Liquid Spray Means Patents (Class 96/53)
  • Patent number: 5595587
    Abstract: Apparatus for treating gas or vapor includes an impeller arranged in a conduit which draws dusty or fume-laden air through the duct. One or more nozzles are arranged to spray fine droplets of water onto the impeller. Downstream of the impeller, a set of angled collection plates collect the fine water droplets emitted by the nozzle, together with dust or fumes collected by the droplets. The nozzle is connected to a high voltage source, so that the droplets emitted by the nozzle are electrostatically charged. This causes them to attract dust particles and other contaminants. The collection plates are earthed, so that the charged droplets are attracted to them, improving the effectiveness of the apparatus.
    Type: Grant
    Filed: March 18, 1996
    Date of Patent: January 21, 1997
    Inventor: Victor O. Steed
  • Patent number: 5567226
    Abstract: The present invention provides an apparatus and method to improve the performance of a variety of particulate collection devices. Gaseous ammonia is injected by one or more injectors into a waste gas upstream from a particulate collection device. The amount of ammonia injected from each injector is controlled so that the local concentration of ammonia in the waste gas is approximately the same as the corresponding local concentration of sulfur trioxide in the waste gas. The flow of ammonia from each injector is controlled by measuring several local sulfur trioxide concentrations in the waste stream after the ammonia has been injected. The sulfur trioxide can occur naturally or result from injection. By keeping the concentration of ammonia approximately equal to the concentration of sulfur trioxide, ammonia and sulfur trioxide react to form a liquid product. This liquid reaction product coats the surfaces of particles entrained in the gas stream.
    Type: Grant
    Filed: November 14, 1994
    Date of Patent: October 22, 1996
    Inventors: Aziz A. Lookman, Roger W. Glickert, James E. Gabrielson
  • Patent number: 5518525
    Abstract: Method for treating gas or vapor includes an impeller arranged in a duct which draws dusty or fume-laden air through the duct. One or more nozzles are arranged to spray fine droplets of water onto the impeller. Downstream of the impeller, a set of angled collection plates collect the fine water droplets emitted by the nozzle, together with dust or fumes collected by the droplets. The nozzle is connected to a high voltage source, so that the droplets emitted by the nozzle are electrostatically charged. This causes them to attract dust particles and other contaminants. The collection plates are earth, so that the charged droplets are attracted to them, improving the effectiveness of the apparatus. A second, auxiliary spray of fine uncharged droplets is directed over an entrance opening of the duct to prevent ignition of explosive gas or particles outside the duct.
    Type: Grant
    Filed: July 14, 1994
    Date of Patent: May 21, 1996
    Inventor: Victor O. Steed
  • Patent number: 5449390
    Abstract: A flue gas conditioning system uses the waste heat of the flue gas to heat a sulfuric acid solution to add sufficient heat energy to the solution to vaporize the solution before being injected into the flue gas to condition the flue gas so that particulate removal by a precipitator is enhanced.
    Type: Grant
    Filed: March 8, 1994
    Date of Patent: September 12, 1995
    Assignee: Wilhelm Environmental Technologies, Inc.
    Inventors: Kent S. Duncan, Robert A. Wright
  • Patent number: 5427608
    Abstract: A method and apparatus for separating solid and/or liquid particles and/or polluting gas from a gas stream includes two component nozzles by which a washing liquid is finely distributed in a gaseous phase and introduced in the gas stream within a gas washer. The two-component nozzles are distributed over the whole cross section of the washer, preferably on a plane that extends perpendicularly to the gas flow direction.
    Type: Grant
    Filed: September 26, 1994
    Date of Patent: June 27, 1995
    Assignee: Voest Alpine Industrieanlagenges, m.b.H.
    Inventors: Werner Auer, Walter Gebert, Franz Parzermair, Harald Furschuss, Sotirios Raptis
  • Patent number: 5370720
    Abstract: A flue gas conditioning system uses the waste heat of the flue gas to heat a conditioning agent such as water to add sufficient heat energy to the water to generate steam that can be used to atomize the water into a very fine mist with droplets less than 50 microns injected into the flue gas. The fine mist evaporates quickly conditioning the flue gas to enhance particulate removal by a precipitator or filter. Also, humidification of the flue gas causes trace heavy metals--arsenic, mercury, selium, copper, zinc, etc.--to condense on fly ash particles. Such metals are targeted for removal by the EPA under the blanket description "air toxics.
    Type: Grant
    Filed: July 23, 1993
    Date of Patent: December 6, 1994
    Assignee: Welhelm Environmental Technologies, Inc.
    Inventor: Kent S. Duncan
  • Patent number: 5364457
    Abstract: In the purification of gases generated in metallurgical and similar furnace operations, the impurities include solid particles and compounds or elements which are gaseous at the furnace temperatures and only form solid or liquid at temperatures approaching ambient conditions. Proper cleaning therefore requires cooling of the gases to at least the water dew point to cause these impurities to form as particles or droplets. This invention describes an apparatus for collecting such particles or droplets in which a charging device and condensation equipment are combined to provide a simple, yet effective apparatus at a fraction of the cost of conventional apparatus.
    Type: Grant
    Filed: November 29, 1993
    Date of Patent: November 15, 1994
    Assignee: Cecebe Technologies Inc.
    Inventor: Gordon M. Cameron
  • Patent number: 5308589
    Abstract: An odor control system includes an inlet section of a chamber for spraying waste gas with a suitable reactive chemical agent, for odor removal purposes. An electrostatic precipitator is mounted downstream of the inlet section, within the chamber, for removing chemical residues. The electrical field strength of the electrostatic precipitator is adjustable as needed, to satisfy operating system requirements.
    Type: Grant
    Filed: December 20, 1991
    Date of Patent: May 3, 1994
    Assignee: Calvert Environmental, Inc.
    Inventor: Shui-Chow Yung
  • Patent number: 5282885
    Abstract: In the purification of gases generated in metallurgical and similar furnace operations, the impurities include solid particles and compounds or elements which are gaseous at the furnace temperatures and only form solid or liquid at temperatures approaching ambient conditions. Proper cleaning therefore requires cooling of the gases to at least the water dew point to cause these impurities to form as particles or droplets. This invention describes a process and apparatus for collecting such particles or droplets in which a charging device and condensation equipment are combined to provide a simple, yet effective apparatus at a fraction of the cost of conventional apparatus.
    Type: Grant
    Filed: January 22, 1992
    Date of Patent: February 1, 1994
    Assignee: Cecebe Technologies Inc.
    Inventor: Gordon M. Cameron
  • Patent number: 5254155
    Abstract: A wet electrostatic precipitator device is provided which has a plurality of hexagonal honeycomb collector passage ways, a corresponding mating plurality of stationary rod elements to be centrally located at axes of each said hexagonal honeycomb collector passage ways and a set of bands integrally formed with a multiplicity of the ionizing blades which protrude from the surfaces of each of the stationary rod elements. The geometry of the design has a high degree of efficiency, while at the same time causes the ionizing blades to maintain their electrostatic charging characteristics under a harsh set of environmental conditions.
    Type: Grant
    Filed: April 27, 1992
    Date of Patent: October 19, 1993
    Inventor: Fred E. Mensi
  • Patent number: 4168170
    Abstract: A dry, activator sheet for a dry, thermal silver dye-bleach process, in the absence of a silver dye-bleach catalyst, comprises a support having thereon a nonvolatile, diffusible acid and a non-hydrolyzable polymeric vehicle having an effective pH up to 4.0 and a melting point lower than 200.degree. C. The activator sheet is useful to bleach a silver image containing a bleachable dye.
    Type: Grant
    Filed: February 17, 1978
    Date of Patent: September 18, 1979
    Assignee: Eastman Kodak Company
    Inventors: Rowland G. Mowrey, Edwin N. Oftedahl
  • Patent number: 4168169
    Abstract: A dry, activator sheet for a dry, thermal silver dye bleach process comprises a support having thereon a non-volatile, diffusible acid, a substituted heterocyclic thiazoline, oxazoline, imidazoline or imidazolidine silver halide complexing agent and a non-hydrolyzable polymer vehicle having an effective pH up to 6.0 and a melting point lower than 200.degree. C. The activating sheet is useful to bleach a silver image containing a bleachable dye.
    Type: Grant
    Filed: February 17, 1978
    Date of Patent: September 18, 1979
    Assignee: Eastman Kodak Company
    Inventors: Wilbert J. Humphlett, Rowland G. Mowrey
  • Patent number: 4152157
    Abstract: A color image forming process which comprises processing a photographic light-sensitive element comprising a support having thereon a layer containing silver imagewise distributed therein with an aqueous alkaline solution containing a boron hydride compound in the presence of a dye to bleach the dye in an imagewise manner. By the process of this invention, color images which are stable to light, heat and moisture are formed using light-sensitive elements containing a reduced amount of silver salt and without using chemicals causing environmental pollution problems for the processing.
    Type: Grant
    Filed: May 2, 1978
    Date of Patent: May 1, 1979
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shigeru Nakamura, Isao Shimamura, Masatoshi Sugiyama
  • Patent number: 4145217
    Abstract: Quinoxalines of the formula ##STR1## are provided, in which R.sub.1 is hydrogen if R.sub.3 and R.sub.4 conjointly are --O(CH.sub.2).sub.p O--, or is --CH.sub.2 OR, --CH.sub.2 NRR', --CH.sub.2 OCOR, --CH.sub.2 Cl, --CH.sub.2 Br, --CH.sub.2 CN, --CH.sub.2 SR, --CH.sub.2 SCN, --CH.sub.2 O(CH.sub.2).sub.m OR, --CH.sub.2 (OCH.sub.2 CH.sub.2).sub.n OR, --CH.sub.2 SO.sub.2 R.sub.5, --CH.sub.2 PO(OR.sub.5).sub.2, --CH.sub.2 SO.sub.3 R.sub.6 or --CH.sub.2 PO(OR.sub.6).sub.2 and R.sub.2 is lower alkyl, --CH.sub.2 PO(OR.sub.5).sub.2, --CH.sub.2 PO(OR.sub.6).sub.2 or CH.sub.2 SO.sub.3 R.sub.6, R.sub.3 and R.sub.4 independently are lower alkyl, lower alkoxy, RO(CH.sub.2).sub.m O-- or RO(CH.sub.2 CH.sub.2 O).sub.n -- or R.sub.3 and R.sub.4 conjointly are --O(CH.sub.2).sub.p O--, R and R' independently are hydrogen or lower alkyl, R.sub.5 is lower alkyl, R.sub.6 is hydrogen, an alkali metal cation or --N.sup..sym. (R).sub.4, m is 3 or 4, n is 1 to 3 and p is 1 or 2.
    Type: Grant
    Filed: May 20, 1977
    Date of Patent: March 20, 1979
    Assignee: Ciba-Geigy AG
    Inventors: Gerald Jan, Remon Hagen, John Lenoir
  • Patent number: 4141734
    Abstract: A process for developing photographic silver halide material, which has been exposed image-wise is provided. The aqueous developer preparation used contains a developer compound for the silver halide, a water-soluble solvent for the silver halide and an aliphatic, cycloaliphatic, aromatic or heterocyclic di- or trisulphide. These preparations remain clear over a long period of time during which they do not lose their effectiveness by becoming turbid or by sedimentation of silver. They are of special advantage in continuously operated photographic developing processes.
    Type: Grant
    Filed: December 1, 1977
    Date of Patent: February 27, 1979
    Assignee: Ciba-Geiby AG
    Inventors: John Lenoir, Max Marthaler
  • Patent number: 4138256
    Abstract: A method of processing photographic silver dye bleach materials which have been exposed imagewise is provided. The process steps are (1) silver developing, (2) dye bleaching, (3) silver bleaching and (4) fixing. The treatment baths for the process steps (2), (3) and (4), or the combined treatment baths useful for process step (3) with at least one the process steps (2) or (4) contain water-soluble tertiary phosphines as silver ligands. These phosphines effect an acceleration of the dye and silver bleaching and they are further suitable stabilizers and optionally antioxidants which yield stable treatment baths.
    Type: Grant
    Filed: November 11, 1976
    Date of Patent: February 6, 1979
    Assignee: Ciba-Geigy AG
    Inventors: Christoph Chylewski, Gerald Jan, Roland Kurzen, Max Meier, Matthias Schellenberg
  • Patent number: 4125402
    Abstract: A method of processing silver dye bleaching materials is provided wherein a combined aqueous dye and silver bleaching bath is used which contains a strong acid, a water-soluble iodide, a dye bleaching catalyst, a water-soluble oxidant and an antioxidizing agent, wherein the antioxidizing agent is an alkali metal, alkaline earth metal or ammonium bisulphite adduct of an organic carbonyl compound. The dye and silver bleaching can also be carried out in separate baths and then the aqueous dye bleaching bath contains a strong acid, a water-soluble iodide, a dye bleaching catalyst and the antioxidizing agent, which is again said bisulphite adduct. The strongly acid baths which contain as antioxidizing agents the bisulphite adducts are stable over a lengthy period of time, exert a lasting antioxidizing action and are free of offensive odors.
    Type: Grant
    Filed: August 12, 1977
    Date of Patent: November 14, 1978
    Assignee: Ciba-Geigy AG
    Inventor: Herbert Mollet
  • Patent number: 4118232
    Abstract: The invention is directed essentially to photographic material containing, on a carrier, a layer with azo dyestuffs of the formula ##STR1## wherein A, B, X and Y are certain substituents, in a second main aspect azo dyestuffs of the formula ##STR2## wherein B' represents certain substituents and in a third main aspect azo deystuffs of the formulaA.sub.1 --N.dbd.N--B.sub.1 --NH--CO--X.sub.1 --Y--Z.sub.1 --OC--HN--B.sub.1 --N.dbd.N--A.sub.1wherein A.sub.1, B.sub.1, X.sub.1, Z.sub.1 and Y are certain substituents.The photographic materials provide advantages stemming from the use of the dyestuffs of the invention which are distinguished by particularly high fastness to light coupled with excellent bleachability, good resistance to diffusion and advantageous color strength.
    Type: Grant
    Filed: March 15, 1977
    Date of Patent: October 3, 1978
    Assignee: Ciba-Geigy AG
    Inventors: Bernhard Piller, John Lenoir, Alfred Froehlich, Thomas Stauner, Paul Tschopp
  • Patent number: 4081278
    Abstract: A heat bleachable layer comprising a benzopinacol and a reducible dye or dye precursor is useful in an imaging element. The heat bleachable layer can be, for instance, an antihalation layer of a photographic element, such as a photothermographic element.
    Type: Grant
    Filed: May 23, 1977
    Date of Patent: March 28, 1978
    Assignee: Eastman Kodak Company
    Inventors: Jonas Dedinas, George Leland Fletcher, Jr.
  • Patent number: 4070188
    Abstract: A one bath type silver dye bleaching and silver bleaching solution which comprises at least a) a compound which forms a salt or a complex with silver, b) at last one acid selected from sulfamic acid, aliphatic and aromatic sulfonic acids, aliphatic and aromatic sulfinic acids, phosphoric acid and sulfuric acid, c) an organic acid having at least one carboxylic group in its molecule and d) a ferric salt (or a complex thereof with the organic acid c), in which case the solution comprises element a), b) and the complex).
    Type: Grant
    Filed: June 23, 1976
    Date of Patent: January 24, 1978
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takashi Nakamura, Shigeru Watanabe
  • Patent number: 4022616
    Abstract: A process is disclosed for producing a positive colored image in an imagewise exposed photographic element. The element is comprised of a support having coated thereon at least one layer of a hydrophilic colloid coating containing at least one light-sensitive silver halide and, in association with said silver halide, a substantially colorless, image dye-providing compound. The image dye-providing compound is reactive with oxidized color-forming reducing agent to yield a bleachable image dye. The process is comprised of the following steps: A silver image is developed in the imagewise exposed areas of the photographic element and a low level silver fog is formed in the remaining areas of the element. Image dye-providing compound is then converted to a bleachable image dye uniformly throughout the photographic element using the silver as a catalyst for a redox reaction of a color-forming reducing agent and a cobalt(III) complex amplifier oxidizing agent.
    Type: Grant
    Filed: March 1, 1976
    Date of Patent: May 10, 1977
    Assignee: Eastman Kodak Company
    Inventors: Charles Robert Barr, John Vincent Williams
  • Patent number: 4014698
    Abstract: The present invention relates to a new method for processing silver dye bleach material. The process measures of this method, consisting of (1) silver developing, (2) dye bleaching, (3) silver bleaching, (4) silver fixing are carried out in the sequence (1) to (4) with appropriate preparations. The silver bleaching (3) preparation contains (a) a strong acid, (b) a water-soluble iodide, (c) a water-soluble oxidizing agent, (d) a diazine compound and (e) an anti-oxidant. An excellent and rapid bleaching is achieved.
    Type: Grant
    Filed: June 30, 1975
    Date of Patent: March 29, 1977
    Assignee: Ciba-Geigy AG
    Inventor: Max Marthaler
  • Patent number: 3963492
    Abstract: The present invention relates to a simplified method for processing silver dye bleach material by (1) silver developing, (2) dye and silver bleaching (3) silver fixing and (4) soaking. The sequence (1), (2), (3), (4) is followed and the bleaching bath (2) contains (a) a strong acid, (b) a water-soluble iodide, (c) a water-soluble oxidizing agent (d) an antioxidant and (e) a dye bleach catalyst.
    Type: Grant
    Filed: October 1, 1974
    Date of Patent: June 15, 1976
    Assignee: Ciba-Geigy AG
    Inventors: Max Marthaler, Matthias Schellenberg, Herbert Mollet, Christoph Chylewski
  • Patent number: 3961957
    Abstract: The invention relates to a dye bleach preparation which contains in addition to an acid, a water-soluble iodide and optionally a dye bleach catalyst at least one bifunctional sulphur compound having a sufficient solubility in the preparation and a low vapor pressure and containing at least one HS-group and at least one oxygen, nitrogen, phosphorus or additional sulphur atom, the sulphur atom of each HS-group being separated from the next oxygen, sulphur, nitrogen and phosphorus atom present in the molecule by at least three carbon atoms.The subject of the present invention is a dye bleach preparation for the photographic silver dye bleach process, which contains an acid, a water-soluble iodide and optionally a dye bleach catalyst. The preparation is characterised in that it contains at least one organic, at least bifunctional sulphur compound of which the solubility is at least 5.times.10.sup.-.sup.4 mol per liter of preparation and of which the vapour pressure in the temperature range of -20.degree.
    Type: Grant
    Filed: May 10, 1974
    Date of Patent: June 8, 1976
    Assignee: Ciba-Geigy AG
    Inventors: Ekkehard Kramp, John Lenoir, Max Marthaler, Robert Schaller
  • Patent number: 3957516
    Abstract: The present invention relates to an oil-in-water emulsion which is suitable for processing photographic material. There is present or produced during the processing a substance which exerts its action on the photographic material from the aqueous phase. Contingent on the consumption the active substance is replenished or regenerated from the oily phase. The active substance is more readily soluble in the oily phase than in the aqueous one. The active substance may be, e.g., a dye bleach catalyst for silver dye bleach material or an alkylmercaptan, the latter acting as an antioxidant.
    Type: Grant
    Filed: May 10, 1974
    Date of Patent: May 18, 1976
    Assignee: Ciba-Geigy AG
    Inventors: Matthias Schellenberg, Christoph Chylewski, Max Meier