5403360Abstract: A process for dyeing or printing cellulosic fibre material with reactive dyes, which comprises dyeing or printing said material with at least one reactive dye that contains a chlorotriazinyl radical, and washing off the dyeing or print so obtained with an aqueous solution to which at least 0.01 gram per liter of an alkaline earth metal salt has been added. Dyeings and prints of good fastness properties are obtained.Type: GrantFiled: February 1, 1994Date of Patent: April 4, 1995Assignee: Ciba-Geigy CorporationInventors: Wolfgang Sutterlin, Rolf Bitterli, Paul Schafflutzel
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Patent number: 5286854Abstract: Basic azo dyes useful for dyeing or printing polymeric material have the formula ##STR1## where R.sup.1 is hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkanoylamino,R.sup.2 is hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or a radical of the formula CO-X, andX is hydroxyl, C.sub.1 -C.sub.4 -alkoxy, amino, mono- or di(C.sub.1 -C.sub.6 -alkyl)amino or a radical of the formula ##STR2## where n is 0 or 1,R.sup.3, R.sup.4 and R.sup.5 are hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl,R.sup.6 is hydrogen or C.sub.1 -C.sub.4 -alkyl,L is C.sub.2 -C.sub.6 -alkylene, andAn.sup..crclbar. is one equivalent of an anion,with the proviso that at least one basic or quaternary radical is present in the molecule.Type: GrantFiled: December 30, 1992Date of Patent: February 15, 1994Assignee: BASF AktiengesellschaftInventors: Erwin Hahn, Heidi Hengelsberg, Udo Mayer
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Patent number: 5227475Abstract: Water-soluble dyestuffs which correspond to the formula (1) given below, have fiber-reactive properties and dye synthetic and natural materials, in particular fiber materials, containing hydroxyl and/or carboxamide groups, such as wool and in particular cellulose fiber materials, in deep shades ##STR1## in which: F is the radical of a dyestuff, such as of an azo dyestuff, heavy metal complex azo dyestuff, anthraquinone dyestuff or phthalocyanine dyestuff,R.sup.x is hydrogen or lower alkyl, which can be substituted by halogen, hydroxyl, cyano, lower alkoxy, lower alkoxycarbonyl, carboxyl, sulfamoyl, sulfo or sulfato;n is the number 1 or 2; andQ is a group of the formula ##STR2## in whichR.sup.Type: GrantFiled: January 10, 1992Date of Patent: July 13, 1993Assignee: Hoechst AktiengesellschaftInventors: Holger M. Buch, Reinhard Hahnle, Hartmut Springer
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Patent number: 5199956Abstract: Polyester textile material can be dyed from supercritical CO.sub.2 with special disperse dyes.Type: GrantFiled: August 28, 1991Date of Patent: April 6, 1993Assignee: Ciba-Geigy CorporationInventors: Wolfgang Schlenker, Dieter Werthemann, Peter Liechti, Angelo D. Casa
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Patent number: 5174792Abstract: The invention relates to mixtures of monoazo dyes, which are characterized in that they consist of one or more dyes of the general formula I ##STR1## and one or more dyes of the general formula II ##STR2## where R.sup.1 is methyl, ethyl, n-propyl or i-propyl,R.sup.2 is ethyl or n-propyl,m is 2 or 3 andn is 1 or 2, with the proviso that m+n is 4,processes for preparing same and the use thereof for dyeing and printing hydrophobic fibre materials and blends thereof with natural fibre materials.Type: GrantFiled: August 12, 1991Date of Patent: December 29, 1992Assignee: Cassella AktiengesellschaftInventors: Hirotsugu Tsumura, Ulrich Buhler, Reinhard Kuhn, Margareta Boos
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Patent number: 5071443Abstract: The dyestuff mixture contains at least one dyestuff of the formula I ##STR1## and at least one dyestuff of the formula II ##STR2## wherein X and Y denote chlorine or bromine,R.sup.1 and R.sup.5 denote methyl or ethyl,R.sup.2 and R.sup.6 denote methyl, ethyl, n-propyl or i-propyl andR.sup.3, R.sup.4, R.sup.7 and R.sup.8 denote, for example, C.sub.1 - to C.sub.11 -alkyl, in the weight ratio of I:II=(5 to 95):(95 to 5), and is, for example, outstandingly suitable for dyeing synthetic fibres.Type: GrantFiled: March 5, 1990Date of Patent: December 10, 1991Assignee: Cassella AktiengesellschaftInventors: Ulrich Buhler, Hubert Kruse, Manfred Hahnke, Margareta Boos, Reinhard Kuhn
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Patent number: 5038415Abstract: A disperse dye composition comprising (a) a pyridone monoazo compound of the formula (I), ##STR1## wherein X.sup.1 and X.sup.2 are each hydrogen, halogen, alkyl, alkoxy or others, and R.sup.1 is alkyl, alkenyl, cycloalkyl, phenyl or anilino, and (b) a pyridone monoazo compound of the formula (II). ##STR2## wherein X.sup.3 and X.sup.4 are each hydrogen, halogen, alkyl, alkoxy or others, and R.sup.2 is alkyl, alkenyl, cycloalkyl, phenyl or anilino, optionally together with (c) a quinophthalone compound of the formula (III), ##STR3## wherein Y is hydrogen or bromine, and the ring A is unsubstituted or substituted benzene or naphthalene ring, which is useful as a yellow dye component for dyeing or printing hydrophobic fiber materials with superior dye bath stability and level dyeing property.Type: GrantFiled: January 9, 1990Date of Patent: August 13, 1991Assignee: Sumitomo Chemical Company, LimitedInventors: Yasuyoshi Ueda, Junichi Sekihachi, Takashi Omura, Hideo Hattori, Kiyoharu Nakatsuka
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Patent number: 5019131Abstract: A process for redyeing partially bleached fabric or garments to yield sharply-etched multicolored designs comprises the steps of:(a) dyeing the fabric, or purchasing a commercial garment, with a background first color;(b) gathering selected areas of the dyed fabric with ligatures to restrict access of further reagents;(c) bleaching the gathered background dyed to remove the first color from the areas outside the gathered areas; and(d) redyeing the bleached areas with a second color,whereby sharply defined multicolored patterns are formed having from about 0.2 mm to about 2 mm of white gap between each color.Type: GrantFiled: July 9, 1990Date of Patent: May 28, 1991Assignee: MMOQ, Ltd.Inventor: James L. Nitsch, Jr.
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Patent number: 4992078Abstract: Improved sulfur dye dispersions are obtained by subjecting an aqueous suspension of oxidized sulfur dye particles to membrane separation. The oxidized sulfur dye is obtained by controlled aeration whereby the content of sulfides, polysulfur and inorganic salts is significantly decreased.Type: GrantFiled: February 23, 1989Date of Patent: February 12, 1991Assignee: Sandoz Ltd.Inventor: Laszlo A. Meszaros
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Patent number: 4985044Abstract: Since anthraquinonoid disperse dyes of the dark blue and navy region give only a low color strength on synthetic fibers, there was an urgent need for their coloristically advantageous substitution by high performance blue azo dyes which are suitable for being used in the carrier dyeing process.According to the invention, the systematic development of multi-component mixtures based on selected blue azo dyes from the dicyano azo series makes it possible to avoid most of the disadvantages mentioned.Type: GrantFiled: June 7, 1989Date of Patent: January 15, 1991Assignee: Hoechst AktiengesellschaftInventors: Manfred Hahnke, Reinhard Kuhn, Ulrich Buhler
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Patent number: 4968318Abstract: Mixtures of at least two different dyestuffs of the formulae ##STR1## in which the symbols have the meanings mentioned in the text represent a low-priced replacement for the known anthraquinone dyestuff Disperse Red 60.In the dyeing of mixed yarn, they are even superior with respect to sublimation fastness and cotton staining.Type: GrantFiled: December 19, 1989Date of Patent: November 6, 1990Assignee: Bayer AktiengesellschaftInventors: Dieter Wiegner, Wolf-Dieter Elsner
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Patent number: 4929249Abstract: Textile materials made of polyester, triacetate, acetate or polyamide or mixtures thereof are printed by the discharge printing or discharge resist printing technique by using as discharging agent for disperse dyes a 3-aminoreductone of the formula ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are identical or different and each is hydrogen, methyl or ethyl and R.sup.4 is linear or branched alkyl or alkenyl of from 1 to 20 carbon atoms, which may be monosubstituted or polysubstituted by hydroxyl, alkoxy of from 1 to 3 carbon atoms in the alkyl or acetoxy, or is a radical --(CH.sub.2 --CH.sub.2 --O).sub.n H where n is from 1 to 10 and which may be etherified with alkyl of from 1 to 3 carbon atoms or esterified with acetyl, or R.sup.4 together with the N-atom is the radical of an aliphatic .alpha.- or .beta.-amino acid of from 2 to 15 carbon atoms, in which case the carboxyl group may be present in neutralized form as an alkali metal, alkaline earth metal or ammonium salt or in esterified form as a C.sub.1 -c.Type: GrantFiled: May 4, 1989Date of Patent: May 29, 1990Assignee: BASF AktiengesellschaftInventors: Peter Lechtken, Peter Kutschera
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Patent number: 4874392Abstract: A Monoazo compounds of the formula ##STR1## wherein D is a diazo component radical of the 4-nitrophenyl series, thienyl-2 series, thiazolyl-2 series or 5-nitrobenzoisothiazolyl-3 series,R.sub.1 is hydrogen; C.sub.1-2 alkyl; C.sub.1-2 alkoxy; formylamino; (C.sub.1-4 alkyl)carbonylamino; (C.sub.1-4 alkyl)carbonylamino the alkyl group of which is substituted by 1 to 3 substituents independently selected from halo, C.sub.1-3 alkoxy, cyano, phenyl, phenoxy and benzyloxy; (C.sub.2-4 alkenyl)carbonylamino; halo(C.sub.2-4 alkenyl)carbonylamino; benzoylamino; benzoylamino the phenyl group of which is substituted by 1 to 3 substituents independently selected from halo, C.sub.1-4 alkyl and C.sub.1-4 alkoxy; (C.sub.1-4 alkoxy)carbonylamino; (C.sub.1-4 alkoxy)carbonylamino the alkyl moiety of which is substituted by 1 to 3 substituents independently selected from halo, C.sub.1-3 alkoxy, cyano, phenyl, phenoxy and benzyloxy; (C.sub.8-14 alkyl)carbonylamino or (C.sub.8-14 alkoxy)carbonylamino,R.sub.2 is C.sub.Type: GrantFiled: July 29, 1987Date of Patent: October 17, 1989Assignee: Sandoz Ltd.Inventor: Beat Henzi
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Patent number: 4872883Abstract: The mixture of monoazo dyestuffs which contains one or more dyestuffs of the formula I ##STR1## and one or more dyestuffs of the formula II ##STR2## wherein R.sup.1 and R.sup.2 independently of one another denote linear or branched alkyl with 1 to 6 carbon atoms and R denotes linear or branched alkyl with 1 to 3 carbon atoms, is outstandingly suitable for dyeing and printing hydrophobic materials a deep blue color.Type: GrantFiled: January 27, 1988Date of Patent: October 10, 1989Assignee: Bayer AktiengesellschaftInventors: Ulrich Buhler, Klaus Hofmann, Manfred Hahnke
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Patent number: 4851012Abstract: A mixture of monoazo dyestuffs which contains one or more dyestuffs of the formula I ##STR1## and one or more dyestuffs of the formula II ##STR2## wherein R.sup.1 and R.sup.2 independently of one another each denote linear or branched alkyl with 1 to 6 carbon atoms, R denotes linear or branched alkyl with 1 to 5 carbon atoms and Hal denotes chloro or bromo, are outstandingly suitable for dyeing and printing hydrophobic materials.Type: GrantFiled: February 1, 1988Date of Patent: July 25, 1989Assignee: Cassella AktiengesellschaftInventors: Ulrich Buhler, Hubert Kruse, Reinhard Kuhn, Margareta Boos
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Patent number: 4802889Abstract: Monoazo dyestuff of the formula ##STR1## wherein R.sup.1 is 4 alkyl having 1 to 3 carbon atoms, andR.sup.2 is methyl, ethyl or alkoxy having 1 to 4 carbon atoms hich is unsubstituted or substituted by methoxy or ethoxy is useful for dyeing and printing hydrophobic fibers a blue color.Type: GrantFiled: August 24, 1987Date of Patent: February 7, 1989Assignee: Cassella AktiengesellschaftInventors: Ulrich Bte,uml/u/ hler, Horst Tappe, Reinhard Kuhn, Albert Bode, Margareta Boss
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Patent number: 4772292Abstract: A dyestuff mixture for coloring synthetic fibers a yellow color contains as component A a dyestuff of the formula ##STR1## and as component B a different yellow disperse dyestuff species.Type: GrantFiled: November 30, 1987Date of Patent: September 20, 1988Assignee: Cassella AktiengesellschaftInventors: Manfred Hahnke, Ulrich Buhler, Albert Bode
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Patent number: 4689050Abstract: Disperse Blue 56 is an important blue dyestuff for dyeing PES fibers at the boil or under high-temperature conditions. This anthraquinonoid compound Disperse Blue 56, in addition to its advantages (high light fastness, pH/reduction insensitivity, purity of hue), has some technical disadvantages (poor leveling properties, pronounced staining of adjacent fiber, metameric red shift).By combining a plurality of blue disperse azo dyestuffs having selected structural features in the form of mixtures or mix-crystals it is possible to match the advantages of Disperse Blue 56 while substantially avoiding its disadvantages at the same time. These azo dyestuffs are based on coupling products of diazotized 2,6-substituted 4-nitroanilines with substituted N,N-dialkylanilines.Type: GrantFiled: December 20, 1985Date of Patent: August 25, 1987Assignee: Hoechst AktiengesellschaftInventors: Manfred Hahnke, Reinhard Kuhn, Reinhard Hahnle, Rudolf Schickfluss
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Patent number: 4678473Abstract: Cellulosic fibers are converted to cellulosate by immersion in an alkali metal hydroxide and then reacted with an aqueous solution of thioarylsulfonium salts to produce modified cellulosic fibers which are substantive to acid, direct, disperse, reactive and sulfur dyes. Cellulosic/synthetic and cellulosic/wool blends can also be treated to produce a fabric blend comprising modified cellulosic components that are substantive to diverse dye classes and synthetic and wool components which are substantive to a single dye class. When using a disperse dyebath of one color the entire fabric blend is dyed one color. When adding an acid, reactive or sulfur dye of a second color to the dyebath, the synthetic or wool component is dyed one color and the cellulosic component is dyed a different color.Type: GrantFiled: September 3, 1986Date of Patent: July 7, 1987Assignee: The United States of America as represented by the Secretary of AgricultureInventors: Tyrone L. Vigo, Eugene J. Blanchard
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Patent number: 4678476Abstract: Synthetic fiber materials are effectively colored by dyeing or printing with a dyestuff mixture containing at least two separate dyestuffs (I) and (II) in a weight ratio of (I):(II) of from (20 to 99):(80 to 1) wherein:(I) is at least one dyestuff of the formula ##STR1## and (II) is at least one dyestuff of the formula ##STR2## in which X and Y are the same or different and each is independently chloro and bromo:R.sup.1 and R.sup.Type: GrantFiled: September 26, 1986Date of Patent: July 7, 1987Assignee: Cassella AktiengesellschaftInventors: Horst Tappe, Hubert Kruse, Reinhard Kuhn, Albert Bode, Margareta Boos
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Patent number: 4624677Abstract: The use of a bath containing the same antimicrobial agent as that previously incorporated in a fiber permits the antimicrobial concentration in the fiber to be controlled when the fiber is processed through liquid media such as dye baths and the like.Type: GrantFiled: October 3, 1984Date of Patent: November 25, 1986Assignee: Morton Thiokol, Inc.Inventors: Lawrence J. Guilbault, Thomas C. McEntee, Judith L. Koob
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Patent number: 4615709Abstract: A cationic compound of the formula [I] below is used for improving the dyeing properties of a textile material by treating therewith the textile material before or after dyeing with an anionic dye. ##STR1## wherein A is a group of the formula [II]: ##STR2## wherein p and q are an integer of 1 to 8, n is an integer of 0 to 2, X is halogen, R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are (C1-4) alkyl, OH-- or cyano-substituent-having (C1-4) alkyl or (C1-4) alkenyl, and Q.sub.1, Q.sub.2 and Q.sub.3 are: ##STR3## in which Y is halogen.Type: GrantFiled: December 17, 1984Date of Patent: October 7, 1986Assignee: Ipposha Oil Industries Co., Ltd.Inventor: Katsuaki Nakao
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Patent number: 4582509Abstract: The mixture of monoazo dyestuffs containing at least different individual dyestuffs of the formula ##STR1## wherein R.sup.1 is alkyl of 1 to 6 carbon atoms, cyclopentyl, cyclohexyl, fluoro, chloro, bromo, alkoxy of 1 to 4 carbon atoms or trifluoromethyl,R.sup.2 is alkyl of 1 to 3 carbon atoms andR.sup.3 and R.sup.4, independently of each other, are alkyl of 1 to 4 carbon atoms,is highly suitable for dyeing and printing hydrophobic materials.Type: GrantFiled: February 4, 1985Date of Patent: April 15, 1986Assignee: Cassella AktiengesellschaftInventors: Ulrich Buhler, Manfred Hahnke, Albert Bode, Kurt Roth, Margarete Boos
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Patent number: 4571246Abstract: An improved process for production of discharge resist prints on textile material which contain hydrophobic fibers wherein at least one disperse dyestuff dischargeable to white discharge-resistant disperse dyestuff is applied, in the form of a dye liquor or printing paste, to the textile material and a discharge resist printing paste is printed on the material in the desired pattern, and the material is subsequently subjected to heat treatment at 100.degree. to 230.degree. C., wherein the improvement comprises the discharge resist printing paste containing, as the discharging agent, at least one salt of hydrogen sulphide, polysulphanes, compounds have a thiolate group of the formula --S.sup..crclbar. or a tautomerizable thio-group of the formula .dbd.S, and mixtures thereof.Type: GrantFiled: September 17, 1984Date of Patent: February 18, 1986Assignee: Cassella AktiengesellschaftInventors: Ulrich Buhler, Theo Stahl, Konrad Mix, Kurt Roth
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Patent number: 4568351Abstract: A textile finishing process in which there is employed, as a pH regulator, a compound or a mixture of compounds of formula I ##STR1## in which p is from 1 to 20,R is hydrogen, C.sub.1-3 alkyl or C.sub.1-3 alkyl substituted by hydroxyR' has independently one of the significances given for R or is --CO--R andA is --CH.sub.2 CH.sub.2 --; --CH.sub.2 --CH.sub.2 --CH.sub.Type: GrantFiled: May 17, 1984Date of Patent: February 4, 1986Assignee: Sandoz Ltd.Inventors: Jose M. Palleiro Cardona, Karl-Heinz Weible
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Patent number: 4556625Abstract: The present invention discloses a method of photolytically developing a colored image on a cellulosic material. In this method, the material is contacted with a nitrogen containing polymer in solution and a mono-sulfonyl azide compound in solution. The sample is thereafter exposed to a UV-containing light source for an amount of time sufficient to develop a color thereon.Type: GrantFiled: November 25, 1983Date of Patent: December 3, 1985Assignee: Armstrong World Industries, Inc.Inventors: Ronald S. Lenox, Anne L. Schwartz, Charles E. Hoyle
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Patent number: 4550178Abstract: There are described dye mixed crystals consisting of 1 part of the dye of the formula ##STR1## and 0.5-5 parts of the dye of the formula ##STR2## the production thereof, and their use for dyeing and printing hydrophobic fiber materials, particularly polyester materials. Blue dyeings having a good dye build-up are obtained.Type: GrantFiled: February 8, 1984Date of Patent: October 29, 1985Assignee: Ciba Geigy CorporationInventors: Urs Karlen, Roland Putzar, Rudolf Schaulin
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Patent number: 4548613Abstract: C.I. Disperse Yellow 54 and 64 are important yellow dyestuffs of the quinophthalone type used in coloring synthetic fibers, particularly polyamide, polyester, acrylic and acetate fibers at boiling temperature conditions. Yellow azo dyestuffs of the hydroxypyridone type, e.g., C.I. Disperse Yellow 114, 180 227 and 230 have found widespread application in the high-temperature dyeing of such synthetic fibers. It has now been found that improved tinctorial results on these synthetic fiber materials can be obtained by applying a dyeing composition derived from these yellow coloring means and comprising a mixture of 70-90 parts by weight of one or more dyestuffs of the C.I. 54 and 64 type with 5 to 30 parts by weight of an azo dyestuff of the hydroxypyridone type. These improved dyestuff compositions exhibit superior leveling, high tinctorial strength or color build-up, high dyebath exhaustion and deep shade dyeing over the individual components.Type: GrantFiled: May 18, 1984Date of Patent: October 22, 1985Assignee: American Hoechst CorporationInventors: Albert Bode, Thomas V. Chambers, Manfred Hahnke, Wolfgang Kretzschmar
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Patent number: 4537597Abstract: Mixtures of dyes of the formula I ##STR1## where X is chlorine or bromine, Z is hydrogen, methyl, ethyl, C.sub.1 -C.sub.4 -alkoxy or acetylamino, R is C.sub.1 -C.sub.4 -alkyl, R.sup.1 and R.sup.2 independently of one another are each allyl or methallyl or are each C.sub.1 -C.sub.6 -alkyl which is unsubstituted or substituted by hydroxyl, C.sub.1 -C.sub.4 -alkoxy or alkanoyloxy, or R.sup.1 and R.sup.2 together with the nitrogen atom are morpholino or tetra-, penta- or hexamethyleneimino, and one of the radicals R.sup.1 and R.sup.2 may furthermore be hydrogen.Type: GrantFiled: May 17, 1984Date of Patent: August 27, 1985Assignee: Basf AktiengesellschaftInventors: Udo Bergmann, Helmut Degen, Guenter Hansen, Reinhold Krallmann, Hans Weber
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Patent number: 4529406Abstract: A monoazo compound of the formula, ##STR1## wherein X is hydrogen atom or lower alkyl group; Z is hydrogen atom, halogen atom, alkyl group, acylamino group, benzoylamino group or alkylsulfonylamino group; R.sub.1, R.sub.2, R.sub.3 and R.sub.4 independently are hydrogen atom or alkyl group, provided that R.sub.1, R.sub.2, R.sub.3 and R.sub.4 cannot simultaneously be hydrogen atoms; and R.sub.5 is hydrogen atom, alkyl group, substituted alkyl group, alkenyl group, cycloalkyl group, aralkyl group or phenyl group.Type: GrantFiled: July 18, 1983Date of Patent: July 16, 1985Assignee: Research Association of Dyestuff ManufacturersInventors: Kiyoyasu Hashimoto, Akira Murata, Kiyoteru Kojima, Toshio Nakamatzu, Akira Takeshita
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Patent number: 4523926Abstract: Dyestuff mixtures of(a) an anthraquinone dyestuff of the formula ##STR1## (b) a preferably blue azo dyestuff of the formula ##STR2## wherein R.sub.1 =H or halogen,R.sub.2 =alkyl,R.sub.3 =H or alkoxy, andR.sub.4 and R.sub.5 =alkyl or alkenyl,and(c), optionally, shading dyestuffs are particularly inexpensive and are distinguished by good dyebath stability and application properties.Type: GrantFiled: August 13, 1984Date of Patent: June 18, 1985Assignee: Bayer AktiengesellschaftInventors: Horst Brandt, Gunter Gehrke, Rolf Muders, Hans-Gunter Otten, Dieter Wiegner
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Patent number: 4502867Abstract: The electrolyte sensitivity of carboxyl-containing synthetic thickeners causes problems on application together with disperse dyestuffs, the commercial finish (dispersants) of which is of anionic nature.These known disadvantages can be eliminated by adding natural thickenings which are based on polysaccharides to the synthetically based products the properties of which are considered unsatisfactory, and setting a certain, acidic pH value in the thickening mixtures. Illustratively, proceeding in this manner it was found on pad-dyeing and printing, for example, polyester fibers with conventionally finished disperse dyestuffs that the use of the auxiliary combinations according to the invention not only stabilized the thickening but also brought about an increase in depth of shade. The systematic pH adjustment of the thickening mixtures results in considerable color yield gains.Type: GrantFiled: December 29, 1983Date of Patent: March 5, 1985Assignee: Hoechst AktiengesellschaftInventor: Friedrich Reinhardt
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Patent number: 4501589Abstract: A process for dyeing or printing sized textiles comprising applying to the sized substrate a dyeing liquor or a printing paste which contains, in addition to the dyestuffs(i) a compound or a mixture of compounds selected from compounds having solubilizing, washing, emulsifying, dispersing or dye fixation accelerating properties, and(ii) a textile size or a mixture of textile sizes.Type: GrantFiled: June 10, 1983Date of Patent: February 26, 1985Assignee: Sandoz Ltd.Inventor: Christian Oschatz
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Patent number: 4464181Abstract: Dye mixtures which comprise two or more dyes of the formula ##STR1## ps where X is hydrogen, methyl or chlorine, and R is a radical of the formula OR.sup.1, OCOCH.sub.3, OCOC.sub.2 H.sub.5, R.sup.1 being hydrogen or C.sub.1 -C.sub.4 -alkyl, are very useful for dyeing cellulose esters.Type: GrantFiled: January 11, 1983Date of Patent: August 7, 1984Assignee: BASF AktiengesellschaftInventors: Helmut Degen, Johannes P. Dix, Norbert Grund, Guenter Hansen, Reinhold Krallmann
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Patent number: 4460375Abstract: A dyeing-stable modification (.beta.-modification) of the dyestuff of the formula (I) ##STR1## which has the X-ray diffraction diagram shown in FIG. 1 and having the characteristic reflections at the following glancing angles and relative intensities:______________________________________ [.theta.] 2.74 4.27 4.70 5.50 8.74 11.24 12.44 relative 100 72 40 23 27 32 26 intensity ______________________________________a process for its preparation by heating the dyestuff of said formula (I) of the dyeing-unstable .alpha.-modification, characterized by an X-ray diffraction diagram having the characteristic reflections at the following glancing angles and relative intensities ______________________________________ [.theta.] 3.55 4.15 5.35 9.45 10.41 12.71 13.89 relative 42 100 35 24 34 94 48 intensity ______________________________________at temperatures of 60.degree. to 120.degree. C. in an organic solvent, and its use for dyeing fiber materials made of cellulose esters or synthetic linear polyesters.Type: GrantFiled: November 14, 1983Date of Patent: July 17, 1984Assignee: Hoechst AktiengesellschaftInventors: Karl Sommer, Manfred Schneider, Rudolf Schickfluss
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Patent number: 4439207Abstract: Disperse dye compositions comprising(a) 20 to 55% by weight of a dye of the formula ##STR1## wherein each R.sub.1 is independently halogen, (b) 5 to 40% by weight of at least one dye of the formula ##STR2## wherein R.sub.1 is halo, and R.sub.2 is hydrogen, (C.sub.1-4 alkyl)carbonyl or benzoyl; and(c) 30 to 60% by weight of one or more dispersing agents and any other additives that may be present.Components (a), (b) and (c) forming 100% dry weight of the composition.Type: GrantFiled: August 5, 1982Date of Patent: March 27, 1984Assignee: Sandoz Ltd.Inventors: Ruedi Altermatt, Hans Jakob
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Patent number: 4427413Abstract: A dye mixture is described which contains the dye of the formula I ##STR1## and the dye of the formula II ##STR2## and in which the dye of the formula II is present in excess. Such a dye mixture, with or without further transferrable dyes, is used in transfer printing and enables the preparation of sharply contoured, aureole-free prints.Type: GrantFiled: November 23, 1982Date of Patent: January 24, 1984Assignee: Ciba-Geigy A.G.Inventor: Rolf Bauerle
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Patent number: 4421516Abstract: An improved process for preparing discharge prints on textile materials containing hydrophobic fibers wherein at least one disperse dyestuff dischargeable to white is applied to the textile material in the form of a dyeing liquor of print paste and also contacted by a pattern-applied discharge resist print paste, and then the material is heat treated at 100.degree. to 230.degree. C., wherein the improvement comprises said discharge resist print paste having, under the heat treatment conditions, a pH value of zero to 3.Type: GrantFiled: March 10, 1983Date of Patent: December 20, 1983Assignee: Cassella AktiengesellschaftInventors: Theo Stahl, Ulrich Buhler
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Patent number: 4400174Abstract: Process for printing on synthetic fibers of polyester, triacetate, acetate and polyamide as well as mixtures of these substances with disperse dyes according to the discharge or reserve discharge process, wherein a mixture of(a) 5 to 75 parts by weight of at least one reducing agent and(b) 5 to 90 parts by weight of a specified alkoxylated amine is used as the discharging agent.Type: GrantFiled: April 1, 1982Date of Patent: August 23, 1983Assignee: BASF AktiengesellschaftInventors: Adolf Blum, Norbert Grund
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Patent number: 4398914Abstract: Process for printing on synthetic fibers of polyester, triacetate, acetate and polyamide and mixtures of these fibers with dispersion dyes according to the discharge or discharge resist process, where a mixture of the following substances is used as a discharging agent:(a) 5 to 50 parts by weight of a compound having formula ##STR1## in which Me=Na, K, NH.sub.4 and alkyl substituted ammonium groups or an ammonium derivative which contains at least one radical derived from an alkali metal or ammonium salt of methane sulfinic acid,(b) 5 to 50 parts by weight of hexamethylene tetramine and(c) 0 to 20 parts by weight of anthraquinone.Type: GrantFiled: February 8, 1982Date of Patent: August 16, 1983Assignee: BASF AktiengesellschaftInventors: Adolf Blum, Peter Kutschera, Guenther Vogl
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Patent number: 4274829Abstract: Process for the continuous dyeing of synthetic fibre materials from organic solvents, wherein the material, preheated to at least 100.degree. C., is impregnated with a halogenated hydrocarbon impregnating liquor containing dyestuff or optical brightener to give a liquor absorption of more than 100%, and is then passed through a vapor zone filled with halogenated hydrocarbon at a temperature above the boiling point of the halogenated hydrocarbon in such a manner that during passage of the material through this zone the liquor becomes concentrated on the material, whereby(a) the amount of solvent on the material is not increased by condensation of halogenated hydrocarbon vapor, and(b) more than 5% of liquor is present on the material when it emerges from the vapor zone, so that the material during its passage through this vapor zone never becomes dry.Type: GrantFiled: October 4, 1978Date of Patent: June 23, 1981Assignee: Ciba-Geigy CorporationInventor: Jacques Zurbuchen
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Patent number: 4264325Abstract: 2-Phenyl-5-benzimidazol-2'-yl-furanes of the formula ##STR1## in which R.sub.1 to R.sub.6 are as defined in the specification, n is the number 0 or 1 and A.crclbar. is a colorless anion equivalent to the cation of the fluorescent brightener, their preparation as well as their use for optically brightening organic materials are disclosed.Type: GrantFiled: July 2, 1979Date of Patent: April 28, 1981Assignee: Ciba-Geigy CorporationInventors: Hans R. Meyer, Kurt Weber
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Patent number: 4255153Abstract: Textile materials containing at least 50% by weight triacetate fibers are dyed with disperse dyes in an aqueous dyebath containing an emulsifier and, as carrier, an aliphatic dicarboxylic acid diester having 6 to 24 carbon atoms, such as dibutyl maleate.Type: GrantFiled: September 27, 1979Date of Patent: March 10, 1981Assignee: Sandoz, Inc.Inventors: Eric Altherr, Ronald L. Hafer, Richard L. Pepin
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Patent number: RE33908Abstract: Synthetic fiber materials are effectively colored by dyeing or printing with a dyestuff mixture containing at least two separate dyestuffs (I) and (II) in a weight ratio of (I):(II) of from (20 to 99):(80 to 1) wherein:(I) is at least one dyestuff of the formula ##STR1## and (II) is at least one dyestuff of the formula ##STR2## in which X and Y are the same or different and each is independently chloro and bromo:R.sup.1 and R.sup.Type: GrantFiled: February 19, 1991Date of Patent: May 5, 1992Assignee: Cassella AktiengesellschaftInventors: Horst Tappe, Hubert Kruse, Reinhard Kuhn, Albert Bode, Margareta Boos