And Heating Patents (Class 95/165)
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Patent number: 8920544Abstract: A method for removing acid gases from a fluid flow using an absorbent including an aqueous solution with at least two different amines. An amine in a proportion of greater than 50 wt. % of the total amine amount in the aqueous solution is the first amine component in the aqueous solution, and a sterically hindered amine in a proportion of less than 50 wt. % is the second amine component in the aqueous solution. The fluid flow is brought into contact with the absorbent at a partial pressure of <200 mbar.Type: GrantFiled: December 21, 2010Date of Patent: December 30, 2014Assignee: ThyssenKrupp Uhde GmbHInventors: Johannes Menzel, Olaf Von Morstein
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Patent number: 8864879Abstract: Disclosed herein is a method comprising contacting a residual flue gas stream with a lean solution stream in an appendix stripper; where the residual flue gas stream comprises nitrogen, oxygen and moisture; and where the lean solution stream comprises ammonium, ammonium carbonate, ammonium bicarbonate and ammonium sulfate; forming a vapor phase that comprises ammonia vapor, water vapor, carbon dioxide and nitrogen; forming a liquid phase that comprises water, ammonium sulfate and ammonia; discharging the vapor phase to a capture system; and discharging the liquid phase to a direct contact cooler.Type: GrantFiled: March 30, 2012Date of Patent: October 21, 2014Inventors: Jalal Askander, Fred Kozak
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Patent number: 8840707Abstract: A gas condensate production plant comprises a plurality of separation units in which C2 and/or C3 lighter components are stripped from the separator feeds using compressed heated stripping vapor produced from the feed in respective downstream separation units. Contemplated plants substantially reduce heating and cooling duties by using the waste heat from the compressor discharges in the separation process. Furthermore, the multi-stage fractionation according to the inventive subject matter provides improved gas condensate recovery at reduced energy costs.Type: GrantFiled: June 22, 2005Date of Patent: September 23, 2014Assignee: Fluor Technologies CorporationInventor: John Mak
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Patent number: 8834609Abstract: A method for separating carbon dioxide from a flue gas of a fossil fuel-operated power plant is provided. In the method, a fossil fuel is initially burned in a combustion process, wherein a hot waste gas containing carbon dioxide is produced. In a next process step, waste gas containing carbon dioxide is brought into contact with an absorption medium in an absorption process, wherein carbon dioxide is absorbed by the absorption medium, thus forming a charged absorption medium. Next, gaseous carbon dioxide is thermally expelled from the charged absorption medium in a desorption process. For this purpose, a vapor is supplied to the desorption process, the vapor is injected into the charged absorption medium, wherein the condensation heat released by the condensation of the vapor is transferred to the charged absorption medium, and the partial pressure of the carbon dioxide is simultaneously reduced in the desorption unit.Type: GrantFiled: May 14, 2009Date of Patent: September 16, 2014Assignee: Siemens AktiengesellschaftInventors: Ralph Joh, Rüdiger Schneider, Henning Schramm
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Patent number: 8690992Abstract: Processes for operating an ammonia stripper at a low pressure in a gas purification system include providing a first side-draw stream from the ammonia stripper; heating the first side-draw stream with a second side-draw stream from a regenerator; providing a stripper offgas stream from the ammonia stripper to a stripper overhead condenser; and utilizing the stripper offgas stream as a heat source for a regenerating system fluidly coupled to the stripper overhead condenser. Also disclosed are systems for implementing the processes.Type: GrantFiled: March 19, 2013Date of Patent: April 8, 2014Assignee: ALSTOM Technology LtdInventors: Sanjay Kumar Dube, Daniel Nicolaus Secundus Mattstedt, Joseph P. Naumovitz
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Patent number: 8673062Abstract: A method of removing acid gases from raw gas is disclosed in which the raw gas is supplied to an absorption column where it is contacted with a physical absorption agent, having a boiling point lower than 100° C. at atmospheric pressure, under elevated operating pressure to load, the physical absorption agent with acid gases and usable gases and then the physical absorption agent loaded with acid gases and usable gases is driven from the absorption column at its sump while drawing off at the head of the absorption column a purified top gas containing up to a few ppm of acid-gas components. Following the absorption, the physical absorption agent undergoes stripping to remove usable gases, and regeneration to remove the acid gases as well as to provide a regenerated physical absorbent which may be used to treat additional raw gas.Type: GrantFiled: November 4, 2009Date of Patent: March 18, 2014Assignee: UHDE GmbHInventor: Johannes Menzel
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Patent number: 8562719Abstract: A gas purification system including a hydrogen sulfide (H2S) absorber, a carbon dioxide (CO2) absorber, a flash tank, and a H2S concentrator. The gas purification system may also include a gas path though the H2S absorber prior to the CO2 absorber, a first solvent path sequentially through the CO2 absorber, the H2S absorber, and the H2S concentrator, and a second solvent path sequentially through the CO2 absorber, the flash tank, and the H2S concentrator, wherein the first and second solvent paths flow a common solvent.Type: GrantFiled: July 6, 2010Date of Patent: October 22, 2013Assignee: General Electric CompanyInventors: Anindra Mazumdar, Judith Pauline Oppenheim
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Publication number: 20130255495Abstract: Disclosed herein is a method comprising contacting a residual flue gas stream with a lean solution stream in an appendix stripper; where the residual flue gas stream comprises nitrogen, oxygen and moisture; and where the lean solution stream comprises ammonium, ammonium carbonate, ammonium bicarbonate and ammonium sulfate; forming a vapor phase that comprises ammonia vapor, water vapor, carbon dioxide and nitrogen; forming a liquid phase that comprises water, ammonium sulfate and ammonia; discharging the vapor phase to a capture system; and discharging the liquid phase to a direct contact cooler.Type: ApplicationFiled: March 30, 2012Publication date: October 3, 2013Applicant: ALSTOM TECHNOLOGY LTD.Inventors: Jalal Askander, Fred Kozak
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Publication number: 20130247758Abstract: CO2 is absorbed from a gas mixture by contacting the gas mixture with an absorption medium which comprises at least water as solvent and at least one amine of formula (I) where R1 is an aliphatic radical, having 2 to 6 carbon atoms and at least one amino group, and R2 is hydrogen, a C1-4 alkyl radical or a radical R1.Type: ApplicationFiled: November 10, 2011Publication date: September 26, 2013Applicant: Evonik Degussa GmbHInventors: Matthias Seiler, Rolf Schreider, Jörn Rolker, Daniel Dembkowski, Manfred Neumann, Daniel Witthaut, Michael Keup, Volker Brehme, Muhammad Irfan
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Patent number: 8512445Abstract: The present invention relates to systems and processes for reducing the amount of carbon dioxide in a carbon dioxide-containing gas. In particular, the carbon dioxide-containing gas is contacted with a carbonate-containing solution. At least a portion of carbon dioxide in the carbon dioxide-containing gas is absorbed in the carbonate-containing solution to produce a carbon dioxide-, carbonate-containing solution. A heat recovery mechanism is employed to recover heat from the carbon dioxide-, bicarbonate-, carbonate-containing solution exiting the chamber to maintain the temperature of the chamber within a range of from about 50° C. to about 90° C.Type: GrantFiled: June 23, 2010Date of Patent: August 20, 2013Inventors: Shiaoguo Chen, Zijiang Pan
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Patent number: 8470077Abstract: Processes for operating an ammonia stripper at a low pressure in a gas purification system include providing a first side-draw stream from the ammonia stripper; heating the first side-draw stream with a second side-draw stream from a regenerator; providing a stripper offgas stream from the ammonia stripper to a stripper overhead condenser; and utilizing the stripper offgas stream as a heat source for a regenerating system fluidly coupled to the stripper overhead condenser. Also disclosed are systems for implementing the processes.Type: GrantFiled: November 17, 2011Date of Patent: June 25, 2013Assignee: ALSTOM Technology LtdInventors: Sanjay Kumar Dube, Daniel Nicolaus Secundus Mattstedt, Joseph P. Naumovitz
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Patent number: 8425655Abstract: The present invention provides a gas pressurized separation system to strip a product gas from a liquid stream and yield a high pressure gaseous effluent containing the product gas. The system comprises a gas pressurized stripping apparatus, such as a column, with at least one first inlet allowing flow of one or more liquid streams in a first direction and at least one second inlet allowing flow of one or more high pressure gas streams in a second direction, to strip the product gas into the high pressure gas stream and yield through at least one outlet a high pressure gaseous effluent containing the product gas; and two or more heat supplying apparatuses provided at different locations along the column. Processes for separating a product gas from a gaseous mixture to yield a high pressure gaseous effluent containing the product gas, utilize the gas pressurized separation system described above.Type: GrantFiled: July 9, 2010Date of Patent: April 23, 2013Assignee: Carbon Capture Scientific, LLCInventors: Shiaoguo Chen, Zijiang Pan
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Patent number: 8398748Abstract: Contemplated configurations and methods include a solvent regenerator (58) that has an upper (93) and a lower stripping section (94). Cooled rich solve is used as reflux while heated rich solvent (11) is used as a source of stripping agent in the upper section (91). A reboiler (62) in the lower section provides further stripping agent, hi especially preferred configurations, a portion of lean solved from the regenerator (58) is further stripped in a separate or integrated regenerator (62) to form an ultra-lean solvent. Both lean and ultra-lean solvents are preferably used in a two-stage absorber (52) to thereby from the rich solvent and an offgas that is very low in acid gas.Type: GrantFiled: April 18, 2006Date of Patent: March 19, 2013Assignee: Fluor Technologies CorporationInventor: John Mak
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Publication number: 20120240761Abstract: To include a boiler 11 that burns fuel F, an air heater 13 that recovers heat of flue gas 18 from the boiler 11, a first precipitator 14 that reduces dust in the flue gas 18 after heat recovery, a desulfurizer 15 that reduces sulfur oxides in the flue gas 18 after dust reduction by an absorbent, a dewaterer 32 that reduces gypsum 31 from desulfurization discharged water 30 discharged from the desulfurizer 15, a spray drying device 34 including an atomizer that atomizes a dewatering filtration fluid 33 discharged from the dewaterer 32, and a flue-gas introducing line L11 that introduces a part of the flue gas 18 into the spray drying device 34.Type: ApplicationFiled: May 31, 2011Publication date: September 27, 2012Applicant: MITSUBISHI HEAVY INDUSTRIES, LTD.Inventors: Nobuyuki Ukai, Seiji Kagawa, Tatsuto Nagayasu, Naoyuki Kamiyama, Toshihiro Fukuda
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Publication number: 20120060689Abstract: A method for reducing energy requirements of a CO2 capture system comprises: contacting a flue gas stream with a CO2 lean absorbent stream in an absorber, thereby removing CO2 from the flue gas and providing a CO2 rich absorbent stream; heating a first portion of the CO2 rich absorbent stream using heat from the CO2 lean absorbent stream, and providing the heated first portion of the CO2 rich absorbent stream to a regenerator; providing a second portion of the CO2 rich absorbent stream to the regenerator, wherein the heated first portion is hotter than the second portion and the heated first portion is provided to the regenerator at a lower elevation in the regenerator relative to that of the second portion.Type: ApplicationFiled: August 2, 2011Publication date: March 15, 2012Applicant: ALSTOM TECHNOLOGY LTDInventors: Joseph P. Naumovitz, Michael Koch
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Publication number: 20120006197Abstract: The present invention relates to a method for recovery of carbon dioxide from a gas (G3), in particular the present invention relates to a method for recovery of carbon dioxide using a process gas (G1) heated reboiler (A1) for carbon dioxide removal in a stripper (A3).Type: ApplicationFiled: February 1, 2010Publication date: January 12, 2012Applicant: UNION ENGINEERING A/SInventor: Rasmus Find
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Publication number: 20110192191Abstract: A process for at least partly regenerating a first absorption solvent stream, at high pressure, and loaded with a dissolved gaseous component X; comprising the following steps: contacting a feed gas stream with a lean second absorption solvent stream thereby producing a rich second solvent stream and a stripping gas stream that has a lower concentration of X than said feed gas stream; heating at least part of said rich second solvent stream by up to 100° C. before or during contacting it with a part of said stripping gas stream to produce a regenerated second solvent stream; and regenerating the loaded first solvent stream by contacting this stream with a further part of said stripping gas stream to yield a regenerated first solvent stream.Type: ApplicationFiled: October 13, 2009Publication date: August 11, 2011Inventors: Cyril Timminns, Keith R. Tart
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Patent number: 7972423Abstract: An apparatus for stripping and strengthening and subsequent condensing and final strengthening of an easily vaporizable component of a preferably aqueous mixture permits the heat necessary for stripping and strengthening to be transferred through a common heat transmission body (3), where the heat is derived from condensing the vapor generated by stripping and strengthening, which vapor via compression using a heat pump (26) has obtained the increase in boiling point necessary for condensation. The apparatus is comprised of two sections, namely a stripping and strengthening section or first section (1) and a condensing and final strengthening section or second section (2), said sections being joined around a common heat transmission body (3) forming a dividing wall, each section being further defined by a horizontal partially cylindrical housing (13) and an end wall at each end.Type: GrantFiled: April 28, 2006Date of Patent: July 5, 2011Assignee: Holm Christensen Biosystemer APSInventor: Erik Jensen
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Patent number: 7901488Abstract: Carbon dioxide and other acid gases are removed from gaseous streams using aqueous absorption and stripping processes. By replacing the conventional stripper used to regenerate the aqueous solvent and capture the acid gas with a matrix stripping configuration, less energy is consumed. The matrix stripping configuration uses two or more reboiled strippers at different pressures. The rich feed from the absorption equipment is split among the strippers, and partially regenerated solvent from the highest pressure stripper flows to the middle of sequentially lower pressure strippers in a “matrix” pattern. By selecting certain parameters of the matrix stripping configuration such that the total energy required by the strippers to achieve a desired percentage of acid gas removal from the gaseous stream is minimized, further energy savings can be realized.Type: GrantFiled: October 2, 2007Date of Patent: March 8, 2011Assignee: Board of Regents, The University of Texas SystemInventors: Gary T. Rochelle, Babatunde A. Oyenekan
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Publication number: 20110023714Abstract: The invention relates to a process for scrubbing medium regeneration in a physical gas scrubbing, in which predominantly substances of a first type are separated from a laden scrubbing medium (2, 17) by stripping (cold stripping) in a stripping column (enrichment column (A)) and predominantly substances of a second type are separated from a laden scrubbing medium (2, 17) by subsequent thermal regeneration in a thermal regeneration column (H), and to an apparatus for carrying out the process. The laden scrubbing medium (6) is, after the cold stripping, withdrawn from the enrichment column (A), preheated (E1), expanded (a) and subsequently subjected to a thermal desorption in a device for carrying out a thermal desorption (thermal desorption device (W)), in which the content of substances of the first type in the laden scrubbing medium is further reduced.Type: ApplicationFiled: November 27, 2007Publication date: February 3, 2011Inventors: Horst Weiss, Ulvi Kerestecioglu, Ulrich Prussner
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Publication number: 20100192770Abstract: An absorption medium for removing acid gases from a fluid stream comprises an aqueous solution of A) at least one cyclic amine compound having solely tertiary amine groups and/or sterically hindered secondary amine groups and B) at least one cyclic amine compound having at least one sterically unhindered secondary amine group. The absorption medium comprises, e.g., an aqueous solution of A) 1-hydroxyethylpiperidine and/or triethylenediamine and B) piperazine. The absorption medium is particularly suitable for separating off carbon dioxide from flue gases and satisfies the following criteria: (i) sufficient capacity at low CO2 partial pressures; (ii) sufficiently rapid absorption rate at low CO2 partial pressures; (iii) stability toward oxygen; (iv) low vapor pressure for reducing solvent losses; and (v) low energy requirement for regeneration of the absorption medium.Type: ApplicationFiled: February 2, 2010Publication date: August 5, 2010Applicant: BASF SEInventors: Hugo Rafael Garcia Andarcia, Ute Lichtfers, Georg Sieder, Oliver Spuhl, Steven Brughmans
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Publication number: 20100186590Abstract: An absorption medium for removing acid gases from a fluid stream comprises an aqueous solution of a) of at least one metal salt of an aminocarboxylic acid, and b) of at least one acid promoter, wherein the molar ratio of b) to a) is in the range from 0.0005 to 1.0. The acid promoter is selected from mineral acids, carboxylic acids, sulfonic acids, organic phosphonic acids and partial esters thereof. The absorption medium, compared with absorption media based on amino acid salts, has a reduced regeneration energy requirement without significantly reducing the absorption capacity of the solution for acid gases. In a process for removing acid gases from the fluid stream, the fluid stream is brought into contact with the absorption medium.Type: ApplicationFiled: January 28, 2010Publication date: July 29, 2010Applicant: BASF SEInventors: Gerald Vorberg, Torsten Katz, Georg Sieder, Christian Riemann, Rupert Wagner, Ute Lichtfers, Erika Dengler
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Patent number: 7083662Abstract: Method of making a product gas mixture comprising providing a first gas mixture, contacting the first gas mixture with a lean absorber liquid at a first pressure and absorbing a portion of the first gas mixture in the lean absorber liquid to provide a rich absorber liquid and a non-absorbed residual gas, pressurizing the rich absorber liquid provide a pressurized rich absorber liquid, stripping the pressurized rich absorber liquid with a stripping gas at a second pressure greater than the first pressure to provide a pressurized lean absorber liquid and the product gas mixture, and reducing the pressure of the pressurized lean absorber liquid to provide the lean absorber liquid at the first pressure.Type: GrantFiled: December 18, 2003Date of Patent: August 1, 2006Assignee: Air Products and Chemicals, Inc.Inventors: Jianguo Xu, Xiang-Dong Peng, Harold Henry Gunardson
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Patent number: 6461413Abstract: In a process using a hydrophilic liquid desiccant, for dehydrating a gas containing water with regeneration of the steps of: (a) absorbing water by contact between the moist gas and regenerated liquid desiccant from step c), producing a dry gaseous effluent and a stream of liquid desiccant charged with water and absorbed gases; (b) regenerating the liquid desiccant charged with water in a regeneration zone constituting a reboiling zone and a distillation zone, the charged liquid desiccant being sent to said distillation zone, from which a vapor containing water leaves overhead and from which liquid desiccant still containing water leaves from the bottom in the reboiling zone; (c) passing the liquid desiccant from the reboiling zone of step b) and still containing water to an absorption zone, in which the water in the desiccant is vaporized and the water vapor is absorbed by a fraction of regenerated or non regenerated desiccant, passing the resultant desiccant which has absorbed water vapor to the reboiling zType: GrantFiled: November 27, 2000Date of Patent: October 8, 2002Assignee: ProsernatInventors: Benoit Landreau, Jean-Claude Amande
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Patent number: 6238461Abstract: A natural gas dehydrator wherein a portion of the wet glycol from the absorber is pumped under pressure as circulating wet glycol which is used as a coolant for effluents removed from a reboiler and a power source for an educator to form a vacuum in a first chamber of a liquid water removal separator apparatus. The cooled effluents, comprising liquid water, liquid hydrocarbons and uncondensed vapors, move in to the first chamber wherein the liquid water is separated therefrom. The liquid hydrocarbons and the uncondensed vapors are removed from the first chamber and move into the eductor wherein they are combined into the circulating wet glycol. The separated liquid water is transferred to a second chamber of the liquid water removal separator apparatus and then removed therefrom. Also, gases from gas emitting level control apparatus in the natural gas dehydrator are collected and fed into the first chamber.Type: GrantFiled: June 15, 1999Date of Patent: May 29, 2001Inventor: Rodney T. Heath
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Patent number: 6174348Abstract: A system for regenerating chemical solvent loaded with acid gas with improved energy efficiency wherein the chemical solvent is partially flash vaporized, heated, and passed in countercurrent mass transfer contact with nitrogen gas.Type: GrantFiled: August 17, 1999Date of Patent: January 16, 2001Assignee: Praxair Technology, Inc.Inventors: M. Mushtaq Ahmed, Minish Mahendra Shah, Raymond Francis Drnevich
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Patent number: 5545330Abstract: A water treatment system and process separates contaminants from water by flotation, by forming a removable floating scum of impurities utilizing a bubbling process, by filtering out suspended solids, by stripping dissolved impurities from the water with air, by oxidizing organic compounds, by adsorbing organic compounds, and finally, by disinfecting. Utilization of the disclosed process and system will transform contaminated water into an environmentally suitable state.Type: GrantFiled: December 1, 1994Date of Patent: August 13, 1996Assignee: Amerada Hess CorporationInventor: Robert T. Ehrlich
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Patent number: RE39944Abstract: A natural gas dehydrator wherein a portion of the wet glycol from the absorber is pumped under pressure as circulating wet glycol which is used as a coolant for effluents removed from a reboiler and a power source for an educator to form a vacuum in a first chamber of a liquid water removal separator apparatus. The cooled effluents, comprising liquid water, liquid hydrocarbons and uncondensed vapors, move in to the first chamber wherein the liquid water is separated therefrom. The liquid hydrocarbons and the uncondensed vapors are removed from the first chamber and move into the eductor wherein they are combined into the circulating wet glycol. The separated liquid water is transferred to a second chamber of the liquid water removal separator apparatus and then removed therefrom. Also, gases from gas emitting level control apparatus in the natural gas dehydrator are collected and fed into the first chamber.Type: GrantFiled: May 29, 2003Date of Patent: December 25, 2007Inventor: Rodney T. Heath