Patents Represented by Attorney Beverly K. Johnson
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Patent number: 5435822Abstract: A spray-dried foliar fertilizer for enhancing plant nutrition and health, prepared by spray drying nutrient compounds. The foliar fertilizer is amorphous, free-flowing and water dispersible and may be applied directly to the plant foliage by dusting or spraying.Type: GrantFiled: February 18, 1994Date of Patent: July 25, 1995Assignee: W. R. Grace & Co.-Conn.Inventor: John J. Blouin
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Patent number: 5431817Abstract: The resistance to an oxidizer of a biocompatible polysulfone membrane can be enhanced by the incorporation of a specific hydrophilic polyurethane polymer.Type: GrantFiled: September 13, 1993Date of Patent: July 11, 1995Assignee: W. R. Grace & Co.-Conn.Inventors: James A. Braatz, Denise A. Miller
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Patent number: 5427995Abstract: An alumina sorbent capable of adsorbing NOx and SOx from waste gases and being regenerated by heating above 650.degree. C. is made by incorporating an alumina stabilizing agent into the sorbent. A preferred method is to add the stabilizer when the alumina is precipitated. The precipitated powder is formed subsequently into a slurry, milled and spray dried to form the stabilized spheroidal alumina particles having a particle size of less than 500 microns. These particles are impregnated with an alkali metal or alkaline earth metal to form the stabilized sorbent. Alumina stabilizers include one or more of silica, lanthana, other rare earths, titania, zirconia and alkaline earths.Type: GrantFiled: February 24, 1993Date of Patent: June 27, 1995Assignee: W. R. Grace & Co.-Conn.Inventors: Michael S. Ziebarth, Michael J. Hager, Jean W. Beeckman, Stanislaw Plecha
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Patent number: 5422083Abstract: There is provided a reinforced converter body, especially one useful as a "light-off" converter in a gas treating system for treating exhaust gas from internal combustion engines. The invention utilizes corrugated and flat thin metal strips in alternating relation. Reinforcement is enhanced by the use of thin metal strips of a stronger alloy for at least a part of the thin metal strips.Type: GrantFiled: June 29, 1993Date of Patent: June 6, 1995Assignee: W. R. Grace & Co.-Conn.Inventor: David T. Sheller
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Patent number: 5413771Abstract: An alumina sorbent capable of adsorbing NOx and SOx from waste gases and being regenerated by heating above 600.degree. C. is made by incorporating an alumina stabilizing agent into the sorbent. A preferred method is to add the stabilizer when the alumina is precipitated. The precipitated powder is formed subsequently into a slurry, milled and dripped to form the stabilized spheroidal alumina particles. These particles are impregnated with an alkali metal or alkaline earth metal to form the stabilized sorbent. Alumina stabilizers include one or more of silica, lanthana, other rare earths, titania, zirconia and alkaline earths.Type: GrantFiled: November 6, 1992Date of Patent: May 9, 1995Assignee: W. R. Grace & Co.-Conn.Inventors: Michael S. Ziebarth, Michael J. Hager, Jean W. Beeckman, Stanislaw Plecha
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Patent number: 5411724Abstract: Aluminum can be removed from tetrahedral framework sites of zeolite frameworks and substituted with elements such as silicon, gallium, titanium or zirconium. The process involves three steps:(a) forming a mixture of the ammonium or alkaline metal form of the zeolite in the hydrated state and a crystalline ammonium fluoro-halo-metallate salt;(b) heating the mixture at elevated temperatures to remove the aluminum from the zeolite and to introduce the metal from the salt into the structure of the zeolitic component by solid-state reaction while forming a fluoro-halo-aluminate complex salt; and(c) removing the formed fluoro-halo-aluminate complex salt.Type: GrantFiled: June 2, 1993Date of Patent: May 2, 1995Assignee: W. R. Grace & Co.-Conn.Inventors: Herman K. Beyer, Gabriella Pal-Borbely
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Patent number: 5411736Abstract: A novel insecticide derived from a neem seed extract comprising neem oil which is substantially free of azadirachtin, said neem oil being prepared by extracting dried, coarsely ground neem seeds with a non-polar, hydrophobic solvent to obtain a neem oil extract, and then removing the solvent to obtain the neem oil. These neem oil insecticides exhibit the ability to repel insects from plant surfaces and kill insect pests at various life stages.Type: GrantFiled: July 9, 1993Date of Patent: May 2, 1995Assignee: W. R. Grace & Co.-Conn.Inventors: James C. Locke, James F. Walter, Hiram G. Larew, III
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Patent number: 5409708Abstract: Novel fungicide compositions prepared from neem seeds are disclosed. Two distinct neem derived fungicides obtained non-polar, hydrophobic solvent neem seed extracts which are substantially free of azadirachtin, by removing the hydrophobic solvent and cooling the resulting neem oil to separate a semi-solid neem wax fraction and a clarified neem oil fraction.Type: GrantFiled: January 31, 1994Date of Patent: April 25, 1995Assignee: W. R. Grace & Co.-Conn.Inventors: John C. Locke, James F. Walter, Hiram G. Larew, III
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Patent number: 5405612Abstract: A novel insecticide derived from a neem seed extract comprising neem oil which is substantially free of azadirachtin, said neem oil being prepared by extracting dried, coarsely ground neem seeds with a non-polar, hydrophobic solvent to obtain a neem oil extract, and then removing the solvent to obtain the neem oil. These neem oil insecticides exhibit the ability to repel insects from plant surfaces and kill insect pests at various life stages.Type: GrantFiled: December 2, 1993Date of Patent: April 11, 1995Assignee: W. R. Grace & Co.-Conn.Inventors: James C. Locke, James F. Walter, Hiram G. Larew, III
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Patent number: 5403750Abstract: Affinity matrices useful for the chromatography and immobilization of biological materials and the method of preparing and using the same are disclosed. The affinity supports are based on hydrated polyurethane polymers which have been activated to provide a means for covalently attaching a variety of bioaffinity agents. The hydrated polymer matrices are characterized by their biocompatibility and resistance to nonspecific protein adsorption. Preferably, the prepolymers used to prepare the hydrated polymers are isocyanate-capped oxyethylene-based diols or polyols, at least 75% of said diols and polyols having a molecular weight of 7000 to about 30,000.Type: GrantFiled: April 8, 1991Date of Patent: April 4, 1995Assignee: W. R. Grace & Co.-Conn.Inventors: James A. Braatz, Aaron H. Heifetz
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Patent number: 5397571Abstract: Disclosed is an improved method of extracting neem seeds. The method involves co-solvent extracting neem seeds with a solvent mixture of a nonpolar, aliphatic hydrocarbon solvent and a polar solvent to simultaneously remove the hydrophilic and hydrophobic extracts from the neem seeds. The method provides novel neem extract mixtures which contain both the hydrophobic and hydrophilic portion Of the neem seeds. The extract mixtures may be further extracted to yield an azadirachtin-containing solid product having greater than 10 weight percent of azadirachtin.Type: GrantFiled: March 25, 1993Date of Patent: March 14, 1995Assignee: W. R. Grace & Co.-Conn.Inventors: Michael T. Roland, John J. Blouin
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Patent number: 5395808Abstract: Porous bodies are produced which are suitable for use as supports for catalysts, including living cells, such as bacteria. The bodies have a significantly large average pore diameter of about 0.5 to 100 microns, (i.e. 5,000 to 1,000,000 .ANG.) and a total pore volume of about 0.1 to 1.5 cc/g with the large pores contributing a pore volume of from about 0.1 to 1.0 cc/g. The bodies are made by preparing a mixture of ultimate particles of bound clay, one or more optional ingredients such as inorganic binders, extrusion or forming aids, burnout agents, or a forming liquid, such as water. In a preferred embodiment, the ultimate particles are formed by spray drying.Type: GrantFiled: December 21, 1992Date of Patent: March 7, 1995Assignee: W. R. Grace & Co.-Conn.Inventors: James G. Miller, Michael J. Wax, Richard F. Wormsbecher
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Patent number: 5395600Abstract: A multicellular monolith converter body having a plurality of corrugated thin metal sheets or strips in alternating relation with a thin wire mesh or frame, and which monolith has a cell density up to 100 cells per square inch. These monoliths are useful under conditions where back-pressure is a critical factor, e.g., natural draft exhaust applications. These devices may have corrugated thin metal sheets coated with a refractory metal oxide, e.g., alumina, with or without a noble metal catalyst.Type: GrantFiled: July 13, 1993Date of Patent: March 7, 1995Assignee: W. R. Grace & Co.-Conn.Inventor: Richard C. Cornelison
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Patent number: 5382351Abstract: When a zeolite additive composition of a medium-pore zeolite with a Constraint Index from about 1 to about 12 and a silica to alumina mole ratio greater than about 12 is added to a conventional cracking catalyst dispersed in an inorganic matrix, the octane will be improved, but there will be a yield loss in the amount of gasoline produced. An improvement in that catalyst system is obtained by partially exchanging the medium-pore zeolite additive with cations from one or more elements of Group IA, Group IIA or Group IIIA excluding rare earths of the Periodic Table. The octane number of the gasoline-range product of an FCC process is still improved while the amount of the gasoline yield loss typically observed for such octane-enhancing additives is reduced.Type: GrantFiled: December 16, 1993Date of Patent: January 17, 1995Assignee: W. R. Grace & Co.-Conn.Inventors: James G. Miller, Robert R. Gatte
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Patent number: 5372817Abstract: Novel insecticide compositions prepared from neem seeds are disclosed. Two distinct neem derived insecticides obtained non-polar, hydrophobic solvent neem seed extracts which are substantially free of azadirachtin, by removing the hydrophobic solvent and cooling the resulting neem oil to separate a semi-solid neem wax fraction and a clarified neem oil fraction.Type: GrantFiled: December 13, 1993Date of Patent: December 13, 1994Assignee: W. R. Grace & Co.-Conn.Inventors: James C. Locke, James F. Walter, Hiram G. Larew, III
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Patent number: 5368856Abstract: A novel method of controlling fungi is disclosed. The method involves contacting the fungi, or a surface to be protected from the fungi, with a neem oil fungicide derived from a neem seed extract. The neem oil is prepared by extracting dried, coarsely ground neem seeds with a non-polar, hydrophobic solvent to obtain a neem oil extract and then removing the solvent to obtain the neem oil.Type: GrantFiled: August 2, 1993Date of Patent: November 29, 1994Assignee: W. R. Grace & Co.-Conn.Inventors: James C. Locke, James F. Walter, Hiram G. Larew, III
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Patent number: 5360607Abstract: The present invention provides a process, formulations, and method of using novel biopesticides comprised of a prilled formulation comprising a carrier and a pathogenic fungal mycelium.Type: GrantFiled: March 10, 1992Date of Patent: November 1, 1994Assignee: W. R. Grace & Co.-Conn.Inventors: Jacob Eyal, James F. Walter, Osborne, Lance, Zdenek Landa
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Patent number: 5356628Abstract: A novel fungicide derived from a neem seed extract comprising neem oil which is substantially free of azadirachtin, said neem oil being prepared by extracting dried, coarsely ground neem seeds with a non-polar, hydrophobic solvent to obtain a neem oil extract, and then removing the solvent to obtain the neem oil. These neem oil fungicides exhibit the ability to control various fungi.Type: GrantFiled: December 2, 1993Date of Patent: October 18, 1994Assignees: W. R. Grace & Co.-Conn., The United States of America as represented by the Secretary of AgricultureInventors: James C. Locke, James F. Walter, Hiram G. Larew, III
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Patent number: 5346389Abstract: This invention includes a multiple-stage combustion apparatus which can be used in a high-temperature environment, such as with a gas turbine. In particular, the invention includes a novel structure for the first stage of such apparatus, and a method of making that first stage. The first stage, which is an ignition stage, is a reactor formed of a metal strip which is coated with a catalyst on only one side. The strip is also corrugated with a herringbone pattern. The strip is then folded back and forth upon itself to form a reactor of a desired cross-section. The reactor has rows of channels that are formed between the layers of the metal. The single coated side of the metal defines the walls of the channels in every other row. The fuel-air mixture that flows through the coated channels is combusted. The fuel-air mixture that flows through the uncoated channels is not combusted, and cools the catalyzed surfaces.Type: GrantFiled: September 30, 1992Date of Patent: September 13, 1994Assignee: W. R. Grace & Co.-Conn.Inventors: William B. Retallick, William R. Alcorn
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Patent number: 5298251Abstract: Novel fungicide compositions prepared from neem seeds are disclosed. Two distinct neem derived fungicides obtained non-polar, hydrophobic solvent neem seed extracts which are substantially free of azadirachtin, by removing the hydrophobic solvent and cooling the resulting neem oil to separate a semi-solid neem wax fraction and a clarified neem oil fraction.Type: GrantFiled: July 21, 1993Date of Patent: March 29, 1994Assignee: W. R. Grace & Co.-Conn.Inventors: James C. Locke, James F. Walter, Hiram G. Larew, III