Abstract: A novel process for preparing functionalized polypropylenes entailing apportioned introduction of free radical initiator is described. Also described are novel functionalized polypropylenes having a yellowness index color of at least 77 and a Brookfield Thermosel viscosity of greater than 7000 cP at 190° C. Preferably, the functionalized polypropylenes are further characterized by having an acid number greater than 6 milligrams of KOH per gram of polymer.

Abstract: Solid acids are used as catalysts for the polymerization of a feed stream containing at least one of pure monomer, C5 monomers, and C9 monomers to produce hydrocarbon resins. Freely-associated water may be removed from the solid acid catalyst prior to use. Resins with softening points (Ring and Ball) in the range of about 5° C. to 170° C. can be prepared. These catalysts offer advantages over the traditional Friedel-Crafts polymerization catalysts since the acid sites are an integral part of the solid. The solid acid catalysts are relatively nonhazardous, reusable catalysts which eliminate or at least reduce contamination of the resulting resin products with acid residues or by-products.