Abstract: Copolymer beads made by suspension copolymerization of styrenic monomer with divinylbenzene under conditions such that the products had defined solubility, gel content, molecular weight and bead size characteristics which enabled their use (after impregnation with a blowing agent and pre-expansion) in molding into foamed cups over a much broader range of time and temperature and the resultant cups are stiffer per given weight than cups made from conventional polystyrenes utilized for making foamed cups. These advantages are realized without any sacrifice in cup appearance.
Abstract: Blends of polypropylene-poly(vinyl aromatic monomer) interpolymer with certain polymers and/or rubbers can be impregnated with blowing agents to give products which can be expanded under atmospheric steam conditions to give low density, fine cell structure foam particles.
Abstract: Expandable styrene polymer particles which have anti-static and anti-lumping properties during expansion are produced by adding 0.1 to 0.4 parts of alkyl and alkylaryl ethers of polyethoxyethanol mono- and diesters of phosphoric acid per 100 parts of polymer particles during impregnation of the polymer particles with blowing agents. The esters may be added as sole antistatic agent or in addition to the known internal additives which impart fast-cool and antilump properties.
Abstract: An alternate procedure for preparing multilithium initiators using DVB has been developed in order to achieve better control over the specific number of anionic sites per initiator molecule and to prepare star-block copolymers having a pre-determined number of branches. The process consists of 3 distinct steps; oligomerization, activation and polymer growth. The initial step involves the oligomerization of DVB yielding a mini-block having a predetermined number of pendant vinyl groups using a monofunctional initiator such as polystyryllithium. This is quickly followed by activation of the pendant vinyl groups using s-butyllithium prior to polymer growth.
Abstract: A process for producing a polypropylene-polystyrene interpolymer which can be impregnated with a blowing agent and can then be expanded under normal conditions for polystyrene particles to low density, fine cell structure foams. The interpolymer must be viscbroken, lubricated and stress relaxed in order to foam at 100.degree. C. to densities less than 2.0 pcf.
Abstract: Styrenic polymer beads that are useful in forming foamed cups with improved strength and thermal properties are prepared by forming an aqueous suspension of initial styrenic polymer beads and adding thereto an emulsion of a comonomer solution of styrenic monomer and divinylbenzene, which emulsion also contains free-radical-producing catalysts, and the suspension with added monomers is heated to copolymerize the styrenic monomer and divinylbenzene within and on the initial beads and form modified beads.
Abstract: Thermoplastic particles are suspended in water or other suspending fluids with a suspending aid(s) to prevent agglomeration of the beads, pellets or particles. To this suspension is added monomer(s) containing a multifunctional initiator(s). The monomer and initiator(s) are preemulsified in water or other fluid(s) before the addition in order to improve distribution of the monomer(s) and initiator(s) in or on the particles. After or during the addition(s), the suspension temperature is raised to cause polymerization. The procedures may be repeated to increase the coating or penetrated polymer content. New compositions of matter are made by this technique wherein the new compositions are plastic resins either coated or penetrated, or both, with a thermoplastic(s) of very high molecular weight not obtainable by present, commercial polymerization techniques. The compositions are superior to the feed resins because of the enhancement of physical properties brought about by the high molecular weights phase(s).
Type:
Grant
Filed:
October 3, 1986
Date of Patent:
June 16, 1987
Assignee:
Atlantic Richfield Company
Inventors:
Bernard H. Meyer, Adolph V. DiGiulio, Joseph C. Kinslow, Dennis M. Hajnik
Abstract: Styrenic polymer beads that are useful in forming foamed cups with improved strength and thermal properties are prepared by forming an aqueous suspension of initial styrenic polymer beads and adding thereto an emulsion of a comonomer solution of styrenic monomer and divinylbenzene, which emulsion also contains free-radical-producing catalysts, and the suspension with added monomers is heated to copolymerize the styrenic monomer and divinylbenzene within and on the initial beads and form modified beads.
Abstract: Blends of polypropylene-poly(vinyl aromatic monomer) interpolymer with certain polymers and/or rubbers can be impregnated with blowing agents to give products which can be expanded under atmospheric steam conditions to give low density, fine cell structure foam particles.
Abstract: Styrenic polymer beads that are useful in forming foamed cups with improved strength and thermal properties are prepared by forming an aqueous suspension of initial styrenic polymer beads and adding thereto an emulsion of a comonomer solution of styrenic monomer and divinylbenzene, which emulsion also contains free-radical-producing catalysts, and the suspension with added monomers is heated to copolymerize the styrenic monomer and divinylbenzene within and on the initial beads and form modified beads.
Abstract: Thermoplastic particles are suspended in water or other suspending fluids with a suspending aid(s) to prevent agglomeration of the beads, pellets or particles. To this suspension is added monomer(s) containing a multifunctional initiator(s). The monomer and initiator(s) are pre-emulsified in water or other fluid(s) before the addition in order to improve distribution of the monomer(s) and initiator(s) in or on the particles. After or during the addition(s), the suspension temperature is raised to cause polymerization. The procedures may be repeated to increase the coating or penetrated polymer content. New compositions of matter are made by this technique wherein the new compositions are plastic resins either coated or penetrated, or both, with a thermoplastic(s) of very high molecular weight not obtainable by present, commercial polymerization techniques. The compositions are superior to the feed resins because of the enhancement of physical properties brought about by the high molecular weights phase(s).
Type:
Grant
Filed:
May 12, 1986
Date of Patent:
May 5, 1987
Assignee:
Atlantic Richfield Company
Inventors:
Bernard H. Meyer, Adolph V. DiGiulio, Joseph C. Kinslow, Dennis M. Hajnik
Abstract: Styrenic polymer beads that are useful in forming foamed cups with improved strength and thermal properties are prepared by forming an aqueous suspension of initial styrenic polymer beads and adding thereto an emulsion of a comonomer solution of styrenic monomer and divinylbenzene, which emulsion also contains free-radical-producing catalysts, and the suspension with added monomers is heated to copolymerize the styrenic monomer and divinylbenzene within and on the initial beads and form modified beads.
Abstract: Styrenic polymer beads that are useful in forming foamed cups with improved strength and thermal properties are prepared by forming an aqueous suspension of initial styrenic polymer beads and adding thereto an emulsion of a comonomer solution of styrenic monomer and divinylbenzene, which emulsion also contains free-radical-producing catalysts, and the suspension with added monomers is heated to copolymerize the styrenic monomer and divinylbenzene within and on the initial beads and form modified beads.
Abstract: Styrenic polymer beads that are useful in forming foamed cups with improved strength and thermal properties are prepared by forming an aqueous suspension of initial styrenic polymer beads and adding thereto an emulsion of a comonomer solution of styrenic monomer and divinylbenzene, which emulsion also contains free-radical-producing catalysts, and the suspension with added monomers is heated to copolymerize the styrenic monomer and divinylbenzene within and on the initial beads and form modified beads.
Abstract: Styrenic polymer beads that are useful in forming foamed cups with improved strength and thermal properties are prepared by forming an aqueous suspension of initial styrenic polymer beads and adding thereto an emulsion of a comonomer solution of styrenic monomer and divinylbenzene, which emulsion also contains free-radical-producing catalysts, and the suspension with added monomers is heated to copolymerize the styrenic monomer and divinylbenzene within and on the initial beads and form modified beads.
Abstract: Acrylic pressure sensitive hot melt adhesives having improved creep resistance at ambient temperatures and desirable melt viscosity at elevated application temperatures are prepared by copolymerizing suitable acrylic and methacrylic acids and alkyl esters with 10-40 percent by weight of an acrylate or methacrylate terminated vinyl aromatic monomer based macromolecular monomer.Compounding these adhesives with suitable tackifiers and plasticizers produces adhesives having low molten viscosity and significantly better shear adhesion, tack, and peel adhesion than is possible with the uncompounded acrylic adhesives.
Abstract: A vessel having a floor which includes a tap outlet through which liquid contents in the vessel can be drained. The tap outlet features a shallow aperture circumscribed by first and second drip lines. The second drip line circumscribes the first drip line and is substantially coplanar with the first drip line. The two drip lines are connected one to the other by an annular hollow surface.
Type:
Grant
Filed:
April 16, 1985
Date of Patent:
March 31, 1987
Assignee:
The Dow Chemical Company
Inventors:
Bruce C. Peters, M. Dale Mayes, Richard M. Gross, Stanley R. Pearson
Abstract: Styrenic polymer beads that are useful in forming foamed cups with improved strength and thermal properties are prepared by forming an aqueous suspension of initial styrenic polymer beads and adding thereto an emulsion of a comonomer solution of styrenic monomer and divinylbenzene, which emulsion also contains free-radical-producing catalysts, and the suspension with added monomers is heated to copolymerize the styrenic monomer and divinylbenzene within and on the initial beads and form modified beads.
Abstract: A slight tube assembly, in combination with a sensing instrument, such as an optical pyrometer, for use in continuously monitoring the temperature of the first row of rotating blades in large gas turbines, particularly the type used in industry. Temperature data received by the pyrometer unit is fed to a control circuit, which regulates fuel input to the tubine to control the firing temperature. The key to obtaining reliable blade temperature data in the practice of this invention is the position of the sight tube in the turbine, which enables the pyrometer to "view" the rotating blades along a direct line of sight that penetrates a hot gas duct, but not the turbine section of the engine.
Abstract: A method for the production of polyolefin resins containing both an organic amide and a zinc compound. One composition is prepared which contains the polyolefin and the amide, but which does not contain the zinc compound. Another composition is prepared which contains the polyolefin and the zinc compound, but which does not contain the amide. The two compositions are extruded separately, and the individual resins so obtained are blended to form the desired resin composition containing both the amide and the zinc compound, thereby preventing the zinc stearate from catalyzing the dehydration of the aliphatic amide to a nitrile.