Abstract: A photographic element comprising a support, a layer containing certain photographically useful fragments and a layer containing a dye mordant composition comprising a polymer having recurring units of the formula: ##STR1## wherein: A comprises polymerized units of ethylenically unsaturated monomers;R is H or alkyl;R.sup.1 is H, alkyl or is a group containing at least one atomatic nucleus;Q is a linking group;Y is H or an inert group;X is a leaving group;E and F are the atoms necesary to complete a 5-7 membered heterocyclic ring;N is 0 to 2;M is 1 to 3;P is 0 or 1;X is 0 to 90 weight percent; andY is 10 to 100 weight percent of the polymer.The polymeric mordants covalently bond with dyes or dye precursors and are especially useful in diffusion transfer processes.
Abstract: Aromatic nitro compounds are disclosed where the aromatic ring contains electron-withdrawing groups and said aromatic nitro compound is capable of undergoing intramolecular nucleophilic displacement after reduction of the nitro group. The compounds are especially useful in photographic elements where an image dye-providing material or a photographic reagent are released upon cleavage from the compound.
Abstract: A novel class of redox releasing compounds contains an N,N-disubstituted carbamoyl ballast group. These compounds can be used in photographic elements and processes to release a dye or other photographically useful group as a function of silver halide development.
Type:
Grant
Filed:
September 9, 1977
Date of Patent:
January 23, 1979
Assignee:
Eastman Kodak Company
Inventors:
Jose M. Fernandez, Michael D. McCreary, Robert E. Ross, Jon T. Staples
Abstract: Polymeric derivatives of tetrazole-5-thiols are useful in conjunction with photosensitive silver halide elements as interlayers to provide interimage control, as dispersants for dye image-forming materials or as silver scavengers.
Abstract: A combination of phthalazine and certain aromatic acids or anhydrides thereof serves as a toner during heat development of exposed dry silver image forming sheet materials.
Type:
Grant
Filed:
August 9, 1976
Date of Patent:
October 31, 1978
Assignee:
Minnesota Mining and Manufacturing Company
Abstract: The invention is directed essentially to photographic material containing, on a carrier, a layer with azo dyestuffs of the formula ##STR1## wherein A, B, X and Y are certain substituents, in a second main aspect azo dyestuffs of the formula ##STR2## wherein B' represents certain substituents and in a third main aspect azo deystuffs of the formulaA.sub.1 --N.dbd.N--B.sub.1 --NH--CO--X.sub.1 --Y--Z.sub.1 --OC--HN--B.sub.1 --N.dbd.N--A.sub.1wherein A.sub.1, B.sub.1, X.sub.1, Z.sub.1 and Y are certain substituents.The photographic materials provide advantages stemming from the use of the dyestuffs of the invention which are distinguished by particularly high fastness to light coupled with excellent bleachability, good resistance to diffusion and advantageous color strength.
Type:
Grant
Filed:
March 15, 1977
Date of Patent:
October 3, 1978
Assignee:
Ciba-Geigy AG
Inventors:
Bernhard Piller, John Lenoir, Alfred Froehlich, Thomas Stauner, Paul Tschopp
Abstract: Photographic elements, processes for forming images in photographic elements and new compounds are disclosed. Generally, the invention relates to immobile compounds which can be used to provide positive images from negative recording-developing photographic materials such as negative silver halide emulsions. The compounds contain a photographically useful group such as a dye or dye precursor and are capable of releasing said photographically useful group under alkaline conditions, and are also capable of reaction with an oxidized silver halide developing agent before substantial release of said photographically useful group occurs, to provide a reaction product having a substantially lower rate of release of said photographically useful group. In specific embodiments, the compounds of this invention contain an electrophilic cleavage group located in the linkage between a ballast group and a photographically useful moiety wherein said electrophilic cleavage group is a carbamic acid derivative.
Type:
Grant
Filed:
October 2, 1974
Date of Patent:
September 14, 1976
Assignee:
Eastman Kodak Company
Inventors:
Donald Lee Fields, Richard Paul Henzel, Philip Thiam Shin Lau, Richard Allan Chasman
Abstract: New polymers and copolymers containing silver and/or copper, useful e.g. in manufacturing dialysis and filtration membranes, ion exchangers, light sensitive layers, catalysts and hydrophilic coatings, are prepared from copolymers or polymer mixtures containing both nitrile groups and strong acidic groups, by bringing them in contact with monovalent silver or copper ions or with their mixtures. Silver and/or copper are attached to nitrile groups by secondary valences, thus forming complex compounds. The probable formulae of the complex groups are: --CN.Ag.sup.+ or perhaps --CN.Ag.sup.+.NC-- and --CN.Cu.sup.+ or perhaps --CN.Cu.sup.+.Cu.sup.+.NC-- , the complex cations forming polymeric salts with strong acidic groups of the same or of an adjoining macromolecule, to which all said nitrile and strongly acidic groups are attached as substituents.