Patents Represented by Attorney B. J. Boshears
  • Patent number: 8198371
    Abstract: Polymer blends comprising polyesters made from terephthalic acid; 2,2,4,4-tetramethyl-1,3-cyclobutanediol; and 1,4-cyclohexanedimethanol, and copolymers made from acrylonitrile, butadiene, and styrene (ABS) monomers. These blends have a combination of toughness, heat resistance, high modulus, and good flowability—making them particularly useful in films, fibers, engineering molding plastics, and packaging.
    Type: Grant
    Filed: February 23, 2009
    Date of Patent: June 12, 2012
    Assignee: Eastman Chemical Company
    Inventor: Gary Michael Stack
  • Patent number: 7510768
    Abstract: This invention relates to thermoplastic article having one or more decorative materials embedded therein which is obtained by applying heat and pressure to one or more laminates wherein at least one of said laminates comprises, in order, (1) an upper sheet material; (2) one or more decorative materials; and (3) a lower sheet material; wherein the upper and lower sheet materials are formed from a polyester/aromatic polycarbonate blend wherein the thermoplastic article comprises at least one polyester composition comprising at least one polyester which comprises terephthalic acid and 2,2,4,4-tetramethyl-1,3-cyclobutanediol.
    Type: Grant
    Filed: March 28, 2006
    Date of Patent: March 31, 2009
    Assignee: Eastman Chemical Company
    Inventors: Emmett Dudley Crawford, David Scott Porter, Gary Wayne Connell
  • Patent number: 7491760
    Abstract: This invention relates to a polymer composition comprising (A) at least one polyester prepared by the reaction of at least one diol with at least one dicarboxylic acid/or dialkyl ester thereof in the presence of a metallic catalyst; (B) a salt comprising at least one suitable phosphorus-containing acid and at least one suitable basic organic compound, such as a hindered amine light stabilizer; (C) at least one ultraviolet light absorbing compound and optionally at least one phenolic antioxidant. A second embodiment of the present invention pertains to a blend of (A) at least one polyester prepared by the reaction of at least one diol with at least one dicarboxylic acid/or dialkyl ester thereof in the presence of a metallic catalyst; (B) a salt comprising at least one suitable phosphorus-containing acid and at least one suitable basic organic compound; (C) at least one ultraviolet light absorbing compound and, optionally, at least one phenolic antioxidant; and (D) at least one polycarbonate.
    Type: Grant
    Filed: August 16, 2005
    Date of Patent: February 17, 2009
    Assignee: Eastman Chemical Company
    Inventors: Jason Clay Pearson, Douglas Stephens McWilliams, Gether Irick, Jr., Max Allen Weaver
  • Patent number: 7482397
    Abstract: This invention relates to polycarbonate compositions comprising: (A) at least one polycarbonate comprising repeating units derived from a dihydroxyaromatic compound or a dihydroxyaliphatic compound of the formula HO—Y—OH; and (B) at least one salt prepared from the reaction of one or more acidic phosphorus-containing compounds and one or more hindered amine light stabilizers. The polycarbonate compositions exhibit improved hydrolytic stability.
    Type: Grant
    Filed: August 16, 2005
    Date of Patent: January 27, 2009
    Assignee: Eastman Chemical Company
    Inventors: Jason Clay Pearson, Douglas Stephens McWilliams, Gether Irick, Jr., Max Allen Weaver
  • Patent number: 7468409
    Abstract: Disclosed are polymer compositions comprising: (A) at least one polyester prepared by the reaction of at least one diol with at least one dicarboxylic acid or dialkyl ester thereof in the presence of a metallic catalyst; and (B) at least one salt prepared from the reaction of one or more acidic phosphorus-containing compounds and one or more basic organic compounds which contain nitrogen. The polyester compositions exhibit improved color, especially when used as a component of a polyester/polycarbonate blend. Also disclosed are polymer compositions comprising a polycarbonate in combination with components (A) and (B).
    Type: Grant
    Filed: August 16, 2005
    Date of Patent: December 23, 2008
    Assignee: Eastman Chemical Company
    Inventors: Jason Clay Pearson, Douglas Stephens McWilliams, Gether Irick, Jr., Max Allen Weaver
  • Patent number: 7462684
    Abstract: Disclosed is a process for the preparation of multilayered, shaped articles having high transparency and low haze and in which at least one layer contains at least one polyester comprising 2,2,4,4-tetramethyl-1,3-cyclobutanediol and a separate layer which contains a transamidized, homogeneous blend of a least two polyamides. The polyester component and the polyamide component have refractive indices which differ by about 0.006 to about ?0.0006. The small difference in the refractive indices enable the incorporation of regrind into one or more of the layers of the article while maintaining high clarity. These articles can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties. Metal catalysts can be incorporated into one or more layers to impart oxygen-scavenging properties.
    Type: Grant
    Filed: March 28, 2006
    Date of Patent: December 9, 2008
    Assignee: Eastman Chemical Company
    Inventors: Wesley Raymond Hale, Thomas Joseph Pecorini, Mark Edward Stewart, Martin Emerson Rogers, Spencer Allen Gilliam, Michael Duane Cliffton, Emmett Dudley Crawford, David Scott Porter, Gary Wayne Connell, Marcus David Shelby
  • Patent number: 7425590
    Abstract: Polymer compositions comprising: (A) at least one polyester (A) comprising: (1) diacid residues comprising about 70 to 100 mole percent phthalic acid residues; and 0 to about 30 mole percent of modifying dicarboxylic acid residues, wherein the total mole percent of diacid residues is equal to 100 mole percent; and (2) diol residues comprising about 0 to 45 mole percent 1,4-cyclohexanedimethanol residues, and 100 to about 55 mole percent of other alkylene glycol residues, wherein the total mole percent of diol residues is equal to 100 mole percent; and (B) a miscible blend of: (1) at least one polycarbonate (B) of bisphenol A; (2) at least one polyester (C) consisting essentially of 1,4-cyclohexanedicarboxylic acid residues and at least one glycol selected from 70 to 100 mole percent of residues of 1,4-cyclohexanedimethanol residues and 0 to 30 mole percent of residues of polytetramethylene glycol.
    Type: Grant
    Filed: July 12, 2005
    Date of Patent: September 16, 2008
    Assignee: Eastman Chemical Company
    Inventor: Wesley Raymond Hale
  • Patent number: 7345104
    Abstract: Blends of polycarbonate and copolyester that are capable of being extrusion blow-molded are described. The blends preferably comprise (I) about 1 to 99% by weight of a linear or branched polycarbonate and (II) about 1 to 99% by weight of a mixture of (i) about 40 to 100% by weight of a first copolyester and (ii) about 0 to 60% by weight of a second copolyester. The first copolyester preferably comprises (A) diacid residues comprising terephthalic acid residues, (B) diol residues comprising about 45 to 75 mole percent of 1,4-cyclohexanedimethanol (CHDM) residues and about 25 to 55 mole percent of ethylene glycol residues, and (C) about 0.05 to 1.0 mole percent of the residue of a trifunctional monomer. The optional second copolyester preferably comprises (A) diacid residues comprising terephthalic acid residues and (B) diol residues comprising about 52 to 90 mole percent of CHDM residues and about 10 to 48 mole percent of ethylene glycol residues.
    Type: Grant
    Filed: November 5, 2004
    Date of Patent: March 18, 2008
    Assignee: Eastman Chemical Company
    Inventors: Wesley Raymond Hale, Thomas Joseph Pecorini, Harold Eugene Dobbs, Spencer Allen Gilliam
  • Patent number: 7342059
    Abstract: Blends of polycarbonate and copolyester that are capable of being extrusion blow-molded are described. The blends preferably comprise (I) about 1 to 99% by weight of a linear or branched polycarbonate and (II) about 1 to 99% by weight of a mixture of (i) about 40 to 100% by weight of a first copolyester and (ii) about 0 to 60% by weight of a second copolyester. The first copolyester preferably comprises (A) diacid residues comprising terephthalic acid residues, (B) diol residues comprising about 45 to 75 mole percent of 1,4-cyclohexanedimethanol (CHDM) residues and about 25 to 55 mole percent of ethylene glycol residues, and (C) about 0.05 to 1.0 mole percent of the residue of a trifunctional monomer. The optional second copolyester preferably comprises (A) diacid residues comprising terephthalic acid residues and (B) diol residues comprising about 52 to 90 mole percent of CHDM residues and about 10 to 48 mole percent of ethylene glycol residues.
    Type: Grant
    Filed: December 16, 2003
    Date of Patent: March 11, 2008
    Assignee: Eastman Chemical Company
    Inventors: Thomas Joseph Pecorini, Harold Eugene Dobbs, Spencer Allen Gilliam, Wesley Raymond Hale
  • Patent number: 7297735
    Abstract: This invention relates to polycarbonate compositions comprising: (A) at least one polycarbonate comprising repeating units derived from a dihydroxyaromatic compound or a dihydroxyaliphatic compound of the formula HO—Y—OH; and (B) at least one salt prepared from the reaction of one or more acidic phosphorus-containing compounds and one or more hindered amine light stabilizers. The polycarbonate compositions exhibit improved hydrolytic stability.
    Type: Grant
    Filed: March 5, 2003
    Date of Patent: November 20, 2007
    Assignee: Eastman Chemical Company
    Inventors: Jason Clay Pearson, Douglas Stephens McWilliams, Gether Irick, Jr., Max Allen Weaver
  • Patent number: 7297736
    Abstract: Disclosed are polymer blends comprising polycarbonate(s) and polyester(s) wherein the polycarbonate is a polycarbonate derived from bisphenol A and the polyester comprises residues of or is derived from one or more aromatic dicarboxylic acids, neopentyl glycol, and 1,4-cyclohexanedimethanol.
    Type: Grant
    Filed: October 28, 2004
    Date of Patent: November 20, 2007
    Assignee: Eastman Chemical Company
    Inventors: Wesley Raymond Hale, Thomas Joseph Pecorini, Sam Richard Turner
  • Patent number: 7279123
    Abstract: A polyester resin composition is calendered to produce a film or a sheet. The polyester resin composition is a polyester having a crystallization half time from a molten state of at least 5 minutes combined with an additive for preventing sticking of the polyester to calendering rolls.
    Type: Grant
    Filed: December 1, 2004
    Date of Patent: October 9, 2007
    Assignee: Eastman Chemical Company
    Inventors: Paul Mary Flynn, Richard Leon McConnell, Hubertus Jacobus Wilhelmus Moolenaar, Timothy Michael Sanders
  • Patent number: 7230065
    Abstract: The present invention relates to miscible blends of the polycarbonate of bisphenol A and polyesters from aromatic dicarboxylic acids, 1,4-cyclohexanedimethanol, ethylene glycol, and 2,2?-(sulfonylbis(4,1-phenyleneoxy)-bis(ethanol).
    Type: Grant
    Filed: July 12, 2005
    Date of Patent: June 12, 2007
    Assignee: Eastman Chemical Company
    Inventors: Wesley Raymond Hale, Sam Richard Turner, Gary Wayne Connell
  • Patent number: 7226985
    Abstract: Disclosed are polymer compositions comprising: (A) a first component comprising about 1 to 99 percent by weight at least one polyester (A) comprising: (1) diacid residues selected from the group consisting of terephthalic acid residues, isophthalic acid residues and mixtures thereof, and (2) diol residues selected from the group consisting of 1,4 -cyclohexanedimethanol residues, ethylene glycol residues and mixtures thereof; wherein the molar ratio of 1,4-cyclohexanedimethanol to ethylene glycol is less than 0.
    Type: Grant
    Filed: July 12, 2005
    Date of Patent: June 5, 2007
    Assignee: Eastman Chemical Company
    Inventors: Wesley Raymond Hale, David Gayle Salyer
  • Patent number: 7157547
    Abstract: An ultraviolet absorption composition has been developed for the protection of packaging or container contents in the ultraviolet range of 290 nm to 390 nm, offering effective screening from all wavelengths of solar radiation. A combination of an optical brightener with an ultraviolet absorber has been found to provide effective screening without adding significant color to the polymer composition. This extended range of ultraviolet blocking over what can be achieved with ultraviolet absorbers alone is especially valuable in food and drink packaging applications where the contents of the packages need ultraviolet protection to prevent discoloration or development of undesirable flavors.
    Type: Grant
    Filed: November 13, 2003
    Date of Patent: January 2, 2007
    Assignee: Eastman Chemical Company
    Inventors: Rondell Paul Little, Jr., Gether Irick, Jr., Emerson Eston Sharpe, Jr.
  • Patent number: 7147927
    Abstract: Disclosed are biaxially oriented polyester film produced from a polyester comprising: (1) diacid residues comprising at least 90 mole percent of terephthalic acid residues, naphthalenedicarboylic acid residues or combinations thereof; and (2) diol residues comprising at least 90 mole percent of 1,4-cyclohexanedimethanol residues; wherein the polyester comprises a total of 100 mole percent diacid residues and a total of 100 mole percent diol residues; wherein the polyester film is stretched at a ratio of about 2.5× to 3× in the machine direction (MD) and about 2.5× to 3× in the transverse direction (TD) at stretching temperatures between 90 and 1 10OC, wherein the stretched film is subsequently heat-set at an actual film temperature of from 260° C.
    Type: Grant
    Filed: June 25, 2003
    Date of Patent: December 12, 2006
    Assignee: Eastman Chemical Company
    Inventors: Thomas Joseph Pecorini, Gary Darrel Boone
  • Patent number: 7118799
    Abstract: This invention relates to thermoplastic article having one or more decorative materials embedded therein which is obtained by applying heat and pressure to one or more laminates wherein at least one of said laminates comprises, in order, (1) an upper sheet material; (2) one or more decorative materials; and (3) a lower sheet material; wherein the upper and lower sheet materials are formed from a polyester/aromatic polycarbonate blend.
    Type: Grant
    Filed: November 22, 2002
    Date of Patent: October 10, 2006
    Assignee: Eastman Chemical Company
    Inventors: Emmett Dudley Crawford, Robert William Seymour
  • Patent number: 7037576
    Abstract: The invention relates to polyester/polyolefin laminate materials having improved properties. The invention also relates to copolyester/polyolefin laminate materials having improved properties. The laminates herein exhibit improved results in flammability studies. The invention further relates to methods of making laminate structures.
    Type: Grant
    Filed: January 31, 2003
    Date of Patent: May 2, 2006
    Assignee: Eastman Chemical Company
    Inventors: John Edward Christopher Willham, Thomas Joseph Pecorini
  • Patent number: 6914120
    Abstract: This invention relates to a process for producing a polyester comprising the steps of: (g) obtaining an aqueous homogenous solution of isosorbide; (h) feeding the aqueous homogenous solution of step (a) into a reactor; (i) feeding one or more glycols and one or more dicarboxylic acids either into the aqueous solution of step (a) or into the reactor of step (b) either prior to, during and/or subsequent to step (b); (j) esterifying the reactor contents at sufficient temperatures and pressures, and optionally in the presence of suitable catalysts, to effect esterification; (k) forming a prepolymer; and (l) polycondensing the prepolymer at sufficient temperatures and pressures in the presence of a suitable catalyst to effect polycondensation to form a polyester.
    Type: Grant
    Filed: November 13, 2002
    Date of Patent: July 5, 2005
    Assignee: Eastman Chemical Company
    Inventors: Ted Calvin Germroth, Sam Richard Turner, Lanny Calvin Treece
  • Patent number: 6896966
    Abstract: This invention relates to thermoplastic article having one or more decorative materials on the surface thereof which is obtained by applying heat and pressure to a laminate wherein said thermoplastic article comprises (1) one or more decorative materials; and (2) an upper or lower sheet material; wherein the upper or lower sheet material is formed from a polyester/aromatic polycarbonate blend.
    Type: Grant
    Filed: November 22, 2002
    Date of Patent: May 24, 2005
    Assignee: Eastman Chemical Company
    Inventors: Emmett Dudley Crawford, Robert William Seymour