Abstract: A membrane air drier utilizes an orifice to serve as the sweep air inlet with a sweep diffuser placed a short distance from the orifice. Preferably, an open channel extends from the product end of the membrane module on the shell side of the fibers with a porous diffuser at one end of the open channel and an orifice at the other end of the channel.

Abstract: A fully perfluorinated thermoplastic hollow fiber membrane fluid-fluid contactor and a process for manufacturing the contactor is described. The contactor has a unitary end structure produced by a single step potting and bonding process. The contactor can be operated with low surface tension liquids and in harsh chemical environments.

Abstract: A high carbon content membrane and method for making the same are disclosed. The carbon membrane includes an asymmetric hollow filamentary carbon membrane, including a partial carbonization product of an asymmetric hollow filament including an aromatic imide polymer material. The carbon membrane is at least 95 weight percent carbon, and has a dense layer located in the outside surface portion of the hollow filamentary membrane and a porous base layer continued from the dense layer and located in the inside portion of the hollow filamentary membrane. A process for separating CO2 from natural gas is described including: contacting a mixture of CO2 and natural gas with a first side of a carbon membrane in a manner to cause a portion of the mixture to pass through the carbon membrane to a permeate side. The resulting mixture on the permeate side becomes enriched in CO2 over that of the mixture on the first side. The contacting step occurs at a pressure of at least about 200 psia.

Abstract: A method and system is provided for combusting a fuel having application to a heat consuming device such as a boiler or furnace or a reactor. An oxygen-containing stream is introduced into one or more oxygen transport membranes subjected to a reactive purge or a sweep gas. The oxygen transport membrane(s) can advantageously be subjected to a reactive purge or a sweep gas passing in a cross-flow direction with respect to the membranes to facilitate separation of the oxygen. In case of a reactive purge, temperature control of the oxygen transport membrane(s) is effectuated by the use of a suitable heat sink. Further, the oxygen transport membranes can be arranged in a row and be connected in series such that retentate streams of ever lower oxygen concentrations are passed to successive oxygen transport membranes in the row. The fuel or sweep gas can be introduced in a direction counter-current to the bulk flow of the retentate streams.

Abstract: The present invention is directed to a method for debubbling an ink. The method comprises the steps of: providing an ink having an entrained gas; providing a membrane contactor comprising a plurality of integrally asymmetric hollow fiber microporous membranes; a membrane defining within the contactor a lumen side and a shell side; providing a vacuum source; passing the gas entrained ink through the shell side of the contactor; applying the vacuum source to the lumen side of the contactor; and debubbling the gas entrained ink across the membrane.

Abstract: A humidifier includes a housing that accommodates bundles of a large number of water permeable hollow fiber membranes arranged along the longitudinal direction of the housing. Two different gasses having different moisture contents pass through outside and inside of the bundle of the hollow fiber membranes separately to exchange their moistures through the hollow fiber membranes resulting in the dry gas of lesser moisture content being humidified. A heating or temperature adjuster is provided to maintain the temperature of the exhaust gas introduced to the humidifier or the bundles of hollow fiber membranes substantially at a temperature of a fuel cell in operation.

Abstract: A hollow fiber membrane dehumidification device with a housing chamber open to atmosphere via a through hole. Hollow fiber membranes are disposed in the housing chamber and cause compressed air entering from one end to flow through and be discharged at the other end as dehumidified air by discharging moisture to the outside housing chamber. A reflux route is provided to permit a portion of the dehumidified air to flow back to the housing chamber as purged air. First and second orifices are provided on the reflux route wherein the second orifice has an opening diameter larger than that of the first orifice.

Abstract: A hollow fiber membrane dehumidification device that possess hollow fiber membranes that cause the compressed air supplied from one end to the interior to flow through and at the same time discharge moisture in the compressed air to the outside, and by so doing exhausts the compressed air to the other end as dehumidified air. There is a reflux route that causes a portion of the dehumidified air exhausted from the hollow fiber membranes to flow back to the outside of the hollow fiber membranes as purged air and a variable restrictor that is provided on the reflux route that increases or decreases the opening-closing volume in accordance with the increase or the decrease of the pressure of the compressed air that flows through the interior of the hollow membranes.

Abstract: The present invention provides a hollow fiber membrane gas separation assembly having an integral purge control aperture or purge reflux system which is internal to the hollow fiber apparatus. The assembly is particularly useful for separating water vapor from a gas stream.

Abstract: Contaiminated hydrogen gas from a catalytic steam reformer is purified by passing it through a membrane assembly having a metallic membrane sealed between two tubular stainless steel members having perforations (or being formed as screen or mesh) and having an encapsulating chamber around it. Pressure regulating valve means in recycle path of residual gas flowing out of the membrane assembly maintains a constant pressure of contaminated hydrogen gas in the membrane assembly. The purified hydrogen gas may be further purified, if needed, by directing the purified hydrogen gas out of a side tube of the chamber through a second encapsulated membrane assembly that is a replica of the first encapsulated membrane assembly. A directional valve may be selectively set to recycle residual gas out of the first membrane assembly until it is virtually free of hydrogen. Residual gas out of the second membrane assembly approaches being 100% free of hydrogen and may always be exhausted to a burner.

Abstract: An integral hollow fiber membrane gas purification apparatus is disclosed. The apparatus comprises one or more filtration elements and a hollow fiber membrane cartridge placed coaxially in a common housing. In some embodiments, the filtration elements are omitted and the hollow fiber membrane cartridge is employed as a combined gas separation/filtration device. The apparatus of this invention is particularly useful for conditioning compressed air that includes the removal of both suspended matter and water vapor.

Abstract: Process for producing integrally asymmetrical hydrophobic polyolefinic membranes with a separation layer, in particular for gas exchange, via thermally induced liquid-liquid phase separation. A solution of at least one polyolefin in a solvent system containing a compound A and a compound B is extruded to form a shaped object. Compound A is a strong solvent and compound B a weak non-solvent for the polymer. After leaving the die, the shaped object is cooled using a solid or liquid cooling medium, which does not dissolve the polymer and does not react chemically with it, until the phase separation and solidification of the high-polymer-content phase take place.

Abstract: A flow-through vacuum degassing unit for degassing a liquid includes a vacuum chamber adapted to be connected to a source for creating a vacuum in the chamber, an inlet and an outlet connection for admitting and discharging liquid to be degassed, a tube for conducting the liquid through the chamber, wherein the tube is a gas permeable polymeric resin material, and a control circuit for operating the source for creating a vacuum in the chamber responsive to a sensed vacuum level in the chamber.

Abstract: A method and apparatus for purifying an aqueous suspension comprising feeding an aqueous suspension containing fine particles comprising an inorganic component from the outer surface of a wavy hollow fiber membrane having an outer diameter of from 0.5 to 3.1 mm to filter, followed by physical wash of the hollow fiber membrane. The purifying method can reduce the damage of the membrane outer surface during the physical wash step, prevent open pores on the surface from covering and achieve stable filtration. The hollow fiber membrane bundle can be produced by having a pulsation flow contacted with the hollow fiber material being extruded from the double spinning nozzle under specific conditions and cooling and solidifying or coagulating it while shaking.

Abstract: The present invention relates generally to on board inert gas generating systems, and more particularly, to an on board inert gas generating system having a fast warm up feature. Even more particularly, the present invention relates to a method and apparatus for quickly warming up a permeable membrane air separation system.

Abstract: A membrane separation process and apparatus for carrying out the process involves contacting a gas feed mixture with one side of a selectively gas permeable membrane and allowing the components to pass through the membrane to form a permeate composition in contact with the opposite side of the membrane and leave a retentate composition on the feed side of the membrane. The process includes introducing a sweep flow of feed gas into the permeate composition near the membrane at a rate effective to increase the enrichment of the retentate composition in the less preferentially permeable component of the feed mixture to a concentration much greater than is achieved without the sweep flow. This process is especially well suited to improve single stage membrane separation effectiveness so that the need for conventional multistage separations to achieve moderate to high purity retentate compositions can be obviated.

Abstract: A hollow fiber membrane gas separation apparatus of a compact design suitable for separation and purification of gases is disclosed. The apparatus comprises an outer housing that consists of a detachable bowl and a head closure, and a removable hollow fiber membrane cartridge positioned therein. The cartridge contains several concentric separation zones and provides for efficient countercurrent flow configuration between the feed gas on the shell side and the permeate sweep gas on the lumen side of the hollow fiber membranes.

Abstract: A hollow fiber membrane gas separation apparatus of a compact design suitable for separation and purification of gases is disclosed. The apparatus comprises an outer housing that consists of a detachable bowl and a head closure, and a removable hollow fiber membrane cartridge positioned therein. The cartridge contains a concentric tubular inner core member and is surrounded by a shell and at least one end closure. The cartridge is attached by its first axial end in a sealed and removable manner to a gas flow conduit positioned coaxially in the housing closure wherein said conduit being in fluid communication with a gas inlet or product gas outlet port formed in the housing head closure and by its second axial end to a waste gas exit port in the bowl.

Abstract: An asymmetric membrane is formed using a mixture of two or more different polymers including at least one type of polyimide. It is thereby possible to produce a gas separation membrane with low permeation resistance (a high permeation rate) for permeate gases passing through the porous layer of the membrane, which also maintains a practical level of mechanical strength of the membrane and has excellent water resistance and hot water resistance.

Abstract: An apparatus for extracting a gas, in particular hydrogen, from a fluid stream utilizing a plate membrane flattened with a wave spring on the low pressure side of the membrane and a turbulence generator on the high pressure side. Alternately, the membrane is folded and wrapped against a central conduit within the membrane fold. Extraction membranes have a substrate layer of Ta—W, V—Co, V—Pd, V—Au, V—Cu, V—Al, Nb—Ag, Nb—Au, Nb—Pt, Nb—Pd, V—Ni—Co, V—Ni—Pd, V—Nb—Pt or V—Pd—Au alloy or combination thereof and a first layer affixed to the outer surface of the substrate towards a mixed gas flow which is composed of palladium, platinum, rhodium, or palladium alloys.

Abstract: The invention relates to a permeation installation comprising: a single pressure resistant chamber (30), a plurality of permeation modules (34, 36) disposed within the chamber, each module being constituted by at least one permeator formed of hollow fibers with porous walls and being disposed within an envelope (38) provided with perforations placing in communication the external portion of each module and the common gaseous circuit, elements (32) to supply the installation with the gaseous mixture to be treated, elements (46) to recover the fraction of the gaseous mixture having passed through the wall of the fibers; and elements (44) to recover the fraction of the gaseous mixture that has not passed through the wall of the fibers.

Abstract: A multi-channel porous ceramic fiber is provided, preferably having a particular geometry, together with a filtration and/or reaction module comprising such fibers and a precursor paste for the fiber comprising a compression binder as the extrusion binder.

Abstract: An apparatus for the separation of hydrogen from a gas mixture comprising hydrogen and at least one further gas, wherein hollow structures with a wall consisting of a membrane permeable for hydrogen are disposed in a diffusion chamber, the mixture can be led into and through the diffusion chamber, the hydrogen which diffuses through the membrane into the hollow structures can be led out of the hollow structures and the gas mixture depleted with respect to its hydrogen content can be led out of the diffusion chamber is characterized in that the hollow structures comprise crossed tubes which open at least at their one end into a collecting chamber which leads away the hydrogen. Through this arrangement of the hollow structures, turbulence arises in the diffusion chamber which improves the efficiency of the separation process.

Abstract: Water- and ion-conducting membranes composed of sulfonated statistical arylvinyl polymers, the arylvinyl polymer comprising at least one arylvinyl monomer and at least one olefin monomer and wherein aromatic moieties derived from the arylvinyl monomer are at least partially sulfonated, are used as proton-conducting membranes for production of electricity, as water-conducting membranes for humidification of fuel gases in fuel cells and heat and moisture exchange in heating/ventilation/air conditioning systems. Water-conducting membranes composed of sulfonated arylvinyl polymers, the arylvinyl polymer comprising at least one arylvinyl monomer and wherein aromatic moieties derived from the arylvinyl monomer are at least partially sulfonated are used for desalination of seawater.

Abstract: A membrane air drier utilizes an orifice to serve as the sweep air inlet with a sweep diffuser placed a short distance from the orifice. Preferably, an open channel extends from the product end of the membrane module on the shell side of the fibers with a porous diffuser at one end of the open channel and an orifice at the other end of the channel.

Abstract: A membrane contactor degasses a liquid. A liquid having a dissolved gas is introduced into a contactor which is connected to a vacuum source. The contactor has a perforated core, a plurality of hollow fiber membranes, a tube sheet affixing each end of the fibers, and a shell having a liquid egress. The shell encloses the fibers, the tube sheet, and the core. The hollow fiber lumens are in fluid communication with the vacuum source. Liquid enters the contactor via the core's open end radially exits the core, crosses over the membranes within the shell, and exits the contactor by the liquid egress. The dissolved gas thereby diffuses from the liquid across the membrane into the lumen. The liquid exiting may have a dissolved gas content to less than 1 ppb.

Abstract: An oxygen separation and combustion apparatus such as a boiler or a nitrogen generator in which a plurality of fluid passages and oxygen transport membranes are located within a combustion chamber. The oxygen transport membranes separate oxygen from an oxygen containing gas, thereby to provide the oxygen within the combustion chamber to support combustion of a fuel and thereby to generate heat. The fluid passages are positioned to allow a portion of the heat to be transferred from the combustion to the oxygen transport membranes to heat said oxygen transport membranes to an operational temperature and a further portion of the heat to be transferred from the combustion to the fluid, thereby to heat the fluid and also, to help stabilize the operational temperature of said oxygen transport membranes. Fuel is introduced into the combustion chamber by injection or as a mixture with circulated flue gas.

Abstract: A partially carbonized asymmetric hollow fiber separation membrane which is a hollow fiber separation membrane having an asymmetric structure obtained by partial carbonization of an aromatic polyimide hollow fiber separation membrane with an asymmetric structure, wherein the thickness of the aromatic polyimide hollow fiber membrane to be partially carbonized is 8-50 &mgr;m, the thickness of the hollow fiber separation membrane obtained by the carbonization is 8-45 &mgr;m, and the carbon content of the hollow fiber membrane obtained by partial carbonization is at least 1.05 times the carbon content of the aromatic polyimide hollow fiber membrane to be partially carbonized, and no greater than 90 wt %; also, a process for its production and a gas separation method employing it.

Abstract: The gas permeable member makes it possible to reduce the number of fabrication steps and the fabrication cost, thereby lowering the cost. In addition, the gas permeable member exhibits excellent gas permeability and excels in durability. Further, the gas permeable member exhibits the effect of alleviating the buildup of stress in a hydrogen storage container due to the expansion of a hydrogen storage alloy.

Abstract: Improved polymer blends, and polymer blend membranes having improved mechanical properties are provided by alteration of the critical solution temperature of the polymer blend spinning solution through the incorporation of organic or inorganic complexing agents.

Abstract: A modified system of an adsorption/regeneration type dehumidifier that is equipped with a dehumidification case that internally supports an adsorption/regeneration type dehumidification cartridge that is inserted from an opening part. A check valve is provided on this dehumidification case that blocks the back flow from the secondary side by its being arranged in the passage that connects with the dry air discharge part of the dehumidification cartridge. A regeneration restrictor is arranged inside fastening holes formed inside the dehumidification case parallel to the check valve. A bottom cover supports the dehumidification cartridge while covering the opening part of the dehumidification case and a modified system of a dehumidifier that includes a hollow-fiber membrane type dehumidification cartridge that can be supported on the interior of the dehumidification case. There is a stopper plug for stopping up the fastening holes of the regeneration restrictor.

Abstract: The invention relates to an apparatus for performing membrane gas/liquid absorption at elevated pressure, comprising a pressure vessel in which a membrane unit is provided for separate feed-through of the gas phase and the liquid phase, in such a way that exchange of components to be absorbed can take place between the gas phase and the liquid phase, the flow direction of the gas phase through the absorber being essentially perpendicular to the flow direction of the liquid phase through the absorber. The invention further relates to a method for performing gas/liquid membrane absorption employing this absorber, in particular for the absorption of CO2, H2S, mercury (vapor) and/or water (vapor) from a gas phase at elevated pressure. The invention finally relates to a method for refining natural gas using the absorber and method according to the invention.

Abstract: Apparatus and method for the deoxygenation of liquid fuel in the fuel system of an energy conversion device, such as an aircraft gas turbine engine. A membrane filter is disposed in the fuel system and is selected to remove oxygen from the fuel, typically a hydrocarbon, while excluding the fuel. The membrane filter may be permeable or porous to the oxygen and, in a preferred embodiment, is of polytetraflouroethylene. Fuel with dissolved oxygen (typically from air) is flowed in contact with one surface of the membrane filter, and removed oxygen is collected from the opposite surface of the filter. The difference in the partial pressure of oxygen across the membrane filter may be controlled to regulate the driving force for moving oxygen through the membrane. Reduction of the oxygen concentration in jet fuel to less than 10 ppm at liquid space velocities of 100/hr and greater are attained.

Abstract: A gas permeable membrane apparatus comprises a chamber having an inlet-end connector portion and an outlet-end connector portion; a tube bundle housed within said chamber and composed of a plurality of gas-permeable tubes; a cylindrical coupling insertable into each of the connector portions of said chamber, having at a first end thereof a line connector portion for connecting a liquid inlet line or outlet line and having at a second end thereof a tube bundle connector portion for connecting said tube bundle; a fastener member for threadably fastening each of said cylindrical couplings; and a ferrule arranged about the outer peripheral surface of each said cylindrical coupling interposed between said coupling and said connector when fastening said coupling with said fastener member so as to maintain a gas-tight seal of said cylindrical coupling.

Abstract: A flow-through vacuum degassing unit for degassing a mobile phase includes a vacuum conduit adapted to be connected to a source for creating a vacuum in the conduit, an inlet port and an outlet port for admitting and discharging the mobile phase to be degassed, a degassing tube for conducting the mobile phase through the conduit, wherein the degassing tube is a gas-permeable, liquid impermeable material. In a particular embodiment, the degassing tube receives multiple mobile phases blended together in a discrete volume of desired composition.

Abstract: The invention includes a process for separating CO2 from natural gas including: contacting a mixture of CO2 and natural gas with a first side of a carbon membrane in a manner to cause a portion of the mixture to pass through the carbon membrane to a permeate side. The resulting mixture on the permeate side becomes enriched in CO2 over that of the mixture on the first side. The carbon membrane includes an asymmetric hollow filamentary carbon membrane, including a partial carbonization product of an asymmetric hollow filament including an aromatic imide polymer material. The carbon membrane is at least 95 weight percent carbon, and has a dense layer located in the outside surface portion of the hollow filamentary membrane and a porous base layer continued from the dense layer and located in the inside portion of the hollow filamentary membrane. The contacting step occurs at a pressure of at least about 200 psia.

Abstract: The dryer for compressed air comprises a filter bowl (20), which has an inlet (22) for damp compressed air, an outlet (24) for dried compressed air, a scavenging air inlet (26) and a scavenging air outlet (28). A membrane is accommodated in the filter bowl (20). The membrane lets selectively water steam flow through and has two sides. One side of the membrane is stroked by the compressed air, while scavenging air flows on the other side of the membrane. A feeder pipe (32) is provided, through which dried compressed air coming from the outlet (24) is fed into the scavenging air inlet (26). A closing device (34, 36, 38) is arranged in the feeder pipe (32) and has a closed position. The closed position depends on the consumption of compressed air in such a way that more or less scavenging air is made available when more or less compressed air is taken by a consumer device, operated by dried compressed air.

Abstract: An oxygen separator and method for separating oxygen from a heated oxygen containing gas that employs oxygen-selective ceramic membranes of elongated, tubular configuration within a duct for separation of oxygen from a heated gas. The duct can be attached between the exhaust of a gas turbine and a power generator driven by the exhaust or can be connected to one or more burners of a gas turbine. Supplementary compressed feed air may be added at a flow rate at least equal to that of the permeated oxygen for cooling and flow balancing purposes. A purge stream can also be introduced. Additionally, combustor tubes fabricated from an oxygen-selective ceramic membrane material may also be provided to produce combustion products that in turn can be used as a purge for downstream oxygen-selective ceramic membranes.

Abstract: Multicomponent hollow fiber membrane tubesheets are disclosed that provide for improved membrane performance, particularly at high operating pressures. The multicomponent tubesheets have an epoxy resin having, when cured, different degrees of hardness in different portions of the tubesheet. Methods for producing such multicomponent tubesheets are also provided.

Abstract: The invention relates to a method for producing a membrane module, comprising a plurality of bar-shaped ceramic filter elements disposed parallel to each other and stretched on the ends of the bay by covers, which extend perpendicular to said bars. Said modules also comprise sealing elements provided in-between the ends of the bars in addition to holes in the covers. The invention is characterized by the following features: initially, the individual sealing element is partially produced by finishing the inner hole thereof intended for surrounding the end of the bar to its final size while the outer surface of the sealing element remains unprocessed so that a sealing blank is formed; the sealing blank is then inserted into a support having outer dimensions in the insertion area corresponding to the mean outer dimensions of all filter elements or a plurality of filter elements.

Abstract: The invention relates to a permeation installation comprising:

Abstract: A flow-through vacuum degassing unit for degassing a liquid includes a vacuum chamber adapted to be connected to a source for creating a vacuum in the chamber, an inlet and an outlet connection for admitting and discharging liquid to be degassed, a tube for conducting the liquid through the chamber, wherein the tube is a gas permeable polymeric resin material, and a control circuit for operating the source for creating a vacuum in the chamber responsive to a sensed vacuum level in the chamber.

Abstract: A reactor for carrying out gas/liquid/solid phase reactions, comprises a housing (1) which encloses an essentially closed reaction chamber (2) for holding a first liquid phase, the solid phase and a gas phase fed through the chamber; at least one feed (3), connected to the reaction chamber, for feeding a first liquid phase to the reaction chamber (2); at least one hollow fiber (4), the wall of which defines an internal flow channel for at least removing a second liquid phase, such that exchange of matter can take place between the reaction chamber (2) and the flow channel through the wall of hollow fiber (4); at least one discharge (6), connected to the flow channel, for removing the second liquid phase; at least one gas inlet (7) and at least one gas outlet (8), connected to reaction chamber (2) such that, in the use position, the at least one gas inlet (7) opens essentially into the bottom of the reaction chamber (2) and the at least one gas outlet (8) is located essentially at the top of the reaction chamb

Abstract: A gas recovery device utilizes membranes of a gas permeable, liquid impermeable substance to strip gas from gas-containing liquids, such as brine in subterranean geological formations. The device includes a shell defined by perforated outer walls and a plurality of elongated permeation tubes. Only one end of the tubes is attached to a plenum with the tube lumina in fluid communication with the plenum. The remainder of the tubes is not anchored and therefore is free to move. Substantially liquid-free gas is removed from the plenum through a pipe to a remote facility for storage and use. The gas recovery device can be deployed within the casing of a well suspended by the product discharge pipe and immersed in gas-containing brine flowing from a natural geological formation. The brine seeps into the well casing and flows through the perforations to surround the permeation tubes.

Abstract: A mixed gas-separating membrane module having a high separating efficiency includes a cylindrical container having a mixed gas-feed section, a non-permeated gas-delivery section, and a middle section; a bundle of a plurality of hollow fibers each extending through the middle section and each having an end portion opening to the mixed gas-feed section and an opposite end portion opening to the non-permeated gas-delivery section; a pair of a first disk supporting the hollow fiber end portion opening to the mixed gas-feed section and partitioning the middle section from the mixed gas-feed section, and a second disk supporting the opposite hollow fiber end portions opening to the non-permeated gas-delivery section and partitioning the middle section from the non-permeated gas-delivery section, the first and second disks supporting the hollow fibers so that the hollow fibers are spaced from each other, to leave a continuous space between the hollow fibers; and a cylindrical film member surrounding the hollow fiber

Abstract: The membrane module includes tube membranes (6), which are arranged in the membrane module in coiled, curved form (8). As a result, a greater total membrane surface area per unit of volume, simplified assembly, and processing of material mixtures with a high solid proportion are all attained. The modules are arranged to facilitate cross flow filtration over membrane surfaces disposed between a supply conduit manifold and a discharge conduit manifold. Optionally, the coils are aligned in parallel and are in coaxial relation to each other.

Abstract: A multi-passage capillary arrangement can be formed from ductile glass material into an assembly that has an essentially round outer cross section and multiple capillary passages with diameters of 250 micrometers or less. The multiple capillary assembly provides multiple capillary sized passages of a regularly recurring shape in a single cohesive bundle. The round outer cross section facilitates the use of the multiple capillary by providing a suitable surface for connections. The multiple capillary arrangement can be made by a method that provides uniform or nearly uniform capillary passages throughout the arrangement. The capillaries are useful for chromatograph applications and as flow restrictors.

Abstract: A method of separating at least one gaseous component from a feed comprising a mixture of gases using a liquid membrane barrier and a sweep fluid is disclosed that includes selecting a sweep gas or a sweep liquid membrane and providing a treatment zone in a treatment chamber having a plurality of hydrophobic microporous hollow fibers, the treatment chamber having opposed end walls with ports including feed and membrane inlets and a sweep outlet at one end and a sweep inlet and a feed and membrane outlets at the opposed end and a plurality of hydrophobic elongated microporous hollow fibers extending between the feed and sweep inlet ports and feed and sweep outlet ports respectively and arranged for counter-current flow of feed gas and sweep fluids therethrough.

Abstract: A gas separation membrane device comprising an internally staged permeator containing a three dimensional array of hollow fiber membranes grouped into multiple sets in intimate contact with each other is described. The incorporation of the internally staged permeator, particularly, the arrangement of the multiple sets of fiber membranes in intimate contact with each other, results in improved efficiency of the device, especially for feed streams or membrane types that lead to high permeate flow rate that result in excessive shellside pressure drops.

Abstract: A reactor comprising: a hollow shell defining a hermetic enclosure; a plurality of tube sheets disposed within said hermetic enclosure, a first one of said plurality of tube sheets defining a first chamber; at least one reaction tube each having a first end and an opposing second end, said first end being fixedly attached and substantially hermetically sealed to one end of said plurality of tube sheets and opening into said first chamber, the second end being axially unrestrained; each of said reaction tubes is comprised of an oxygen selective ion transport membrane with an anode side wherein said oxygen selective ion transport membrane is formed from a mixed conductor metal oxide that is effective for the transport of elemental oxygen at elevated temperatures and at least a portion of said first and second heat transfer sections are formed of metal; each of said reaction tubes includes first and second heat transfer sections and a reaction section, said reaction section disposed between said first and second