Parallel Hollow Fibers Or Cylinders (e.g., Bundled, Etc.) Patents (Class 96/8)
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Patent number: 8758490Abstract: A method of forming a fluid separation filter for use in a fluid separation device includes aligning a series of fluid separation or drying fibers (102) and fixing them together using a self-adhesive and electrically conductive tape (116) or by weaving copper threads between them. The connected fibers then form a mat and a strip of potting sealant (112) may be added, if required, along the top and bottom of the fibers. The mat may then be rolled to form a bundle of fibers.Type: GrantFiled: August 2, 2010Date of Patent: June 24, 2014Assignee: Nano-Porous Solutions LimitedInventors: John Pearson, Caytlin Green
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Patent number: 8753426Abstract: The invention describes a polymeric material comprising repeating units of Formulae I-III and methods of preparation. Novel polymeric materials, gas separation membranes and fluid component separation methods are also described.Type: GrantFiled: August 3, 2012Date of Patent: June 17, 2014Assignee: Air Products and Chemicals, Inc.Inventors: Shiying Zheng, Jeffrey Raymond Quay
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Patent number: 8747525Abstract: A composite hollow ceramic fiber includes a porous hollow core supporting a thin, dense sheath. The non-gas-tight core comprises a first ceramic compound and an interconnecting network of pores. The gas-tight sheath comprises a second ceramic compound. The fiber is made by extruding first and second suspensions of the first and second ceramic compounds in polymeric binders and solvent from a spinnerette and coagulating the nascent hollow fiber to effect phase inversion of the polymeric binders. The resultant green fiber is sintered in a two step process. First, the binder is burned off. Second, the sheath is densified and the second ceramic compound is sinter without fully sintering the first ceramic compound. The first ceramic compound has a melting point higher than that of the second ceramic compound.Type: GrantFiled: June 30, 2011Date of Patent: June 10, 2014Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Dean W. Kratzer, Tao Li, Madhava R. Kosuri
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Patent number: 8741031Abstract: A composite hollow ceramic fiber includes a porous hollow core supporting a thin, dense sheath. The non-gas-tight core comprises a first ceramic material and an interconnecting network of pores. The gas-tight sheath comprises a second ceramic material. The fiber is made by extruding core and sheath suspensions from a spinnerette. The core suspension includes particles of the first ceramic material, a polymeric binder, a solvent, and a pore former material insoluble in the solvent. The sheath suspension includes particles of the second ceramic material, a polymeric binder and a solvent. The nascent hollow fiber is coagulated in a coagulant bath to effect phase inversion of the polymeric binders. The resultant green fiber is sintered in a two step process. First, the binders and pore former material are burned off. Second, the sheath is densified and the second ceramic material is sintered without fully sintering the core.Type: GrantFiled: July 31, 2011Date of Patent: June 3, 2014Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Madhava R. Kosuri, Dean W. Kratzer
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Patent number: 8734568Abstract: The present invention relates to an asymmetric hollow fiber membrane for gas separation made of a soluble aromatic polyimide, wherein an orientation index is 1.3 or less, a separation coefficient ?(P?O2/P?N2) as a permeation rate ratio of oxygen gas/nitrogen gas at 40° C. is 5.3 or more, and a tensile fracture elongation is 15% or more.Type: GrantFiled: March 30, 2011Date of Patent: May 27, 2014Assignee: Ube Industries, Ltd.Inventors: Hiroki Hisamori, Tatsuya Hayashi, Seiji Morihashi, Tomonori Kanougi
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Patent number: 8734567Abstract: Disclosed herein is a method for preparing a crosslinked hollow fiber membrane. The method involves spinning a one phase solution comprising a monoesterified polyimide polymer, acetone as a volatile solvent, a spinning solvent, a spinning non-solvent, and optionally an organic and/or inorganic additive, wherein the volatile solvent is present in an amount of greater than 25 wt. % to about 50 wt. %, based on the total weight of the solution.Type: GrantFiled: April 29, 2013Date of Patent: May 27, 2014Assignee: Chevron U.S.A. Inc.Inventor: Shabbir Husain
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Patent number: 8728181Abstract: The inventive stage system for producing hydrogen consists of at least two upstream/downstream stages, respectively, each of which comprises, optionally, a catalytic reactor (C1 to C5) followed by a separator comprising a space (E1 to E4) for circulation of a gaseous mixture contacting at least one oxygen extracting membrane and a hydrogen collecting space, wherein the reactor (C1) of the upstream stage is connected to a reaction gaseous mixture source, the circulation stage (E1) of the upstream stage separator is connected to the reactor (C2) of the downstream stage and the spaces for extracting/collecting oxygen from two separators are connected to a hydrogen collecting circuit (TC, 8) which is common for two stages.Type: GrantFiled: January 19, 2011Date of Patent: May 20, 2014Assignee: Compagnie Europeenne des Technologies de l'Hydrogene (C.E.T.H.)Inventors: Eric Gernot, Arnaud Deschamps
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Patent number: 8709133Abstract: The invention concerns carbon molecular sieve membranes (“CMS membranes”), and more particularly the use of such membranes in gas separation. In particular, the present disclosure concerns an advantageous method for producing CMS membranes with desired selectivity and permeability properties. By controlling and selecting the oxygen concentration in the pyrolysis atmosphere used to produce CMS membranes, membrane selectivity and permeability can be adjusted. Additionally, oxygen concentration can be used in conjunction with pyrolysis temperature to further produce tuned or optimized CMS membranes.Type: GrantFiled: June 28, 2013Date of Patent: April 29, 2014Assignees: Georgia Tech Research Corporation, Shell Oil CompanyInventors: Mayumi Kiyono, Paul Jason Williams, William John Koros
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Patent number: 8709132Abstract: In some implementations, a system for disassociating water includes a decomposition chamber, a heating element, a plurality of hollow fiber membranes, and a water inlet. The heating element is positioned in the decomposition chamber and configured to generate heat sufficient to dissociate at least a portion of water to hydrogen and oxygen. The plurality of hollow fiber membranes include at least a section of each hollow fiber membrane that passes through the decomposition chamber and has an inner conduit and an outer wall. The inner conduit for each hollow fiber membrane is configured to pass a sweep gas, and the outer wall for each hollow fiber membrane is configured to selectively pass either oxygen or hydrogen. The water inlet connected to the decomposition chamber and configured to pass water vapor into the decomposition chamber.Type: GrantFiled: October 17, 2011Date of Patent: April 29, 2014Assignee: Stellar Generation, LLCInventor: Jerome Lee Elkind
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Patent number: 8697760Abstract: A process for producing a zeolite film is provided in which seed crystals thinly adhere to the surface of a support to form a thin and even zeolite film having fewer defects than conventional zeolite films. Also provided is a zeolite film obtained by the producing process. The process for producing the zeolite film comprises: a particle adhesion step of allowing a slurry, where zeolite particles which become seeds are dispersed, to flow down on the surface of a base material by the self-weight of the slurry, so that the zeolite particles adhere to the base material; and a film formation step of immersing the base material, to which the zeolite particles adhere, into a sol to carry out hydrothermal synthesis, thereby forming the zeolite film on the base material.Type: GrantFiled: March 28, 2012Date of Patent: April 15, 2014Assignee: NGK Insulators, Ltd.Inventors: Shinji Nakamura, Makiko Niino, Makoto Miyahara
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Patent number: 8690994Abstract: In at least certain embodiments, the present invention is directed to contactors, modules, components, systems, and/or methods of manufacture, and/or methods of use including degassing liquids. In at least particular possibly preferred embodiments, the contactor or module is integrally potted, has planar, disc shaped end caps, and a cylindrical housing or shell receiving and supporting a membrane structure. In at least particular possibly preferred embodiments, each of the planar disc shaped end caps has a central opening therein adapted to receive a liquid end port or nozzle, another opening therein adapted to receive a gas end port or threaded pipe, and is held in place in the housing or shell by at least one retaining element such as a retaining or locking ring. In at least particular possibly preferred embodiments, the integrally potted membrane structure is potted in place in the housing or shell by an inverted potting process involving the use of a removable plunger or plug to recess the potting.Type: GrantFiled: May 16, 2013Date of Patent: April 8, 2014Assignee: Celgard LLCInventors: Gareth P. Taylor, Elmer Wayne Bouldin, Jr., Timothy D. Price, Tony R. Vido
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Patent number: 8668763Abstract: A liquid degassing apparatus is arranged to prevent pervaporated solvent cross-contamination by counteracting liquid vapor pervaporation flow. Liquid vapor pervaporation cross-contamination among a plurality of degassing modules is counteracted with specifically configured volumes and bleed inlet flow to conduits fluidly coupling permeate sides of said plurality of degassing chambers.Type: GrantFiled: January 24, 2012Date of Patent: March 11, 2014Assignee: IDEX Health & Science LLCInventor: Yuri Gerner
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Patent number: 8661648Abstract: The present invention is directed toward spiral wound modules along with methods for making and using the same. Several embodiments are described including methods for making spiral wound filtration modules using membrane sheet provided from a roll, wherein the membrane sheet is unrolled and assembled in a direction parallel to the permeate collection tube of the module.Type: GrantFiled: February 23, 2011Date of Patent: March 4, 2014Assignee: Dow Global Technologies LLCInventors: Steven D. Jons, Allyn R. Marsh, III
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Patent number: 8661830Abstract: A hybrid multichannel porous structure for processing between two fluid streams of different compositions includes a housing and one or more structures disposed within the cavity of the housing in a shell and tube configuration. Each structure includes a body made of a porous, inorganic material and a plurality of channels for processing an optional sweep stream. Each channel is coated with a membrane layer. A feed stream introduced into the housing is in direct contact with the structures such that a gas selectively permeates through the body and into the channels. The gas combines with the sweep stream to form a permeate that exits from each channel. The remaining feed stream forms a retentate that exits from the housing. The feed stream may consist of syngas containing hydrogen gas and the sweep stream may contain nitrogen gas. A power plant that incorporates the hybrid structure is disclosed.Type: GrantFiled: November 2, 2009Date of Patent: March 4, 2014Assignee: General Electric CompanyInventors: Anthony Yu-Chung Ku, Kevin Paul McEvoy, Patrick Daniel Willson, Parag Parkash Kulkarni, Roger Allen Shisler, Anoop Muralidhara Kurup
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Patent number: 8657921Abstract: A shell-and-tube heat exchanger, for removing volatile substances from a polymer solution by degasification, includes a bundle of tubes arranged vertically and parallel to each other in a shell chamber through which a fluid heat-transfer medium flows. The upper end of each tube is fixed in an upper tube sheet and the lower end of each tube is fixed in a lower tube sheet, and the polymer solution flows through the tubes in the direction of gravity. One feature is that a multilayer woven wire fabric is attached to the top of the upper tube sheet. The finest meshed layer of the fabric has a mesh width of 50 ?m to 1000 ?m. The invention also relates to a method for removing volatile substances from a polymer solution by degasification in a shell-and-tube heat exchanger and use of the shell-and-tube heat exchanger.Type: GrantFiled: April 27, 2010Date of Patent: February 25, 2014Assignee: Styrolution GmbHInventors: Norbert Güntherberg, Rainer Bardon, Hartmut Heinen, Michael Sauer, Ludger Leber, Wolfgang Fischer
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Publication number: 20140047982Abstract: A gas separation membrane module, comprising: a hollow fiber element having a hollow fiber bundle consisting of a number of hollow fiber membranes and a tube sheet provided at an end of the hollow fiber bundle for binding the hollow fiber membranes; a vessel having an opening through which the hollow fiber element is inserted or removed; a lid member having a gas outlet formed therein and attached to cover the opening of the vessel; and a perforated plate having a plurality of through holes for forming gas channels formed therein, the perforated plate being mounted between the tube sheet and the lid member, the gas separation membrane module performing gas separation by supplying mixed gas to the hollow fiber membranes.Type: ApplicationFiled: August 15, 2013Publication date: February 20, 2014Applicant: UBE INDUSTRIES, LTD.Inventors: Nobuhiko Fukuda, Tomohide Nakamura, Nozomu Tanihara, Yutaka Kanetsuki, Manabu Hayashi
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Patent number: 8641807Abstract: Hollow fiber membranes, such as those used in air separation modules, are generally made from solution spinning. Typically, solvent is present in the bore of the fiber for the spinning process. This solvent, in addition to the solvent already present in the polymer casting solution, may cause voids in the fiber material. By adding a polycarboxylic acid to the polymer casting material, these voids may be reduced or eliminated.Type: GrantFiled: January 31, 2011Date of Patent: February 4, 2014Assignee: Honeywell International Inc.Inventor: Adam Glen Thomas
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Patent number: 8623124Abstract: A composition includes a first polymer having monomers each containing an imidazole group, and a second polymer, the first and second polymers being a polymer blend. The first polymer, the second polymer, or both may be cross-linked. The carbonized composition, polymeric and carbon membranes (either in the form of a flat sheet or a hollow fiber) made from the composition are also described. The polymeric and carbon membranes can be used to separate and purify gases or liquids.Type: GrantFiled: October 7, 2009Date of Patent: January 7, 2014Assignee: National University of SingaporeInventors: Seyed Saeid Hosseini, Tai-Shung Chung
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Patent number: 8623784Abstract: Nanocomposite adsorbent materials and methods for their preparation and use are described. As an example, a polyaniline-graphite nanoplatelet nanocomposite may be used to adsorb carbon dioxide.Type: GrantFiled: December 19, 2011Date of Patent: January 7, 2014Assignee: Indian Institute of Technology MadrasInventors: Sundara Ramaprabhu, Ashish Kumar Mishra
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Publication number: 20140000454Abstract: The various embodiments of the disclosure relate generally to carbon molecular sieve membranes (CMSM) and their associated fabrication processes, and more particularly to CMSM that maintain high gas selectivities without losing productivity. Methods for enriching a mixture of gases in one gas via the use of the CMS membranes, and gas enrichment devices using the same, are also disclosed.Type: ApplicationFiled: May 30, 2013Publication date: January 2, 2014Inventors: Rachana Singh, William John Koros
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Patent number: 8617293Abstract: A porous membrane structure is disclosed, which includes a porous substrate, a mesoporous, aluminum oxide layer disposed on the substrate; and a relatively thin, continuous, microporous barrier layer disposed on the mesoporous aluminum oxide layer, also formed from aluminum oxide. The membrane is capable of improving hydrogen selectivity within a gas stream, e.g., a synthesis gas composition. Membrane supports containing these structures are also described, as well as gas separation modules, and related processes. Power plants which incorporate the gas separation modules are also disclosed herein.Type: GrantFiled: August 10, 2009Date of Patent: December 31, 2013Assignee: General Electric CompanyInventors: Geoffrey Mark Eadon, Anthony Yu-Chung Ku, Vidya Ramaswamy
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Solvent-resistant asymmetric hollow fiber gas separation membrane, and method for production thereof
Patent number: 8580012Abstract: An asymmetric hollow fiber gas separation membrane obtained by subjecting an asymmetric hollow fiber polyimide membrane to a heat treatment having a maximum temperature of from 350 to 450° C., wherein the asymmetric hollow fiber polyimide membrane is formed with a polyimide essentially having a repeating unit represented by a general formula (1); is excellent in a solvent resistance and a thermal stability, and as well has such a mechanical strength that a tensile elongation at break is not less than 10% as a hollow fiber membrane.Type: GrantFiled: January 19, 2009Date of Patent: November 12, 2013Assignee: Ube Industries, Ltd.Inventors: Harutoshi Hoshino, Tomonori Kanougi, Toshimune Yoshinaga, Yoji Kase, Kenji Fukunaga -
Patent number: 8574342Abstract: Method and apparatus for a membrane separation system, including process and installation for the separation of air by permeation, using two strategically placed heaters for the production of high purity nitrogen, uniquely designed multi-staged pre-filtration system and a novel method of controlling the nitrogen flow and purity. The system comprises in series an air compressor (1), an air cooler (2) cooled by air or liquid, moisture separator (3), mist removing filter (4), primary heat source (5), coalescing filter (8), carbon tower (9), particle filter (10), secondary heat source (11), membrane separator(s) (14), and control valve (19). The system is to provide and maintain superheated air to the membrane separator(s) using strategically located heaters to eliminate condensation of moisture in the carbon tower or membrane separator(s) eliminating the need for a separate compressed air dryer, or the need for insulation of pipes, vessels and the membrane separator(s).Type: GrantFiled: March 21, 2011Date of Patent: November 5, 2013Inventor: Charles M. Flowe
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Patent number: 8568517Abstract: A gas separation device comprising a porous support structure comprising polymeric hollow fibers, and an inorganic mesoporous membrane disposed on the porous support structure is disclosed. The inorganic mesoporous membrane is uniform and free of defects. Further, the inorganic mesoporous membrane comprises a network of interconnected three-dimensional pores that interconnect with the porous support structure. The gas permeances of the inorganic mesoporous membrane is substantially higher than the gas permeances of the polymeric hollow fibers. A method of fabricating the gas separation device is also disclosed.Type: GrantFiled: August 15, 2011Date of Patent: October 29, 2013Assignee: Phillips 66 CompanyInventors: Sankar Nair, Kwang-Suk Jang, Christopher Jones, William Koros, Justin Johnson
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Patent number: 8557023Abstract: The invention relates to a device for preparing a gas flow for introduction thereof into a mass spectrometer, wherein the gas flow contains one or more analytes and has helium as carrier gas. According to the invention, a selective separating device is provided for separating off a part of the carrier gas from the gas flow (10), to form a residual gas flow (11) and a separated carrier gas flow (12). A higher fraction of the analyte is present therein than in the gas flow and in the separated carrier gas flow there is a lower fraction of the analyte.Type: GrantFiled: March 18, 2009Date of Patent: October 15, 2013Assignee: Thermo Fisher Scientific (Bremen) GmbHInventor: Reinhold Pesch
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Publication number: 20130255488Abstract: An apparatus for capture and sequestration of CO2 from fossil fuel-fired power plant flue gas includes a polymer matrix embedded with a sorbent suitable for removing CO2 from the flue gas and a spacer mated with the polymer matrix. The spacer is adapted to create channels between adjacent portions of the polymer matrix such that the flue gas flows through the channels and comes in contact with the sorbent. Further, an apparatus for the capture and sequestration of CO2 from fossil fuel-fired power plant flue gas includes a hollow fiber membrane embedded with an adsorbent or other suitable material for removing CO2 from the flue gas. The adsorbent particles may be embedded into a wall of the membrane.Type: ApplicationFiled: May 28, 2013Publication date: October 3, 2013Applicant: ELECTRIC POWER RESEARCH INSTITUTE, INC.Inventors: Ramsay Chang, Adam Berger, Abhoyjit Bhown
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Publication number: 20130253250Abstract: A method is proposed for operating a plant for purifying a high-pressure gas mixture from easily permeating components, which plant comprises membrane gas separating units having a high-pressure chamber and a low-pressure chamber with a selectively permeable membrane therebetween, in which method the low-pressure chamber of at least one membrane gas separating unit is continuously flushed with purified gas mixture (semi-finished product or product), wherein the pressure difference between the aforementioned chambers of the membrane gas separating unit and, likewise, the flow rate of the purified gas mixture used for flushing are maintained so that the amount of each easily permeating component in the product does not exceed the desired values. The proposed method makes it possible to purify a raw material from one or more easily permeating components simultaneously, increase purification efficiency, and provide the possibility of using raw material with a higher content of easily permeating components.Type: ApplicationFiled: May 18, 2013Publication date: September 26, 2013Inventors: Mikhail Alexandrovich GULYANSKY, Nicolay Leonidovich DOKUCHAEV, Alexander Alexandrovich KOTENKO, Eugeny Gennadievich KRASHENINNIKOV, Sergey Vladimirovich POTEKHIN, Mikhail Mikhailovich CHELYAK, Marina Kadyrovna TEREKHOVA
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Patent number: 8540806Abstract: There is provided herein a dryer polymer substance including a hetero-phase polymer composition including two or more polymers wherein at least one of the two or more polymers include sulfonic groups, wherein the substance is adapted to pervaporate a fluid. The fluid may include water, water vapor or both. There is also provided herein a process for the preparation of a dryer polymer substance adapted to pervaporate a fluid (such as water, water vapor or both) the process includes mixing two or more polymers, wherein at least one of the two or more polymers may include groups which are adapted to be sulfonated, to produce a hetero-phase polymer composition and processing the polymer blend into a desired form.Type: GrantFiled: January 2, 2013Date of Patent: September 24, 2013Assignee: Oridion Medical (1987) Ltd.Inventors: Amos Ophir, Eyal Cohen, David Dishon, Joshua Lewis Colman
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Blood storage bag system and depletion devices with oxygen and carbon dioxide depletion capabilities
Patent number: 8535421Abstract: A blood storage system. The system has a collection bag for red blood cells; an oxygen/carbon dioxide depletion device; a storage bag for red blood cells; and tubing connecting the collection bag to the depletion device and the depletion device to the storage bag. The depletion device includes a receptacle of a solid material having an inlet and an outlet adapted to receiving and expelling a flushing gas; a plurality of hollow fibers or gas-permeable films extending within the receptacle from an entrance to an exit thereof. The hollow fibers or gas-permeable films are adapted to receiving and conveying red blood cells.Type: GrantFiled: October 8, 2010Date of Patent: September 17, 2013Assignee: New Health Sciences, Inc.Inventors: Tatsuro Yoshida, Paul J. Vernucci -
Patent number: 8523982Abstract: A separation membrane module for separating a specific component from a mixture containing a plurality of components includes a plurality of separation stages each including a plurality of hollow fiber membranes arranged in parallel to each other. The separation stages are connected in series via connection portions allowing passage of the mixture. At lease one parameter relating to separation by the hollow fiber membrane or membranes in each separation stage is determined to provide effective separation throughout the separation stages.Type: GrantFiled: December 2, 2010Date of Patent: September 3, 2013Assignee: Aisan Kogyo Kabushiki KaishaInventors: Takashi Suefuji, Masataka Suzuki, Akio Muraishi, Shota Yamanaka, Yohsuke Koizumi, Hiroyoshi Ohya, Hirokazu Ohno
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Publication number: 20130220127Abstract: A module and an apparatus incorporating such module utilizing a plurality of tubular membrane elements, each configured to separate oxygen from an oxygen containing feed stream when an electric potential difference is applied to induce oxygen ion transport in an electrolyte thereof. The tubular membrane elements can be arranged in a bundle that is held in place by end insulating members. The insulating members can be positioned within opposed openings of end walls of a heated enclosure and can incorporate bores to allow an oxygen containing feed stream to flow past exposed ends of the tubular membrane elements for cooling the end seals of such elements. Further, first and second manifolds can be provided in a module in accordance with the present invention to collect separated oxygen from two separate portions of the tubular membrane elements.Type: ApplicationFiled: April 2, 2013Publication date: August 29, 2013Inventors: GERVASE MAXWELL CHRISTIE, DAVID M. REED, JERRINE L. NEFF, ARTHUR C. SELOVER
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Patent number: 8518150Abstract: Methods for the purification of steam, systems for purifying steam, methods for measuring and/or controlling steam flow rates, and uses for purified steam are provide. Also provided are substantially gas-impermeable membranes, such as perfluorinated ionomers (e.g., perfluoroethylene-sulfonic-acid/tetrafluoroethylene membranes), having a high ratio of water vapor permeation relative to gas permeation through the membrane. Also provided are methods of operation of such membranes at relatively high operating temperatures for the purification of steam and for operation of such membranes at relatively low temperature and sub-atmospheric pressures for the purification of steam. In a preferred embodiment, the system 400 for purifying steam comprises heater 404 for creating a source of a steam feed, and a purification device 416 for housing a substantially gas-impermeable membrane 424. In the operation of system 400, water, such as deionized water, is added to vessel 402 to provide a source of the steam feed.Type: GrantFiled: August 28, 2012Date of Patent: August 27, 2013Assignee: RasircInventors: Jeffrey J. Spiegelman, Richard D. Blethen
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Patent number: 8506808Abstract: A tubesheet, modules incorporating tubesheets and methods for making and using the same. In one embodiment the invention includes a tubesheet comprising: i) a plurality of aligned semi-permeable hollow fiber membranes each comprising a cylindrical porous structure surrounding a lumen and extending between a first and second end and further comprising a first segment located adjacent the first end and a second segment located adjacent to the second end and ii) a block of potting material including an interfacial surface. The first segment of the hollow fiber membrane is embedded within the block of potting material and the second segment extends from the interfacial surface of the block. The tubesheet further comprises a penetrating extension of potting material within the porous structure of the second segment of the hollow fiber membrane that extends along a length from the interfacial surface of the block to a distal end.Type: GrantFiled: September 28, 2010Date of Patent: August 13, 2013Assignee: Dow Global Technologies LLCInventors: Scott T. Burr, Peter E. M. Aerts, Gavin D. Vogel, David J. Moll
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Patent number: 8506685Abstract: In accordance with at least selected embodiments of the present invention, an improved liquid degassing membrane contactor or module includes a high pressure housing and at least one degassing cartridge therein. It may be preferred that the high pressure housing is a standard, ASME certified, reverse osmosis (RO) or water purification pressure housing or vessel (made of, for example, polypropylene, polycarbonate, stainless steel, corrosion resistant filament wound fiberglass reinforced epoxy tubing, with pressure ratings of, for example, 150, 250, 300, 400, or 600 psi, and with, for example 4 or 6 ports, and an end cap at each end) and that the degassing cartridge is a self-contained, hollow-fiber membrane cartridge adapted to fit in the RO high pressure housing.Type: GrantFiled: August 16, 2010Date of Patent: August 13, 2013Assignee: Celgard LLCInventors: Gareth P. Taylor, Amitava Sengupta
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Patent number: 8500871Abstract: A water vapor permeable membrane is provided comprising a dense layer and a support layer that are adjacent to each other, wherein the dense layer contains voids with a void length of 0.1 ?m or less and the dense layer has a thickness of 0.1 ?m or more and 2 ?m or less while in the support layer, void (a), i.e. the void with the largest length in the 2 ?m thick region measured from the boundary between the dense layer and the support layer into the support layer, has a length of 0.3 ?m or more and void (b), i.e. the void with the largest length in the region ranging between 2 ?m and 4 ?m measured from the boundary into the support layer, has a length of 0.5 ?m or more, the length of the void (b) being larger than that of the void (a). A water vapor permeable membrane having both a high water vapor permeability and a low air leakage is provided.Type: GrantFiled: August 21, 2009Date of Patent: August 6, 2013Assignee: Toray Industries, Inc.Inventors: Masahiro Osabe, Kazumi Tanaka, Hiroyuki Sugaya
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Patent number: 8501668Abstract: The invention provides a porous nanoscale membrane. In one embodiment, the membrane can be used as a filtration device to screen agents that disrupt or prevent molecular interactions. In one embodiment, the membrane allows for screening agents that disrupt or prevent molecular interactions using a small sample volume with efficient high-throughput screening applications.Type: GrantFiled: September 9, 2010Date of Patent: August 6, 2013Assignee: University of RochesterInventors: James L. McGrath, Harold C. Smith
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Patent number: 8486179Abstract: The invention concerns carbon molecular sieve membranes (“CMS membranes”), and more particularly the use of such membranes in gas separation. In particular, the present disclosure concerns an advantageous method for producing CMS membranes with desired selectivity and permeability properties. By controlling and selecting the oxygen concentration in the pyrolysis atmosphere used to produce CMS membranes, membrane selectivity and permeability can be adjusted. Additionally, oxygen concentration can be used in conjunction with pyrolysis temperature to further produce tuned or optimized CMS membranes.Type: GrantFiled: June 17, 2010Date of Patent: July 16, 2013Assignees: Georgia Tech Research Corporation, Shell Oil CompanyInventors: Mayumi Kiyono, Paul Jason Williams, William John Koros
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Patent number: 8479487Abstract: A hybrid multichannel porous structure for processing between two fluid streams of different compositions includes a housing and one or more structures disposed within the cavity of the housing in a shell and tube configuration. Each structure includes a body made of a porous, inorganic material and a plurality of channels for processing an optional sweep stream. Each channel is coated with a membrane layer. A feed stream introduced into the housing is in direct contact with the structures such that a gas selectively permeates through the body and into the channels. The gas combines with the sweep stream to form a permeate that exits from each channel. The remaining feed stream forms a retentate that exits from the housing. The feed stream may consist of syngas containing hydrogen gas and the sweep stream may contain nitrogen gas. A power plant that incorporates the hybrid structure is disclosed.Type: GrantFiled: August 10, 2009Date of Patent: July 9, 2013Assignee: General Electric CompanyInventors: Anthony Yu-Chung Ku, Kevin Paul McEvoy, Patrick Daniel Willson, Parag Parkash Kulkarni, Roger Allen Shisler, Anoop Muralidhara Kurup
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Patent number: 8449658Abstract: A high-pressure capillary degas assembly includes an assembly block having an eluent inlet and an eluent outlet, and a separator support extending therebetween, a wash inlet and a wash outlet and a groove extending therebetween, a tubular separator extending within the assembly block, the separator having an inner surface and an outer surface, the inner surface defining an eluent fluid line fluidly interconnecting the eluent inlet and outlet, the outer surface abutting against the separator support and enclosing the groove to define a wash line within the groove. The separator may be configured to retain liquid in the eluent fluid line at a first pressure and allow gas to flow through the separator to the wash fluid line at a second pressure lower than the first pressure. A method of using the high-pressure capillary degas assembly is also disclosed.Type: GrantFiled: February 14, 2011Date of Patent: May 28, 2013Assignee: Dionex CorporationInventors: Michael McAdams, Milton Liu, Gary L. Gleave
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Patent number: 8449659Abstract: The present invention is directed to contactors, modules, components, systems, and/or methods of manufacture, and/or methods of use including degassing liquids. The contactor or module is integrally potted, has planar, disc shaped end caps, and a cylindrical housing or shell receiving and supporting a membrane structure. Each of the planar disc shaped end caps has a central opening therein adapted to receive a liquid end port or nozzle and is held in place in the housing or shell by at least one retaining element. The integrally potted membrane structure is preferably potted in place in the housing or shell by an inverted potting process involving the use of a removable plunger or plug to recess the potting.Type: GrantFiled: September 28, 2011Date of Patent: May 28, 2013Assignee: Celgard LLCInventors: Gareth P. Taylor, Elmer Wayne Bouldin, Jr., Timothy D. Price, Tony R. Vido
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Patent number: 8449651Abstract: Disclosed herein is a method for preparing a crosslinked hollow fiber membrane. The method involves spinning a one phase solution comprising a monoesterified polyimide polymer, acetone as a volatile solvent, a spinning solvent, a spinning non-solvent, and optionally an organic and/or inorganic additive, wherein the volatile solvent is present in an amount of greater than 25 wt. % to about 50 wt. %, based on the total weight of the solution.Type: GrantFiled: August 25, 2010Date of Patent: May 28, 2013Assignee: Chevron U.S.A. Inc.Inventor: Shabbir Husain
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Patent number: 8435332Abstract: A module and an apparatus incorporating such module utilizing a plurality of tubular membrane elements, each configured to separate oxygen from an oxygen containing feed stream when an electric potential difference is applied to induce oxygen ion transport in an electrolyte thereof. The tubular membrane elements can be arranged in a bundle that is held in place by end insulating members. The insulating members can be positioned within opposed openings of end walls of a heated enclosure and can incorporate bores to allow an oxygen containing feed stream to flow past exposed ends of the tubular membrane elements for cooling the end seals of such elements. Further, first and second manifolds can be provided in a module in accordance with the present invention to collect separated oxygen from two separate portions of the tubular membrane elements.Type: GrantFiled: April 8, 2011Date of Patent: May 7, 2013Assignee: Praxair Technology, Inc.Inventors: Gervase Maxwell Christie, David M. Reed, Jerrine L. Neff, Arthur C. Selover
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Patent number: 8430949Abstract: A liquid degassing apparatus is arranged to limit pervaporation through a membrane by establishing a pervaporation control space at a permeate side of the membrane. The pervaporation control space is defined in a vacuum chamber between the membrane and a shield member. The shield member may be substantially gas and liquid impermeable to maintain an environment in contact with the permeate side of the membrane that is relatively rich in solvent vapor concentration, thereby limiting further liquid pervaporation across the membrane.Type: GrantFiled: March 25, 2011Date of Patent: April 30, 2013Assignee: IDEX Health & Science LLCInventors: Yuri Gerner, Quan Liu, Carl W. Sims
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Patent number: 8425656Abstract: An apparatus and method for enhancing the heat and water recovery from a transport membrane condenser (TMC) includes a non-moving mechanical device inserted into the TMC tubes to increase the heat transfer efficiency via the enhancement of the fluid turbulence and/or surface area. The apparatus and methods may be applied to porous tubes arranged in a spaced array, similar to a conventional shell and tube heat exchanger device. Other configurations of the TMC may be conceived and adapted for use with the described apparatus and method.Type: GrantFiled: January 25, 2011Date of Patent: April 23, 2013Assignee: Media and Process Technology, Inc.Inventors: Richard J. Ciora, Jr., Paul K T Liu, Eric Cheponis
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Patent number: 8414684Abstract: A degas assembly including a low pressure fluid channel for carrying a wash fluid at a first pressure, a pressurized channel for carrying eluent including a gas at a second pressure higher than the first pressure, and a degas separator defining a fluid barrier between the low pressure fluid channel and pressurized fluid channel, the separator configured to retain liquid in the pressurized fluid channel and allow gas to flow through the separator to the low pressure fluid channel. The pressurized fluid channel may extend along an outer periphery of the low pressure fluid channel. The eluent may be received from an eluent generator at a pressure of at least about 3300 psi, and in various embodiments up to about 5000 psi. A liquid chromatography system and method are also disclosed.Type: GrantFiled: June 1, 2010Date of Patent: April 9, 2013Assignee: Dionex CorporationInventors: Yan Liu, Christopher A. Pohl, Michael McAdams, Hamish Small, Zhongqing Lu, Milton Liu, Khosro Moshfegh
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Patent number: 8414693Abstract: To provide a humidifying membrane module that is reduced in weight, size and cost by making a case in a single layer structure, the humidifying membrane module has a hollow fiber membrane bundle constructed from plural hollow fiber membranes, a case accommodating the hollow fiber membrane bundle, a first flow passage extending through hollows of the hollow fiber membranes, and a second flow passage extending through the outer surface sides of the hollow fiber membranes, the membrane bundle and the case are simultaneously integrated at both ends of the membrane bundle by using potting members sealing gaps between the membrane bundle and the case, an inlet and an outlet constructing the first flow passage are formed at the both ends of the case respectively, and an entrance and an exit constructing the second flow passage are formed in side surfaces near the both ends of the case respectively.Type: GrantFiled: July 7, 2008Date of Patent: April 9, 2013Assignee: NOK CorporationInventor: Takayuki Takagi
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Patent number: 8414686Abstract: The present invention is directed to degassing devices for dialysate circuits. One embodiment has a first housing and a second housing positioned within the first housing in an annular relationship. A second embodiment comprises a dialysate regeneration system with urease, a dialyzer, and a housing with an external wall, where the external wall is exposed to atmosphere and comprises a material that passes gas but does not pass liquid and where the housing is positioned between the urease and dialyzer.Type: GrantFiled: September 21, 2011Date of Patent: April 9, 2013Assignee: Fresenius Medical Care Holdings, Inc.Inventors: Victor Gura, Carlos Jacobo Ezon, Masoud Beizai
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Publication number: 20130081537Abstract: A hollow fiber fluid separation device includes a hollow fiber cartridge, comprising a plurality of hollow fiber membranes arranged around a central tubular core, a first tubesheet and a second tubesheet encapsulating respective distal ends of the hollow fiber bundle. The tubesheets have boreholes in fluid communication with bores of the hollow fiber membrane. In at least one of the tubesheets, the boreholes are formed radially and are in communication with the central tubular core. The hollow fiber fluid separation device can be utilized in liquid separation applications such as ultrafiltration and in gas separation processes such as air separation. The design disclosed herein is light weight and compact and is particularly advantageous at high operating temperatures when the pressure of the feed fluid introduced into the bores of hollow fibers is higher than the pressure on the shell side of the device.Type: ApplicationFiled: June 8, 2012Publication date: April 4, 2013Inventors: Benjamin Bikson, Stephen Etter, Nathaniel Ching
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Patent number: 8409325Abstract: There is disclosed an asymmetric gas separation membrane exhibiting both improved gas separation performance and improved mechanical properties, which is made of a soluble aromatic polyimide comprised of a repeating unit represented by general formula (1): wherein B in general formula (1) B comprises 10 to 70 mol % of tetravalent unit B1 represented by general formula (B1) and 90 to 30 mol % of tetravalent unit B2 represented by general formula (B2), and A in general formula (1) comprises 10 to 50 mol % of bivalent unit A1 represented by general formula (A1a) or the like and 90 to 30 mol % of bivalent unit A2 represented by general formula (A2a) or the like.Type: GrantFiled: September 30, 2009Date of Patent: April 2, 2013Assignee: Ube Industries, Ltd.Inventors: Toshimune Yoshinaga, Makoto Nakamura, Tomonori Kanougi, Yoji Kase, Kenji Fukunaga
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Patent number: 8409324Abstract: An air dehydration membrane module is provided with a sweep gas which is taken from the waste gas of a pressure swing adsorption (PSA) unit. No additional compressor is required, other than the compressor forming part of the PSA unit. In another embodiment, the sweep gas includes the combination of dried product gas, taken from the dehydration membrane module, and a supplemental gas, which may be ambient air, or permeate gas from an air separation membrane, or waste gas from a PSA unit. An air ejector combines the streams, without the use of an additional compression step, and the combined gas is used as a sweep stream for the dehydration module. The invention also includes the method of selecting an optimum point at which the sweep gas is injected into the module.Type: GrantFiled: November 20, 2012Date of Patent: April 2, 2013Assignee: Generon IGS, Inc.Inventors: Marc Straub, John A. Jensvold, Raymond K. M. Chan