Abstract: A light-reflective, flowable and curable composition is described which comprises a resin containing light-reflective solid particles in an amount and of average particle size sufficient to provide the desired light reflectance/transmittance characteristics to the cured composition. Preferably, the composition is self-leveling, and the solid particles may be particles of magnesium oxide, barium sulfate, aluminum oxide or mixtures thereof. The compositions of the invention are useful as reflective coatings in various applications such as for radiation detector devices including scintillator crystals.

Abstract: A method of preparing colloidal sols of pentavalent antimony containing increased amounts of metal is described. More particularly, a method of converting substantially water-insoluble metal antimonates to colloidal sols of pentavalent antimony is described. The method comprises mixing a substantially water-insoluble metal antimonate with a pentavalent antimony sol and agitating the mixture for a period of time sufficient to convert at least a portion of the crystalline metal antimonate to the colloidal state. The colloidal sols obtained in the described manner contain an increased amount of the metal, and such sols are useful as flame-retardants.

Abstract: A process for improving the flame-retardant properties of cellulose containing fibrous materials in the absence of halogen compounds which comprises treating said fibrous materials with an effective amount of a colloidal aqueous dispersion of an alkali metal polyantimonate containing a mole ratio of alkali metal to antimony in the dispersion of at least about 0.3:1, and drying said materials is described.

Abstract: Antioxidant compositions as described which are the reaction products of a mixture of(a) at least one compound selected from compounds having the formula ##STR1## wherein each Ar is an aromatic group, and R and R.sup.1 are each independently hydrogen, alkyl, substituted alkyl, oxyalkylene or --C(O)--R.sup.2 --COOH groups wherein R.sup.2 is an alkylene or alkenylene group, with the proviso that at least one of the R and R.sup.1 groups must be hydrogen or a group containing at least one substituent reactive with an epoxy group, andAr--NH--Ar--O--R.sup.3 (FORMULA II)wherein Ar is as defined above and R.sup.3 is hydrogen, or a substituted alkyl group containing at least one substituent reactive with an epoxy group, or --C(O)--R.sup.2 --COOH wherein R.sup.2 is an alkylene or alkenylene group, and(b) at least one polyepoxide having at least 2 epoxy groups per molecule.

Abstract: A method of preparing esters and salts of esters of pentavalent antimony from hydrated metal antimonates is disclosed. The method comprises heating a mixture of a hydrated metal antimonate and an organic compound selected from the group consisting of(i) a polyhydroxy or a polymercapto compound containing vicinal hydroxy or mercapto groups, or a mixture of the two groups,(ii) an alpha-hydroxy or alpha-mercapto carboxylic acid or thiocarboxylic acid, and(iii) glyoxal,To a temperature sufficient to form the salt of the ester. The salts which are prepared in this manner are effective flame retardants for cotton and other organic polymers.

Abstract: The invention relates to new salts of 2,5-dihydroxy benzene sulphonic acids and the process for their production.The new compounds according to the invention are salts corresponding to the general formula (I): ##STR1## in which M.sup.++ represents the divalent cation of a transition metal,N is the number 1 or 2, but with the proviso that, when n is the number 2, the two radicals --SO.sub.3.sup.- are situated in the para-position relative to one another.The new compounds are useful for treating disorders of the scalp.

Abstract: A method of preparing a colloidal aqueous dispersion of antimony pentoxide from substantially water-insoluble metal antimonate is described. The method comprises contacting an aqueous slurry of the metal antimonate with a cation exchange resin whereby the metal antimonate is converted to the colloidal antimony pentoxide. A preferred method involves passing the slurry of metal antimonate through a fluidized bed containing a cation exchange resin. The colloidal sols obtained in the prescribed manner are useful as flame retardants when combined with halogen compounds.

Abstract: Finely divided particulate inorganic antimony compounds which are surface-modified with an organic zirconate having the formula(RO).sub.4 Zrwherein each R is independently an aliphatic radical containing from one to about 18 carbon atoms are described. These surface-modified antimony compounds may be incorporated into various organic resin and elastomer systems to improve the flame-retardant properties of these materials.

Abstract: Finely divided particulate inorganic antimony compounds which are surface modified with an organic titanium compound having the formulaTi(OR).sub.4wherein each R is independently an alkyl, aryl, cycloalkyl, or vinyl group containing from one to about 18 carbon atoms, orTi(OR').sub.2 (OYX).sub.2wherein X is oxygen or nitrogen, Y is a two- or three-carbon atom chain, and R' is equal to R, H or the ligand represented by XYOH are described. These surface modified antimony compounds may be incorporated into various organic resin and elastomer systems to improve the flame-retardant properties of these materials.

Abstract: Finely divided particulate inorganic antimony compounds which are surface modified with up to about 5% by weight of an organosilane having the formula ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are each independently hydrogen, lower alkyl, lower alkenyl, alkoxyalkyl aryl, lower alkylaryl, or lower arylalkyl groups, and R' is an organo functional group are described. These surface modified antimony compounds may be incorporated into various organic resin and elastomer systems to improve the flame-retardant properties of these materials.

Abstract: A method for extracting antimony from solids containing antimony sulfides is described. An improvement in the method of extracting antimony by oxidation of an aqueous mixture of the solids in an acid or by oxidation of a leaching liquor obtained by leaching the antimony from the solids with an aqueous basic solution comprises conducting the oxidation in the presence of a catalyst comprising a water-soluble copper salt, a quinone, a hydroquinone or mixtures of one or more of these. The catalyst significantly increases the rate of oxidation and the rate of the recovery of the antimony from antimony sulfide bearing solids, particularly natural ores. Where the oxidation is conducted in a basic solution, the antimony is recovered as pentavalent antimony in the form of metal antimonates. Facile reduction of the metal antimonate to antimony trioxide also is described.

Abstract: An aqueous plating bath for the electrodeposition of a zinc coating on a substrate is disclosed and comprises zinc ions, and an amount, sufficient to provide a level zinc electrodeposit, of one or more bath-soluble leveling phosphorus cations having the formula:R.sub.4 P .sym.wherein each R is independently a hydroxy alkyl group. Baths are also described which contain, in addition to the phosphorus cations identified above, at least one nitrogen-containing compound obtained by reacting (a) ammonia, an aliphatic amine containing at least one primary amine group, or mixtures of two or more of any of these with (b) one or more epihalohydrins, glycerol halohydrins, or mixtures thereof, and at least one thiourea having the general formula:[R'.sub.2 N].sub.2 CSwherein each R' is independently hydrogen or an alkyl or alkenyl group. Methods for electrodeposition of level zinc deposits from such baths and additive compositions for preparing and maintaining the baths are disclosed.

Abstract: The present invention provides an ammonia-free acid zinc plating bath for electrodepositing bright zinc on a substrate in which the zinc deposit produced thereby is ductile and presents a glossy to bright coating on the substrate over a wide cathodic current density range. The ammonia-free acid zinc plating baths of the invention comprise zinc ions, chloride ions, at least one polyoxyalkylated naphthol, at least one aromatic carboxylic acid or bath-soluble salt thereof, and at least one anionic aromatic sulfonic acid or bath-soluble salt thereof. In addition to the above components, the ammonia-free acid zinc plating baths of the invention may contain at least one nonionic polyoxyethylene compound and at least one aromatic aldehyde, ketone, or mixtures thereof. The ammonia-free acid zinc plating baths of the invention are free from significant amounts of complexing agents that would impede the removal of zinc ions from the baths prior to disposal.