Carbon Dioxide Removed Patents (Class 95/183)
  • Patent number: 8535428
    Abstract: To include an absorber (1006) that brings CO2 absorbent that absorbs CO2 contained in flue gas (1002) into contact with the flue gas to remove CO2 from the flue gas, a regenerator (1008) that strips CO2 from CO2 absorbent (rich solution), which is fed from the absorber through a first feed line L1 and has absorbed CO2, to regenerate CO2 absorbent, thereby acquiring regenerated CO2 absorbent (lean solution) (1009), falling film reboilers (1101-1 and 1101-2) that draw off CO2 absorbent (amine solution) (1033) from near the bottom of the regenerator and reheats regenerated CO2 absorbent via steam (1031), a first liquid-vapor separator (1103) that separates the CO2 absorbent reheated by the falling film reboilers into regenerated CO2 absorbent in which CO2 has been removed and vapor containing CO2, and a second feed line L2 for supplying the separated regenerated CO2 absorbent to the absorber.
    Type: Grant
    Filed: January 26, 2009
    Date of Patent: September 17, 2013
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Katsufumi Inoue, Takashi Kamijo, Tsuyoshi Oishi, Takahito Yonekawa, Hiroshi Tanaka
  • Patent number: 8535419
    Abstract: A modular amine plant having a front-end module and a back-end module in fluid communication with each other. The front-end module having pre-fabricated connections for the association of various equipment including: a filter, an absorption tower, and a flash tank. The back-end module having pre-fabricated connections for the association of other various equipment including: a heat exchanger, a distillation tower, and a reboiler. The modular amine plant capable of being installed at a site in less than about 5 days. The modular amine plant further having moment forces sufficient to withstand wind speeds of about 100 miles per hour.
    Type: Grant
    Filed: April 1, 2010
    Date of Patent: September 17, 2013
    Assignee: Zephyr Gas Services LLC
    Inventors: Glen Wind, John Kenton Thompson, Lance Perryman
  • Patent number: 8523979
    Abstract: A process for removing acid gases from a fluid stream in which a) the fluid stream is treated with an absorption liquid which comprises at least one amine, a stripping aid, and water, wherein the stripping aid is selected from water-miscible liquids, the boiling temperature of which at atmospheric pressure is lower than that of water, b) the treated fluid stream is treated with a liquid aqueous phase in order to convert entrained stripping aid at least in part to the aqueous phase, c) the loaded aqueous phase is heated in order to expel the stripping aid at least in part, and d) the regenerated aqueous phase is cooled and at least in part recycled to step b). The stripping aid promotes the regeneration of the absorbent by stripping. Emissions of the stripping aid via the treated fluid stream are avoided by the treated fluid stream being scrubbed with a liquid aqueous phase.
    Type: Grant
    Filed: June 21, 2010
    Date of Patent: September 3, 2013
    Assignee: BASF SE
    Inventors: Hugo Rafael Garcia Andarcia, Ralf Notz, Georg Sieder, Oliver Spuhl, Hans Hasse, Inga Toennies, Sebastian Hoch, Hari Prasad Mangalapally
  • Patent number: 8523978
    Abstract: A method of deacidizing a gaseous effluent comprising acid compounds where the gaseous effluent is contacted in C1 with an adsorbent solution so as to obtain a gaseous effluent depleted in acid compounds and an absorbent solution laden with acid compounds, the absorbent solution being selected for its property of forming two separable phases when it has absorbed an amount of acid compounds and when it is heated. The absorbent solution laden with acid compounds is then heated in E1 and E3 so as to separate two fractions: a first absorbent solution fraction depleted in acid compounds and a second absorbent solution fraction enriched in acid compounds. These two fractions are then separated in BS1. The second fraction is regenerated in C2 so as to release part of the acid compounds, and the first absorbent solution fraction and the regenerated absorbent solution are recycled as absorbent solution.
    Type: Grant
    Filed: March 9, 2007
    Date of Patent: September 3, 2013
    Assignee: Institut Francais du Petrole
    Inventors: Alexandre Rojey, Renaud Cadours, Pierre-Louis Carrette, Pierre Boucot
  • Publication number: 20130220122
    Abstract: In one embodiment, a carbon dioxide separating and collecting system includes an absorbing tower to cause an absorbing liquid to absorb carbon dioxide, and discharge a rich liquid. The system includes a regenerating tower to cause the absorbing liquid to release the carbon dioxide, and discharge a lean liquid. The system includes a heat exchanger to heat the rich liquid by using the lean liquid. A discharge port of the rich liquid of the exchanger is at a higher position than a supply port of the rich liquid of the regenerating tower so that the rich liquid discharged from the exchanger contains a descending flow by which liquid head pressure loss in a path from the discharge port to the supply port becomes negative, and an absolute value of the liquid head pressure loss becomes larger than an absolute value of flow friction pressure loss in the path.
    Type: Application
    Filed: January 29, 2013
    Publication date: August 29, 2013
    Applicant: KABUSHIKI KAISHA TOSHIBA
    Inventor: KABUSHIKI KAISHA TOSHIBA
  • Patent number: 8518156
    Abstract: A process and system (100) for removing contaminants from a solution to regenerate the solution within the system. The process includes providing a solution (165) from a wash vessel (160) to a stripping column (181), the solution (165) including contaminants removed from a flue gas stream (150) present in the wash vessel (160) and contacting the solution with steam (185) inside the stripping column (181) thereby removing the contaminants from the solution and regenerating the solution. The stripping column (181) is operated at a pressure less than about 700 kilopascal.
    Type: Grant
    Filed: August 3, 2010
    Date of Patent: August 27, 2013
    Assignee: ALSTOM Technology Ltd
    Inventors: Frederic Z. Kozak, Arlyn V. Petig, Ritesh Agarwal, Rameshwar S. Hiwale
  • Patent number: 8512660
    Abstract: The absorptive removal of carbon dioxide from biogas using a scrubbing liquid in which carbon dioxide is chemically bound proceeds by heating the loaded scrubbing liquid, occurring after the absorption, to a temperature at which liberation of CO2 begins. Immediately thereafter, the loaded scrubbing liquid is fed to at least one centrifugal separator for separating off the gas phase from the liquid phase, wherein methane and dissolved fractions of CO2 escape via the gas phase. After separation is complete, the gas phase is passed into the absorber unit and the liquid phase is further heated to the temperature required for desorption and fed to the desorption unit for regeneration.
    Type: Grant
    Filed: September 14, 2012
    Date of Patent: August 20, 2013
    Assignee: MT-Biomethan GmbH
    Inventors: Stephan Engelke, Uwe Jordan
  • Patent number: 8506683
    Abstract: An absorbent liquid according to the present invention is an absorbent liquid for absorbing CO2 or H2S or both from gas, in which the absorbent liquid includes an alkanolamine as a first compound component, and a second component including a nitrogen-containing compound having in a molecule thereof two members or more selected from a primary nitrogen, a secondary nitrogen, and a tertiary nitrogen or a nitrogen-containing compound having in a molecule thereof all of primary, secondary, and tertiary nitrogens. The absorbent liquid has an excellent absorption capacity performance and an excellent absorption reaction heat performance, as compared to an aqueous solution containing solely an alkanolamine and a nitrogen-containing compound in the same concentration in terms of wt %, and can recover CO2 or H2S or both from gas with smaller energy.
    Type: Grant
    Filed: June 11, 2010
    Date of Patent: August 13, 2013
    Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.
    Inventors: Ryuji Yoshiyama, Masazumi Tanoura, Noriko Watari, Shuuji Fujii, Yukihiko Inoue, Mitsuru Sakano, Tarou Ichihara, Masaki Iijima, Tomio Mimura, Yasuyuki Yagi, Kouki Ogura
  • Patent number: 8500865
    Abstract: The gaseous effluent to be treated is contacted in C1 with an absorbent solution selected for its property of forming two separable phases when it has absorbed an amount of acid compounds and when it is heated. According to the invention, the absorbent solution is regenerated in at least two stages in regeneration zones Z1 and Z2. At the end of the first regeneration stage in Z1, at least part of the partly regenerated absorbent solution is separated into two fractions in B1: a fraction rich in acid compounds and a fraction depleted in acid compounds. Fraction 10 rich in acid compounds is sent to the second regeneration stage in Z2. The fraction depleted in acid compounds and regenerated absorbent solution 6 from the second regeneration stage are recycled to absorption column C1. The method can be applied to combustion fumes decarbonation and to natural gas or synthesis gas deacidizing.
    Type: Grant
    Filed: November 20, 2009
    Date of Patent: August 6, 2013
    Assignee: IFP
    Inventors: Pierre-Antoine Bouillon, Marc Jacquin, Alain Methivier
  • Patent number: 8480798
    Abstract: A system for separating and storing carbon dioxide (CO2) in exhaust produced by an internal combustion engine. The system uses a scrubber tank containing a carbon dioxide absorbent fluid to capture CO2 in the exhaust. The system also includes a carbon dioxide storage means configured to temporarily store the captured CO2, and a CO2 recovery facility to refine the captured CO2 for future use or prepare the CO2 for permanent storage. The system is intended for installation on vehicles such as automobiles to reduce the amount of CO2 emitted by automobiles into the environment, but could also be used for other applications such as stationary power generators.
    Type: Grant
    Filed: December 29, 2010
    Date of Patent: July 9, 2013
    Assignee: Delphi Technologies, Inc.
    Inventors: Bruce A. Myers, David W. Ihms
  • Patent number: 8475566
    Abstract: The present invention relates to a method for recovery of carbon dioxide from a gas stream. The method is a two-step method in which carbon dioxide is compressed in the first step, while the residual carbon dioxide is recovered by an absorption process in a subsequent step. The present invention also relates to the use of the method for the recovery of carbon dioxide and a plant for recovery of carbon dioxide.
    Type: Grant
    Filed: June 6, 2005
    Date of Patent: July 2, 2013
    Assignee: Union Engineering A/S
    Inventor: Rasmus Find
  • Patent number: 8470079
    Abstract: The present invention relates to a process for separating off CO2 from a gas stream, wherein in a second step the CO2 is removed from the CO2-absorbing agent by means of phase separation.
    Type: Grant
    Filed: July 31, 2007
    Date of Patent: June 25, 2013
    Assignee: Universital Dortmund
    Inventors: David Agar, Yudy Halim Tan, Zhang Xiaohui
  • Patent number: 8435325
    Abstract: Disclosed are methods for recovering CO2 and H2S from a feed gas including at least CO2 and H2S.
    Type: Grant
    Filed: October 19, 2009
    Date of Patent: May 7, 2013
    Assignee: Hitachi, Ltd.
    Inventor: Tomoko Akiyama
  • Patent number: 8425655
    Abstract: The present invention provides a gas pressurized separation system to strip a product gas from a liquid stream and yield a high pressure gaseous effluent containing the product gas. The system comprises a gas pressurized stripping apparatus, such as a column, with at least one first inlet allowing flow of one or more liquid streams in a first direction and at least one second inlet allowing flow of one or more high pressure gas streams in a second direction, to strip the product gas into the high pressure gas stream and yield through at least one outlet a high pressure gaseous effluent containing the product gas; and two or more heat supplying apparatuses provided at different locations along the column. Processes for separating a product gas from a gaseous mixture to yield a high pressure gaseous effluent containing the product gas, utilize the gas pressurized separation system described above.
    Type: Grant
    Filed: July 9, 2010
    Date of Patent: April 23, 2013
    Assignee: Carbon Capture Scientific, LLC
    Inventors: Shiaoguo Chen, Zijiang Pan
  • Patent number: 8419843
    Abstract: In one embodiment, a system includes a hydrogen sulfide (H2S) absorber, a first flash tank, a flash gas treatment column, and a CO2 absorber. The system also includes a first fluid path extending sequentially through the H2S absorber, the first flash tank, the flash gas treatment column, the H2S absorber, and the CO2 absorber.
    Type: Grant
    Filed: May 18, 2010
    Date of Patent: April 16, 2013
    Assignee: General Electric Company
    Inventors: Arnaldo Frydman, Pradeep Stanley Thacker, Sachin Suhas Naphad
  • Patent number: 8419831
    Abstract: Disclosed is a method for recovering carbon dioxide from a gas containing carbon dioxide, comprising the step (1) of bringing a gas containing carbon dioxide into contact with an aqueous solution containing 2-isopropylaminoethanol and at least one substance selected from the group consisting of piperazines and alkanolamines to absorb carbon dioxide into the aqueous solution; and the step (2) of heating the aqueous solution containing carbon dioxide absorbed therein, which is obtained in the step (1), to separate and recover carbon dioxide from the solution.
    Type: Grant
    Filed: June 24, 2008
    Date of Patent: April 16, 2013
    Assignee: Research Institute of Innovative Technology for the Earth
    Inventors: Shinkichi Shimizu, Firoz Alam Chowdhury, Hiromichi Okabe, Kazuya Goto
  • Patent number: 8414694
    Abstract: Provided are a CO2 absorber that reduces CO2 contained in flue gas; a regenerator that reduces CO2 contained in rich solvent absorbing CO2 to regenerate the rich solvent, so that lean solvent having the CO2 reduced in the regenerator is reused in the CO2 absorber; a heat exchanger that allows the rich solvent to exchange heat with the lean solvent; and a controller that controls to extract rich solvent portion that is part of the rich solvent, to allow the rich solvent portion to by pass the heat exchanger, and to be supplied into the top of the regenerator without exchanging heat so as to minimize a sum of an enthalpy that is taken out of the regenerator as CO2 gas accompanying steam and an enthalpy of the lean solvent after heat exchange with the rich solvent in the heat exchanger.
    Type: Grant
    Filed: December 23, 2009
    Date of Patent: April 9, 2013
    Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.
    Inventors: Masaki Iijima, Kouki Ogura, Masahiko Tatsumi, Yasuyuki Yagi
  • Patent number: 8409339
    Abstract: A CO2 recovery system includes an absorption tower and a regeneration tower. CO2 rich solution is produced in the absorption tower by absorbing CO2 from CO2-containing gas. The CO2 rich solution is conveyed to the regeneration tower where lean solution is produced from the rich solution by removing CO2. A regeneration heater heats lean solution that accumulates near a bottom portion of the regeneration tower with saturated steam thereby producing steam condensate from the saturated steam. A steam-condensate heat exchanger heats the rich solution conveyed from the absorption tower to the regeneration tower with the steam condensate.
    Type: Grant
    Filed: January 25, 2011
    Date of Patent: April 2, 2013
    Assignees: Mitsubishi Heavy Industries, Ltd., Kansai Electric Power Co., Inc.
    Inventors: Masaki Iijima, Takashi Kamijo, Takahito Yonekawa, Tomio Mimura, Yasuyuki Yagi
  • Patent number: 8398749
    Abstract: A process for the recovery of carbon dioxide, which includes: (a) an absorption step of bringing a carbon dioxide-containing gaseous feed stream into gas-liquid contact with an absorbing fluid, whereby at least a portion of the carbon dioxide present in the gaseous stream is absorbed into the absorbing fluid to produce (i) a refined gaseous stream having a reduced carbon dioxide content and (ii) an carbon dioxide-rich absorbing fluid; and (b) a regeneration step of treating the carbon dioxide-rich absorbing fluid at a pressure of greater than 3 bar (absolute pressure) so as to liberate carbon dioxide and regenerate a carbon dioxide-lean absorbing fluid which is recycled for use in the absorption step, in which the absorbing fluid is an aqueous amine solution containing a tertiary aliphatic alkanol amine and an effective amount of a carbon dioxide absorption promoter, the tertiary aliphatic alkanol amine showing little decomposition under specified conditions of temperature and pressure under co-existence with
    Type: Grant
    Filed: December 12, 2006
    Date of Patent: March 19, 2013
    Assignee: BASF SE
    Inventors: Ute Lichtfers, Norbert Asprion, Mark Claessen, Hiroshi Umino, Koji Tanaka
  • Patent number: 8388737
    Abstract: A method and apparatus for recovering a gaseous component from an incoming gas stream is described. The incoming gas stream is contacted with a lean aqueous absorbing medium to absorb at least a portion of the gaseous component from the incoming gas stream to form a lean treated gas stream and a rich aqueous absorbing medium. At least a portion of the gaseous component is desorbed from the rich aqueous absorbing medium at a temperature to form an overhead gas stream and a regenerated aqueous absorbing medium. At least a portion of the overhead gas stream is treated to recover a condensate stream. At least a portion of the condensate stream is used to form a heated stream. At least a portion of the heated stream is recycled back to the desorbing step. Novel absorbing medium compositions to recover carbon dioxide and/or hydrogen sulfide are also described.
    Type: Grant
    Filed: May 29, 2008
    Date of Patent: March 5, 2013
    Assignee: University of Regina
    Inventors: Don Gelowitz, Paitoon Tontiwachwuthikul, Raphael Idem
  • Patent number: 8388747
    Abstract: Produced natural gas containing carbon dioxide is dehydrated and chilled to liquefy the carbon dioxide and then fractionated to produce a waste stream of liquid carbon dioxide and hydrogen sulfide. Natural gas liquids may be first separated and removed before fractionation. After fractionation, the waste stream is pressurized and transmitted to a remote injection well for injection either for disposal of the waste stream and preferably to urge hydrocarbons toward the producing well. A hydrocarbon stream proceeds from fractionation to a methanol absorber system which removes carbon dioxide gas. The hydrocarbon stream is thereafter separated into at least hydrocarbon gas, nitrogen and helium. Some of the nitrogen is reintroduced into a fractionation tower to enhance the recovery of hydrocarbons. A methanol recovery system is provided to recover and reuse the methanol. The hydrocarbons are sold as natural gas and the helium is recovered and sold. Excess nitrogen is vented.
    Type: Grant
    Filed: August 22, 2008
    Date of Patent: March 5, 2013
    Inventor: Donald Leo Stinson
  • Patent number: 8388738
    Abstract: A process for removing carbon dioxide from a fluid flow, wherein a) the fluid flow is brought into contact with an absorption agent which contains a solution of ammonia and at least one amino carboxylic acid and/or amino sulfonic acid, a charged absorption agent being obtained, and b) the charged absorption agent is regenerated while releasing carbon dioxide. The additional use of the amino carboxylic acid and/or amino sulfonic acid increases the circulation absorption capacity of the absorption agent.
    Type: Grant
    Filed: November 14, 2008
    Date of Patent: March 5, 2013
    Assignee: BASF SE
    Inventors: Norbert Asprion, Georg Sieder, Ute Lichtfers, Hugo Rafael Garcia Andarcia
  • Patent number: 8377184
    Abstract: A CO2 recovery apparatus according to a first embodiment of the present invention includes: a CO2 absorber that brings flue gas containing CO2 into contact with CO2 absorbing liquid to reduce CO2 in the flue gas; a regenerator that reduces CO2 in CO2 absorbing liquid (rich solvent) that has absorbed the CO2 in the CO2 absorber to regenerate the CO2 absorbing liquid, so that the regenerated absorbing liquid (lean solvent), having CO2 reduced in the regenerator, is reused in the CO2 absorber; a first compressor to a fourth compressor that compress the CO2 gas released from the regenerator; and an O2 reducing apparatus arranged between the second compressor and a second cooler to reduce O2 in the CO2 gas.
    Type: Grant
    Filed: October 27, 2009
    Date of Patent: February 19, 2013
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Keiji Fujikawa, Takuya Hirata, Tatsuya Tsujiuchi, Tsuyoshi Oishi
  • Patent number: 8361195
    Abstract: A slurried solid media for simultaneous water purification and carbon dioxide removal from gas mixtures includes the steps of dissolving the gas mixture and carbon dioxide in water providing a gas, carbon dioxide, water mixture; adding a porous solid media to the gas, carbon dioxide, water mixture forming a slurry of gas, carbon dioxide, water, and porous solid media; heating the slurry of gas, carbon dioxide, water, and porous solid media producing steam; and cooling the steam to produce purified water and carbon dioxide.
    Type: Grant
    Filed: May 21, 2010
    Date of Patent: January 29, 2013
    Assignee: Lawrence Livermore National Security, LLC
    Inventors: Roger D. Aines, William L. Bourcier, Brian Viani
  • Patent number: 8361424
    Abstract: The gaseous effluent to be treated is contacted in C1 with an absorbent solution selected for its property of forming two separable phases when it has absorbed an amount of acid compounds and when it is heated. The absorbent solution laden with acid compounds is then heated in E1 and E3 so as to separate two fractions in BS1: a first absorbent solution fraction depleted in acid compounds and a second absorbent solution fraction enriched in acid compounds. The second fraction is regenerated in C2 so as to release part of the acid compounds, and the first absorbent solution fraction and the regenerated absorbent solution are recycled as absorbent solution. According to the invention, an absorbent solution portion circulating in C1 is cooled in E2 in order to prevent demixing of the solution in column C1.
    Type: Grant
    Filed: September 23, 2009
    Date of Patent: January 29, 2013
    Assignee: IFP
    Inventors: Pierre-Antoine Bouillon, Marc Jacquin, Ludovic Raynal
  • Patent number: 8353979
    Abstract: A heat recovery apparatus, for an absorption apparatus for removing CO2 in combustion exhaust gas emitted from a thermal power plant 112 and for regeneration apparatuses 104 to 107 for regenerating CO2 in an absorbing liquid from the absorption apparatus, includes a regeneration-apparatus-exit-CO2-gas cooling apparatus 100 for cooling CO2 gas from an exhaust port of the regeneration apparatus, and may further include a circulation line 102 for circulating reflux water among boiler feedwater heaters 114 and 116 in the thermal power plant 112 and the regeneration-apparatus-exit-CO2-gas cooling apparatus 100.
    Type: Grant
    Filed: April 6, 2010
    Date of Patent: January 15, 2013
    Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.
    Inventors: Tsuyoshi Oishi, Hiroshi Tanaka, Takahiko Endo, Masahiko Tatsumi, Yasuyuki Yagi
  • Patent number: 8328911
    Abstract: A method for removing and capturing carbon dioxide from a fluid stream includes the steps of exposing the fluid stream to an aqueous scrubbing solution that removes and holds carbon dioxide from the fluid stream, passing the aqueous scrubbing solution through a membrane in order to separate excess water from the scrubbing solution and increase the concentration of carbon dioxide in the scrubbing solution, heating the scrubbing solution having an increased concentration of carbon dioxide so as to release carbon dioxide gas and recycling the scrubbing solution. A carbon dioxide capture apparatus includes a carbon dioxide scrubber, a membrane downstream from the scrubber for separating water and concentrating carbon dioxide in a scrubbing solution and a stripper vessel.
    Type: Grant
    Filed: June 21, 2010
    Date of Patent: December 11, 2012
    Assignee: The University of Kentucky Research Foundation
    Inventors: Kunlei Liu, James K. Neathery, Joseph E. Remias, Xiansen Li
  • Publication number: 20120279395
    Abstract: A fuel system comprising a fuel tank, a catalytic inerting device for producing oxygen depleted air (ODA) by reaction of fuel vapour from the fuel tank with air, and a separator device for separating carbon dioxide from the ODA gas before feeding the carbon dioxide depleted ODA gas to the fuel tank so as to render the fuel tank ullage atmosphere inert. Also, a method of reducing the carbon dioxide content of oxygen depleted air (ODA) produced by a catalytic inerting device for inerting a fuel tank ullage atmosphere, the method comprising separating carbon dioxide from the ODA gas before feeding the carbon dioxide depleted ODA gas to the fuel tank. The system may be installed in an aircraft.
    Type: Application
    Filed: May 4, 2012
    Publication date: November 8, 2012
    Applicant: AIRBUS OPERATIONS LIMITED
    Inventors: Joseph K-WLam, Gregory HYLANDS
  • Patent number: 8303685
    Abstract: An improved acid gas regeneration and injection process wherein the separated acid gas stream emerging from a regenerator is compressed and injected into subsurface reservoir, the improvement comprising conducting the acid gas separation in the regenerator under pressure that exceeds 50 psia and does not exceed 300 psia.
    Type: Grant
    Filed: June 21, 2004
    Date of Patent: November 6, 2012
    Assignee: Dow Global Technologies LLC
    Inventors: Craig N. Schubert, Timothy C. Frank
  • Patent number: 8287626
    Abstract: A method for treating a gas mixture containing acid gases, including: contacting the gas mixture with an absorbing solution, to obtain a de-acidified gas mixture and an absorbing solution with acid gases. To regenerate the absorbing solution with acid gases, the absorbing solution is passed into a first regenerator at a first pressure, then the solution is passed into a second regenerator at a second pressure, and finally to a third regenerator at a third pressure, the third pressure being less than the second pressure which is less than the first pressure. The gases from the second and third regenerator are compressed and recycled to the first and second regenerator, respectively. Gases from the second and/or the third regenerator are drawn off to provide a gas mixture rich in hydrogen sulfide. Gases from the first regenerator are drawn off to provide a gas mixture rich in carbon dioxide.
    Type: Grant
    Filed: January 18, 2008
    Date of Patent: October 16, 2012
    Assignee: Total S.A.
    Inventors: Viep Hoang-Dinh, Damien Roquet, Kenza Habchi-Tounsi, Olivier Chazelas, Claire Weiss
  • Publication number: 20120222557
    Abstract: Some embodiments described herein relate to ionic liquids comprising an anion of a heteraromatic compound such as optionally substituted pyrrolide, optionally substituted pyrazolide, optionally substituted indolide, optionally substituted phospholide, or optionally substituted imidazolide. Methods and devices for gas separation or gas absorption related to these ionic liquids are also described herein.
    Type: Application
    Filed: November 3, 2010
    Publication date: September 6, 2012
    Applicant: UNIVERSITY OF NOTRE DAME DU LAC
    Inventors: William F. Schneider, Joan F. Brennecke, Edward J. Maginn, Elaine Mindrup, Burcu Gurkan, Erica Price, Brett Goodrich
  • Patent number: 8257476
    Abstract: A first contaminant selected from oxygen and carbon monoxide is removed from impure liquid carbon dioxide using a mass transfer separation column system which is reboiled by indirect heat exchange against crude carbon dioxide fluid, the impure liquid carbon dioxide having a greater concentration of carbon dioxide than the crude carbon dioxide fluid. The invention has particular application in the recovery of carbon dioxide from flue gas generated in an oxyfuel combustion process or waste gas from a hydrogen PSA process. Advantages include reducing the level of the first contaminant to not more than 1000 ppm.
    Type: Grant
    Filed: September 17, 2010
    Date of Patent: September 4, 2012
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Vincent White, Rodney John Allam
  • Patent number: 8236091
    Abstract: A fluid separation apparatus suitable for separating a mixed fluid with different properties and capable of separating a complex fluid mixture efficiently is provided. The fluid separation apparatus includes a sampling entrance, a first separation column, a second separation column, a bypass line, a detector and a guide multi-channel valve. A mixed fluid flows into the first separation column via the sampling entrance. The second separation column is connected to the first separation column in series and connected to the bypass line in parallel. The detector is connected to the second separation column and the bypass line. The guide multi-channel valve has different modes to control a flow-through status and a closed status between the first separation column and the second separation column, between the first separation column and the bypass line, between the second separation column and the detector, and between the bypass line and the detector.
    Type: Grant
    Filed: August 4, 2009
    Date of Patent: August 7, 2012
    Assignee: National Taiwan University of Science and Technology
    Inventors: Sheng-Chiang Yang, Shih-Chi Lu, Bing-Joe Hwang
  • Patent number: 8231719
    Abstract: An absorbent liquid according to the present invention is an absorbent liquid for absorbing CO2 or H2S or both from gas, in which the absorbent liquid includes an alkanolamine as a first compound component, and a second component including a nitrogen-containing compound having in a molecule thereof two members or more selected from a primary nitrogen, a secondary nitrogen, and a tertiary nitrogen or a nitrogen-containing compound having in a molecule thereof all of primary, secondary, and tertiary nitrogens. The absorbent liquid has an excellent absorption capacity performance and an excellent absorption reaction heat performance, as compared to an aqueous solution containing solely an alkanolamine and a nitrogen-containing compound in the same concentration in terms of wt %, and can recover CO2 or H2S or both from gas with smaller energy.
    Type: Grant
    Filed: June 12, 2006
    Date of Patent: July 31, 2012
    Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.
    Inventors: Ryuji Yoshiyama, Masazumi Tanoura, Noriko Watari, Shuuji Fujii, Yukihiko Inoue, Mitsuru Sakano, Tarou Ichihara, Masaki Iijima, Tomio Mimura, Yasuyuki Yagi, Kouki Ogura
  • Patent number: 8231706
    Abstract: A method for separating methane and carbon dioxide from biogas and a device are intended for purifying biogas, wherein carbon dioxide is separated off from the biogas. The method is distinguished by an energetically favorable mode of operation. The biogas is passed under atmospheric pressure and standard temperature into an absorption column. While the biogas ascends through a packed bed, which has a surface area of 600 to 1200 m2/m3, and at a space velocity of 5 to 40 Nm3/m3h, carbon dioxide present in the biogas is bound in a wash liquid by chemosorption. The purified methane gas is taken off at the top of the absorption column at a defined flow velocity. Carbon dioxide bound in the wash liquid is removed by desorption at a relatively high pressure of 2 to 30 bar and a temperature of at least 120° C. Biogas may be separated into methane and CO2.
    Type: Grant
    Filed: March 19, 2007
    Date of Patent: July 31, 2012
    Assignee: MT-Biomethan GmbH
    Inventor: Lothar Günther
  • Patent number: 8226748
    Abstract: A CO2 reducing system (10A) is constituted by a low-temperature CO2 reducing apparatus (11-1) that includes a low-temperature absorber (1006-1) that reduces at least one of CO2 and H2S by bringing flue gas (1002) including at least one of CO2 and H2S into contact with a low-temperature absorbing solution (1005-1), a low-temperature regenerator (1008-1) that regenerates a low-temperature rich solution (1007-1), a low-temperature rich-solution supply line (12-1) that feeds the low-temperature rich solution (1007-1) to the low-temperature regenerator (1008-1), and a low-temperature lean-solution supply line (13-1) that feeds a low-temperature lean solution (1009-1) to the low-temperature absorber (1006-1) from the low-temperature regenerator (1008-1); and a high-temperature CO2 reducing apparatus (11-2) that is arranged on a side at which the flue gas (1002) is discharged, and that has the same configuration as the low-temperature CO2 reducing apparatus (11-1).
    Type: Grant
    Filed: June 17, 2008
    Date of Patent: July 24, 2012
    Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.
    Inventors: Yukihiko Inoue, Ryuji Yoshiyama, Tsuyoshi Oishi, Masaki Iijima, Masazumi Tanoura, Tomio Mimura, Kouki Ogura, Yasuyuki Yagi
  • Patent number: 8216351
    Abstract: An Apparatus for purifying a feed stream containing carbon dioxide in which the feed stream, after having been compressed and dried, is partly cooled and then used to reboil a stripping column. Thereafter, the feed stream is further cooled and expanded to a lower operational temperature of the stripping column. A carbon dioxide product stream composed of the liquid column bottoms of the stripping column is expanded at one or more pressures to generate refrigeration, then fully vaporized within the main heat exchanger and compressed by a compressor to produce a compressed carbon dioxide product. Refrigeration is recovered in the main heat exchanger from a column overhead stream extracted from the stripping column within the main heat exchanger either directly or indirectly by auxiliary processing in which carbon dioxide is further separated and optionally recycled back to the main compressor used in compressing the feed stream.
    Type: Grant
    Filed: December 7, 2009
    Date of Patent: July 10, 2012
    Assignee: Praxair Technology
    Inventors: Minish Mahendra Shah, Henry Edward Howard
  • Patent number: 8206489
    Abstract: The present invention relates to a method of deacidizing a gaseous effluent, wherein the following stages are carried out: a) contacting the gaseous effluent with an absorbent solution so as to obtain a gaseous effluent depleted in acid compounds and an absorbent solution laden with acid compounds, the absorbent solution being selected for its property to form two separable phases when it absorbs an amount of acid compounds, b) separating the absorbent solution laden with acid compounds into two fractions: a first absorbent solution fraction depleted in acid compounds and a second absorbent solution fraction enriched in acid compounds, c) regenerating the second fraction so as to release part of the acid compounds, d) mixing a predetermined amount of water with the first absorbent solution fraction obtained in stage b) or with the regenerated absorbent solution fraction obtained in stage c), then e) recycling the first absorbent solution fraction and the regenerated absorbent solution as the absorbent solu
    Type: Grant
    Filed: December 19, 2006
    Date of Patent: June 26, 2012
    Assignee: Institut Francais du Petrole
    Inventors: Renaud Cadours, Pierre-Louis Carrette, Pierre Boucot
  • Patent number: 8197857
    Abstract: A method for the elimination of carbon dioxide from waste gases includes the following steps. First, waste gases, which include carbon dioxide, are provided from a source for waste gases. Next, the waste gases are contacted with an absorbent composition that includes perfluorodecalin solution. The waste gases, especially the carbon dioxide, are then absorbed by the absorbent composition. The absorbent composition thereby absorbs the waste gases to eliminate the carbon dioxide.
    Type: Grant
    Filed: June 6, 2009
    Date of Patent: June 12, 2012
    Inventors: Lawrence V. Dressler, Alexander Chirkov
  • Patent number: 8192524
    Abstract: Disclosed herein are processes for producing a CO2-depleted product gas stream. The processes involve feeding a natural gas feed stream comprising greater than about 10 vol % CO2 to at least one membrane unit comprising a plurality of polymer membranes to provide a CO2-rich permeate comprising at least 95 vol % CO2 and a CO2-depleted product gas stream. The polymer membranes comprise a crosslinked polyimide polymer having covalent ester crosslinks and have a CO2 permeance of at least 20 GPU and a CO2/CH4 selectivity of greater than 20, at 35 degrees C. and a feed pressure of 100 psia. Also disclosed herein is an apparatus incorporating the crosslinked polyimide polymer for producing a CO2-depleted product gas stream from a natural gas feed stream.
    Type: Grant
    Filed: January 29, 2009
    Date of Patent: June 5, 2012
    Assignee: Chevron U.S.A. Inc.
    Inventors: Daniel Chinn, Siji Okeowo, Jeff D. Euhus, Shabbir Husain
  • Patent number: 8192530
    Abstract: A system (10) for regenerating a rich absorbent solution (26), the system including: an absorber (20) facilitating interaction between a process stream (22) and an absorbent solution, wherein the process stream comprises an acidic component, and interaction of the process stream with the absorbent solution produces a reduced acidic component stream (28) and a rich absorbent solution; at least one heat exchanger accepting at least one of said reduced acidic component stream and the process stream to transfer heat to a heat transfer fluid (60); and at least one mechanism (60a) to transfer the heat transfer fluid from said at least one heat exchanger to a regenerator (34) regenerating the rich absorbent solution, wherein each of the at least one mechanisms is fluidly coupled to each of the at least one heat exchangers.
    Type: Grant
    Filed: November 12, 2008
    Date of Patent: June 5, 2012
    Assignee: ALSTOM Technology Ltd
    Inventors: Nareshkumar B. Handagama, Rasesh R. Kotdawala
  • Publication number: 20120132443
    Abstract: A process for the removal of CO2 and/or H2S from a gas comprising CO2 and/or H2S. The process comprises contacting the gas in an absorber with an absorbing solution wherein the absorbing solution absorbs at least part of the CO2 and/or H2S so as, to produce a CO2 and/or H2S lean gas and a CO2 and/or H2S rich absorbing solution. At least part of the CO2 and/or H2S rich absorbing solution is heated to produce a heated CO2 and/or H2S rich absorbing solution. At least part of the CO2 and/or H2S is removed from the heated CO2 and/or H2S rich absorbing solution in a regenerator to produce a CO2 and/or H2S rich gas and a CO2 and/or H2S lean absorbing solution. In the process, at least part of the heat for heating the CO2 and/or H2S rich absorbing solution in step b) is obtained in a sequence of multiple heat exchangers.
    Type: Application
    Filed: June 18, 2010
    Publication date: May 31, 2012
    Inventor: Jiri Peter Thomas Van Straelen
  • Patent number: 8168149
    Abstract: A method and system for CO2 capture from flue gas uses an absorber vessel in which a flue gas stream containing CO2 is contacted with an ammoniated solution to remove CO2 from the flue gas, and a regenerator vessel in which CO2 is released from the ammoniated solution. Parasitic energy consumption of the system can be reduced by adding to the ammoniated solution a promoter effective to enhance the formation of ammonium bicarbonate within the ammoniated solution. The amount of ammoniated solution recycled from the regenerator vessel to the absorber vessel is less than that which would be required using the ammoniated solution without the promoter for removal of the same amount of CO2 from the flue gas.
    Type: Grant
    Filed: December 2, 2010
    Date of Patent: May 1, 2012
    Assignee: ALSTOM Technology Ltd
    Inventors: Eli Gal, Otto Morten Bade, Indira Jayaweera, Gopala Krishnan
  • Patent number: 8137441
    Abstract: A CO2 recovery system includes an absorption tower and a regeneration tower. CO2 rich solution is produced in the absorption tower by absorbing CO2 from CO2-containing gas. The CO2 rich solution is conveyed to the regeneration tower where lean solution is produced from the rich solution by removing CO2. A reclaimer heats the lean solution that is produced in the regeneration tower to produce a condensed waste-product from the lean solution by condensing a depleted material contained in the lean solution, and removes the condensed waste-product. A cooler cools the condensed waste-product.
    Type: Grant
    Filed: October 31, 2007
    Date of Patent: March 20, 2012
    Assignees: Mitsubishi Heavy Industries Ltd., The Kansai Electric Power Co., Inc
    Inventors: Masaki Iijima, Tomio Mimura, Yasuyuki Yagi
  • Publication number: 20120060689
    Abstract: A method for reducing energy requirements of a CO2 capture system comprises: contacting a flue gas stream with a CO2 lean absorbent stream in an absorber, thereby removing CO2 from the flue gas and providing a CO2 rich absorbent stream; heating a first portion of the CO2 rich absorbent stream using heat from the CO2 lean absorbent stream, and providing the heated first portion of the CO2 rich absorbent stream to a regenerator; providing a second portion of the CO2 rich absorbent stream to the regenerator, wherein the heated first portion is hotter than the second portion and the heated first portion is provided to the regenerator at a lower elevation in the regenerator relative to that of the second portion.
    Type: Application
    Filed: August 2, 2011
    Publication date: March 15, 2012
    Applicant: ALSTOM TECHNOLOGY LTD
    Inventors: Joseph P. Naumovitz, Michael Koch
  • Patent number: 8118915
    Abstract: Produced natural gas containing carbon dioxide is dehydrated and chilled to liquefy the carbon dioxide and then fractionated to produce a waste stream of liquid carbon dioxide and hydrogen sulfide. Natural gas liquids may be first separated and removed before fractionation. After fractionation, the waste stream is pressurized and transmitted to a remote injection well for injection either for disposal of the waste stream and preferably to urge hydrocarbons toward the producing well. A hydrocarbon stream proceeds from fractionation to a methanol absorber system which removes carbon dioxide gas. The hydrocarbon stream is thereafter separated into at least hydrocarbon gas, nitrogen and helium. Some of the nitrogen is reintroduced into a fractionation tower to enhance the recovery of hydrocarbons. A methanol recovery system is provided to recover and reuse the methanol. The hydrocarbons are sold as natural gas and the helium is recovered and sold. Excess nitrogen is vented.
    Type: Grant
    Filed: August 22, 2008
    Date of Patent: February 21, 2012
    Inventor: Donald Leo Stinson
  • Patent number: 8088200
    Abstract: In a method for removing acid gases from a fluid stream, the fluid stream, which is in contact with an absorption medium within an absorber, is passed through a first absorption zone in the absorber to remove a majority of acid gases from the fluid stream. The fluid stream is susequently passed through a second absorption zone in the absorber to further remove acid gases from the fluid stream. The loaded absorption medium is passed into a first regeneration zone to obtain a partially regenerated absorption medium, and a part of the partially regenerated absorption medium is passed into the first absorption zone. The other part of the partially regenerated absorption medium is passed into a second regeneration zone to obtain a regenerated absorption medium. A part of the regenerated absorption medium is passed into the first absorption zone and the other part is passed into the second absorption zone.
    Type: Grant
    Filed: February 14, 2007
    Date of Patent: January 3, 2012
    Assignee: BASF SE
    Inventors: Rupert Wagner, Randolf Hugo
  • Patent number: 8075673
    Abstract: A description is given of an absorption medium for removing carbon dioxide from gas streams which comprises aqueous solution of an amine of the formula I HNR2??(I) where one or both radicals R are and the other radical R is hydrogen. The absorption medium is distinguished by particular oxidation resistance.
    Type: Grant
    Filed: October 19, 2006
    Date of Patent: December 13, 2011
    Assignee: BASF SE
    Inventors: Joachim-Thierry Anders, Johann-Peter Melder, Norbert Asprion, Ole Brettschneider, Iven Clausen, Bernd Eck, Ute Lichtfers
  • Patent number: 8043588
    Abstract: This invention relates to a method and plant for energy-efficient removal of CO2 from a gas phase by means of absorption. The invention is particularly suitable for use in connection with thermal power plants fired by fossil fuels, and is also well-suited for retrofitting in existing thermal power plants. A processing plant according to the invention comprises three sections: a primary CO2-generating process that serves as main product supplier; a CO2-capture and separation plant based on absorption and desorption of CO2 respectively by/from at least one absorbent; and a second CO2-generating process where combustion of carbonaceous fuel in pure oxygen atmosphere serves as energy supply to at least a part of the thermal energy necessary to drive the regeneration of the absorbent in the desorption column(s).
    Type: Grant
    Filed: January 12, 2007
    Date of Patent: October 25, 2011
    Assignees: CO2-Norway AS, Nebb Engineering AS
    Inventors: Carl W. Hustad, Ingo Tronstad
  • Patent number: 8016919
    Abstract: A solution contained in a regeneration tower is supplied to a filtering unit. The filter unit filters out solid particles contained in the solution. A washing unit washes out with backwash water solid particles filtered out by the filter unit. An evaporating unit receives the backwash water containing the solid particles, and heats received backwash water thereby obtaining solid-particles concentrated backwash water.
    Type: Grant
    Filed: January 30, 2008
    Date of Patent: September 13, 2011
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Masaki Iijima, Takashi Kamijo