Abstract: Hydroxyaromatic compounds such as phenol are carbonylated with oxygen and carbon monoxide in the presence of a catalyst system comprising a Group VIIIB metal, preferably palladium; an iodide salt, preferably sodium iodide; and at least one organic bisphosphine such as 1,3-bis(diphenylphosphino)propane or 1,4-bis(diphenylphosphino)butane. The catalyst system also preferably contains a compound of cerium or lead.
Type:
Grant
Filed:
February 12, 2001
Date of Patent:
September 9, 2003
Assignee:
General Electric Company
Inventors:
Ben Purushotam Patel, Grigorii Lev Soloveichik, John Yaw Ofori