Patents Represented by Attorney Alan Holler
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Patent number: 7128813Abstract: A process for the high yield production of high purity glacial methacrylic acid (“HPMAA”) with minimization of decomposition of hydroxy isobutyric acid (HIBA). The HPMAA is substantially pure, specifically 99% pure or greater with a water content of 0.05% or less. This improved process involves the steps of providing a crude MAA stream which was formed by hydrolyzing acetone cyanohydrin and, therefore, includes HIBA which is an intermediate product of the hydrolysis reaction, and purifying that crude methacrylic acid stream in a series of successive distillation steps.Type: GrantFiled: April 22, 2003Date of Patent: October 31, 2006Assignee: Rohm and Haas CompanyInventors: Keith Frederick Briegel, James Clarence Day, Michael Stanley DeCourcy, Donald Alan Ebert, Jamie Jerrick John Juliette
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Patent number: 7049466Abstract: A method for producing an unsaturated carboxylic acid comprises: (a) contacting, in a reaction zone, an alkane with a catalyst containing a mixed metal oxide, under conditions which produce a product gas comprising the unsaturated carboxylic acid, unreacted alkane and a product alkene; (b) recovering unreacted alkane and product alkene from the product gas; and (c) recycling the recovered unreacted alkane and product alkene to the reaction zone; wherein the mixed metal oxide consists of a material having the formula AaMmNnXxOo wherein A is at least one element selected from the group consisting of molybdenum and tungsten, wherein M is at least one element selected from the group consisting of vanadium, cerium and chromium, wherein N is at least one element selected from the group consisting of tellurium, bismuth and selenium, wherein X is at least one element selected from the group consisting of niobium, tantalum, titanium, aluminum, zirconium, chromium, manganese, iron, ruthenium, cobalt, rhodium, nickel,Type: GrantFiled: September 25, 2001Date of Patent: May 23, 2006Assignee: Rohm and Haas CompanyInventors: Leonard Edward Bogan, Jr., Daniel A. Bors, Fernando Antonio Pessoa Cavalcanti, Scott Han, Bradley Anson Jacobs, Frederick William Kaiser, Peter David Klugherz, Manhua Lin, Donald Lee Zolotorofe
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Patent number: 7015173Abstract: A catalyst comprising a mixed metal oxide is useful for the vapor phase oxidation of an alkane or a mixture of an alkane and an alkene to an unsaturated carboxylic acid and for the vapor phase ammoxidation of an alkane or a mixture of an alkane and an alkene to an unsaturated nitrile.Type: GrantFiled: July 18, 2003Date of Patent: March 21, 2006Assignee: Rohm and Haas CompanyInventors: Leonard Edward Bogan, Jr., Alex Pak
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Patent number: 6841699Abstract: A mixed metal oxide, which may be an orthorhombic phase material, is improved as a catalyst for the production of unsaturated carboxylic acids, or unsaturated nitriles, from alkanes, or mixtures of alkanes and alkenes, by: contacting with a liquid contacting member selected from the group consisting of organic acids, alcohols, inorganic acids and hydrogen peroxide to form a contact mixture; recovering insoluble material from the contact mixture; and calcining the recovered insoluble material in a non-oxidizing atmosphere.Type: GrantFiled: April 8, 2002Date of Patent: January 11, 2005Assignee: Rohm and Haas CompanyInventors: Leonard Edward Bogan, Jr., Anne Mae Gaffney, Scott Han, Michele Doreen Heffner, Ruozhi Song
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Patent number: 6825380Abstract: A catalyst comprising a promoted mixed metal oxide is useful for the vapor phase oxidation of an alkane or a mixture of an alkane and an alkene to an unsaturated carboxylic acid and for the vapor phase ammoxidation of an alkane or a mixture of an alkane and an alkene to an unsaturated nitrile.Type: GrantFiled: March 12, 2002Date of Patent: November 30, 2004Assignee: Rohm and Haas CompanyInventors: Sanjay Chaturvedi, Anne Mae Gaffney, Scott Han, Michele Doreen Heffner, Ruozhi Song
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Patent number: 6809219Abstract: A catalyst useful for the gas phase oxidation of alkanes to unsaturated aldehydes or carboxylic acids is disclosed. Processes for preparing the catalyst and using the catalyst to convert alkanes to unsaturated aldehydes or carboxylic acids are also disclosed.Type: GrantFiled: December 9, 2002Date of Patent: October 26, 2004Assignee: Rohm and Haas CompanyInventors: Scott Han, Dominique Hung Nhu Le, Nneka Namono McNeal
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Patent number: 6790988Abstract: A catalyst comprising a promoted mixed metal oxide is useful for the vapor phase oxidation of an alkane or a mixture of an alkane and an alkene to an unsaturated carboxylic acid and for the vapor phase ammoxidation of an alkane or a mixture of an alkane and an alkene to an unsaturated nitrile.Type: GrantFiled: May 7, 2003Date of Patent: September 14, 2004Assignee: Rohm and Haas CompanyInventors: Sanjay Chaturvedi, Anne Mae Gaffney, Scott Han, Michele Doreen Heffner, Ruozhi Song
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Patent number: 6746983Abstract: Hydrothermally synthesized catalysts comprising a mixed metal oxide are utilized to produce unsaturated carboxylic acids by the vapor phase oxidation of an alkane, or a mixture of an alkane and an alkene, in the presence thereof; or to produce unsaturated nitrites by the vapor phase oxidation of an alkane, or a mixture of an alkane and an alkene, and ammonia in the presence thereof.Type: GrantFiled: June 10, 2002Date of Patent: June 8, 2004Assignee: Rohm and Haas CompanyInventors: Anne Mae Gaffney, Ruozhi Song
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Patent number: 6740620Abstract: An orthorhombic phase mixed metal oxide is produced selectively in quantitative yield.Type: GrantFiled: April 8, 2002Date of Patent: May 25, 2004Assignee: Rohn and Haas CompanyInventors: Leonard Edward Bogan, Jr., Daniel A. Bors, Fernando Antonio Pessoa Cavalcanti, Michael Bruce Clark, Jr., Anne Mae Gaffney, Scott Han
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Patent number: 6734136Abstract: A catalyst comprising a promoted mixed metal oxide is useful for the vapor phase oxidation of an alkane or a mixture of an alkane and an alkene to an unsaturated carboxylic acid and for the vapor phase ammoxidation of an alkane or a mixture of an alkane and an alkene to an unsaturated nitrile.Type: GrantFiled: August 10, 2001Date of Patent: May 11, 2004Assignee: Rohm and Haas CompanyInventors: Sanjay Chaturvedi, Anne Mae Gaffney, Scott Han, Michele Doreen Heffner, Ruozhi Song
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Patent number: 6700015Abstract: A catalyst comprising a promoted mixed metal oxide is useful for the vapor phase oxidation of an alkane or a mixture of an alkane and an alkene to an unsaturated carboxylic acid and for the vapor phase ammoxidation of an alkane or a mixture of an alkane and an alkene to an unsaturated nitrile.Type: GrantFiled: May 6, 2003Date of Patent: March 2, 2004Assignee: Rohm and Haas CompanyInventors: Sanjay Chaturvedi, Anne Mae Gaffney, Scott Han, Dominique Hung Nhu Le
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Patent number: 6620968Abstract: This invention relates to a high load process for preparing (meth)acrylic acid from a reactive hydrocarbon using a high reactive hydrocarbon space velocity to provide increased capacity and throughput.Type: GrantFiled: November 8, 2000Date of Patent: September 16, 2003Assignee: Rohm and Haas CompanyInventors: Charles Michael Lonzetta, James Edward Elder, Peter David Klugherz, Timothy Allen Hale
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Patent number: 6610177Abstract: A high yield process for the production of methyl methacrylate or methacrylic acid and an apparatus for increasing the yield in a process for the production of methyl methacrylate or methacrylic acid are disclosed.Type: GrantFiled: July 29, 2002Date of Patent: August 26, 2003Assignee: Rohm and Haas CompanyInventors: Chorng-Shyuan Tsay, Michael Stanley DeCourcy, I-Hwa Midey Chang-Mateu, Heather Granzin Thompson, Diana Elaine Chase
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Patent number: 6589907Abstract: A catalyst comprising a promoted mixed metal oxide is useful for the vapor phase oxidation of an alkane or a mixture of an alkane and an alkene to an unsaturated carboxylic acid and for the vapor phase ammoxidation of an alkane or a mixture of an alkane and an alkene to an unsaturated nitrile.Type: GrantFiled: August 10, 2001Date of Patent: July 8, 2003Assignee: Rohm and Haas CompanyInventors: Sanjay Chaturvedi, Anne Mae Gaffney, Scott Han, Dominique Hung Nhu Le
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Patent number: 6545176Abstract: A high yield process for the production of methyl methacrylate or methacrylic acid and an apparatus for increasing the yield in a process for the production of methyl methacrylate or methacrylic acid are disclosed.Type: GrantFiled: October 28, 1999Date of Patent: April 8, 2003Assignee: Rohm and Haas CompanyInventors: Chorng-Shyuan Tsay, Makarand Dattatraya Phadke, Abraham Benderly, I-Hwa Midey Chang-Mateu, Nicole Rendon Koegel, Heather Granzin Thompson, Diana Elaine Chase
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Patent number: 6518216Abstract: A catalyst useful for the gas phase oxidation of alkanes to unsaturated aldehydes or carboxylic acids is disclosed. Processes for preparing the catalyst and using the catalyst to convert alkanes to unsaturated aldehydes or carboxylic acids are also disclosed.Type: GrantFiled: September 12, 2000Date of Patent: February 11, 2003Assignee: Rohm and Haas CompanyInventors: Scott Han, Dominique Hung Nhu Le, Nneka Namono McNeal
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Patent number: 6515138Abstract: An improved transesterification process is disclosed for forming certain (meth)acrylates by the transesterification of an alkyl (meth)acrylate with a hydroxyl alkyl imidazolidin-2-one using a transesterification catalyst in the presence of a polymerization inhibitor.Type: GrantFiled: March 6, 2002Date of Patent: February 4, 2003Assignee: Rohm and Haas CompanyInventors: William David Weir, Donald Robert Weyler, William Joseph Grieco
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Patent number: 6514468Abstract: This invention relates to an improved catalyst system utilizing flow through radiation shielding of the reaction zone and to processes for using the catalyst system for the production of hydrogen cyanide. The process has decreased methane usage while maintaining yield of cyanide.Type: GrantFiled: April 9, 2001Date of Patent: February 4, 2003Assignee: Rohm and Haas CompanyInventors: Michael Stanley DeCourcy, Michel Gene Woody, Karen Ann Shaw, Joy Lyndon Mendoza
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Patent number: 6514903Abstract: An improved catalyst including a compound of the formula (I) AaMmNnXxOo (I) wherein 0.25<a<0.98, 0.003<m<0.5, 0.003<n<0.5, 0.003<x<0.Type: GrantFiled: October 22, 1999Date of Patent: February 4, 2003Assignee: Rohm and Haas CompanyInventors: Manhua Lin, Michael William Linsen
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Patent number: 6514901Abstract: A process for preparing a catalyst is disclosed. The catalyst is useful for the gas phase oxidation of alkanes to unsaturated aldehydes or carboxylic acids.Type: GrantFiled: October 22, 1999Date of Patent: February 4, 2003Assignee: Rohm and Haas CompanyInventors: Manhua Lin, Michael William Linsen