Polyolefin Patents (Class 8/DIG9)
  • Patent number: 5447539
    Abstract: A method of dyeing polypropylene fiber to create areas of different color on the fiber. A first dye solution containing a disperse dye and a dye-promoting agent is applied to substantially the entire surface of the fiber to cover the fiber with a first color. Thereafter, and while the fiber surface is still wet with the first dye solution, a second dye solution containing a disperse dye of a second color is applied only to selected discontinuous areas of the fiber. The second dye solution displaces the first dye solution in those areas of the fiber surface to which the second dye solution is applied. Then, the fiber is subjected to an elevated temperature high enough, and for a period of time sufficient, to fix the dyes in the fiber. Preferably, the second dye solution is more viscous than the first dye solution. After the dye fixation step, the fiber is scoured to remove excess dye. If desired, the second dye solution also contains a dye-promoting agent.
    Type: Grant
    Filed: February 10, 1994
    Date of Patent: September 5, 1995
    Assignee: DKE Incorporated
    Inventors: David R. Kelly, Hobert C. Sweatman, Robert R. Hixson
  • Patent number: 4906775
    Abstract: Esters of 3-tert-butyl- and 3-tert-butyl-5-alkyl-4-hydroxyphenyl (alkane) carboxylic acids with oxyethylates of polythiols are useful as stabilizers for polymers, especially for polyethylene and polypropylene.
    Type: Grant
    Filed: November 18, 1987
    Date of Patent: March 6, 1990
    Assignee: Huels Aktiengesellschaft
    Inventors: Friedrich-Wilhelm Kupper, Heinz-Werner Voges, Hans-Jurgen Haage
  • Patent number: 4859790
    Abstract: Esters of 3-tert-butyl- and 3-tert-butyl-5-alkyl-4-hydroxyphenyl(alkane) carboxylic acids of Formula I ##STR1## with oxethylates of polyhydroxyaromatics of 2-6 hydroxy groups of general Formulae II and III, containing 1-6 oxethylate units, ##STR2## with X=(CH.sub.2).sub.q OHX'=(CH.sub.2).sub.r OHwherein q, r, s can be 0 or 1, preferably 0,X"=(CH.sub.2).sub.s OHR,R', R"=H, alkyl, halogen, ##STR3## preferably 4-hydroxyphenyl, n=2 to 6 for z or z'=0, preferably 2 or 3, andn=1 to 5 for z or z'.noteq.0, preferably 2 or 3,o+p=n0.ltoreq.a, z.ltoreq.a+z.ltoreq.6-n (in Formula II)0.ltoreq.b, c, z'.ltoreq.4.ltoreq.8-n (in Formula III).are useful for the stabilization of polymers.
    Type: Grant
    Filed: November 18, 1987
    Date of Patent: August 22, 1989
    Assignee: Huels Aktiengesellschaft
    Inventors: Friedrich-Wilhelm Kupper, Heinz-Werner Voges, Werner Patzold, Richard Schaaf
  • Patent number: 4670486
    Abstract: High molecular weight organic material is effectively colored by the incorporation therein of a copper or nickel complex of the ligand compound of formula I ##STR1## wherein A is an isocyclic or heterocyclic aromatic moiety, R is H, halogen, lower alkyl or alkoxy, R.sub.1 is H, lower alkyl, phenyl or substituted phenyl, and B is H, lower alkyl, ureido or substituted ureido, guanidino, anilino, benzamido or a heterocyclic aromatic moiety.
    Type: Grant
    Filed: June 13, 1985
    Date of Patent: June 2, 1987
    Assignee: Ciba-Geigy Corporation
    Inventors: Georg Cseh, Paul Lienhard
  • Patent number: 4666452
    Abstract: A shaped polyolefin structure, such as a polyolefin fiber or a nonwoven web containing polyolefin fibers, is rendered hydrophilic by contacting the structure with a gaseous mixture of chlorine, sulfur dioxide, and oxygen or carbon monoxide or a mixture thereof, in the presence of a free radical-producing means. Such treatment results in the formation of hydrogen sulfato groups at the structure surface. Preferably, the hydrogen sulfato groups are converted to ammonium sulfato groups by subsequent treatment with ammonia or a sufficiently basic amine.
    Type: Grant
    Filed: March 12, 1986
    Date of Patent: May 19, 1987
    Assignee: Kimberly-Clark Corporation
    Inventors: Ronald S. Nohr, Vincent D. McGinniss
  • Patent number: 4624793
    Abstract: Improved lubricant compositions useful as finishes for polypropylene fibers, filaments and yarns and comprised of components which meet the requirements of 21 CFR 178.3400 as indirect food additives are provided. The finish compositions are comprised of specific ethoxylated secondary linear alcohols, specific ethoxylated linear or branched alcohol phosphate esters neutralized with potassium or sodium hydroxide and water. A hydroxylic coupling agent may also be present.
    Type: Grant
    Filed: June 20, 1984
    Date of Patent: November 25, 1986
    Assignee: National Distillers and Chemical Corporation
    Inventors: John E. Phifer, Charles R. Tucker, Roger H. Garst
  • Patent number: 4374258
    Abstract: Novel chroman derivatives ##STR1## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each H or C.sub.1 -C.sub.4 -alkyl, R.sup.5 is sec.--C.sub.3 -C.sub.8 --alkyl or tert.--C.sub.4 -C.sub.8 --alkyl, R.sup.6 is H or R.sup.5, m is 1, 2 or 3, and n is 0, 1, 2 or 3, a process for the preparation of these compounds, and their use as stabilizers for plastics.
    Type: Grant
    Filed: January 28, 1982
    Date of Patent: February 15, 1983
    Assignee: BASF Aktiengesellschaft
    Inventors: Michael Horner, Gernot Teege
  • Patent number: 4320046
    Abstract: Ethylene or propylene polymers are dyed by dispersing a small quantity of a copolymer of a C-14 or higher alpha-olefin and maleic anhydride therein and subsequently treating the composition with an aqueous solution of a basic dye stuff such as Malachite Green.
    Type: Grant
    Filed: September 15, 1980
    Date of Patent: March 16, 1982
    Assignee: Gulf Oil Corporation
    Inventor: Richard H. Havens
  • Patent number: 4248594
    Abstract: Compositions of nickel salts of 4-hydroxybenzoic acids and esters of aliphatic or aromatic carboxylic acids, which esters have boiling points of at least about 250.degree. C. are useful for stabilizing polyolefins against degradation by heat and ultraviolet radiation and for rendering polyolefins dyeable.
    Type: Grant
    Filed: February 4, 1980
    Date of Patent: February 3, 1981
    Assignee: American Cyanamid Company
    Inventors: Robert J. Tucker, Joseph A. Hoffman
  • Patent number: 4240795
    Abstract: Oxidized C.sub.20+ alpha-olefins are useful in improving the properties of textiles.
    Type: Grant
    Filed: July 9, 1979
    Date of Patent: December 23, 1980
    Assignee: Sun Chemical Corporation
    Inventor: William T. Hendrix
  • Patent number: 4238193
    Abstract: Durable excellent water absorption property and antistatic property can be given to synthetic fiber by a simple method. In the method, a polymerization initiator is absorbed in the fiber and then the fiber is applied with a water-soluble polymerizable monomer and heat treated to form a polymer thereon.
    Type: Grant
    Filed: September 19, 1978
    Date of Patent: December 9, 1980
    Assignee: Kanebo, Ltd.
    Inventors: Akio Kisaichi, Masao Oguchi, Toshihide Takeda, Akira Aikawa, Toshio Saito
  • Patent number: 4200433
    Abstract: A dyeable olefinic polymer composition comprising an olefinic polymer, and the reaction product of 50 to 90% by weight of the full nickel phenolate of o,o'-bis(p-1,1,3,3-tetramethylbutylphenol)sulfone and 50 to 10% by weight of a secondary or tertiary organic phosphite.
    Type: Grant
    Filed: September 1, 1978
    Date of Patent: April 29, 1980
    Assignee: American Cyanamid Company
    Inventor: Robert J. Tucker
  • Patent number: 4188422
    Abstract: Textiles containing blends of a proteinous animal fiber and polypropylene are rendered shrink-resistant by heating the textile to a temperature of about 165.degree.-250.degree. C. for a period of 0.1 to 60 seconds.
    Type: Grant
    Filed: September 30, 1977
    Date of Patent: February 12, 1980
    Assignee: The United States of America as represented by the Secretary of Agriculture
    Inventors: William L. Wasley, Walter W. Ingenthron, Jr.
  • Patent number: 4118185
    Abstract: It has been found that nickel-containing polyolefins can be dyed and printed in deep colors and with very good to excellent fastness properties when a thiazole-azo-(3-cyano-2,6-dihydroxypyridine) dyestuff is used.
    Type: Grant
    Filed: September 29, 1976
    Date of Patent: October 3, 1978
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Reinhard Mohr, Kurt Hohmann
  • Patent number: 4000967
    Abstract: A nonwoven mat of polyolefin fiber is contacted with a gaseous sulfur dioxide-chlorine mixture to sulfo-chlorinate the surface of the polyolefin fibers to a relatively high sulfur content and then preferably treated with an amine, either after compacting the mat or before compacting the mat to form a structure suitable as a battery separator. The mat can be used for other structures besides battery separators. And it can be separated into individually wettable staple fibers before compaction, i.e. individual separate fibers which are wettable.
    Type: Grant
    Filed: July 26, 1973
    Date of Patent: January 4, 1977
    Assignee: Exxon Research and Engineering Company
    Inventors: Burnett H. Johnson, Terrence Huff
  • Patent number: 3971627
    Abstract: Disclosed are epoxy-azido compounds of the formula ##EQU1## WHERE R is a polyvalent organic radical, R' is a hydrogen, alkyl, cycloalkyl, aryl, or aralkyl radical, A is ##EQU2## and n and m are integers from 1 to 100. Also disclosed is the use of said epoxy-azido compounds in modifying polymers, cross-linking polymers, and adhering polymers to certain substrates, e.g. glass and other polymers.
    Type: Grant
    Filed: June 24, 1975
    Date of Patent: July 27, 1976
    Assignee: Hercules Incorporated
    Inventor: David S. Breslow