Plural Layers (e.g., Laminated Barrier, Etc.) Patents (Class 96/11)
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Patent number: 8882875Abstract: Various high performance, high efficiency filter media are provided that are cost effective and easy to manufacture. In particular, various filter media are provided having at least one layer with a waved configuration that results in an increased surface area, thereby enhancing various properties of the filter media. The filter media can be used to form a variety of filter elements for use in various applications.Type: GrantFiled: August 2, 2012Date of Patent: November 11, 2014Assignee: Hollingsworth & Vose CompanyInventor: David T. Healey
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Patent number: 8876948Abstract: A method of making a composite gas separation module by providing a porous support material having deposited thereon a metal membrane layer, by imposing upon the surface of the metal membrane layer certain surface characteristics including an abrasion pattern and a relatively high surface roughness that provides for surface activation that enhances the placement thereon of a subsequent metal membrane layer without the use of a chemical activating solution. The composite gas separation module is useful in the separation of hydrogen from hydrogen-containing gas streams.Type: GrantFiled: December 18, 2012Date of Patent: November 4, 2014Assignee: Shell Oil CompanyInventor: John Charles Saukaitis
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Patent number: 8876949Abstract: A method of preparing a palladium-silver alloy gas separation membrane system, wherein the surface of the palladium layer or a silver layer is activated by a non-chemical activation method involving abrasion to a controlled surface roughness and abrasion pattern, thereby permitting the plating or deposition of an overlayer of silver on the palladium layer, silver on a silver layer, or palladium on a silver layer. The palladium and silver layers are preferably supported on a porous metal support to which an intermetallic diffusion barrier has been applied.Type: GrantFiled: December 18, 2012Date of Patent: November 4, 2014Assignee: Shell Oil CompanyInventor: John Charles Saukaitis
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Publication number: 20140318373Abstract: Apparatuses and systems for removing water vapor from a gas stream and for providing water purification, recovery and/or concentration. The apparatuses and systems employ a graphene oxide or a perforated graphene monolayer membrane to separate liquid water molecules and/or water vapor molecules from gasses, liquids, and other substances such as a wet muck or an aqueous sample. In one embodiment, an apparatus for removing water from a gas or liquid stream includes a first lumen, a second lumen, and a graphene oxide membrane separating the first lumen from the second lumen. Water molecules within a humid gas or liquid stream introduced into the first lumen pass through the graphene oxide membrane into a dry gas stream introduced into the second lumen.Type: ApplicationFiled: April 24, 2014Publication date: October 30, 2014Applicant: LOCKHEED MARTIN CORPORATIONInventors: John A. Wood, Rebecca Schwartz, Paul J. Lilly
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Publication number: 20140318374Abstract: A ventilation member (10) includes an air-permeable membrane (2), a support body (4), a cover body (6), and a column portion (8). The support body (4) has a through hole (14) serving as an air passage. The through hole (14) includes (a) a first portion (14a) having a relatively large inner diameter and (b) a second portion (14b) having a relatively small inner diameter. An annular ridge portion (12) is formed on an outer peripheral surface of the support body (4) along a circumferential direction of the support body (4). When the housing (20) has a nozzle opening portion (22), the ventilation member (10) is attached to the housing (20) by inserting the nozzle opening portion 22 into the support body 4. When the housing (20) has a recess opening portion (24), the ventilation member (10) is attached to the housing (20) by fitting the support body (4) into the recess opening portion (24).Type: ApplicationFiled: November 21, 2012Publication date: October 30, 2014Inventor: Youzou Yano
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Publication number: 20140322518Abstract: A method and porous multi-component material for the capture, separation or chemical reaction of a species of interest is disclosed. The porous multi-component material includes a substrate and a composite thin film. The composite thin film is formed by combining a porous polymer with a nanostructured material. The nanostructured material may include a surface chemistry for the capture of chemicals or particles. The composite thin film is coupled to the support or device surface. The method and material provides a simple, fast, and chemically and physically benign way to integrate nanostructured materials into devices while preserving their chemical activity.Type: ApplicationFiled: April 24, 2013Publication date: October 30, 2014Inventors: Raymond S. Addleman, Wilaiwan Chouyyok, Xiaohong S. Li, Anthony D. Cinson, Aleksandr A. Gerasimenko
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Patent number: 8871010Abstract: A plasma spray method for the manufacture of an ion conductive membrane is provided which ion conductive membrane has an ion conductivity, in which method the membrane is deposited as a layer (11) onto a substrate (10) in a process chamber, wherein a starting material (P) is sprayed onto a surface of the substrate (10) in the form of a process beam (2) by means of a process gas (G), wherein the starting material is injected into a plasma at a low process pressure, which is at most 10,000 Pa, and is partially or completely molten there. Oxygen (O2; 22) is supplied to the process chamber (12) during the spraying at a flow rate which amounts to at least 1%, preferably at least 2%, of the overall flow rate of the process gas.Type: GrantFiled: March 15, 2012Date of Patent: October 28, 2014Inventors: Malko Gindrat, Rajiv J. Damani
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Publication number: 20140311345Abstract: A hydration container includes a hydration regulator, and an impermeable main body, lid, and sealing structure. The main body includes a main cavity for storage of one or more items or substances. The main body and lid engage via threads. A hydration regulator regulates the moisture level within the main cavity, and is fixed to an upper inner lid surface. The sealing structure includes a seal aperture, and can be fixed to the upper inner lid surface or the hydration regulator with the seal aperture exposing at least a portion of the hydration regulator. A hydration container can optionally include a grinding element and/or a hydration seal.Type: ApplicationFiled: September 23, 2013Publication date: October 23, 2014Inventor: JAMES PETER MORRISSETTE
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Publication number: 20140311346Abstract: A method of producing a composite oxygen ion membrane and a composite oxygen ion membrane in which a porous fuel oxidation layer and a dense separation layer and optionally, a porous surface exchange layer are formed on a porous support from mixtures of (Ln1-xAx)wCr1-yByO3-? and a doped zirconia. In the porous fuel oxidation layer and the optional porous surface exchange layer, A is Calcium and in the dense separation layer A is not Calcium and, preferably is Strontium. Preferred materials are (La0.8Ca0.2)0.95Cr0.5Mn0.5O3-? for the porous fuel oxidation and optional porous surface exchange layers and (La0.8Sr0.2)0.95Cr0.5Fe0.5O3-? for the dense separation layer. The use of such materials allows the membrane to sintered in air and without the use of pore formers to reduce membrane manufacturing costs. The use of materials, as described herein, for forming the porous layers have application for forming any type of porous structure, such as a catalyst support.Type: ApplicationFiled: July 3, 2014Publication date: October 23, 2014Inventors: Gervase Maxwell Christie, Jonathan A. Lane
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Publication number: 20140298994Abstract: The present invention relates to a multilayer module for hydrogen separation using a pressure-resistant chamber so that unit cells using a metal separation membrane through which only hydrogen selectively passes are stacked to improve separation efficiency, and a mixed gas is uniformly supplied into each of the unit cells. In the multilayer module, the unit cells are stacked on each other, and the mixed gas is supplied into the chamber. Also, mixed gas input ports are each disposed in the side surfaces of the unit cells to supply the mixed gas.Type: ApplicationFiled: August 8, 2012Publication date: October 9, 2014Applicant: KOREA INSTITUTE OF ENERGY RESEARCHInventors: Jong-Soo Park, Kyung-Ran Hwang, Shin-Kun Ryi, Chun-Boo Lee, Sung-Wook Lee, Jin-Woo Park
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Patent number: 8852324Abstract: A venting device for a housing, for example, a battery housing, has a gas-permeable and liquid-impermeable membrane attached to the housing so as to close off a venting opening of the housing. The membrane has a membrane section that overlaps and covers the venting opening. The membrane section has a predetermined bursting pressure. The membrane section deforms without being destroyed when pressure differences between the interior of the housing and the environment occur that are below the bursting pressure and when gas passes through the membrane section.Type: GrantFiled: April 2, 2012Date of Patent: October 7, 2014Assignee: Mann+Hummel GmbHInventors: Sascha Bauer, Stefan Maier, Robert Zbiral, Markus Beylich
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Patent number: 8840711Abstract: A modular element having a high-temperature stable main body, including at least one metallic or ceramic plate, which has at least one through-going aperture for the insertion of a ceramic capillary membrane and at least one potting in the form of a sufficiently gas-tight and high-temperature stable joint between the metallic or ceramic plate and the ceramic capillary membrane. The through-going aperture of the metallic or ceramic plate having an extension for accommodating the sufficiently gas-tight and high-temperature stable joint on at least one side of the metallic or ceramic plate.Type: GrantFiled: August 25, 2010Date of Patent: September 23, 2014Assignees: Thyssenkrupp Uhde GmbH, Borsig Process Heat Exchanger GmbHInventors: Steffen Schirrmeister, Bernd Langanke, Thomas Schiestel, Björn Hoting
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Publication number: 20140262894Abstract: A gas sterilization package component having (a) a gas diversion wall stock for at least a portion of a container, the wall stock having an opening therethrough; (b) a gas diversion layer; (c) a filter sheet disposed between (a) and (b), the filter sheet having a first surface and an opposing second surface circumscribed by a perimeter edge; and wherein the first surface of the filter sheet is attached to a surface of said gas diversion layer and the second surface of the filter sheet is sealed to a surface of the wall stock whereby an opening in the wall stock is covered by the filter sheet and a gas passageway is defined from the opening through a portion of the second surface of the filter sheet and extending through said filter perimeter edge.Type: ApplicationFiled: March 15, 2013Publication date: September 18, 2014Inventor: Christopher Rene Jansen
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Patent number: 8834612Abstract: A hydrogen separation apparatus, provided with an independent hydrogen permeable membrane, capable of suppressing or preventing deformation of the hydrogen permeable membrane. The hydrogen separation apparatus includes a porous support member, an independent hydrogen permeable membrane disposed adjacent to the porous support member, and a joining member for joining the porous support member and the hydrogen permeable membrane. A production process for the hydrogen separation apparatus includes (1) disposing a joining member forming material at a surface side of a porous support member, to be opposite to an independent hydrogen permeable membrane, (2) disposing the independent hydrogen permeable membrane adjacent to the porous support member at the surface side of the porous support member to which surface side the joining member forming material is disposed, and (3) joining the porous support member and the independent hydrogen permeable membrane with the joining member forming material.Type: GrantFiled: June 5, 2008Date of Patent: September 16, 2014Assignee: Nissan Motor Co., Ltd.Inventors: Maki Hoshino, Takao Izumi
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Patent number: 8834604Abstract: A membrane for use in a high temperature gas processing system and method for making the same. The membrane includes a dense, gas impermeable layer and a first and second porous layer, wherein each of the first and second porous layers is a ceramic oxide material having a non-symmetrical load bearing skeleton of a plurality of pores having a graded porosity. Each porous layer provides a reduction of an oxygen partial pressure gradient across the dense layer and reduces resultant stresses in the dense layer that are small compared to its strength thereby improving long term mechanical durability of the dense layer.Type: GrantFiled: September 16, 2011Date of Patent: September 16, 2014Assignee: Volt Research, LLCInventors: Ajit Y. Sane, Thomas L. Cable
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Patent number: 8828119Abstract: A membrane cartridge is manufactured by repeatedly folding and joining two strips of membrane to form a cross-pleated cartridge with a stack of openings or fluid passageways configured in an alternating cross-flow arrangement. The cartridge can be modified for other flow configurations including co-flow and counter-flow arrangements. Methods for manufacturing such cross-pleated membrane cartridges, as well as apparatus used in the manufacturing process are described. Cross-pleated membrane cartridges comprising water-permeable membranes can be used in a variety of applications, including in heat and water vapor exchangers. In particular they can be incorporated into energy recovery ventilators (ERVs) for exchanging heat and water vapor between air streams being directed into and out of buildings.Type: GrantFiled: November 12, 2013Date of Patent: September 9, 2014Assignee: DPoint Technologies Inc.Inventors: Greg Montie, James Franklin Dean, Curtis Mullen, Robert Hill
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Patent number: 8828120Abstract: A device for separating a gas mixture into product gas and offgas by way of gas permeation includes four membrane units and a compressor connected upstream of the first membrane unit. The membrane units have a gas inlet, a retentate outlet and a permeate outlet. Lines connect the membrane units to each other and to the compressor. Product gas is obtained via the permeate outlet of the second membrane unit and offgas via the retentate outlet of the first membrane unit. Additional product gas is obtained via the retentate outlet of an upstream membrane unit and additional offgas is obtained via the permeate outlet of a further upstream membrane unit. A method includes use of the device to separate a gas mixture into product gas and offgas.Type: GrantFiled: April 16, 2010Date of Patent: September 9, 2014Assignee: Axiom Angewandte Prozesstechnik Ges. m.b.H.Inventors: Johannes Szivacz, Michael Harasek
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Patent number: 8821616Abstract: DDR nanocrystals were synthesized using hydrothermal secondary growth. The morphology of the nanoparticles can be manipulated by changing the ratio of silica to water, the synthesis temperature, and the mineralizing agents. Specifically, nanocrystals with morphology of hexagonal plates, octahedral, and diamond-like plates are disclosed. These nanoparticles can be used as seed coatings for DDR membrane growth on substrates, and for the fabrication of mixed matrix membranes, and for any other use where uniform, small DDR zeolite crystals are beneficial.Type: GrantFiled: February 14, 2012Date of Patent: September 2, 2014Assignee: Georgia Tech Research CorporationInventors: Zhengzhi Zhou, Sankar Nair
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Publication number: 20140230649Abstract: A gas separation method includes flowing a gas feed along a feed flow path within a housing directionally from a product end to a feed end of a gas separation membrane. After the feed flow path, the gas feed flows along a membrane flow path defined by the membrane from the feed end to the product end. The feed flow path is counter to the membrane flow path. Heat may be exchanged between the feed flow path and the membrane flow path and increase separation efficiency. Also, heat exchanged may compensate for some temperature drop in the membrane due to enthalpy of gas separation. A gas separation module includes a feed flow path within a housing extending directionally from a product end to a feed end of a membrane. The feed flow path is counter to a membrane flow path defined by the membrane.Type: ApplicationFiled: February 19, 2013Publication date: August 21, 2014Applicant: THE BOEING COMPANYInventor: The Boeing Company
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Publication number: 20140230653Abstract: Methods for forming an ultrathin GO membrane are provided. The method can include: dispersing a single-layered graphene oxide powder in deionized water to form a single-layered graphene oxide dispersion; centrifuging the graphene oxide dispersion to remove aggregated graphene oxide material from the single-layered graphene oxide dispersion; thereafter, diluting the single-layered graphene oxide dispersion by about ten times or more through addition of deionized water to the graphene oxide dispersion; and thereafter, passing the single-layered graphene oxide dispersion through a substrate such that a graphene oxide membrane is formed on the substrate. Filtration membranes are also provided and can include: a graphene oxide membrane having a thickness of about 1.8 nm to about 180 nm, with the graphene oxide membrane comprises about 3 to about 30 layers of graphene oxide flakes.Type: ApplicationFiled: February 14, 2014Publication date: August 21, 2014Inventors: Miao Yu, Hang Li
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Publication number: 20140220462Abstract: [Problem] The object of the invention is to provide the filter device disposed in the moist fluid passage of the fuel cell system in that, water is not adhered and never remains in the filter and when leaving it under the low temperature after the system stops, blockage by freezing the filter can surely be prevented, and the complex control and the heat source such as heaters for the decompression as conventional is unnecessary, and the filter device is cheap and compact.Type: ApplicationFiled: August 30, 2012Publication date: August 7, 2014Applicants: NISSAN MOTOR CO., LTD., KABUSHIKI KAISHA SAGINOMIYA SEISAKUSHOInventors: Tsuyoshi Takeda, Kazuhiko Osawa, Daisaku Inamura, Ichiro Okawara, Takatada Usami, Shinichiro Takemoto
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Patent number: 8795417Abstract: A method of producing a composite oxygen ion membrane and a composite oxygen ion membrane in which a porous fuel oxidation layer and a dense separation layer and optionally, a porous surface exchange layer are formed on a porous support from mixtures of (Ln1-xAx)wCr1-yByO3-? and a doped zirconia. In the porous fuel oxidation layer and the optional porous surface exchange layer, A is Calcium and in the dense separation layer A is not Calcium and, preferably is Strontium. Preferred materials are (La0.8Ca0.2)0.95Cr0.5Mn0.5O3-? for the porous fuel oxidation and optional porous surface exchange layers and (La0.8Sr0.2)0.95Cr0.5Fe0.5O3-? for the dense separation layer. The use of such materials allows the membrane to sintered in air and without the use of pore formers to reduce membrane manufacturing costs. The use of materials, as described herein, for forming the porous layers have application for forming any type of porous structure, such as a catalyst support.Type: GrantFiled: October 4, 2012Date of Patent: August 5, 2014Assignee: Praxair Technology, Inc.Inventors: Gervase Maxwell Christie, Jonathan A. Lane
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Patent number: 8784542Abstract: The invention relates to a nanofiber membrane layer having a basis weight of 0.01-50 g/m2 and a porosity of 60-95%, comprising a nanoweb made of polymeric nanofibers with a number average diameter in the range of 50-600 nm, consisting of a polymer composition comprising a semicrystalline polyamide having a C/N ratio of at most 5.5. The invention also relates to water and air filtration devices comprising such a nanofiber membrane layer.Type: GrantFiled: July 15, 2010Date of Patent: July 22, 2014Assignee: DSM IP Assets B.V.Inventors: Konraad Albert Louise Hector Dullaert, Marko Dorschu, Arnaud David Henri Chiche
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Patent number: 8784541Abstract: Composite-membrane monoliths include a cordierite monolith having a cordierite-ceramic composite membrane bonded to surfaces thereof with a surface median pore size. The cordierite-ceramic composite membrane has membrane surfaces with a membrane median pore size of 0.3 ?m or less. The cordierite-ceramic composite membrane may be a composite formed by firing the cordierite monolith subsequent to applying a cordierite-ceramic composite slip to surfaces thereof. The cordierite-ceramic slip may include cordierite particles and ceramic particles. The cordierite particles may have a cordierite median particle size smaller than the surface median pore size. The ceramic particles may have a ceramic median particle size smaller than the cordierite median particle size.Type: GrantFiled: November 10, 2011Date of Patent: July 22, 2014Assignee: Corning IncorporatedInventors: Joel Edward Clinton, Yunfeng Gu
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Patent number: 8778054Abstract: A method for generating heat energy in a power plant by burning a carbonaceous fuel in a combustion chamber of the power plant and a system for carrying out the method is described. A combustion chamber is fluidly connected to a membrane chamber that includes a membrane operating at a temperature between 600 and 1000° C. The combustion chamber receives a cleaned flue-gas oxygen mixture for combustion from the membrane chamber. Oxygen from heated air passes through the membrane in the membrane chamber to the permeate side of the membrane, where it is mixed with cleaned heated flue gas and the resulting gas mixture is fed to the combustion chamber. Flue gas removed from the combustion chamber are cooled, cleaned and heated as described herein and recirculated to the membrane chamber.Type: GrantFiled: April 3, 2010Date of Patent: July 15, 2014Assignee: Forschungszentrum Juelich GmbHInventors: Jewgeni Nazarko, Ernst Riensche, Reinhard Menzer, Wilhelm Albert Meulenberg, Stefan Baumann
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Patent number: 8778058Abstract: The invention relates to thin, hydrogen-permeable, sulfur-resistant membranes formed from multi-layers of palladium or palladium-alloy coatings on porous, ceramic or metal supports, methods of making these membranes, methods of repairing layers of these membranes and devices that incorporate these membranes.Type: GrantFiled: July 15, 2011Date of Patent: July 15, 2014Assignee: Colorado School of MinesInventors: J. Douglas Way, Oyvind Hatlevik
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Patent number: 8778056Abstract: There are provided a process for producing a zeolite membrane which, even when large, has few defects and which has higher separation performance than conventional zeolite membranes, and a zeolite membrane obtained by the process. In the process, the structure-directing agent is removed in the atmosphere having an O2 concentration of 22.0 vol % or more. Specifically, the process includes: a particle adhesion step of allowing zeolite particles functioning as seeds to flow down the surface of the substrate by means of the weight of the slurry itself, thereby adhering to the substrate and a membrane-forming step of forming a zeolite membrane on the substrate by immersing the substrate having the zeolite particles adhering thereto in sol containing the structure-directing agent for hydrothermal synthesis, thereby forming a zeolite membrane on the substrate.Type: GrantFiled: July 9, 2012Date of Patent: July 15, 2014Assignee: NGK Insulators, Ltd.Inventors: Tetsuya Uchikawa, Kenji Yajima, Makiko Niino
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Patent number: 8771404Abstract: A composite hollow ceramic fiber includes a porous hollow core supporting a thin, dense sheath. The non-gas-tight core comprises a first ceramic material and an interconnecting network of pores. The gas-tight sheath comprises a second ceramic material. The fiber is made by extruding a core suspension of particles of the first ceramic material, a polymeric binder, and a solvent and a sheath suspension of particles of the second ceramic material, a polymeric binder and a solvent, respectively, from a spinnerette and coagulating the nascent hollow fiber to effect phase inversion of the polymeric binders. The resultant green fiber is sintered in a two step process. First, the binders are burned off. Second, the sheath is densified and the second ceramic material is sintered without fully sintering the first ceramic material. The first ceramic material of the core suspension has a median particle size greater than that of the second ceramic material of the sheath suspension.Type: GrantFiled: July 31, 2011Date of Patent: July 8, 2014Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Tao Li, Taekyu Kang
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Publication number: 20140183135Abstract: The invention is directed to a nanosieve composite membrane, a method for preparing a nanosieve composite membrane, a roll-to-roll apparatus for carrying out the method, and a method for separating a feed flow with particulate matter. The nanosieve composite of the invention comprises an inorganic nanosieve layer supported on a porous polymer membrane substrate and a metallic adhesion layer or underlayer between the inorganic nanosieve layer and the polymer substrate, wherein said polymer membrane comprises an inorganic coating such that the polymeric support is sandwiched between the inorganic coating and the inorganic sieve layer, and wherein said inorganic nanosieve layer has an average pore diameter as determined by scanning electron microscopy of 200 nm or less.Type: ApplicationFiled: April 26, 2012Publication date: July 3, 2014Applicant: Nederlandse Organisatie voor toegepast- natuurwetenschappelijk onderzoek TNOInventors: Sandeep Unnikrishnan, Edward Willem Albert Young
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Patent number: 8764889Abstract: There is provided a silica membrane filter having performance of selectively separating an aromatic compound and performance of selectively separating an alcohol. The silica membrane filter is provided with a porous substrate and a silica membrane. The ratio of a He gas permeation amount to an N2 gas permeation amount (He gas permeation amount/N2 gas permeation amount) is 7 or less, and the ratio of the N2 gas permeation amount to a SF6 gas permeation amount (N2 gas permeation amount/SF6 gas permeation amount) is 1.5 or more.Type: GrantFiled: December 27, 2012Date of Patent: July 1, 2014Assignee: NGK Insulators, Ltd.Inventors: Mariko Takagi, Kenichi Noda, Nobuhiko Mori, Masaaki Kawai, Aya Satoh
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Patent number: 8764888Abstract: There is provided herein a dryer polymer substance including a hetero-phase polymer composition including two or more polymers wherein at least one of the two or more polymers include sulfonic groups, wherein the substance is adapted to pervaporate a fluid. The fluid may include water, water vapor or both. There is also provided herein a process for the preparation of a dryer polymer substance adapted to pervaporate a fluid (such as water, water vapor or both) the process includes mixing two or more polymers, wherein at least one of the two or more polymers may include groups which are adapted to be sulfonated, to produce a hetero-phase polymer composition and processing the polymer blend into a desired form.Type: GrantFiled: August 22, 2013Date of Patent: July 1, 2014Assignee: Oridion Medical 1987 Ltd.Inventors: Amos Ophir, Eyal Cohen, David Dishon, Joshua Lewis Colman
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Patent number: 8764881Abstract: A membrane suitable for separating a gas from a gas mixture comprising a non cross-linked PVAm having a molecular weight of at least Mw 100,000 carried on a support wherein after casting onto the support, said PVAm has been heated to a temperature in the range 50 to 150° C., e.g. 80 to 120° C.Type: GrantFiled: February 2, 2010Date of Patent: July 1, 2014Assignee: Norwegian University of Science and TechnologyInventors: Marius Sandru, Taek-Joong Kim, May-Britt Hägg
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Patent number: 8764887Abstract: Embodiments of the invention relate to a method for preparing crystalline metal-organic frameworks (MOFs). The method includes the steps of providing an electrolyte solution in contact with a conductive surface, and applying a current or potential to the conductive surface in contact with the electrolyte solution. The electrolyte solution includes a protonated organic ligand, a metal ion, and a probase. Application of the reductive current or potential to the conductive surface produces the crystalline metal-organic framework (MOF) deposited on the conductive surface. The MOFs produced by the method may be incorporated into a gas separation membrane, a purification filter, and/or a sensor.Type: GrantFiled: April 4, 2012Date of Patent: July 1, 2014Assignee: Massachusetts Institute of TechnologyInventors: Mircea Dinca, Minyuan Li
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Publication number: 20140174290Abstract: To provide a CO2 membrane separation and recovery system that is excellent in CO2 permeability and CO2 separation. selectivity on recovery of CO2 in a hydrogen production process and the like. The CO2 membrane separation and recovery system of the present invention comprises a dehydration treatment module (2) preliminary to a CO2 membrane separation module (1), the CO2 membrane separation module (1) comprises a hydrophilic zeolite membrane (3) that exhibits CO2 selective permeability and is formed on a porous substrate, and the hydrophilic zeolite membrane (3) is subjected to a dehydration treatment by a heat treatment at from 100 to 800° C.Type: ApplicationFiled: May 9, 2012Publication date: June 26, 2014Applicants: JX NIPPON OIL & ENERGY CORPORATION, HITACHI ZOSEN CORPORATIONInventors: Ken-ichi Sawamura, Masanobu Aizawa, Takehiro Shimizu
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Patent number: 8758488Abstract: Vents for containers include a perforated substrate portion (20) of polymer material over which is thermally bonded a gas permeable membrane (30). The thermal bond (31) is direct and adhesive-free so that there is no adhesive available for chemical attachment by materials within the containers (58) and no opportunity for an adhesive to interfere with or block perforations through the substrate.Type: GrantFiled: March 26, 1999Date of Patent: June 24, 2014Assignee: Nuclear Filter Technology, Inc.Inventor: Terry J. Wickland
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Publication number: 20140165837Abstract: The present invention provides a carbon dioxide separation membrane having a grafted chain into which a substituent having high selective affinity for carbon dioxide is introduced and thus having high carbon dioxide separation capability. The present invention is a method for producing a carbon dioxide separation membrane. This method includes the steps of: (1) irradiating a polymer film with radiation; (2) forming, in the irradiated polymer film, a grafted chain containing a repeating unit of a monomer having a substituent capable of forming a salt with a fluoride ion; and (3) subjecting the substituent capable of forming a salt with a fluoride ion to treatment with a fluoride salt so as to form a salt with a fluoride ion in the substituent.Type: ApplicationFiled: August 13, 2012Publication date: June 19, 2014Applicant: NITTO DENKO CORPORATIONInventors: Naomichi Kimura, Hideyuki Emori, Hiroyuki Nishii, Takuji Shintani
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Patent number: 8753433Abstract: The invention relates to a diaphragm pipe for permeative separation of hydrogen from gas mixtures containing hydrogen, a method for the production thereof as well as a reactor comprising a diaphragm pipe, wherein the diaphragm pipe comprises a porous pipe (S) made of a sintered metal and a diaphragm (M) containing palladium or made of palladium enclosing the outer surface of the sintered metal pipe (S). The sintered metal pipe (S) has at least on one end a fitting (F) made of gasproof material, which is firmly connected with the sintered metal pipe (S).Type: GrantFiled: March 30, 2010Date of Patent: June 17, 2014Assignee: Plansee SEInventors: Wolfgang Haring, Nicole Schodel, Axel Behrens, Klaus Klapper, Matthias Ruttinger, Karlheinz Scheiber, Markus Kogl, Marco Brandner
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Patent number: 8753425Abstract: A method of preparing a supported gas separation membrane, comprising: preparing crystalline seeds from a synthesis mixture comprising an aluminum source, a phosphorous source, a silicon source, at least one organic templating agent and water; applying the seeds to a porous support to produce a seeded porous support; contacting the seeded porous support with a synthesis gel under hydrothermal synthesis conditions to produce a coated porous support; and calcining the coated porous support is described. A supported gas separation membrane made by this method is also described.Type: GrantFiled: May 27, 2010Date of Patent: June 17, 2014Assignee: Shell Oil CompanyInventors: Brendan Dermot Murray, Paul Jason Williams
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Patent number: 8747525Abstract: A composite hollow ceramic fiber includes a porous hollow core supporting a thin, dense sheath. The non-gas-tight core comprises a first ceramic compound and an interconnecting network of pores. The gas-tight sheath comprises a second ceramic compound. The fiber is made by extruding first and second suspensions of the first and second ceramic compounds in polymeric binders and solvent from a spinnerette and coagulating the nascent hollow fiber to effect phase inversion of the polymeric binders. The resultant green fiber is sintered in a two step process. First, the binder is burned off. Second, the sheath is densified and the second ceramic compound is sinter without fully sintering the first ceramic compound. The first ceramic compound has a melting point higher than that of the second ceramic compound.Type: GrantFiled: June 30, 2011Date of Patent: June 10, 2014Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Dean W. Kratzer, Tao Li, Madhava R. Kosuri
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Patent number: 8747521Abstract: Provided is a gas separation membrane having superior gas permeability, separation selectivity and mechanical properties. A gas separation membrane to separate at least one acid gas from a mix gas, comprising in this order: a first layer that is porous; a second layer that is a separation-active layer containing a compound having a molecular weight of 150,000 or less and capable of interacting with the acid gas; and a third layer having high gas permeability.Type: GrantFiled: February 10, 2011Date of Patent: June 10, 2014Assignee: FUJIFILM CorporationInventor: Satoshi Sano
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Patent number: 8747766Abstract: A hydrogen separation membrane comprising a palladium alloy that includes at least palladium, an added metal A, and an added metal B, the added metal A and the added metal B being two different metals other than palladium, each of the added metal A and the added metal B forming a complete solid solution with palladium, and the added metal A and the added metal B having a triple point in an equilibrium diagram and not forming an intermetallic compound. The hydrogen separation membrane exhibits excellent hydrogen permeability and durability.Type: GrantFiled: November 20, 2009Date of Patent: June 10, 2014Assignee: NGK Insulators, Ltd.Inventor: Kenichi Noda
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Patent number: 8741031Abstract: A composite hollow ceramic fiber includes a porous hollow core supporting a thin, dense sheath. The non-gas-tight core comprises a first ceramic material and an interconnecting network of pores. The gas-tight sheath comprises a second ceramic material. The fiber is made by extruding core and sheath suspensions from a spinnerette. The core suspension includes particles of the first ceramic material, a polymeric binder, a solvent, and a pore former material insoluble in the solvent. The sheath suspension includes particles of the second ceramic material, a polymeric binder and a solvent. The nascent hollow fiber is coagulated in a coagulant bath to effect phase inversion of the polymeric binders. The resultant green fiber is sintered in a two step process. First, the binders and pore former material are burned off. Second, the sheath is densified and the second ceramic material is sintered without fully sintering the core.Type: GrantFiled: July 31, 2011Date of Patent: June 3, 2014Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Madhava R. Kosuri, Dean W. Kratzer
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Patent number: 8741029Abstract: A fuel deoxygenation system includes an oxygen permeable membrane having a porous membrane and an oleophobic layer. The porous membrane has pores that create a passage extending from a first side to an opposite second side of the porous membrane. The pores have an average pore diameter less than or equal to about 0.06 microns. The oleophobic layer and the porous membrane allow oxygen to cross the oxygen permeable membrane but substantially prevent fuel from crossing the oxygen permeable membrane. A method for removing dissolved oxygen from a fuel includes delivering fuel to an oxygen permeable membrane and removing oxygen from the fuel using the oxygen permeable membrane. A method for modifying a surface of a porous membrane includes depositing an oleophobic treatment agent on the porous membrane, removing solvent and heating the porous membrane to form an oleophobic layer on the porous membrane.Type: GrantFiled: June 30, 2011Date of Patent: June 3, 2014Assignee: United Technologies CorporationInventors: Haralambos Cordatos, Louis J. Spadaccini, Thomas G. Tillman
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Publication number: 20140144322Abstract: The present invention relates to a method for protecting a hydrogen separation membrane from particulate contaminants in the process of producing or purifying hydrogen by using the separation membrane. The protection layer, wherein a cermet is formed by coating a ceramic and a metal able to cause surface movement of hydrogen molecules and hydrogen atoms to the surface of the separation membrane, plays the role of blocking contact between the separation membrane and particles (contaminant or catalyst) contained in the gas. In this way, it is possible to improve the durability of the hydrogen separation membrane and to minimize effects on the hydrogen permeability of the separation membrane.Type: ApplicationFiled: July 20, 2012Publication date: May 29, 2014Applicant: Korea Instiute of Energy ResearchInventors: Kyung-Ran Hwang, Jong-Soo Park, Shin-Kun Ryi, Jin-Suk Lee, Chung-Boo Lee, Sung-Wook Lee
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Publication number: 20140144323Abstract: The present invention discloses a silica-like membrane for separating gas, which is modified from poly(dimethylsiloxane) (PDMS) membrane by an atmospheric pressure high temperature plasma torch (APHTPT). Furthermore, the present invention of the separating gas silica-like membrane with an inorganic/organic interface structure which has both the gas flux of the organic membrane and also the gas selectivity of the inorganic membrane.Type: ApplicationFiled: November 30, 2012Publication date: May 29, 2014Applicant: CHUNG YUAN CHRISTIAN UNIVERSITYInventors: Jung-Tsai Chen, Ywu-Jang Fu, Kuo-Lun Tung, Shu-Hsien Huang, Wei-Song Hung, Shingjiang Jessie Lue, Chien-Chieh Hu, Kueir-Rarn Lee, Juin-Yih Lai
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Patent number: 8734573Abstract: An object is to provide a vent plug having a structure in which an air-permeable membrane is unlikely to be damaged. More specifically, a vent plug is produced, which includes: a cylindrical member 1 having a through-hole 1a; a support 2 connected to the cylindrical member 1 so as to be across the through-hole 1a; and an air-permeable membrane 3 circumferentially attached to the cylindrical member 1, wherein the air-permeable membrane 3 is held on the support 2 and a convex portion 3a that follows the shape of the support 2 is formed on the air-permeable membrane 3.Type: GrantFiled: July 14, 2010Date of Patent: May 27, 2014Assignee: W. L. Gore & Associates, Co., Ltd.Inventors: Masashi Ono, Hiroshi Manabe
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Patent number: 8734567Abstract: Disclosed herein is a method for preparing a crosslinked hollow fiber membrane. The method involves spinning a one phase solution comprising a monoesterified polyimide polymer, acetone as a volatile solvent, a spinning solvent, a spinning non-solvent, and optionally an organic and/or inorganic additive, wherein the volatile solvent is present in an amount of greater than 25 wt. % to about 50 wt. %, based on the total weight of the solution.Type: GrantFiled: April 29, 2013Date of Patent: May 27, 2014Assignee: Chevron U.S.A. Inc.Inventor: Shabbir Husain
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Publication number: 20140137739Abstract: A ventilation member is configured to be attached to an opening portion of a housing, and includes: an inner member configured to be fitted to the opening portion and including a tubular portion having a through hole configured to serve as a part of a ventilation path between a space inside the housing and a space outside the housing; and an outer member mounted to the inner member and covering a water-proof gas-permeable membrane attached so as to close an opening of the through hole. The inner member and the outer member have an exposed surface subjected to liquid-repellent treatment.Type: ApplicationFiled: November 19, 2013Publication date: May 22, 2014Applicant: NITTO DENKO CORPORATIONInventors: Kyoko ISHII, Youzou YANO, Yoshiki IKEYAMA
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Patent number: 8728181Abstract: The inventive stage system for producing hydrogen consists of at least two upstream/downstream stages, respectively, each of which comprises, optionally, a catalytic reactor (C1 to C5) followed by a separator comprising a space (E1 to E4) for circulation of a gaseous mixture contacting at least one oxygen extracting membrane and a hydrogen collecting space, wherein the reactor (C1) of the upstream stage is connected to a reaction gaseous mixture source, the circulation stage (E1) of the upstream stage separator is connected to the reactor (C2) of the downstream stage and the spaces for extracting/collecting oxygen from two separators are connected to a hydrogen collecting circuit (TC, 8) which is common for two stages.Type: GrantFiled: January 19, 2011Date of Patent: May 20, 2014Assignee: Compagnie Europeenne des Technologies de l'Hydrogene (C.E.T.H.)Inventors: Eric Gernot, Arnaud Deschamps
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Patent number: 8721756Abstract: The filter of the invention is a cartridge filter comprising a structure that can maintain a filter medium in an air stream to filter particulates to protect a gas turbine power system. The filter combines a mechanically adequate filter structure and an effective filter medium for to obtain a useful system.Type: GrantFiled: September 14, 2012Date of Patent: May 13, 2014Assignee: Donaldson Company, Inc.Inventors: Michael W. Handley, Mark Brandenhoff, Kirit Patel, Timothy D. Sporre