With Control Means Responsive To Sensed Condition Patents (Class 96/109)
  • Patent number: 3980479
    Abstract: Photographic elements, processes for forming images in photographic elements and new compounds are disclosed. Generally, the invention relates to immobile compounds which can be used to provide positive images from negative recording-developing photographic materials such as negative silver halide emulsions. The compounds contain a photographically useful group such as a dye or dye precursor and are capable of releasing said photographically useful group under alkaline conditions, and are also capable of reaction with an oxidized silver halide developing agent before substantial release of said photographically useful group occurs, to provide a reaction product having a substantially lower rate of release of said photographically useful group. In specific embodiments, the compounds of this invention contain an electrophilic cleavage group located in the linkage between a ballast group and a photographically useful moiety wherein said electrophilic cleavage group is a carbamic acid derivative.
    Type: Grant
    Filed: October 2, 1974
    Date of Patent: September 14, 1976
    Assignee: Eastman Kodak Company
    Inventors: Donald Lee Fields, Richard Paul Henzel, Philip Thiam Shin Lau, Richard Allan Chasman
  • Patent number: 3977880
    Abstract: A direct positive silver halide photographic emulsion comprising a hydrophilic colloid containing (1) silver halide grains the surface of which is fogged with a sulfur compound and a gold compound, or (2) silver halide grains which are (a) ripened with a sulfur compound and then the surface of which is fogged by optical exposure or (b) ripened with a sulfur compound and a gold compound and then the surface of which is fogged by optical exposure.
    Type: Grant
    Filed: October 18, 1974
    Date of Patent: August 31, 1976
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Mitsuo Saito
  • Patent number: 3969117
    Abstract: A lith-type light-sensitive silver halide photographic material which gives a hard tone and sharp dot image contains in the emulsion layer or one of the layers adjacent thereto a hydroimidazo-s-triazine compound and a polyalkylene oxide derivative.
    Type: Grant
    Filed: June 11, 1974
    Date of Patent: July 13, 1976
    Inventors: Hidemaru Sakai, Shigeji Baba
  • Patent number: 3967965
    Abstract: A photographic light-sensitive material comprising a support having thereon at least one silver halide photographic emulsion layer and at least one of the layers of the photographic light-sensitive material containing a compound represented by the following general formula (I) or (II); ##EQU1## wherein R.sub.1, R.sub.2 and R.sub.3 each represents a hydrogen atom, an alkyl group, an aryl group or a heterocyclic residue, or R.sub.1 and R.sub.2 can combine to form a ring; and Z represents an alkylene group; or an organic acid salt or a mineral acid salt of the compound represented by the general formula (I) or (II). The photographic material can be developed at an elevated temperature without fog information and a decrease in photographic sensitivity.
    Type: Grant
    Filed: January 14, 1975
    Date of Patent: July 6, 1976
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keiichi Adachi, Akikazu Mikawa, Ikutaro Horie, Hisashi Shiraishi
  • Patent number: 3957490
    Abstract: Silver halide emulsions are prepared by silver halide precipitation in the presence of a reducing agent, physical ripening and, if desired, chemical ripening wherein subsequent to the addition of reducing agent and before the grains have reached their final size an oxidizing agent is added to the emulsion. By means of the reducing and oxidizing agents, the gradation and photosensitivity characteristics of the emulsion can be controlled at will.
    Type: Grant
    Filed: April 25, 1974
    Date of Patent: May 18, 1976
    Assignee: AGFA-GEVAERT N.V.
    Inventors: Marcel Jan Libeer, Frans Henri Claes
  • Patent number: 3957493
    Abstract: A thermodevelopable light-sensitive material having a reduced frequency to fog formation by heat, comprising a support and at least one layer containing (a) an organic silver salt, (b) a catalytic amount of a light-sensitive silver halide or a compound capable of forming a light-sensitive silver halide by reaction with the organic silver salt (a), (c) a reducing agent (d) a binder, and (e) an N-haloacetamide. In order to increase the transparency of the thermodevelopable photographic layer of the material and the density of the image and to improve its preservability, a topcoating of polymer can be formed on the light-sensitive layer.
    Type: Grant
    Filed: December 26, 1973
    Date of Patent: May 18, 1976
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takao Masuda, Keiichi Adachi
  • Patent number: 3957491
    Abstract: A silver halide photographic material having improved sensitivity unaccompanied by an increase in fog formation containing, in a photographic layer thereof, an organic compound having a nitrogen-halogen bond in the molecule.
    Type: Grant
    Filed: September 4, 1973
    Date of Patent: May 18, 1976
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Reiichi Ohi, Keiichi Adachi, Norihiko Katoh, Kimitaka Kameoka, Mitsunori Sugiyama, Toshiaki Aono
  • Patent number: 3955982
    Abstract: A stabilizer precursor comprising a certain halo organic compound having a halogen substituent which is a chlorine, bromine or iodine atom in a photothermographic element or composition provides improved post-processing stability. This stabilizer precursor is useful in photothermographic materials, for example, comprising photosensitive silver salt and an oxidation-reduction image-forming combination comprising a heavy metal salt oxidizing agent with a reducing agent. Certain of the halo organic compounds are incubation antifoggants for certain of the photothermographic materials.
    Type: Grant
    Filed: February 12, 1975
    Date of Patent: May 11, 1976
    Assignee: Eastman Kodak Company
    Inventors: James A. VanAllan, Ronald H. Ericson, Lorenzo F. Costa
  • Patent number: 3954478
    Abstract: A silver halide light-sensitive material which comprises a light-sensitive silver halide emulsion containing a compound represented by the following formula (I): ##SPC1##wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 each represents a hydrogen atom or a lower alkyl group; and R.sub.6 and R.sub.7 each represents a hydrogen atom, a lower alkyl group or a lower alkoxy group or can combine to form a condensed ring, and X.sup.- represents an anion.
    Type: Grant
    Filed: December 23, 1974
    Date of Patent: May 4, 1976
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Naoki Arai, Reiichi Ohi
  • Patent number: 3954474
    Abstract: A method of developing an exposed silver halide photographic material having a silver halide emulsion layer containing a heterocyclic compound having at least one nitrogen atom, having a thione group which does not undergo enolation positioned next to the nitrogen atom, and not having a nitro group in an aldehyde type hardening agent containing developer at a temperature of not less than about 30.degree.C.
    Type: Grant
    Filed: August 20, 1974
    Date of Patent: May 4, 1976
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Akikazu Mikawa, Tadao Shishido, Shoji Ishiguro
  • Patent number: 3953531
    Abstract: 2,5-BIS-(1',1'-Dimethylbutyl)hydroquinone and a process for the production thereof which comprises reacting hydroquinone with 2-methyl-1-pentene.
    Type: Grant
    Filed: December 19, 1974
    Date of Patent: April 27, 1976
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Reiichi Ohi
  • Patent number: 3951661
    Abstract: Substances of the structure ##EQU1## wherein Z is phosphorus, X.sup.-is Cl.sup.-, Br.sup.-, ClO.sub.2 .sup.- or BF.sub.4 .sup.-, and R.sub.1 - R.sub.4 are alkyl or aromatic groups are excellent inhibitors of fog formation when incorporated in photographic emulsions containing silver halides.
    Type: Grant
    Filed: May 24, 1974
    Date of Patent: April 20, 1976
    Assignees: Konishiroku Photo Industry Co., Sankyo Company Limited
    Inventors: Nobuo Soma, Isao Kawamoto, Tomio Nakajima, Sadao Sugita, Tsuneo Wada, Shizuo Saito, Hiroyuki Inokuma, Koichi Horigome, Yukio Morifuji
  • Patent number: 3947274
    Abstract: A photographic light-sensitive material comprising a support having thereon at least one silver halide photographic emulsion layer with at least one of the layers of the photographic light-sensitive material containing a compound represented by the following general formula (I) or (II) ##EQU1## wherein R.sub.1, R.sub.2, and R.sub.3 each represents a hydrogen atom, an alkyl group, an aryl group or a heterocyclic ring residue, and R.sub.2 and R.sub.3 can combine to form an alkylene group; R.sub.4 represents those groups other than a hydrogen atom as described for R.sub.1, R.sub.2 and R.sub.3 ; and R.sub.5 represents an alkylene group of a polyoxyalkylene group having at least 4 carbon atoms, or the organic acid salt or mineral acid salt thereof.
    Type: Grant
    Filed: May 14, 1974
    Date of Patent: March 30, 1976
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Akikazu Mikawa, Ikutaro Horie, Keiichi Adachi, Hisashi Shiraishi
  • Patent number: 3945829
    Abstract: Heterocyclic mercapto compounds are added to a binder layer containing colloidal silver which is comprised in a color photographic multilayer material. The colloidal silver layer may be a yellow filter layer to prevent exposure of the green, and red recording layers to blue light, or an antihalation layer arranged between the layer support and the lowermost light sensitive silver halide emulsion layer. The heterocyclic mercapto compounds reduce the contact fog produced in the (first) developer and increase color density in reversal processing. Additionally there can be present in the colloidal silver layer a sensitizer for the blue, green or red spectral region.
    Type: Grant
    Filed: July 15, 1974
    Date of Patent: March 23, 1976
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Hugo Zorn, Karl Kuffner, Hans Glockner, Jozef Frans Willems, Robrecht Julius Thiers
  • Patent number: 3936300
    Abstract: The present invention is directed to novel photographic products for use in color diffusion transfer systems wherein at least one of the layers of the film unit contains an amount of a glucoside humectant effective to stabilize the silver halide emulsion(s) thereof against fog during storage.
    Type: Grant
    Filed: August 30, 1974
    Date of Patent: February 3, 1976
    Assignee: Polaroid Corporation
    Inventor: Paul A. Cardone
  • Patent number: 3933498
    Abstract: Direct positive silver halide materials based on the Herschel effect having substantially reduced sensitivity to room light exposure contain a heterocyclic compound to prevent white light bleaching along with a second heterocyclic compound to prevent latent image formation due to white light exposure.
    Type: Grant
    Filed: September 28, 1973
    Date of Patent: January 20, 1976
    Assignee: E. I. Du Pont de Nemours and company
    Inventors: Leewellyn C. Fischer, Heman Dowd Hunt
  • Patent number: 3932185
    Abstract: A multi-layer photosensitive material for color photography comprising a support and coated thereon, a first color image-forming layer unit composed of a red-sensitive silver halide emulsion, a second color image-forming layer unit composed of a green-sensitive silver halide emulsion and a third color image-forming layer unit composed of a blur-sensitive silver halide emulsion; characterized in that at least one of said color image-forming layer units has a composite layer structure including a lower layer and an upper layer which are positioned in sequence from the support, said upper layer has a higher sensitivity and a lower maximum developed color density than said lower layer, and at least one of said upper layer and lower layer contains a mercaptan type development inhibitor-releasing compound capable of reacting with an oxidation product of a primary aromatic amine to form a substantially colorless compound.
    Type: Grant
    Filed: August 12, 1974
    Date of Patent: January 13, 1976
    Assignee: Konishiroku Photo Industry Co., Inc.
    Inventor: Katsumi Matsuura
  • Patent number: 3932480
    Abstract: Novel compounds are disclosed which release a silver halide solvent in the presence of alkali, which compounds may be defined as quinone-or naphthoquinone-methide precursors containing the silver halide solvent moiety. These novel compounds are useful in photographic products and processes.
    Type: Grant
    Filed: May 3, 1974
    Date of Patent: January 13, 1976
    Assignee: Polaroid Corporation
    Inventors: J. Michael Grasshoff, Lloyd D. Taylor