Abstract: Method and apparatus for separating solid particles from a mixed fluid stream is provided by this invention. The method comprises helically guiding a fluid mixture of particles and liquid into a porous-walled chamber, discharging the fluids centrifugally from the chamber and recovering the particles at the bottom of the chamber. Apparatus, in accordance with the present invention, includes a helical conduit, in fluid flow connection with a porous chamber, a spiral deflector extending from the top of helical conduit downwardly into the chamber so as to deflect the particles downwardly as the water is ejected centrifugally through the sides of the chamber.

Abstract: This invention provides a process for separating the halide of cobalt, and optionally nickel, from a pregnant aqueous solution, the aqueous solution also containing a manganese halide. The process comprises initially extracting the cobalt halide and a portion of any manganese halide which is present into an organic extract. The nickel halide is then separately extracted from the solution. The manganese halide is preliminarily preferentially stripped from the organic extract containing cobalt and manganese utilizing an aqueous solution comprising halide ions. The cobalt halide in the extract can then be stripped into an aqueous solution together with the remaining manganese to form a strip solution. The manganese is then preferentially extracted from the strip solution, leaving a manganese-free, substantially pure cobalt solution. Any nickel can be selectively extracted from the manganese remaining in the pregnant solution.

Abstract: A process is provided to produce pure elemental metal; such as manganese, by reacting a halide of the elemental metal with aluminum. The halide of the elemental metal is present as a molten pool wherein the temperature at the bottom of the pool is sufficient to maintain the elemental metal molten and the temperature at the top of the pool is below the boiling point of the metal halide in the pool. Aluminum halide is removed as a vapor overhead and a layer of molten metal collects at the bottom of the pool of molten halide.

Abstract: Ocean floor nodules are treated with aqueous hydrogen halide to produce a pregnant leach solution which is subjected to selective solvent extraction to isolate metal values contained in the ore.

Abstract: This invention provides a process for obtaining substantially pure manganese metal by the reduction of a manganese oxide or a manganese halide by reaction with a subhalide of a transport metal. The transport metal can be aluminum, silicon, or titanium. In preferred embodiments of this procedure, a continuous closed cycle process is carried out wherein the transport metal value is reconverted to its subhalide and recycled for reaction with additional manganese compound.

Abstract: This invention provides a process for separating metal values from an anhydrous mixture of metal halides in a fluid state, i.e. vapor or liquid; the separation is made by contacting a fluid mixture containing a halide of at least one less-noble metal selected from the group consisting of iron and manganese, and a halide of at least one more-noble metal selected from the group consisting of copper, cobalt and nickel, with an elemental metal. This procedure is especially effective in the refining of ocean floor nodule ores.

Abstract: This invention provides a process for selectively removing metal values from ocean floor nodule ore by a two-stage procedure. In the first stage, the ore is leached with an aqueous solution of sulfuric acid or a hydrogen halide to preferentially remove nickel and copper. In the second stage, the ore is leached with a reducing agent to preferentially remove cobalt and manganese. The two leach solutions can then be further treated to separate the individual metal values, e.g., by liquid ion exchange procedures.