Polyolefin Patents (Class 8/DIG9)
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Patent number: 5447539Abstract: A method of dyeing polypropylene fiber to create areas of different color on the fiber. A first dye solution containing a disperse dye and a dye-promoting agent is applied to substantially the entire surface of the fiber to cover the fiber with a first color. Thereafter, and while the fiber surface is still wet with the first dye solution, a second dye solution containing a disperse dye of a second color is applied only to selected discontinuous areas of the fiber. The second dye solution displaces the first dye solution in those areas of the fiber surface to which the second dye solution is applied. Then, the fiber is subjected to an elevated temperature high enough, and for a period of time sufficient, to fix the dyes in the fiber. Preferably, the second dye solution is more viscous than the first dye solution. After the dye fixation step, the fiber is scoured to remove excess dye. If desired, the second dye solution also contains a dye-promoting agent.Type: GrantFiled: February 10, 1994Date of Patent: September 5, 1995Assignee: DKE IncorporatedInventors: David R. Kelly, Hobert C. Sweatman, Robert R. Hixson
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Patent number: 4906775Abstract: Esters of 3-tert-butyl- and 3-tert-butyl-5-alkyl-4-hydroxyphenyl (alkane) carboxylic acids with oxyethylates of polythiols are useful as stabilizers for polymers, especially for polyethylene and polypropylene.Type: GrantFiled: November 18, 1987Date of Patent: March 6, 1990Assignee: Huels AktiengesellschaftInventors: Friedrich-Wilhelm Kupper, Heinz-Werner Voges, Hans-Jurgen Haage
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Patent number: 4859790Abstract: Esters of 3-tert-butyl- and 3-tert-butyl-5-alkyl-4-hydroxyphenyl(alkane) carboxylic acids of Formula I ##STR1## with oxethylates of polyhydroxyaromatics of 2-6 hydroxy groups of general Formulae II and III, containing 1-6 oxethylate units, ##STR2## with X=(CH.sub.2).sub.q OHX'=(CH.sub.2).sub.r OHwherein q, r, s can be 0 or 1, preferably 0,X"=(CH.sub.2).sub.s OHR,R', R"=H, alkyl, halogen, ##STR3## preferably 4-hydroxyphenyl, n=2 to 6 for z or z'=0, preferably 2 or 3, andn=1 to 5 for z or z'.noteq.0, preferably 2 or 3,o+p=n0.ltoreq.a, z.ltoreq.a+z.ltoreq.6-n (in Formula II)0.ltoreq.b, c, z'.ltoreq.4.ltoreq.8-n (in Formula III).are useful for the stabilization of polymers.Type: GrantFiled: November 18, 1987Date of Patent: August 22, 1989Assignee: Huels AktiengesellschaftInventors: Friedrich-Wilhelm Kupper, Heinz-Werner Voges, Werner Patzold, Richard Schaaf
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Patent number: 4670486Abstract: High molecular weight organic material is effectively colored by the incorporation therein of a copper or nickel complex of the ligand compound of formula I ##STR1## wherein A is an isocyclic or heterocyclic aromatic moiety, R is H, halogen, lower alkyl or alkoxy, R.sub.1 is H, lower alkyl, phenyl or substituted phenyl, and B is H, lower alkyl, ureido or substituted ureido, guanidino, anilino, benzamido or a heterocyclic aromatic moiety.Type: GrantFiled: June 13, 1985Date of Patent: June 2, 1987Assignee: Ciba-Geigy CorporationInventors: Georg Cseh, Paul Lienhard
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Patent number: 4666452Abstract: A shaped polyolefin structure, such as a polyolefin fiber or a nonwoven web containing polyolefin fibers, is rendered hydrophilic by contacting the structure with a gaseous mixture of chlorine, sulfur dioxide, and oxygen or carbon monoxide or a mixture thereof, in the presence of a free radical-producing means. Such treatment results in the formation of hydrogen sulfato groups at the structure surface. Preferably, the hydrogen sulfato groups are converted to ammonium sulfato groups by subsequent treatment with ammonia or a sufficiently basic amine.Type: GrantFiled: March 12, 1986Date of Patent: May 19, 1987Assignee: Kimberly-Clark CorporationInventors: Ronald S. Nohr, Vincent D. McGinniss
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Patent number: 4624793Abstract: Improved lubricant compositions useful as finishes for polypropylene fibers, filaments and yarns and comprised of components which meet the requirements of 21 CFR 178.3400 as indirect food additives are provided. The finish compositions are comprised of specific ethoxylated secondary linear alcohols, specific ethoxylated linear or branched alcohol phosphate esters neutralized with potassium or sodium hydroxide and water. A hydroxylic coupling agent may also be present.Type: GrantFiled: June 20, 1984Date of Patent: November 25, 1986Assignee: National Distillers and Chemical CorporationInventors: John E. Phifer, Charles R. Tucker, Roger H. Garst
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Patent number: 4374258Abstract: Novel chroman derivatives ##STR1## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each H or C.sub.1 -C.sub.4 -alkyl, R.sup.5 is sec.--C.sub.3 -C.sub.8 --alkyl or tert.--C.sub.4 -C.sub.8 --alkyl, R.sup.6 is H or R.sup.5, m is 1, 2 or 3, and n is 0, 1, 2 or 3, a process for the preparation of these compounds, and their use as stabilizers for plastics.Type: GrantFiled: January 28, 1982Date of Patent: February 15, 1983Assignee: BASF AktiengesellschaftInventors: Michael Horner, Gernot Teege
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Patent number: 4320046Abstract: Ethylene or propylene polymers are dyed by dispersing a small quantity of a copolymer of a C-14 or higher alpha-olefin and maleic anhydride therein and subsequently treating the composition with an aqueous solution of a basic dye stuff such as Malachite Green.Type: GrantFiled: September 15, 1980Date of Patent: March 16, 1982Assignee: Gulf Oil CorporationInventor: Richard H. Havens
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Patent number: 4248594Abstract: Compositions of nickel salts of 4-hydroxybenzoic acids and esters of aliphatic or aromatic carboxylic acids, which esters have boiling points of at least about 250.degree. C. are useful for stabilizing polyolefins against degradation by heat and ultraviolet radiation and for rendering polyolefins dyeable.Type: GrantFiled: February 4, 1980Date of Patent: February 3, 1981Assignee: American Cyanamid CompanyInventors: Robert J. Tucker, Joseph A. Hoffman
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Patent number: 4240795Abstract: Oxidized C.sub.20+ alpha-olefins are useful in improving the properties of textiles.Type: GrantFiled: July 9, 1979Date of Patent: December 23, 1980Assignee: Sun Chemical CorporationInventor: William T. Hendrix
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Patent number: 4238193Abstract: Durable excellent water absorption property and antistatic property can be given to synthetic fiber by a simple method. In the method, a polymerization initiator is absorbed in the fiber and then the fiber is applied with a water-soluble polymerizable monomer and heat treated to form a polymer thereon.Type: GrantFiled: September 19, 1978Date of Patent: December 9, 1980Assignee: Kanebo, Ltd.Inventors: Akio Kisaichi, Masao Oguchi, Toshihide Takeda, Akira Aikawa, Toshio Saito
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Patent number: 4200433Abstract: A dyeable olefinic polymer composition comprising an olefinic polymer, and the reaction product of 50 to 90% by weight of the full nickel phenolate of o,o'-bis(p-1,1,3,3-tetramethylbutylphenol)sulfone and 50 to 10% by weight of a secondary or tertiary organic phosphite.Type: GrantFiled: September 1, 1978Date of Patent: April 29, 1980Assignee: American Cyanamid CompanyInventor: Robert J. Tucker
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Patent number: 4188422Abstract: Textiles containing blends of a proteinous animal fiber and polypropylene are rendered shrink-resistant by heating the textile to a temperature of about 165.degree.-250.degree. C. for a period of 0.1 to 60 seconds.Type: GrantFiled: September 30, 1977Date of Patent: February 12, 1980Assignee: The United States of America as represented by the Secretary of AgricultureInventors: William L. Wasley, Walter W. Ingenthron, Jr.
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Patent number: 4118185Abstract: It has been found that nickel-containing polyolefins can be dyed and printed in deep colors and with very good to excellent fastness properties when a thiazole-azo-(3-cyano-2,6-dihydroxypyridine) dyestuff is used.Type: GrantFiled: September 29, 1976Date of Patent: October 3, 1978Assignee: Hoechst AktiengesellschaftInventors: Reinhard Mohr, Kurt Hohmann
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Patent number: 4000967Abstract: A nonwoven mat of polyolefin fiber is contacted with a gaseous sulfur dioxide-chlorine mixture to sulfo-chlorinate the surface of the polyolefin fibers to a relatively high sulfur content and then preferably treated with an amine, either after compacting the mat or before compacting the mat to form a structure suitable as a battery separator. The mat can be used for other structures besides battery separators. And it can be separated into individually wettable staple fibers before compaction, i.e. individual separate fibers which are wettable.Type: GrantFiled: July 26, 1973Date of Patent: January 4, 1977Assignee: Exxon Research and Engineering CompanyInventors: Burnett H. Johnson, Terrence Huff
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Patent number: 3971627Abstract: Disclosed are epoxy-azido compounds of the formula ##EQU1## WHERE R is a polyvalent organic radical, R' is a hydrogen, alkyl, cycloalkyl, aryl, or aralkyl radical, A is ##EQU2## and n and m are integers from 1 to 100. Also disclosed is the use of said epoxy-azido compounds in modifying polymers, cross-linking polymers, and adhering polymers to certain substrates, e.g. glass and other polymers.Type: GrantFiled: June 24, 1975Date of Patent: July 27, 1976Assignee: Hercules IncorporatedInventor: David S. Breslow