Abstract: A process which comprises heating a reaction mixture comprised of an aqueous solution containing perchlorate ions, chlorate ions and hydrogen ions to produce chlorine dioxide and oxygen gas.The novel process of the present invention provides a commercially viable process for producing chlorine dioxide from mixtures of oxy-chlorine species in the absence of a reducing agent. The process can be operated without producing an acidic salt by-product while producing a chlorine dioxide product which is substantially free of chlorine. In addition, the process of the invention permits a reduction in the amount of acid fed to the chlorine dioxide generator.

Abstract: Compositions consisting essentially of calcium hypochlorite and a water soluble zinc salt, the compositions containing from about 40 percent to about 99 percent by weight of calcium hypochlorite, provide controlled release of the components for continuous and effective sanitation and algae control to waters treated for use in swimming pools and spas.

Abstract: A process for producing dichlorine monoxide which includes: feeding an aqueous solution of hypochlorous acid containing at least 20% by weight of HOCl to a reaction vessel; maintaining the temperature of the aqueous solution of hypochlorous acid in the range of from about -10.degree. to about +40.degree. C.; passing an inert gas through the aqueous solution of hypochlorous acid to produce a gaseous mixture comprising dichlorine monoxide, chlorine and inert gas; an contacting the gaseous mixture with dry ice to provide a solid phase of dry ice and dichlorine monoxide.

Abstract: Ammonium perchlorate is produced a process which comprises:(a) oxidizing a solution of chloric acid substantially free of ionic impurities,(b) introducing gaseous ammonia or an ammonium hydroxide solution into the crystallizing zone to produce ammonium perchlorate crystals, wherein the aqueous solution of perchloric acid and/or the ammonium hydroxide solution is in droplet form.High purity ammonium perchlorate crystals can now be produced directly which are free of transition metals, sulfates and phosphates, as well as substantially free of other ionic impurities including alkali metals, chlorate and chloride.

Abstract: A process for treating wastewater the improvement which comprises admixing with the wastewater at least 0.5 percent by weight of a solution consisting of hypochlorous acid having a pH of less than 3 to prepare disinfected wastewater having substantially no available chlorine residual.The novel process of the present invention provides rapid, intimate mixing of the highly pure, highly acidic hypochlorous acid solution with the wastewater stream to disinfect wastewater bodies while minimizing unwanted side effects. The process eliminates the need for storing and handling pressurized gaseous or liquid chlorine.

Abstract: A process for sanitizing impotable water the improvement which comprises admixing with the impotable water a solution consisting of hypochlorous acid containing at least 0.5 percent by weight of HOCl and having a pH of less than 3 to prepare potable water having an available chlorine residual.

Abstract: A solid calcium hypochlorite composition contains calcium hypochlorite and an alkali metal salt of phosphonobutane polycarboxylic acid having an available chlorine concentration of at least 50 percent by weight.It has been found that the use of the novel compositions of the present invention can significantly reduce scale formation in dispensers for calcium hypochlorite particularly where water having high total alkalinity is used. The prevention or inhibition of scale formation is accomplished without harmfully affecting other properties of the pool water such as the pH.

Abstract: A process for producing 1,2,4-triazol-5-one reacts a semicarbazide compound with a formic acid compound in the presence of a catalytic amount of a catalyst. The catalyst is selected from the group consisting of an organic sulfonic acid and a sulfonic acid-containing polymer or co-polymer, and mixtures thereof. The novel process of the present invention produces 1,2,4-triazol-5-one having significantly lower concentrations of chloride ion which are advantageous, for example, in the production of 3-nitro-1,2,4-triazol-5-one as an explosive used in castable explosive compositions. The organic sulfonic acid compound catalyst can be recovered and reused.

Abstract: A process for treating an alkali metal hydrosulfite solution containing thiosulfate ions as an impurity which comprises reducing cathodically the alkali metal hydrosulfite solution to convert thiosulfate ions to sulfide ions, the alkali metal hydrosulfite solution having a residual alkalinity of from about 0.1 to about 20 grams per liter of hydroxide ion.

Abstract: A process for producing chloric acid in an electrolytic cell having an anode and a cathode which includes feeding an aqueous solution of hypochlorous acid to the electrolytic cell, and electrolyzing the aqueous solution of hypochlorous solution to produce a chloric acid solution. Using the process of the invention, chloric acid can be produced efficiently at substantially reduced production costs using a process which can be operated commercially. In addition, the chloric acid solutions produced are of high purity and are stable at ambient conditions.