Patents Represented by Attorney A. A. Mahassel
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Patent number: 4269922Abstract: Disclosed are positive toners comprised of a toner resin, pigment or colorant, and as a charge inducing material, long chain hydrazinium compounds of the following formula: ##STR1## wherein R.sub.1 is a hydrocarbon radical containing from about 8 to about 22 carbon atoms, R.sub.2 and R.sub.3 are independently selected from hydrogen groups or hydrocarbon radicals containing from about 1 to about 22 carbon atoms and A is an anion which in a preferred embodiment is selected from halides such as chloride, bromide, iodide, sulfate, sulphonate, phosphate, and nitrate. These toners, together with carrier materials can be used to develop images in electrophotographic systems.Type: GrantFiled: March 12, 1979Date of Patent: May 26, 1981Assignee: Xerox CorporationInventors: Chin H. Lu, Peter F. Erhardt
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Patent number: 4251612Abstract: This invention relates to an electrophotographic imaging member or device and an imaging method using this imaging member, which member or device is comprised of a substrate, a layer of a charge carrier injecting material comprised of carbon or graphite dispersed in a polymer, a layer of a charge carrier transport material, a layer of a photoconductive charge carrier generating material and an electrically insulating overcoating layer.Type: GrantFiled: May 12, 1978Date of Patent: February 17, 1981Assignee: Xerox CorporationInventors: Joseph Y. C. Chu, Simpei Tutihasi
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Potassium phthalocyanine complexes, method of preparation, and phthalocyanine purification processes
Patent number: 4197242Abstract: The invention of this application is directed to dipotassium phthalocyanine glyme and crown ether complexes, such as for example dipotassium phthalocyanine bis (methoxy ethyl) ether and dipotassium phthalocyanine bis (18-crown-6) ether. Methods for obtaining these complexes by reacting metal free phthalocyanine with potassium hydroxide and the appropriate glyme or crown ethers in the presence of water is also described. Further methods for obtaining purified metal free phthalocyanines from the glyme and crown ether complexes are disclosed. These materials have many uses including pigments, electrophotographic photoreceptors and photoreceptor devices.Type: GrantFiled: July 3, 1978Date of Patent: April 8, 1980Assignee: Xerox CorporationInventor: Wolfgang H. H. Gunther -
Patent number: 4181772Abstract: Disclosed is an adhesive generating layer for use in an overcoated photoreceptor system, this layer containing a generating pigment dispersed in a copolymer of a siloxane and a dihydroxy compound of the formula: ##STR1## wherein R and R' are independently selected from the group consisting of alkyl, substituted alkyl, alkenes, substituted alkenes, aryl and substituted aryl; Y is a dihydroxy radical; and n is a number of sufficient value that the average molecular weight of the resulting silicone copolymer is between about 2,000 and 250,000. Examples of copolymers include those wherein R and R' are alkyl groups such as methyl and Y is a biphenol such as 2,2-bis-(4-hydroxy phenyl)-propane, one preferred material being a methyl octyl siloxane 2,2-bis-(4-hydroxy phenyl)-propane copolymer.Type: GrantFiled: December 13, 1978Date of Patent: January 1, 1980Assignee: Xerox CorporationInventors: Joseph Y. C. Chu, Richard L. Schank, Simpei Tutihasi
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Patent number: 4175959Abstract: Disclosed is a method of forming finely divided photosensitive trigonal selenium particles which are submicron in size and generally spherical in shape. The method comprises forming an alkaline solution containing selenide and/or polyselenide ions, followed by the precipitation of finely divided trigonal selenium particles from said solution by the addition of an oxidizing agent to said alkaline solution. The trigonal selenium particles are formed into a binder layer photosensitive device by dispersing them with an organic resin in solution with an organic solvent which when applied to a substrate in a uniform layer, is heated to remove the solvent and form the device. Continued heat treatment of the device can result in enhancement of its ability to accept an electrostatic charge.Type: GrantFiled: December 23, 1976Date of Patent: November 27, 1979Assignee: Xerox CorporationInventors: Ronald E. Karam, David J. Swarthout
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Patent number: 4172933Abstract: Disclosed are monomers of the formula: ##STR1## wherein R is ##STR2## R' is hydrogen or methyl; R" is alkyl of 1-10 carbon atoms;X and Y are independently selected from the group consisting of NO.sub.2, halogen, cyano and --CF.sub.3 ;Z is oxygen or dicyanomethylene;A and a' can range from 0-3; andN is 1-10.These monomers can be readily polymerized to polymers suitable for use in electophotographic imaging members and methods.Type: GrantFiled: May 23, 1977Date of Patent: October 30, 1979Assignee: Xerox CorporationInventor: Sam R. Turner
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Patent number: 4161490Abstract: Disclosed are electron acceptor monomers of the formula: ##STR1## wherein R is ##STR2## R' is hydrogen or methyl; X and Y are independently selected from the group consisting of --NO.sub.2, halogen, cyano and --CF.sub.3 ;Z is oxygen or dicyanomethylene; and a and b can range from 0 to 3;With the proviso that at least one of R is ##STR3## AND POLYMERS PREPARED THEREFROM. These monomers and polymers are suitable for use in electrophotographic devices and methods.Type: GrantFiled: September 13, 1978Date of Patent: July 17, 1979Assignee: Xerox CorporationInventor: Sam R. Turner
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Patent number: 4153802Abstract: Disclosed are electron acceptor monomers of the formula: ##STR1## wherein R is ##STR2## or --H; R' is hydrogen or methyl;X and Y are independently selected from the group consisting of --NO.sub.2, halogen, cyano and --CF.sub.3 ;Z is oxygen or dicyanomethylene; andA and b can range from 0 to 3; with the proviso that at least one of R is ##STR3## and polymers prepared therefrom. These monomers and polymers are suitable for use in electrophotographic devices and methods.Type: GrantFiled: May 4, 1977Date of Patent: May 8, 1979Assignee: Xerox CorporationInventor: Sam R. Turner
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Patent number: 4147645Abstract: There is described an electrophotographic toner comprising a resin material and as an additive a sterically hindered phenol, that is a phenol that has its atoms arranged in a particular manner in a molecule and does not undergo an expected chemical reaction due to inhibition by particular atomic groupings. These phenols are effective as thermal stabilizers for toner resins in that they reduce the rate of thermal decomposition and/or act as plasticizers in that they lower the toner melt viscosities and fusing temperatures.Type: GrantFiled: December 23, 1977Date of Patent: April 3, 1979Assignee: Xerox CorporationInventor: Chin H. Lu
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Patent number: 4143225Abstract: Disclosed are monomers of the formula: ##STR1## WHEREIN R is ##STR2## R' is hydrogen or methyl; R" is alkyl of 1-10 carbon atoms;X and Y are independently selected from the group consisting of NO.sub.2, halogen, cyano and --CF.sub.3 ;Z is oxygen or dicyanomethylene;a and a' can range from 0-3; andn is 1-10.These monomers can be readily polymerized to polymers suitable for use in electrophotographic imaging members and methods.Type: GrantFiled: May 23, 1977Date of Patent: March 6, 1979Assignee: Xerox CorporationInventor: Sam R. Turner
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Patent number: 4140529Abstract: A photosensitive member having at least two electrically operative layers is disclosed. The first layer comprises a photoconductive layer which is capable of photogenerating holes and injecting photogenerated holes into a contiguous charge transport layer. The charge transport layer comprises an electrically inactive organic resinous material containing from about 10 to about 75 percent by weight of: ##STR1## where R.sub.1 is selected from the group consisting of an alkyl with from 1 to 12 carbon atoms and an alkyl with from 1 to 12 carbon atoms substituted by aryl groups selected from the group consisting of phenyl, maphthyl, anthryl, and biphenyl and R.sub.2 is selected from the group consisting of methyl, ethyl, chloro, bromo and hydrogen.Type: GrantFiled: September 22, 1977Date of Patent: February 20, 1979Assignee: Xerox CorporationInventors: Damodar M. Pai, John F. Yanus, Milan Stolka
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Patent number: 4117239Abstract: Process for preparation of 2-anthryl and substituted 2-anthryl functional monomers and polymers. In the process for preparation of these monomers, an anthracenic reactant of the formula: ##STR1## wherein X and Y are independently selected from hydrogen, chlorine, bromine, alkyl of 1 to 4 carbon atoms or phenylIs acylated in nitrobenzene under conditions which favor reaction at the two position. The resulting acylated product can then be (a) reacted with an alkylidenephosphorane (Wittig synthesis) or (b) reduced to the corresponding alcohol. Subsequent to such reduction, this alcohol can undergo further modification at the hydroxyl function to form a polymerizable addition monomer.Type: GrantFiled: March 7, 1975Date of Patent: September 26, 1978Assignee: Xerox CorporationInventors: Milan Stolka, James M. Pearson, John F. Yanus
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Patent number: 4116691Abstract: Disclosed are monomers of the formula: ##STR1## R' is hydrogen or methyl; R" is alkyl of 1-10 carbon atoms;X and Y are independently selected from the group consisting of NO.sub.2, halogen, cyano and --CF.sub.3 ;Z is oxygen or dicyanomethylene;a and a' can range from 0-3; andn is 1-10.These monomers can be readily polymerized to polymers suitable for use in electrophotographic imaging members and methods.Type: GrantFiled: May 23, 1977Date of Patent: September 26, 1978Assignee: Xerox CorporationInventor: Sam R. Turner
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Patent number: 4115115Abstract: Disclosed is a method of forming a layer of particulate trigonal selenium dispersed in a polymeric matrix. The method involves:(a) forming a solution containing:I. dibenzoyl peroxide,Ii. an organo selenium compound which interacts with dibenzoyl peroxide to form zero valent selenium, andIii. a matrix polymer which is substantially non-reactive with dibenzoyl peroxide and the organo selenium compound,in a volatile solvent;(b) applying the solution to a substrate in the form of a thin film;(c) allowing the dibenzoyl peroxide and organo selenium compound to react thereby forming amorphous zero valent selenium particles dispersed in the matrix polymer; and(d) heating the matrix polymer/zero valent selenium combination to a temperature and for a time sufficient to convert the amorphous zero valent selenium to its crystalline, trigonal form.Type: GrantFiled: September 23, 1977Date of Patent: September 19, 1978Assignee: Xerox CorporationInventor: Dana G. Marsh
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Patent number: 4115116Abstract: A photosensitive member having at least two electrically operative layers is disclosed. The first layer comprises a photoconductive layer which is capable of photogenerating holes and injecting photogenerated holes into a contiguous charge transport layer. The charge transport layer comprises an electrically inactive organic resinous material containing from about 15 to about 75 percent by weight of N,N'-diphenyl-N,N'-bis(phenylmethyl)-[1,1'-biphenyl]-4,4'-diamine. The charge transport layer while substantially non-absorbing in the spectral region of intended use is "active" in that it allows injection of photogenerated holes from the photoconductive layer, and allows these holes to be transported through the charge transport layer. This structure may be imaged in the conventional xerographic mode which usually includes charging, exposure to light and development.Type: GrantFiled: May 4, 1977Date of Patent: September 19, 1978Assignee: Xerox CorporationInventors: Milan Stolka, Damodar M. Pai, John F. Yanus
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Patent number: 4105445Abstract: A novel liquid developing system is disclosed which employs a rigid member adapted so that it is resilient when employed in operating contact with another rigid member. The resilient member is normally arcuate in configuration and includes a rigid support member and a flexible arcuate surface spaced apart by a resilient member and a means for tensioning the resilient member so that the spacing tension is reduced in an amount sufficient to allow easy movement of the flexible surface with respect to the resilient member.Type: GrantFiled: April 14, 1975Date of Patent: August 8, 1978Assignee: Xerox CorporationInventors: Lional A. Wilson, John Wales, William E. G. Plumtree
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Patent number: 3999481Abstract: A master is formed on a photoconductive surface by first forming an electrostatic charge pattern on the imaging member and developing the charge pattern to form an image of electroscopic marking particles. The developed image is uniformly coated with a thin layer of an adhesive coating and the coated image is then contacted with an adhesive surface transfer element. Upon separation the thin layer of adhesive overcoating fractures. The thin overcoating over the electroscopic particles and these particles transfer to the transfer element so as to leave on the photoconductive member the remaining thin overcoating layer in an image configuration which constitutes the master.The master can be used to make copies by electrostatic, lithographic or gravure printing.Type: GrantFiled: November 15, 1974Date of Patent: December 28, 1976Assignee: Xerox CorporationInventor: Joseph G. Sankus, Jr.
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Patent number: 3951521Abstract: This application relates to an electrolytic process for regulating the transmission of radiant energy, and a radiant energy filter for use in said process. The filter comprises a first film having a dye and a first ionic species therein, an adjacent second film having a second ionic species therein, said first ionic species and said second ionic species being related by a reversible electrochemical reaction, and barrier means positioned between said first and second films for preventing the passage therethrough of said dye, said first ionic species, and said second ionic species but permitting the passage therethrough of current-carrying ions. By passing current through said filter, the color of said dye can be caused to change whereby the transmission of radiant energy can be regulated.Type: GrantFiled: June 6, 1969Date of Patent: April 20, 1976Assignee: Xerox CorporationInventor: Eugene Findl