Abstract: A vacuum metalization process for applying a chrome coating on aluminum and steel substrates, for example vehicle wheels, hub caps, bumpers and the like. The process is environmentally compatible and produces a decorative, wear-resistant chrome finish and comprises four stages: a cleaning or preparation stage, a base coat application stage, a two-step PVD stage, and a topcoat application stage. The surface of the substrate is prepared and pretreated to provide a surface congenial for the adhesion of the base coat and to eliminate any contamination. An organic epoxy, thermosetting powder base coat is applied to smooth the surface to a glass-like finish and to ensure adhesion of the metal coatings. A two part metal coating is then applied via a PVD process, consisting of a Ni/Cr base and a Cr layer. A protective acrylic, thermosetting topcoat is then applied to protect the metal coating layers.