Abstract: The efficacy of a passivating layer in a rechargeable lithium ion cell is increased by heating the charged cell and storing the charged cell for a pre-determined period of time.

Abstract: A method of treating lithium manganese oxide of spinel structure is disclosed. The method involves heating the lithium manganese oxide spinel in an atmosphere of an inert gas which does not react with the spinel. Such gases may be selected advantageously from argon, helium, nitrogen, and carbon dioxide. Preferred nonreacting gases which may be employed for spinel treatment are nitrogen or carbon dioxide. The spinel is advantageously treated with such gases at elevated temperatures. Alternatively, the spinel may be first coated with a hydroxide, preferably lithium, sodium or potassium hydroxide and then heated in an atmosphere of carbon dioxide gas at elevated temperatures. Such treatment of lithium manganese oxide spinel has been determined to improve the performance of the spinel when employed as an electrode in rechargeable cells such as lithium-ion cells.

Abstract: Disclosed is a process for treating manganese dioxide containing ion-exchangeable cations by replacing the ion-exchangeable cations present in the manganese dioxide with lithium by a process comprising first replacing ion-exchangeable cations present in the manganese dioxide with hydrogen. This readily is accomplished by slurrying the manganese dioxide in an aqueous acid solution. The resulting acidic manganese dioxide then is neutralized with a basic solution of a lithium containing compound, such as lithium hydroxide. This neutralization step serves to accomplish replacement of the previously introduced hydrogen, by ion-exchange, with lithium. The manganese dioxide then is washed with water, dried, and heat-treated at an elevated temperature, in conventional manner, to convert the gamma manganese dioxide to a mixture of the gamma and beta forms, which then is used as the active cathodic component in an electrochemical cell.

Abstract: Disclosed is a process for making a lithiated lithium manganese oxide spinel of the formula Li.sub.(1+x)Mn.sub.2 0.sub.4 comprising contacting a lithium manganese oxide spinel of the formula LiMn.sub.2 O.sub.4 with a lithium carboxylate compound, at a temperature and for a time sufficient to decompose the carboxylate compound and free the lithium to form said lithiated spinel.

Abstract: A current interrupt mechanism for electrochemical cells is disclosed. A thermally activated current interrupt mechanism is integrated into an end cap assembly for an electrochemical cell. The thermally responsive mechanism preferably includes a free floating bimetallic disk which deforms when exposed to elevated temperature causing a break in an electrical pathway within the end cap assembly. This prevents current from flowing through the cell and effectively shuts down an operating cell. Alternatively, the thermally responsive mechanism may include a meltable mass of material which melts when exposed to elevated temperature to break an electrical pathway within the end cap assembly. The end cap assembly may also include integrated therein a pressure responsive current interrupt mechanism.

Abstract: A light transparent moisture barrier useful for preventing moisture from destroying the effectiveness of a moisture sensitive cell condition tester on an electrochemical cell comprises a plurality of very thin; alternating layers of an inorganic material and an organic material on a flexible, polymeric substrate. The layers are not laminated, but are formed on the substrate by a deposition or coating process and the thickness of any layer is less than 5 microns.

Abstract: Disclosed is a charger unit for charging a rechargeable energy storage device. In particular, a universal charger unit is disclosed which comprises a connector having a set of externally accessible contacts for making electrical contact with a corresponding set of receptor contacts on a rechargeable energy storage device. The connector, which may comprise a removable module, also preferably includes a sensor to interact with the structure of the receptor on the rechargeable device, so that the output of the charger unit can be regulated to be compatible with the electrical characteristics of the rechargeable device as determined by the sensor. The charger unit and/or connector may include one or more replaceable electronics modules.

Abstract: The present invention relates to coiled electrode assemblies having conductive tabs, methods of attaching the conductive tabs to the coiled electrode, and electrochemical cells employing such assemblies. In the process of the invention, the conductive tab area of an electrode plate coated with active material is pierced with opposing, offset piercing plates having raised surface probes which penetrate the conductive tab area. The resulting area is cleared of active material, and a conductive tab is welded to the thus treated area resulting in an electrode plate having a strong integrated tab assembly.

Abstract: An apparatus for the transfer or conveyance of a slurry and the simultaneous densification thereof through the intermediary of vacuum pumping. Specifically, disclosed is an apparatus for the vacuum pumping of a slurry, particularly a zinc-containing slurry utilized in the preparation of zinc anodes for alkaline batteries, which facilitates the transfer of the slurry and the concurrent densification thereof in conjunction with the elimination of any gas bubbles which are entrapped in the slurry. Also disclosed is a method of transferring and simultaneously densifying a slurry while eliminating entrapped gas bubbles therefrom through the intermediary of a vacuum pumping process utilizing the disclosed apparatus.

Abstract: A method for the production of slurries which are uniform in density and consistency. In particular, a method for preparing zinc anode slurries employed in producing anodes for alkaline batteries. The method comprises a bag slurry forming process, using a drum mixer, involving mixing dry anode components within a sealed, inplated, gas-tight, liquid impervious, flexible, collapsible bag; and, then adding a wet component to the bag, collapsing said bag, and tumbling-kneading the components to form a blended slurry.

Abstract: A tester for determining the condition of an electrochemical power source, e.g. a battery or main cell, is disclosed. The tester may comprise an electrolytic (coulometric) cell connected in series to a auxiliary cell. The auxiliary cell is a miniature electrochemical power cell. The electrolytic (coulometric) cell may have no electromotive force of its own and may comprise an anode and cathode of the same material, desirably silver, with an electrolyte contacting at least a portion of both the anode and cathode. The tester may be permanently connected in parallel to a main cell being tested and is thin enough to be integratable into a label for the main cell. As the main cell discharges, the electrolytic cell anode clears proportionally to the discharge of one of the electrodes of the main cell to provide a continuous visually discernible indication of the state of charge of the main cell.

Abstract: A process is recited for plating elongated current collectors with indium. The current collectors have particular utility in alkaline electrochemical cells, particularly zinc/manganese dioxide alkaline cells containing "zero-added" mercury. The process of the invention involves electroplating conductive wire with indium and then drawing the plated wire to a lesser diameter. The drawn plated wire may then be cut to the desired lengths, typically in the shape of a nail, for use as current collectors within the alkaline cell.

Abstract: A label for an electrochemical cell with a condition tester for the cell integrated with the label to form a label/tester composite is disclosed. The label/tester composite has a thermochromic material in thermal contact with an electrically conductive material. A substructure containing a cured conductive material and preferably also a thermochromic material is formed on a releasable web and transferred from the releasable web to the inside surface of the heat shrinkable base film. A partition coating may be applied over the transferred conductive material. Preferably, a sheet of paper or plastic film having a large window opening therein for entrapping air is applied over the partition coating and aligned over the heat generating portion of the conductive material. The label/tester composite is applied to the cell housing with the insulating paper or plastic film with window opening against the cell housing.

Abstract: A label for an electrochemical cell with a condition tester for the cell integrated with the label to form a label/tester composite is disclosed. The label/tester composite comprises a thermochromic coating in thermal contact with an electrically conductive coating. The label/tester composite is preferably constructed by applying an adhesive to the inside surface of a heat shrinkable base film forming part of the label. A substructure containing a cured conductive coating and preferably also a thermochromic coating is formed on a releasable web. The substructure is transferred from the releasable web to the inside surface of the heat shrinkable base film and in contact with a portion of the adhesive on the base film. A patterned partition insulating coating is then applied over the transferred conductive coating. The label/tester composite is applied to the cell housing. The integrated tester may be manually activated by depressing one or two regions on the surface of the composite.

Abstract: A label for an electrochemical cell with a condition tester for the cell integrated with the label to form a label/tester composite is disclosed. The label/tester composite has a thermochromic material in thermal contact with an electrically conductive material. A substructure containing a cured conductive material and preferably also a thermochromic material is formed on a releasable web and transferred from the releasable web to the inside surface of the heat shrinkable base film. A partition coating may be applied over the transferred conductive material. Preferably, a sheet of paper or plastic film having a large window opening therein for entrapping air is applied over the partition coating and aligned over the heat generating portion of the conductive material. The label/tester composite is applied to the cell housing with the insulating paper or plastic film with window opening against the cell housing.

Abstract: A light transparent moisture barrier useful for preventing moisture from destroying the effectiveness of a moisture sensitive cell condition tester on an electrochemical cell comprises a plurality of very thin, alternating layers of an inorganic material and an organic material on a flexible, polymeric substrate. The layers are not laminated, but are formed on the substrate by a deposition or coating process and the thickness of any layer is less than 5 microns. The organic material is a hydrophobic polymer and the inorganic material is a metal oxide, nitride, a glass or silicon.

Abstract: A condition indicator assembly (tester) for determining the condition of a main cell, e.g. a battery, is disclosed. The condition indicator assembly may comprise an electrochemical indicator cell connected in series to a auxiliary cell. The indicator cell and auxiliary cell each have an anode, cathode and electromotive force (e.m.f.) of its own. The condition indicator assembly may be permanently connected in parallel to the terminals of a main cell being tested. The condition indicator assembly is thin enough that it may be interated into a label for the main cell. As the main cell discharges, the indicator cell anode clears proportionally to the discharge of one of the electrodes of the main cell to provide a continuous visually discernible indication of the state of charge of the main cell.

Abstract: A package for a battery or other article, comprising a sheet of material bent or folded along a plurality of substantially parallel fold lines 21, 22, 25, 26 to define an upwardly extending substantially flat panel region 15, an upper end locating region 11 extending forwardly from the lower extremity of the said panel region, a first limb 3 extending obliquely downwardly and rearwardly from the forward extremity of the end locating region, a second limb 5 extending obliquely forwardly and downwardly and defining with the first limb a V-section channel region, a lower end locating region 13 extending rearwardly from the lower limb, and a rear panel region 17 extending upwardly from the rear extremity of the lower end locating region and secured to the first mentioned panel region 15.

Abstract: A light transparent moisture barrier useful for preventing moisture from destroying the effectiveness of a moisture sensitive cell condition tester on an electrochemical cell, comprises a plurality of very thin layers of amorphous silicon nitride and a hydrophobic fluorocarbon polymer on a flexible, polymeric substrate. The layers are formed on the substrate by a deposition process such as sputtering. The thickness of any individual layer is less than one micron.

Abstract: A sealing and insulating member for a cylindrical galvanic cell wherein said member comprises a plurality of vent membranes of non-circular configuration. The seal can readily be made from mineral filled polyolefin material by injection molding.