Abstract: The maximum useful rate of aluminum refining is substantially increased by the incorporation of baffle means across the refining chamber under the rotor of a spinning nozzle assembly positioned in the refining chamber during aluminum refining operations.
Abstract: Oxygen-permeable polymeric membranes, intended for use in processes for producing oxygen- or nitrogen-enriched air for industrial, medical, and other applications, are characterized by a complex which comprises (a) a copolymer of a vinyl aromatic amine and either (i) a fluoroalkyl acrylate or (ii) a fluoroalkyl methacrylate, and (b) a ligand taken from the group consisting of (1) porphyrins, (2) Schiff bases, (3) cyclidenes, and (4) amine-like macrocycles, and (c) a transition metal (II) ion.
Abstract: Highly efficient membrane drying and other gas separations are carried out by the use of low vacuum levels on the permeate side of the membrane.
Abstract: A calibration device utilizing a series of highly accurate mass flow controllers is provided for rapidly delivering ultra high purity calibration gas mixtures, and sample gas, to a gas analyzer at elevated temperature conditions. Steady flow rates are desirably provided to the highly sensitive analyzer. Valves exterior (20-25) and interior (3-5) to the heated compartment (9), heated by temperature controlled heater strips (9a), control the mixing of the reference gases with the sample gas and/or the flow of sample or calibration gas to the analyzer (16). The interior valves are diaphragm valves.
Type:
Grant
Filed:
August 16, 1991
Date of Patent:
June 1, 1993
Assignee:
Praxair Technology, Inc.
Inventors:
Gregory H. Leggett, Michael H. Sonricker
Abstract: An in-line stripper has a venturi-conical mixer combination in which the annular space thereby is automatically adjustable in response to changes in viscosity or other property conditions.
Abstract: The waste gas of PSA-air separation operations is passed to a membrane system for enhanced recovery of a second product. By capturing the portion found to contain a high concentration of either nitrogen or oxygen in the waste stream, the efficiency of the overall separation is enhanced.
Abstract: Composite adsorbent beds comprised of conventional 13X adsorbent and special cation exchanged adsorbent materials enable vacuum pressure swing adsorption operations for air separation to be carried out at advantageously low oxygen or nitrogen product costs.
Abstract: Bioremediation or other liquid waste biotreatment operations are enhanced by the use of turbulence promoters to create turbulent flow conditions in an oxygen/liquid waste dispersion prior to passage in an improved gas/liquid distribution system for passage through eductors into a lagoon or other holding source of the liquid waste being treated.
Type:
Grant
Filed:
October 2, 1991
Date of Patent:
April 6, 1993
Assignee:
Praxair Technology, Inc.
Inventors:
Thomas J. Bergman, Jr., Lawrence M. Litz
Abstract: The maximum useful rate of aluminum refining is substantially increased by the incorporation of baffle means across the refining chamber under the rotor of a spinning nozzle assembly positioned in the refining chamber during aluminum refining operations.
Abstract: A two stage membrane system is used for the production of oxygen from air. All or a portion of the feed air is passed to the permeate side of the second stage membrane as purge gas. The gas withdrawn from the permeate side of the second stage membrane is passed as feed gas to the first stage membrane, from which product oxygen is recovered.
Abstract: A process for producing highly asymmetric hollow fibers useful as permselective gas separation membranes and for producing composite membranes thereof by extruding the spinning dope through a tube-in-orifice spinneret into a gas-filled chamber maintained at reduced pressure and then conveying the extruded hollow fiber through a liquid bath to solidify the extrudate.
Type:
Grant
Filed:
August 1, 1991
Date of Patent:
January 26, 1993
Assignee:
Union Carbide Industrial Gases Technology Corporation
Inventors:
Benjamin Bikson, James T. Macheras, Joyce K. Nelson
Abstract: Pressure swing adsorption gas separation operations are enhanced by the retention and use of internal refrigeration effects, without the need for externally supplied refrigeration.
Abstract: Clean, dry air and nitrogen product gas are produced in an integrated system including an air separation membrane system and a membrane dryer operated with a significant degree of countercurrency of performance. Waste or recycle streams from the air separation membrane are used as purge in the membrane dryer.
Abstract: A micropanel for the delivery of gas from a supply cylinder to a tool location comprises an arrangement of valves, pressure regulator and associated components adapted to enhance the purity of the delivered gas and the safety of the gas delivery panel.
Abstract: By capturing the portion found to contain a high concentration of either oxygen or nitrogen in the non-primary waste stream from a PSA-air separation operation, a high purity second product stream can be obtained.
Type:
Grant
Filed:
October 8, 1991
Date of Patent:
November 17, 1992
Assignee:
Praxair Technology, Inc.
Inventors:
Frederick W. Leavitt, James Smolarek, Dale A. Lagree
Abstract: An annular double ended hollow fiber bundle, a fluid separation apparatus comprising the annular double ended hollow fiber bundle having bores open at both ends of the hollow fibers embedded in the two tubesheets enclosed in a shell having multiple ports, a fluid entrance port, a non-permeate exit port and at least one permeate exit port, wherein said double ended hollow fiber bundle is encased in an essentially impermeable film barrier except for entrance regions situated in selected areas between the tubesheets and to processes for separating fluids mixtures.
Abstract: Oxygen-permeable polymeric complexes comprise (a) a transition metal (II) ion, (b) a liqand of meso-tris(.alpha., .alpha.,.alpha.-o-substituted-amidophenyl)-mono-(.beta.-o-substituted amidophenyl) porphyrinato, and (c) an aromatic amine polymer.
Type:
Grant
Filed:
June 28, 1991
Date of Patent:
September 15, 1992
Assignee:
Union Carbide Industrial Gases Technology Corporation
Abstract: This invention relates to methods for producing composite gas separation membranes by treating the gas separation layer of the composite membranes with a treating agent that ionically bonds to the gas separation membrane layer of the treated composite membrane. The invention also relates to the membranes produced and to gas separation processes utilizing the improved membranes.
Type:
Grant
Filed:
April 22, 1991
Date of Patent:
July 21, 1992
Assignee:
Union Carbide Industrial Gases Technology Corporation
Abstract: Feed air is separated in a membrane system, with recovered nitrogen being purified in a deoxo unit and dried in an adsorbent dryer using high temperature purge gas. The heat generated in the deoxo unit can be used to satisfy the thermal energy requirements of dryer regeneration, without decrease in product recovery. Membrane permeate gas can be used for purge at high purge/feed ratio to reduce the energy requirements of bed regeneration.
Type:
Grant
Filed:
June 6, 1990
Date of Patent:
June 16, 1992
Assignee:
Union Carbide Industrial Gases Technology Corporation
Inventors:
Ravi Prasad, Oscar W. Haas, Frank Notaro, David R. Thompson