Abstract: The present invention is directed to an apparatus and a method for continuously removing water vapor from a closed loop, re-circulated gas flow in an ion mobility spectrometer using a water permeable membrane, having a first side and a second side opposite the first side. The gas flow is disposed adjacent and carried past the first side to deposit water vapor that passes through the membrane to the second side. An exhaust flow is disposed adjacent and carried passed the second side of the membrane to remove the water vapor from the system. Therefore, the water removal apparatus continuously regenerates in-situ. Heaters, heat sinks and additional treatment systems including charcoal filters can also be included in the system to enhance its performance.

Abstract: A device for dehumidifying room air has a chamber consisting of at least one first cavity (1) and at least one second cavity (2). The cavities are separated by at least one water-permeable and/or water-vapor-permeable structure (3), these structures (3) lying in each case in the direction of the fluid streams flowing through the cavities (1, 2) of the chamber. In this case, a first air stream (11, 12) which is to be dehumidified flows through the first cavity (1). The second cavity (2), with its second air stream (13, 14), at least partly absorbs the moisture extracted from the first stream.

Abstract: The present invention provides for a process for producing carbon monoxide. A feed gas stream of hydrogen, carbon monoxide and carbon dioxide is directed to a membrane unit which separates the feed gas stream into two streams. The stream containing carbon monoxide is directed to second membrane unit for further purification and the steam containing the carbon dioxide and hydrogen is fed to a reverse shift reactor to produce more carbon monoxide. The carbon monoxide recovered from the reverse shift reactor is purified in a third membrane unit and directed back to the first membrane unit and is further purified and recovered as additional carbon monoxide product.

Abstract: Methods of separating fluids using capillary forces and/or improved conditions for are disclosed. The improved methods may include control of the ratio of gas and liquid Reynolds numbers relative to the Suratman number. Also disclosed are wick-containing, laminated devices that are capable of separating fluids.

Abstract: A membrane air dryer includes a proportioning valve for providing sweep air to the dryer. The valve may be located in an easily accessible location and may be oriented so that the movable valve element extends transverse to the length of the shell. The valve may be configured to allow air to flow back from the delivery port to the fibers during a compressor unload cycle to maintain pressure on the fibers, while blocking flow of air from the delivery port to the sweep chamber.

Abstract: Apparatus and methods useful for removal or reduction of moisture from fluids are described. In one embodiment the apparatus comprises a moisture separation unit comprising a thermally regenerable moisture adsorption material having feed and waste sides, and means for regenerating the thermally regenerable moisture adsorption material. The feed fluid contacts the feed side, while a dry, preferably heated purge gas flows past the waste side. The thermally regenerable moisture adsorption material is regenerated by contacting with the heated dry purge gas. The apparatus and methods are particularly useful in supplying dehydrated electronic specialty gases to semiconductor tools.

Abstract: A process and apparatus for dehumidifying a gas stream is provided. The process includes steps of: a) providing a semi-permeable wall having an osmotic membrane with a plurality of pores at least some of which are operably sized to permit capillary condensation, a first side, and a second side; b) placing an osmotic fluid in a compartment formed in part by the semi-permeable wall, wherein the second side of the osmotic membrane is exposed to the osmotic fluid; c) exposing the first side of the osmotic membrane to the gas stream to be dehumidified; and d) maintaining a sufficiently high water concentration gradient across the osmotic membrane during the dehumidification process to result in a flux of water through the osmotic membrane. The apparatus includes at least one semi-permeable osmotic wall, at least one gas stream compartment formed in part by the osmotic wall, and at least one osmotic fluid compartment formed in part by the osmotic wall.

Abstract: A nanostructured substrate is disclosed having a plurality of substrate openings disposed between the nanostructures on the substrate. When a desired fluid comes into contact with the substrate, at least a portion of the fluid is allowed to pass through at least one of the openings. In a first embodiment, the fluid is caused to pass through the openings by causing the fluid to penetrate the nanostructures. In a second embodiment, the substrate is a flexible substrate so that when a mechanical force is applied to the substrate, such as a bending or stretching force, the distance between nanoposts or the diameter of nanocells on the substrate increases and the liquid penetrates the nanostructures. In another embodiment, a first fluid, such as water, is prevented from penetrating the nanostructures on the substrate while a second fluid is permitted to pass through the substrate via the openings in the substrate.

Abstract: Provided is an inexpensive temperature-humidity exchanger having reliably gas-sealed gas manifolds and delivering a gas at high pressure and high dew-point temperature. Upper and lower seal portions surrounding gas manifolds to which the gas is supplied or from which the gas is discharged are provided. The upper and lower seal portions, which partially extend across an aggregate communication groove, are respectively constituted by upper and lower seal formation plates that are arranged in a two-stage manner in a laminating direction. The upper and lower seal portions have flat faces extending in the laminating direction. Furthermore, the upper and lower seal formation plates are disposed such that their projections in the laminating direction are offset from each other.

Abstract: A system for supplying a compressed fluid with a reduced moisture content comprising a membrane dryer for receiving a compressed fluid and removing moisture therefrom, a compressed fluid source located upstream of the membrane dryer, a check valve located upstream of the membrane dryer to prevent backflow therethrough, an accumulator for receiving the compressed fluid discharged from the membrane dryer and an inlet on the membrane dryer for receiving a portion of a compressed fluid from the compressed fluid source wherein the portion of the compressed fluid is diverted from a compressed fluid located upstream of the membrane dryer.

Abstract: A method for separating water from a Fischer-Tropsch reactor product stream in a cost effective and energy efficient manner which comprises feeding a Fischer-Tropsch product stream to a separation membrane, preferably a ceramic membrane, and recovering water vapor from the downstream permeate side of the membrane.

Abstract: There is provided a process for modifying a first organic composition comprising (i) at least one first solvent, (ii) at least one solute, and (iii) optionally, at least one second solvent to produce a modified organic composition in which the concentration of the at least one first solvent is reduced and the concentration of the at least one second solvent is increased, comprising the steps of: (a) providing a selectively permeable membrane having a first surface and a second surface; (b) transferring a portion of the first solvent and optionally a portion of the solute from the first surface to the second surface across the membrane by contacting the first organic composition with the first surface, wherein the pressure at the first surface is greater than the pressure at the second surface, and wherein the membrane is a selectively permeable membrane such that the membrane rejection (R) of the solute is greater than 0%; (c) adding a portion of the second solvent to the organic composition retained at the f

Abstract: A method and mobile system for cleaning dirty gas from a newly stimulated gas well. The entire system is supported on a trailer or other mobile support so that it can be driven from well site to well site for short-term, post-stimulation use only. The system comprises a gas separator, such as a membrane separator. The system also includes a pretreatment assembly for preparing the gas for the gas separator. The pretreatment assembly may include separators, a heater, a guard vessel and a polishing filter. A chiller or heat exchanger cools the treated gas to a marketable temperature. A generator and a hydraulics plant provide power to the system. Each mobile system will be designed to treat gases with widely different operating conditions varying from well to well.

Abstract: A gas-separation membrane, membrane module and membrane process for controlling humidity in an environment. The membrane has a porous support zone impregnated by a selective zone, a configuration that reduces concentration polarization within the membrane itself when the membrane is housed in the module and used in the process.

Abstract: A process for controlling the volume of dry air, dried to a predetermined degree of dryness, from a sweep manifold of an air dryer system, flowing over a plurality of gas/liquid fluid separating membranes, comprising: diverting a predetermined volume of dried air to the manifold; sensing one of the flow volume and humidity values of the remainder of the dried air or the pressure differential within the system; and utilizing one of the differential pressure to control the predetermined volume of dried air and utilizing a controller for achieving the predetermined degree of dryness by controlling at least one solenoid valve which, in turn, controls the flow volume of the predetermined volume of dried air diverted to the manifold.

Abstract: A gas and liquid phase separator apparatus and an apparatus for energy production based on fuel cells within the phase separator.

Abstract: A method and apparatus for preventing contamination of a substrate or a substrate surface, and particularly relates to prevention of contamination of raw materials, semi-finished products, base materials of products and substrate surface in a high-tech industry such as an in the production of semiconductors and liquid crystals. A gas coming into contact with a base material or substrate is purified by dust removing apparatus and adsorption and/or absorption apparatus so that the concentration of fine particles in the gas is below class 1,000 and a non-methane hydrocarbon concentration is below 0.2 ppm. Thereafter, the base material or the substrate surface is exposed to this gas.

Abstract: A method and mobile system for cleaning dirty gas from a newly stimulated gas well. The entire system is supported on a trailer or other mobile support so that it can be driven from well site to well site for short-term, post-stimulation use only. The system comprises a gas separator, such as a membrane separator. The system also includes a pretreatment assembly for preparing the gas for the gas separator. The pretreatment assembly may include separators, a heater, a guard vessel and a polishing filter. A chiller or heat exchanger cools the treated gas to a marketable temperature. A generator and a hydraulics plant provide power to the system. Each mobile system will be designed to treat gases with widely different operating conditions varying from well to well.

Abstract: An air drying system for a vehicle including a membrane air dryer is provided. The air dryer is supplied with a stream of compressed air that has a low and constant concentration of oil vapor. A coalescing filter element may be used to maintain the oil vapor concentration. The filtered material may be discharged from the coalescing filter by a pressure swing drain valve, which discharges the filtered material upon unloading of the compressor.

Abstract: A method and apparatus for preventing contamination of a substrate or a substrate surface, and particularly relates to prevention of contamination of raw materials, semi-finished products, base materials of products and substrate surface in a high-tech industry such as an in the production of semiconductors and liquid crystals. A gas coming into contact with a base material or substrate is purified by dust removing apparatus and adsorption and/or absorption apparatus so that the concentration of fine particles in the gas is below class 1,000 and a non-methane hydrocarbon concentration is below 0.2 ppm. Thereafter, the base material or the substrate surface is exposed to this gas.

Abstract: The present invention relates to the use of a hydrophilic membrane to provide by the process of pervaporation through the membrane water suitable for agricultural irrigation, industrial use, hydrating or rehydrating of food or agricultural or pharmaceutical compositions. The present invention also relates to a water purification apparatus which includes the hydrophilic membrane, comprising one or more layers of hydrophilic polymers, to purify water which may contain suspended or dissolved impurities and solids, including but not limited to seawater, brackish water and other kinds of polluted water.

Abstract: A device for continuously humidifying and dehumidifying feed air for a manufacturing process or a ventilation and air conditioning installation includes a membrane contactor having a membrane, the feed air being passed along one side of the membrane and a hygroscopic liquid being passed along another side of the membrane. A regenerator is provided for lowering the water content of the hygroscopic liquid. A metering device is provided for adding water to increase the water content of the hygroscopic liquid. A control device is connected to the metering device and to the regenerator, the control device being configured to control the water content of the hygroscopic liquid and enable a switching between humidification and dehumidification of the feed air as a function of the water vapor partial pressure difference between the feed air and the hygroscopic liquid.

Abstract: A method and apparatus for mounting an air dryer to a commercial vehicle is provided. The end caps of the membrane air dryer are used to retain the membrane air dryer core and attach the membrane air dryer to the surface of the air supply reservoir. Bosses can be welded to the external surface of the air supply reservoir, which can then be used to mount the membrane air dryer by bolting the end caps to the bosses. The method and apparatus can be applied to two or three tank air supply reservoir systems. A disengagement tank may be included within the air dryer system, in place of a coalescing filter, to reduce the amount of moisture that reaches the membrane air dryer core.

Abstract: Methods of separating fluids using capillary forces and/or improved conditions for are disclosed. The improved methods may include control of the ratio of gas and liquid Reynolds numbers relative to the Suratman number. Also disclosed are wick-containing, laminated devices that are capable of separating fluids.

Abstract: A method of separating a mixture of N (N?2) gases by size exclusion, comprising: contacting the mixture of gases with N?1 gas permeable porous films, each of the N?1 gas permeable porous films being made of a permeable porous material including pores of different sizes, formed with at least one nanostructured compound. wherein the at least one nanostructured compound includes 30% or more polyhedral oligomeric silsequioxane (POSS) by weight: wherein at least one of the N?1 gas permeable porous films has pores which do not allow permeation of at least one of the N gases.

Abstract: Gas separation membranes formed from polyester-polyether block copolymers which are useful for separating gases from gas mixtures. The membranes and processes are especially suited for separating polar gases from mixtures that contain polar and non-polar species. The novel membranes exhibit good permeability and permselectivity as well as durability, making them well suited for industrial applications such as removal of acid gases from natural gas and removal of carbon dioxide from synthesis gas.

Abstract: A system, method, and apparatus for supplying a gas-liquid vapor to a process tank for performing semiconductor manufacturing. In one aspect, the invention is a method of supplying a gas-liquid vapor to a process tank comprising: supplying a gas stream through at least one hydrophobic tube; exposing the outside surface of the hydrophobic tube to a liquid so that the liquid permeates the hydrophobic tube and enters the gas stream, forming a gas-liquid vapor inside the tube; and transporting the gas-liquid vapor to the process tank. In another aspect, the invention is an apparatus for supplying a gas-liquid vapor to a process tank comprising: at least one hydrophobic tube adapted to carry a gas; and a housing forming a chamber that surrounds the tube, the chamber adapted to receive a liquid that can permeate the tube, forming a gas-liquid vapor.

Abstract: Gas separation membranes formed from polyether-urethane or polyether-urea block copolymers are useful for separating gases from gas mixtures. The membranes and processes are especially suited for separating polar gases from mixtures that contain polar and non-polar species. The novel membranes exhibit good permeability and permselectivity, as well as durability, making them well suited for industrial applications such as removal of acid gases from natural gas and removal of carbon dioxide from synthesis gas.

Abstract: Spray-painting apparatus and method in which provision is made for: an inlet for the air under pressure; a heating unit for the compressed air; an air drying/separation unit including hollow-fiber membranes; adjustment of the heating of the treated air; adjustment of the pressure of the treated air; adjustment of either the dew point or the percentage of oxygen in the treated air in the case of hollow fiber membranes for nitrogen separation; and an outlet for the treated air to be used as paint carrier fluid.

Abstract: A hollow fiber membrane gas separation apparatus of a compact design suitable for separation and purification of gases is disclosed. The apparatus comprises an outer housing that consists of a detachable bowl and a head closure, and a removable hollow fiber membrane cartridge positioned therein. The cartridge contains a concentric tubular inner core member and is surrounded by a shell and at least one end closure. The cartridge is attached by its first axial end in a sealed and removable manner to a gas flow conduit positioned coaxially in the housing closure wherein the conduit is in fluid communication with a gas inlet or product gas outlet port formed in the housing head closure and by its second axial end to a waste gas exit port in the bowl. The feed gas inlet port and the product gas outlet port in the head closure are spaced in a straight line for a short overall distance providing for a linear connection with other components of a gas separation system, which is a preferred system component packaging.

Abstract: The present invention relates to the use of a hydrophilic membrane to provide by the process of pervaporation through the membrane water suitable for agricultural irrigation, industrial use, hydrating or rehydrating of food or agricultural or pharmaceutical compositions. The present invention also relates to a water purification apparatus which includes the hydrophilic membrane, comprising one or more layers of hydrophilic polymers, to purify water which may contain suspended or dissolved impurities and solids, including but not limited to seawater, brackish water and other kinds of polluted water.

Abstract: An integral hollow fiber membrane gas purification apparatus is disclosed. The apparatus comprises one or more filtration elements and a hollow fiber membrane cartridge placed coaxially in a common housing. In some embodiments, the filtration elements are omitted and the hollow fiber membrane cartridge is employed as a combined gas separation/filtration device. The apparatus of this invention is particularly useful for conditioning compressed air that includes the removal of both suspended matter and water vapor.

Abstract: An apparatus is disclosed for dehydrating gas in a system having control gas and supply gas. A first housing is fluidly connected to supply gas and a first membrane member is in the first housing flow path, with a plurality of tubes having interstitial spaces therebetween, each tube being more permeable to water vapor than to gas. Supply gas exiting the first membrane member is drier. Drier supply gas is metered to the first membrane member interstitial spaces, whereby dried supply gas sweeps water or water vapor from the first membrane member interstitial spaces to surrounding environment. A second housing similar to the first has a similar second membrane member therein and fluidly connected to control gas. Control gas exiting second membrane member is drier. Drier supply gas is also metered to second membrane member interstitial spaces, and sweeps water or water vapor from second member interstitial spaces through the second housing vent.

Abstract: A humidifier having a plurality of water-permeable hollow fiber membranes placed along the lengthwise direction of a housing accommodated within the housing in which gases each having a different moisture content flow inside and outside the hollow fiber membranes to carry out moisture exchange whereby the dry air having a low moisture content is humidified is disclosed. The humidifier comprises a bypass channel having a larger diameter than that of the hollow fiber membrane, in which the gas flowing outside the hollow fiber membrane, formed on an approximately central portion of the cross-lengthwise direction of the housing along the lengthwise direction of the housing, and an inlet which introduces the gas flowing outside the hollow fiber membrane into the housing and an outlet which discharges the gas flowing outside the hollow fiber membrane formed on the bypass channel.

Abstract: A hollow fiber membrane gas separation apparatus of a compact design suitable for separation and purification of gases is disclosed. The apparatus comprises an outer housing that consists of a detachable bowl and a head closure, and a removable hollow fiber membrane cartridge positioned therein. The cartridge contains several concentric separation zones and provides for efficient countercurrent flow configuration between the feed gas on the shell side and the permeate sweep gas on the lumen side of the hollow fiber membranes.

Abstract: The present invention provides a hollow fiber membrane gas separation assembly having an integral purge control aperture or purge reflux system which is internal to the hollow fiber apparatus. The assembly is particularly useful for separating water vapor from a gas stream.

Abstract: An air drying system for a vehicle including an membrane air dryer is provided. The air dryer is supplied with a stream of compressed air that has a low and constant concentration of oil vapor. A coalescing filter element may be used to maintain the oil vapor concentration. The filtered material may be discharged from the coalescing filter by a pressure swing drain valve, which discharges the filtered material upon unloading of the compressor.

Abstract: Apparatus and methods are disclosed for using membranes to reduce the relative humidity of a compressed air stream. Air dryers employing membranes consist of a permeable membrane capable of blocking the passage of nitrogen and oxygen molecules, but allowing water vapor molecules to pass through. A membrane filter may be adapted to receive process flow of contaminated air. A sweep chamber may be positioned adjacent to filtration media to pass a portion of dried air back into contact with a portion of the membrane. A flow metering device may be positioned downstream from the membrane filter to adjust a portion of the air process flow as sweep air. The amount of process flow air diverted as sweep air may be proportional to the pressure and flow of the process flow. In some applications, an optional minimum pressure valve may be employed downstream of the sweep chamber to maintain a minimum threshold pressure of process air flow.

Abstract: An apparatus is disclosed for dehydrating gas in a system having control gas and supply gas. A first housing is fluidly connected to supply gas and a first membrane member is in the first housing flow path, with a plurality of tubes having interstitial spaces therebetween, each tube being more permeable to water vapor than to gas. Supply gas exiting the first membrane member is drier. Drier supply gas is metered to the first membrane member interstitial spaces, whereby dried supply gas sweeps water or water vapor from the first membrane member interstitial spaces to surrounding environment. A second housing similar to the first has a similar second membrane member therein and fluidly connected to control gas. Control gas exiting second membrane member is drier. Drier supply gas is also metered to second membrane member interstitial spaces, and sweeps water or water vapor from second member interstitial spaces through the second housing vent.

Abstract: Potassium or other alkali metal formate solution is used to absorb moisture from gas through a membrane. The membrane may be supported on permeable tubes, and the potassium or other alkali metal formate may be regenerated for reuse, preferably by a cavitation regenerator. The potassium or other alkali metal formate should be present as a 40-80% solution, most preferably 70-76%. The process is especially useful for the dehydration of natural gas.

Abstract: The present invention is to provide a method for regenerating inorganic porous particles, a method for purifying water and a continuous water purification device, which can be easily applied as a recycling system of water in special environments such as space environment, by safely removing impurities contained in water and water vapor with a usage of a compact facility without using any chemicals. The method for regenerating inorganic porous particles is characterized in that adsorbed products such as ammonia and/or amines, are reduced by heating to 100-200° C. under a reduced pressure of 10 Pa or less. The method for purifying water and the continuous water purification device are characterized in that a dense membrane having cationic groups and/or a composite membrane in which a hydrophilic membrane is layered on a surface of a hydrophobic porous membrane is used as a permeable membrane are used as a permeable membrane.

Abstract: Disclosed is a separation device for the separation of water vapour from a gas stream, comprising a water vapour separation membrane having a porous membrane, whose pores contain a water transfer material, the water transfer material including a first hydrophilic polymer and a second polymer which is interwoven with the first polymer.

Abstract: An apparatus and method for decontaminating chemical and biological agents using the reactive properties of both the single atomic oxygen and the hydroxyl radical for the decontamination of chemical and biological agents. The apparatus is self contained and portable and allows for the application of gas reactants directly at the required decontamination point. The system provides for the use of ultraviolet light of a specific spectral range to photolytically break down ozone into molecular oxygen and hydroxyl radicals where some of the molecular oxygen is in the first excited state. The excited molecular oxygen will combine with water vapor to produce two hydroxyl radicals.

Abstract: A compressed gas system utilizing a membrane air dryer is shown wherein, during unloading, additional sweep gas is provided to the membrane air dryer to prevent excess moisture from being introduced into the accumulator at the end of each unloading cycle. A membrane air drier for use in such system is also described.

Abstract: Water vapor is removed from a mixture of air, metabolic carbon dioxide (CO2), and water vapor prior to removing the CO2 from the mixture. The water vapor-containing mixture is passed through a membrane module which is operative to separate the water vapor from the air and CO2 mixture. The water vapor in the entering mixture will pass in one direction through the membrane in the module from an entry side of the membrane to an exit side of the membrane. The membrane divides the module into two chambers, one of which receives the water vapor-containing mixture, and the other of which receives CO2-free air from a CO2 adsorbant station. The water vapor-containing mixture is removed from a closed habitable environment such as a space station, a space suit, a submarine, or the like, and is moved through the membrane module where the water vapor is removed from the gas stream.

Abstract: A membrane air drier utilizes an orifice to serve as the sweep air inlet with a sweep diffuser placed a short distance from the orifice. Preferably, an open channel extends from the product end of the membrane module on the shell side of the fibers with a porous diffuser at one end of the open channel and an orifice at the other end of the channel.

Abstract: A process for separating nitrogen from a multicomponent gas mixture containing nitrogen and a hydrocarbon, such as natural gas or associated gas, using gas-separation membranes selective for nitrogen over the hydrocarbon. The membranes use a selective layer made from a polymer having repeating units of a fluorinated polymer, and demonstrate good resistance to plasticization by the organic components in the gas mixture under treatment, and good recovery after exposure to liquid aromatic hydrocarbons.

Abstract: The present invention provides a method for purifying a gas by contacting the gas with a liquid ionic compound. Natural gas may be purified, removing water and carbon dioxide, by contacting the natural gas with a liquid ionic compound.

Abstract: The method provides technical nitrogen instead of pure nitrogen in liquid form which has to be heated to be brought in gaseous form for laser cutting. Atmospheric air is compressed and driven through a cascade of high density bundles of hollow membrane fibers to permeate oxygen and air's component gases and yield technical nitrogen, and the pressure of the technical nitrogen is boosted to feed the laser cutting equipment. The method thus improves the laser cutting so as to avoid the drawbacks resulting from use of nitrogen in liquid form obtained by the cryogenic process by using technical nitrogen obtained via the aforesaid hollow fiber membrane technology in an efficient and cost effective manner.

Abstract: A process for treating natural gas or other methane-rich gas to remove excess nitrogen and optionally excess carbon dioxide, water vapor or hydrogen sulfide. The invention relies on gas separation by membranes, using nitrogen/methane selective membranes. The membranes are characterized by having the capability to exhibit a nitrogen/methane selectivity between about 2 and 5 at a temperature higher than about −25° C. The gas may be brought to pipeline specification for nitrogen, and acid gases if present, without requiring the use of amine scrubbing or other acid gas removal technique.