Patents Represented by Attorney Alfred P. Lorenzo
  • Patent number: 5041605
    Abstract: Phenolic cyan-dye-forming couplers characterized by a p-cyanophenylureido group in the 2-position of the phenol are synthesized in high yield by a process comprising the steps of contacting, in a reaction solvent in the presence of a transition metal catalyst at moderate temperature and atmospheric pressure, a coupler intermediate having a nitro group in the 5-position with a hydrogen donor, such as, for example, ammonium formate, to thereby form the corresponding 2-(p-cyanophenylureido)-5-aminophenol and reacting the 2-(p-cyanophenylureido)-5-aminophenol with an acylating agent to form the phenolic cyan-dye-forming coupler.
    Type: Grant
    Filed: November 20, 1989
    Date of Patent: August 20, 1991
    Assignee: Eastman Kodak Company
    Inventors: James J. Huson, Louis F. Valente
  • Patent number: 5041355
    Abstract: Silver halide photographic elements which are capable of high contrast development having incorporated therein, as a nucleating agent, an aryl sulfonamidophenyl hydrazide of the formula: ##STR1## where each R is a monovalent group comprised of at least three repeating ethyleneoxy units, n is 1 to 3, and R.sup.1 is hydrogen or a blocking group.
    Type: Grant
    Filed: May 24, 1990
    Date of Patent: August 20, 1991
    Assignee: Eastman Kodak Company
    Inventors: Harold I. Machonkin, Donald L. Kerr
  • Patent number: 5037725
    Abstract: A process for stabilizing the magenta dye image in a photographic color element comprises the step of treating the element after the step of color developing and prior to the step of bleaching or bleach-fixing with an aqueous solution that has a pH in the range of 7 to 10 and contains an effective amount of an alkali metal formaldehyde bisulfite.
    Type: Grant
    Filed: December 11, 1989
    Date of Patent: August 6, 1991
    Assignee: Eastman Kodak Company
    Inventors: Ann M. Cullinan, Charles M. Darmon, William G. Henry, Paul A. Schwartz
  • Patent number: 5035978
    Abstract: A non-light-sensitive image-receiving element useful in a silver complex diffusion transfer process includes at least one layer containing certain tone controlling agents that accelerate the physical development of silver. Compounds useful for this purpose are alkyl disulfides substituted by a water solubilizing group, thiazolidine carboxylic acids, .gamma.-thiobutyrolactones, higher alkyl thioglycolates, and carboxy-substituted rhodanines.
    Type: Grant
    Filed: July 12, 1990
    Date of Patent: July 30, 1991
    Assignee: Eastman Kodak Company
    Inventors: Anthony M. Barnett, Colin J. Gray, Julie Baker
  • Patent number: 5035982
    Abstract: An aqueous developing composition including(a) a nontoxic developing vehicle which is a non-solvent for any of the components of the lithographic plate;(b) a first surfactant comprising a sodium, lithium or potassium salt of xylene sulfonic acid;(c) a second surfactant comprising a sodium, lithium or potassium salt of toluene, ethyl benzene, cumene or mesitylene sulfonic acid,(d) a third surfactant comprising a sodium, lithium or potassium salt of an alkyl benzene sulfonic acid, the alkyl group containing at least 10 carbon atoms or an alkyl naphthalene sulfonic acid, the alkyl group containing from 1 to 4 carbon atoms;(e) a cold water soluble film forming agent;(f) an alkanol amine desensitizing agent; and(g) an acid to control the pH of the developing composition.
    Type: Grant
    Filed: July 14, 1989
    Date of Patent: July 30, 1991
    Assignee: Eastman Kodak Company
    Inventor: John E. Walls
  • Patent number: 5034057
    Abstract: A photographic element is provided on one or both surfaces thereof with a fire-retardant protective overcoat comprising (1) a water-soluble film-forming copolymer of methyl inyl ether and maleic anhydride cross-linked by a water-soluble polyhydric alcohol and (2) a water-soluble ammonium polyphosphate which reacts with the polyhydric alcohol to form a fire-retardant composition when the protective overcoat is exposed to the heat of a fire. The protective overcoat is transparent, colorless, durable, non-tacky and moisutre resistant and provides especially effective fire-retarding properties for photographic products used in large display format such as back-drops on movie sets or free-hanging murals at trade shows.
    Type: Grant
    Filed: March 26, 1990
    Date of Patent: July 23, 1991
    Assignee: Eastman Kodak Company
    Inventor: Thomas M. Smith
  • Patent number: 5013638
    Abstract: A photographic donor material is described which comprises silver halide having at least 95% silver chloride, which material also contains a minor amount of bromide ions, an amount of development inhibitor and which has a hydrophilic overcoat layer to retard access of processing solution to the silver halide. The photographic material is useful in a silver salt diffusion transfer process.
    Type: Grant
    Filed: October 10, 1989
    Date of Patent: May 7, 1991
    Assignee: Eastman Kodak Company
    Inventors: Anthony M. Barnett, David A. Hallbery
  • Patent number: 5006451
    Abstract: Photographic support materials are comprised of a conventional support, such as polyester film, cellulose acetate film or resin-coated paper, having thereon an antistatic layer comprising vanadium pentoxide and an overlying barrier layer comprised of a latex polymer having hydrophilic functionality. The barrier layer provides excellent adhesion between the antistatic layer and overlying layers, such as silver halide emulsion layers or curl control layers, and also prevents unwanted diffusion of the vanadium pentoxide; whereby the combination of antistatic and barrier layers serves to impart a high level of permanent antistatic protection.
    Type: Grant
    Filed: May 14, 1990
    Date of Patent: April 9, 1991
    Assignee: Eastman Kodak Company
    Inventors: Charles C. Anderson, Diane E. Kestner, Mark A. Lewis, Gary R. Opitz
  • Patent number: 5000928
    Abstract: Ultra-pure silver nitrate is prepared from crude silver by a process comprising the steps of dissolving the crude silver in nitric acid to form a crude silver nitrate solution; adding an alkaline agent, such as sodium hydroxide, to the crude silver nitrate solution to precipitate metallic contaminants and form a partially purified silver nitrate solution; adding a selective reducing agent, such as sodium formate, to the partially purified silver nitrate solution, to reduce silver nitrate to metallic silver and thereby precipitate silver powder while leaving metallic contaminants in solution; dissolving the silver powder in nitric acid to form a highly purified silver nitrate solution; and crystallizing ultra-pure silver nitrate from the highly purified silver nitrate solution.
    Type: Grant
    Filed: March 17, 1986
    Date of Patent: March 19, 1991
    Assignee: Eastman Kodak Company
    Inventor: Weimar W. White
  • Patent number: 4994365
    Abstract: Silver halide photographic elements which are capable of high contrast development having incorporated therein, as a nucleating agent, an aryl sulfonamidophenyl hydrazide of the formula: ##STR1## where each R is an alkyl group, n is 1 to 3, X is an anion, m is 1 to 6, Y is a divalent aromatic radical, and R.sup.1 is hydrogen or a blocking group.
    Type: Grant
    Filed: May 24, 1990
    Date of Patent: February 19, 1991
    Assignee: Eastman Kodak Company
    Inventors: Jerome J. Looker, Donald L. Kerr
  • Patent number: 4988604
    Abstract: Silver halide photographic elements which are capable of high contrast development having incorporated therein, as a nucleating agent, an aryl sulfonamidophenyl hydrazide of the formula: ##STR1## where R is a monovalent group comprised of at least three repeating ethyleneoxy units, m is 1 to 6, Y is a divalent aromatic radical, and R.sup.1 is hydrogen or a blocking group.
    Type: Grant
    Filed: May 24, 1990
    Date of Patent: January 29, 1991
    Assignee: Eastman Kodak Company
    Inventors: Harold I. Machonkin, Donald L. Kerr
  • Patent number: 4975356
    Abstract: Improved bleach-accelerating compositions that are especially useful in the reversal color processing of photographic elements are comprised of a bleach-accelerating agent and a dye-stabilizing agent. Formaldehyde precursors function as particularly effective dye-stabilizing agents in such compositions. The bleach-accelerating composition is utilized subsequent to the color developing step and prior to the bleaching step and serves to enhance the effectiveness of the bleaching step and to provide improved dye stability.
    Type: Grant
    Filed: November 29, 1989
    Date of Patent: December 4, 1990
    Assignee: Eastman Kodak Company
    Inventors: Ann M. Cullinan, Paul A. Schwartz
  • Patent number: 4975354
    Abstract: Silver halide photographic elements which are capable of high contrast development, when processed in the presence of a hydrazine compound that functions as a nucleating agent, include certain secondary or tertiary amino compounds which function as incorporated boosters. Such elements are particularly useful in the field of graphic arts.
    Type: Grant
    Filed: May 30, 1989
    Date of Patent: December 4, 1990
    Assignee: Eastman Kodak Company
    Inventors: Harold I. Machonkin, Donald L. Kerr
  • Patent number: 4975357
    Abstract: Hydroxylamine compounds are commonly included in photographic color developing solutions to retard aerial oxidation. When the photographic element processed in the color developing solution is one which contains an aromatic polyhydroxy compound which serves as a stabilizing addendum, there will be a build-up of the level of such compound in the developing solution as seasoning occurs. Also, as a consequence of seasoning, there is a gradual build-up of the level of trace metal impurities in the solution. Interaction of a trace metal impurity with the aromatic polyhydroxy compound can form a metal-complex which catalyzes the oxidation of the hydroxylamine compound and thereby renders it ineffective for its intended purpose. In the improved method of this invention, the color developing solution is protected against the unwanted metal-complex catalyzed oxidation by incorporation therein of an aminopolycarboxylic acid sequestering agent.
    Type: Grant
    Filed: May 23, 1989
    Date of Patent: December 4, 1990
    Assignee: Eastman Kodak Company
    Inventors: Jean M. Buongiorne, Janet M. Huston, Paul A. Schwartz, Sheridan E. Vincent
  • Patent number: 4968571
    Abstract: An electrophotographic recording element comprising a combination of photoconductive perylene materials that are dispersed in a binder to form layers having excellent photosensitivity and resistance to abrasion. The materials are perylene-3,4,9,10-tetracarboxylic acid imide derivatives that contain a phenethyl radical bonded to a 3,4-dicarboximide nitrogen atom.
    Type: Grant
    Filed: July 21, 1989
    Date of Patent: November 6, 1990
    Assignee: Eastman Kodak Company
    Inventors: William T. Gruenbaum, Khe C. Nguyen, Jeanne E. Kaeding
  • Patent number: 4965131
    Abstract: A method of preparing polymer particles having narrow size distribution in a suspension process employing a solid colloidal stabilizing agent. The solid colloidal stabilizer is a copolymer of about 25 to about 80% by weight, based on total monomer weight, of an additional polymerizable nonionic oleophilic monomer, about 5 to about 45%, by weight, of an addition polymerizable nonionic hydrophilic monomer, about 1 to about 50% of an addition polymerizable ionic monomer, and 0 to about 20 percent, by weight, of a crosslinking monomer having at least two addition polymerizable groups. Also disclosed are polymeric particles comprising a core polymer covered by a layer of the smaller copolymer stabilizer particles and electrostatographic toners comprising such polymeric particles.
    Type: Grant
    Filed: March 21, 1988
    Date of Patent: October 23, 1990
    Assignee: Eastman Kodak Company
    Inventors: Mridula Nair, Zona R. Pierce, Donna A. DiPrima
  • Patent number: 4960682
    Abstract: Improved photographic bleaching compositions for use in the color processing of photographic elements comprise an aqueous solution containing a photographic bleaching agent, such as, for example, an ammonium or alkali metal salt of a ferric complex of an aminopolycarboxylic acid, and a dye-stabilizing amount of a formaldehyde percursor.
    Type: Grant
    Filed: December 19, 1988
    Date of Patent: October 2, 1990
    Assignee: Eastman Kodak Company
    Inventors: Ann M. Cullinan, Paul A. Schwartz
  • Patent number: 4957947
    Abstract: A radiation-curable composition useful in forming an abrasion-resistant antistatic layer is comprised of a salt, such as an alkali metal fluoroborate, dissolved in a mixture of (1) a poly(alkylene glycol)diacrylate and (2) an acrylic monomer containing at least three acrylic ester groups. The composition can be coated in the form of a thin layer and cured by suitable means, such as an electron beam accelerator or a source of ultraviolet radiation, to form an antistatic layer of particular utility as a component of a photographic material.
    Type: Grant
    Filed: June 17, 1988
    Date of Patent: September 18, 1990
    Assignee: Eastman Kodak Company
    Inventors: Janglin Chen, Billy R. Dotson
  • Patent number: 4946965
    Abstract: Solid photographic addenda, such as photographic color couplers or sensitizing dyes, which are wet with occluded organic liquid, after being subjected, for example, to processes such as crystallization or washing, are contacted with an extractant composed of carbon dioxide in liquid form or in the form of a supercritical fluid to remove the organic liquid. The process is capable of use with any solid photographic addendum which is insoluble in the extractant and any organic liquid which is soluble in the extractant. It can be completed much more quickly than conventional processes in which such solids are dried with the aid of heat and/or vacuum, while effectively avoiding problems of clumping and thermal degradation which commonly occur in dryers. It provides a product that is capable of meeting the demanding requirements of the photographic art with respect to both physical and chemical characteristics.
    Type: Grant
    Filed: January 23, 1990
    Date of Patent: August 7, 1990
    Assignee: Eastman Kodak Company
    Inventors: Frank M. Jahnke, Carl B. Richenberg
  • Patent number: 4927746
    Abstract: A stabilizing bath which provides reduced stain and enhanced dye stability for photographic color elements which are processed therein is comprised of a dye stabilizing agent, an alkanolamine, and polyacrylic acid or a water-soluble salt thereof. The stabilizing bath is used as a final processing bath which follows treatment of the element in a fixing or bleach-fixing bath containing a thiousulfate fixing agent. The alkanolamine functions to prevent the precipitation of sulfur resulting from carryover of the thiosulfate fixing agent into the stabilizing bath, while the polyacrylic acid or water-soluble salt thereof functions to avoid the formation of unwanted precipitates.
    Type: Grant
    Filed: June 3, 1988
    Date of Patent: May 22, 1990
    Assignee: Eastman Kodak Company
    Inventor: Paul A. Schwartz