Abstract: Disclosed are coatings made of inorganic materials on molds for glass molding, particularly, a graded coating of element diffusion inhibition and adhesion resistance on molds for glass molding. The graded coating includes a Cr adhesion layer which is bonded with a substrate, a CrN intermediate layer and a CrxWyN(1-x-y) surface layer, where 0.15<x<0.4, and 0.2?y<0.45. The graded coating has excellent crack growth suppression and adhesion resistance.

Abstract: Refractory glass-forming tools, including glass-forming molds incorporating protective metal nitride surface coatings, with optional alumina barrier layers disposed between the mold bodies and coating for high-temperature nitride coating stability, offering particular advantages for the manufacture by direct molding of optically finished glass products such as information display cover glasses from refractory alkali aluminosilicate glasses at molding temperatures up to and above 800° C.

Abstract: A method is disclosed for mechanically bonding a metal component to a ceramic material, comprising providing a metal component comprising an anchor material attached to at least a first portion of one surface of the metal component; providing a ceramic material having a first surface and a second surface, wherein the ceramic material defines at least one conduit extending from the first surface to the second surface, wherein the at least one conduit has a first open end defined by the first surface, a second open end defined by the second surface, a continuous sidewall and a cross sectional area; positioning the ceramic material such that at least a portion of the at least one conduit is in overlying registration with at least a portion of the anchor material; and applying a bonding agent into at least a portion of the at least one conduit.

Abstract: A method for producing a silica container having a rotational symmetry is provided. The method includes forming a preliminarily molded article by feeding a powdered substrate's raw material to an inner wall of an outer frame having aspiration holes with rotating the frame, and forming a silica substrate. The preliminarily molded article is aspirated from an outer peripheral side with controlling a humidity inside the outer frame by ventilating gases present in the outer frame with charging from inside the preliminarily molded article a gas mixture comprised of an O2 gas and an inert gas and made below a prescribed dew-point temperature by dehumidification, and at the same time heated from inside the preliminarily molded article by a discharge-heat melting method with carbon electrodes, thereby making an outer peripheral part of the preliminarily molded article to a sintered body while an inner peripheral part to a fused glass body.

Abstract: A mold for shaping glass can be made by a method that includes providing a mold body having a shaping surface comprising at least about 90% nickel and modifying the composition of the shaping surface of the mold body by exposing the shaping surface to an oxidizing heat treatment. The oxidizing heat treatment may include a ramping heat treatment, a fixed heat treatment, or both the ramping heat treatment and the fixed heat treatment. The ramping heat treatment may include increasing a heating temperature at a rate from about 20° C./hour to about 500° C./hour to a temperature from about 700° C. to about 1000° C. The fixed heat treatment may include holding the heating temperature from about 700° C. to about 1000° C. for a holding time of at least about 5 minutes.

Abstract: The present disclosure relates to high purity nickel molds for use in forming three dimensional glass substrates, along with methods of making three dimensional glass substrates. The mold compositions minimize imperfections in the formed glass substrates providing optical quality shaped glass articles for use in electronics applications.

Abstract: A silica crucible and a fabricating method thereof are provided. The silica crucible includes a vitreous silica body having an inner surface and an outer surface, the inner surface of the vitreous silica body defining a cavity adapted for containing a molten material or a powder material; and a first coating layer formed on the inner surface of the vitreous silica body. The first coating layer is formed by pyrolysing a composite of aluminum, magnesium, calcium, titanium, zirconium, radium, chromium, selenium, barium, yttrium, cerium, hafnium, tantalum, tin or silicon under a predetermined temperature. The first coating layer substantially includes of a nonhomogeneous material, and an interface is defined by the homogeneous material and the nonhomogeneous material between the vitreous silica body and the coating layer. The first coating layer has strong adhesion capability and guarantees the coating layer will not be easily peeled off or removed.

Abstract: Methods for reducing the evaporation rate of platinum and Pt alloys upon their use at high temperatures >1,200° C. in an oxidizing atmosphere include the steps: (A) providing a component made of platinum or a platinum alloy; (B) wrapping the outer surface of the component with a flexible bandage having open porosity and provided with an oxide ceramic material and/or a glass-forming material; (C) using the component at operating temperatures >1,200° C. Methods for scavenging noble metal oxides evaporating or sublimating from the surface of platinum or Pt alloys include: (A) providing a component made of platinum or a platinum alloy; (B) wrapping the outer surface of the component with a flexible bandage having open porosity; and (C) using the component at operating temperatures >1,200° C. Correspondingly wrapped components are also provided.

Abstract: Refractory materials are provided which contain P2O5/R2O3 constituents, where R is Y, Sc, Er, Lu, Yb, Tm, Ho, Dy, Tb, Gd, or a combination thereof, and/or V2O5/R?2O3 constituents where R? is Y, Sc, one or more rare earth elements, or a combination thereof. In certain embodiments, the refractory materials are xenotime-type materials and/or xenotime-stabilized zircon-type materials. The refractory materials can be used in the manufacture of glass and glass-ceramics. For example, the refractory materials, especially those that contain P2O5/R2O3 constituents, can be used as forming structures (“isopipes”) in the fusion process for making flat sheets of glass such as the glass sheets used as substrates in the manufacture of flat panel displays.

Abstract: An oblong conduit (13) for conditioning molten glass is disclosed. The wall (23) of the conduit is composed of a precious metal, e.g., a platinum-rhodium alloy, and can be equipped with precious metal tabs (29) for supporting the upper surface (25) of the wall so as to reduce sag of that surface at such times as the conduit is at an elevated temperature and is not filled with glass. The precious metal tabs (29) can be received in channels (31) formed in a refractory support structure (27). The refractory support structure (27) can be a laminate of two layers (33,35), where one of the layers (33) has a smaller grain structure than the other layer (35), the layers being held together by an adhesive (37).

Abstract: A glass manufacturing container includes a container body and an electron donor. The container body is made of a precious metal or an alloy containing a precious metal and has an inner surface to be brought into contact with molten glass and an outer surface kept from contact with molten glass. The electron donor is electrically connected to the outer surface of the container body. The electron donor is made of an electron donating material capable of donating electrons to the container body at operating temperatures.

Abstract: A mold for making a fused silica crucible includes a cylindrical can having an interior bore. A graphite insert is received in the bore and has an upper surface adapted to form the lower surface of the crucible while the interior bore of the can forms the side wall of the crucible. Silica grain is deposited in the mold while it rotates. Bores formed in the can above the insert and in the insert draw air through the silica during fusion.

Abstract: A knitted fabric made from yarn comprising fibers. At least part of these are metal fibers. The yarn comprises at least 3 bundles or single yarns. The bundles or single yarns have an equivalent bundle diameter which are equal or differ maximally 40%. The fabric is used as a separation cloth (12) between mould (11) and glass (14), which is utilized in the process of forming glass plates, or for covering of press-on rings or press-rings and the means of transport by which glass plates are moved during the forming process. The use of yarns composed of least 3 bundles which more or less have the same equivalent bundle diameter reduces the risks for markings on the glass.

Abstract: The invention relates to a coating for a device for forming glass products, comprising: a first quasicrystalline or approximant or amorphous metallic phase; and a second phase composed of a eutectic alloy having a melting point between 950 and 1150° C. and having a nominal hardness between 30 and 65 HRc; a mould for manufacturing hollow glass products that is provided with this coating; equipment for forming glass in sheets or plates that is provided with this coating; a material constituting this coating; a premixed or prealloyed powder, or a flexible cord or cored-wire that makes it possible to obtain this coating; a thermal spraying process for obtaining this coating.

Abstract: Disclosed is a mold for glass substrate molding, which enables to produce a glass substrate having high flatness by a method for producing a glass substrate through press molding of molten glass. Also disclosed is a method for producing a glass substrate by using such a mold. Specifically disclosed is a mold comprising a lower mold having a first molding surface for pressing a molten glass supplied thereto, and an upper mold having a second molding surface for pressing the molten glass against the first molding surface. In the first molding surface, the surface roughness Ra of the peripheral portion which is in contact with the molten glass after pressing is higher than the surface roughness Ra of the central portion which is in contact with the molten glass before pressing.

Abstract: Refractory glass-forming tools, including glass-forming molds incorporating protective metal nitride surface coatings, with optional alumina barrier layers disposed between the mold bodies and coating for high-temperature nitride coating stability, offering particular advantages for the manufacture by direct molding of optically finished glass products such as information display cover glasses from refractory alkali aluminosilicate glasses at molding temperatures up to and above 800° C.

Abstract: Refractory materials are provided which contain P2O5/R2O3 constituents, where R is Y, Sc, Er, Lu, Yb, Tm, Ho, Dy, Tb, Gd, or a combination thereof, and/or V2O5/R?2O3 constituents where R? is Y, Sc, one or more rare earth elements, or a combination thereof. In certain embodiments, the refractory materials are xenotime-type materials and/or xenotime-stabilized zircon-type materials. The refractory materials can be used in the manufacture of glass and glass-ceramics. For example, the refractory materials, especially those that contain P2O5/R2O3 constituents, can be used as forming structures (“isopipes”) in the fusion process for making flat sheets of glass such as the glass sheets used as substrates in the manufacture of flat panel displays.

Abstract: The present invention provides a metal member that is used so that there is a portion that is exposed to the atmosphere in a float bath, and with which diffusion of Fe into the float bath is inhibited and thereby preventing the defect from being generated on the surface of a plate glass. The present invention relates to a metal member with a film for a float glass manufacturing equipment that has a portion exposed to the atmosphere in a float bath in which the film has a mean thickness of from 50 to 500 ?m and contains Ni and/or Co, Cr and Al2O3 as main components; the Al2O3 content in the film is from 5 to 40% by volume; the Al2O3 is present in a thin film state in the surface direction of the metal member, inside the film; and the metal member contains Fe in an amount of from 40 to 98% by mass and has the film on the exposed portions.

Abstract: A method of forming an optical element forming metal mold to form an optical element, having steps of: laminating a heat insulation layer 13 on a surface of the base member 11 where the optical element is formed; laminating an intermediate metal layer 14 on a surface of the heat insulation layer 13 by thermal spraying; laminating a surface forming layer 15, on which a surface shape to be transferred to the optical element is formed, on the intermediate metal layer 14; wherein the intermediate metal layer 14 is laminated in a way that parts of the heat insulation layer 13 are exposed substantially evenly from the intermediate layer 14.

Abstract: A glass manufacturing container includes a container body and an electron donor. The container body is made of a precious metal or an alloy containing a precious metal and has an inner surface to be brought into contact with molten glass and an outer surface kept from contact with molten glass. The electron donor is electrically connected to the outer surface of the container body. The electron donor is made of an electron donating material capable of donating electrons to the container body at operating temperatures.

Abstract: A composite mold includes a mold base, a protective film provided on the mold base, and a water-cooling heat dissipation system disposed within the mold base. Wherein, the protective film is comprised of with a plurality of RexIry layers and a plurality of SiC layers, the RexIry layers and the SiC layers are alternatively stacked one on another, x is in the range from 0.25 to 0.55, and y is in the range from 0.45 to 0.75. Alternatively, the protective film is comprised of an RexIry layer, a catalyst layer and a carbon nanotube layer in that order, x is in the range from 0.25 to 0.55, and y is in the range from 0.45 to 0.75.

Abstract: The invention relates to a corrosion resistant reactor tube, method for providing a passivating or corrosion resistant coating to the inside of the reactor tube, and a method of making high bismuth glass powders using the corrosion resistant reactor tube.

Abstract: A hard coating combining excellent mold releasability with respect to glass with excellent durability at high temperature environment of 600° C. or more, and a glass molding die having the hard coating are provided. A glass molding die has a hard coating formed on a molding surface of a base. The hard coating includes one or two of W and V, and B, C and N; wherein when a composition of the coating is expressed as Wa1Va2BbCcNd, 0.1?a1+a2?0.5, 0.05?b?0.5, 0.02?c?0.15, 0.05?d?0.5, and a1+a2+b+c+d=1 are given. The hard coating can be formed on the molding surface of the base via an intermediate layer including an amorphous CrSiN film.

Abstract: A glass molding die and renewing method thereof. The molding die for molding glass includes a substrate, a first noble metal layer overlying the substrate, a second noble metal layer overlying the first noble metal layer, a carbon-containing third noble metal layer overlying the second noble metal layer, and a DLC passivation film overlying the third noble metal layer. In addition, the carbon-containing third noble metal layer and the DLC passivation film can be easily renewed.

Abstract: Refractory materials are provided which contain P2O5/R2O3 constituents, where R is Y, Sc, Er, Lu, Yb, Tm, Ho, Dy, Tb, Gd, or a combination thereof, and/or V2O5/R?2O3 constituents where R? is Y, Sc, one or more rare earth elements, or a combination thereof. In certain embodiments, the refractory materials are xenotime-type materials and/or xenotime-stabilized zircon-type materials. The refractory materials can be used in the manufacture of glass and glass-ceramics. For example, the refractory materials, especially those that contain P2O5/R2O3 constituents, can be used as forming structures (“isopipes”) in the fusion process for making flat sheets of glass such as the glass sheets used as substrates in the manufacture of flat panel displays.

Abstract: The present invention provides a molding die for molding glass, which includes a base member, on which a first buffer layer and a protective film are provided in order. The first buffer layer is made of titanium or any material which is easily attacked by a first attack solution. The first attack solution includes hydrofluoric acid. The protective film is made of platinum-iridium alloy, iridium-rhenium alloy, tantalum-ruthenium alloy, molybdenum-ruthenium alloy, molybdenum-rhenium alloy, or molybdenum-hafnium alloy. The method of repairing the molding die includes using the first attack solution to remove the first buffer layer that causes no damage on the base member, and then operating a sputtering process to build a new first buffer layer and a new protective layer on the base member.

Abstract: A quartz glass crucible for use in pulling up a silicon single crystal, wherein it has, at least in the curved portion thereof, a three-layer structure comprising a transparent inner layer being composed of a synthetic quartz glass and having a low Al concentration, a transparent or nontransparent intermediate layer being composed of a natural quartz glass or a mixture of natural and synthetic quartz glasses and having a high Al concentration, and a nontransparent outer layer being composed of a natural quartz glass and having an Al concentration higher than that of the intermediate layer. The quartz glass crucible is reduced in the deformation of the transparent inner layer, and allows the suppression of the change in the amount of dissolution of the quartz glass crucible associated with the pull-up of a single crystal and the achievement of the uniform oxygen concentration in the longitudinal direction of a single crystal.

Abstract: A molding die for molding glass and renewal method thereof. The molding die includes a substrate, a nickel-phosphorous alloy layer, with phosphorous content 30 wt % or less, overlying the substrate, an intermediate layer overlying the nickel-phosphorous alloy layer, and a passivation film overlying the intermediate layer.

Abstract: A molding die for molding glass thousand times is provided in the invention. The molding die includes a substrate, a first intermediate layer of Ni-containing Ir—Re alloy overlying the substrate, a second intermediate layer of metal-containing Ir—Re alloy overlying the first intermediate layer, and a passivation film overlying the second intermediate layer. The Ni concentration of the first intermediate layer decreases gradually with distance from the substrate/first intermediate layer interface. The metal is Cr, Ta, Ti, or Ti—Cr alloy. The metal concentration of the second intermediate layer increases with distance from the first intermediate layer/second intermediate layer interface.

Abstract: The suction feeder for glass processing includes a housing containing a material; a heatable noble metal or noble metal alloy feed line embedded in the housing in a thermally insulated fashion; a connection element at one end of the feed line for connection with a molten glass supply device and an outlet element for operative engagement with a suction device at the other end of the feed line. To prevent aspiration of bubbles through the feed line the material together with the housing surrounds the heatable feed line and has a composition and/or structure such that in operation a negative pressure can be produced on an outer side of the feed line. Preferably this negative pressure is lower than a minimum internal pressure within the feed line that is established during a suction process.

Abstract: Methods of manufacturing glass sheets with manufacturing systems that including platinum-containing components are provided. The method includes providing a barrier coating to reduce the hydrogen permeability of the platinum-containing components which reduces the propensity for blistering of glass sheets made using the components.

Abstract: A structural component for a device for the treatment of melts, especially of glass melts, having a base body of metal or of a metal alloy and a cooling system in which a cooling medium is led through the structural component for the leading-off of heat. The base body is provided with a coating of a material the decomposition temperature of which lies below the temperature of the melt, and the cooling system is designed and arranged in such manner that the temperature of the boundary layer of the melt that immediately surrounds the structural component lies below the decomposition temperature of the coating material.

Abstract: A system and method for suppressing the formation of gaseous inclusions in glass sheets and the resulting glass sheets are described herein. The system includes a melting, fining, delivery, mixing or forming vessel that has a refractory metal component (e.g., platinum component) which has an inner wall that contacts molten glass and an outer wall coated with an oxygen ion transportable material (e.g., zirconia) which is coated with a conductive electrode. The system also includes a DC power source that supplies DC power across the oxygen ion transportable material which causes oxygen ions to migrate from the refractory metal component to the conductive electrode and enables one to control the partial pressure of oxygen around an exterior of the vessel which helps one to effectively prevent hydrogen permeation from the molten glass in order to suppress the formation of undesirable gaseous inclusions and surface blisters within the glass sheet.

Abstract: A plate-shaped shearing knife is provided made of hard metal for shearing off allotments of liquid glass. The hard metal of the shearing knife has a thermal conductivity of at least 85 W/mK. Next to a V-shaped or circular-shaped cutting region -2-, there are edge regions on both sides that do not flare out wedge-like, and have an average width b which is in a range of 5% to 30% of the total width of the shearing knife B in this section.

Abstract: A method for making a lens molding replica die for molding a lens made of glass or a synthetic resin comprises the steps of: (1) making a master die having a reference surface; (2) forming a separating film on the master die; (3) forming an SiC film on the reference surface; (4) machining a surface of the die base member into a prescribed shape and machining the SiC film into a shape in conformity of the surface of the die base member; (5) bonding a die base member onto the SiC film; and (6) separating the SiC film bonded onto the die base member from the master die.

Abstract: A mold (1) for press-molding glass optical articles with high precision includes a mold base (2) having a press surface, and a thin film (3) of (ZrO2)x(Y2O3)y(Al2O3) z material deposited on the press surface; wherein x is in the range from 0.77 to 0.92, y is in the range from 0.05 to 0.15, and z is in the range from 0.03 to 0.08. A thickness of the thin film is in the range from 100 to 500 angstroms. The mold base is made of a hard metallic alloy or a ceramic material. The mold does not adhere to glass material, and is resistant to oxidization. A method for making the mold is also disclosed.

Abstract: A method for manufacturing display tube includes a first stage of press-forming molten glass put in a mold using a plunger, and a second stage of cooling the formed glass after it has been taken out from the mold. After removal of the plunger the heat radiation of the inner face portion of the central panel portion is reduced.

Abstract: A mold (1) for press-molding glass optical articles with high precision includes a mold base (2) having a press surface and a thin film (3) of (ZrO2)x(Y2O3)y material deposited on the press surface, wherein x is in the range from 0.85 to 0.95 and y is in the range from 0.05 to 0.15. A thickness of the thin film is in the range from 100 to 500 angstroms. The mold base is made of a hard metallic alloy or a ceramic material. The mold does not adhere to glass material, and is resistant to various acids, alkalis and other harmful gases. A method for making the mold is also disclosed.

Abstract: A system and method for forming infrared glass optical components are provided. The system includes first and second mold halves having first and second respective faces. The first and second mold halves are configured to be removably coupled such that the first face and the second face form an interface that defines a lens-shaped cavity. A tapered surface of the first face cooperates with a tapered surface of the second face to enhance centering of the first face with respect to the second face.

Abstract: Methods of manufacturing glass sheets with manufacturing systems that including platinum-containing components are provided. The method includes providing a barrier coating to reduce the hydrogen permeability of the platinum-containing components which reduces the propensity for blistering of glass sheets made using the components.

Abstract: A mold has a moling surface of a material containing silicon carbide and/or silicon nitride as a main component and a carbon thin film formed on the molding surface to prevent fusion sticking. A glass substance which has a sag point not higher than 565° C. and a predetermined composition free from arsenic oxide is introduced into the mold. The glass substance is press-formed in a heated and softened condition into a glass optical element of high precision.

Abstract: The invention relates to a method and a device for reducing the adhesion tendency during the hot forming of a glass body, using at least two moulds, which are positioned on either side of the glass body and are brought into contact with the glass body at a temperature, at which the glass is deformable, whereby the moulds are configured with electrically conductive surfaces. The disadvantage of existing methods and devices is that the moulds have a tendency to adhere to the glass body to be formed and that the surface quality of the glass is impaired. The invention therefore discloses a method, according to which the conductive surfaces of the moulds that come into contact with the glass body are supplied with an alternating current. The device for carrying out said method has electrically conductive mould surfaces, which are connected to an alternating current source. This guarantees that a larger processing window is available as a result of the reduced adhesion tendency, i.e.

Abstract: The invention relates to a coating for tools that are used to process heat treated glass, e.g., molten glass or the like, to reduce the adhesion of said glass. The coating consists at least partially of a system of carbon-based layers and/or hard materials containing carbon.

Abstract: A method for fabricating a molding tool for mold glass optical elements therewith is taught. The method comprises the steps of figuring the molding tool to have a predetermined mold surface; applying an attenuating coating to the predetermined mold surface; implanting metal ions through the attenuating coating and into the predetermined mold surface; and removing the attenuating coating leaving the predetermined mold surface with metal ions implanted therein.

Abstract: While avoiding the disadvantages of the screen printing technique employed until now, the invention provides a shaping tool (1) with a structured surface for creating structures on glass (2) which, in an economical way, makes it possible to form high-precision microstructures by local heating of the region of glass to be structured. The shaping tool (1) has a rolling cylinder (3) including a metal hollow cylinder (7) and a shaping sheet (8) secured in a surface contact to it, as well as a continuous shaft (5) for continuously driving the rolling cylinder (3) via drivers (4) coupled to the hollow cylinder (7). Between the shaft (5) and the hollow cylinder (7), an electric heater (6) for targeted local heating of the glass during structuring is disposed in an electrically insulated fashion. The electric heater (6) is advantageously thermally insulated from the shaft (5) with a ceramic cylinder (14).

Abstract: A plate-shaped shearing knife is provided made of hard metal for shearing off allotments of liquid glass. The hard metal of the shearing knife has a thermal conductivity of at least 85 W/mK. Next to a V-shaped or circular-shaped cutting region -2-, there are edge regions on both sides that do not flare out wedge-like, and have an average width b which is in a range of 5% to 30% of the total width of the shearing knife B in this section.

Abstract: Apparatus for delivering a cased glass stream having an inner core glass surrounded by an outer casing glass includes a first or upper orifice ring having at least one orifice for receiving core glass, and a second or lower orifice ring secured beneath the first orifice ring and having a second orifice aligned with each first orifice. A chamber for receiving casing glass is formed between the first and second orifice rings surrounding the second orifice. A bushing is received in an opening in the second orifice ring to form each second orifice in the second orifice ring. The bushing has a first radially extending flange supported on an upper surface of the second orifice ring and a bushing end spaced upwardly from the first flange for admitting casing glass from the chamber to the second orifice.

Abstract: The present invention is directed to an apparatus for thermal treatment of glass and method and thermally treated glass therefrom. The apparatus is capable of supporting the glass during thermal treatment such as tempering, annealing, bending, and/or shaping which can include any cooling or quenching to remove heat or any combination of these. The apparatus is a support member like a ring or outline mold with a horizontal surface suitable for contacting the glass. The support member has at least a surface with or without a coating for contact with the glass of one or more metals having a thermal conductivity such that the glass heated for shaping cools at a rate not much slower than the cooling rate of unsupported sections of the glass. Suitable metals include those with a thermal conductivity of greater than around 16 BTU/(hour×feet×° F.).

Abstract: An oxidation and corrosion resistant coating is applied to glass forming equipment by physical vapor deposition. The coating material is preferably aluminum oxide.

Abstract: A device for the melting of highly pure optical glasses and/or for the treatment of melts is provided. The device is intended for a subsequent refining or homogenization process making use of the skull technique. The device uses a number of coated metal tubes whose surface is free of glass-coloring ions.