Abstract: A method of making a fluorinated ether includes combining, in a polar aprotic solvent: a fluorinated alcohol represented by the formula X—Rf1CH2OH, and a fluorinated sulfonate ester represented by the formula Rf2CH2OS(?O)2Rf3, and base; and obtaining a fluorinated ether represented by the formula Y—Rf1CH2OCH2Rf2—Y. Rf1 is selected from perfluorinated C1-C10 alkylene groups having from 1 to 10 carbon atoms and partially fluorinated C1-C10 alkylene groups, and derivatives thereof having catenated heteroatom(s). X represents H, F, or an HOCH2— group. Rf2 is selected from perfluorinated C1-C10 alkyl groups and partially fluorinated C1-C10 alkyl groups, and derivatives thereof having catenated heteroatom(s). Rf3 is a C1-C4 alkyl group. Y represents H, F, or an Rf2CH2OCH2— group. A variant method, useful for preparing symmetric fluorinated ethers, is also disclosed. The present disclosure also provides fluorinated ethers preparable according to the methods.

Abstract: A structured abrasive article includes a backing having a structured abrasive layer disposed on and secured thereto. The structured abrasive layer includes shaped abrasive composites that comprise abrasive particles and nonionic polyether surfactant dispersed in a crosslinked polymeric binder. The abrasive particles have a mean particle size of less than 10 micrometers. The nonionic polyether surfactant is not covalently bound to the crosslinked polymeric binder and is present in an amount of from 2.5 to 3.2 percent by weight based on a total weight of the shaped abrasive composites. The structured abrasive articles are useful for abrading a workpiece.

Abstract: A method of making nanostructured alloy particles includes milling a millbase in a pebble mill containing milling media. The millbase comprises: (i) silicon, and (ii) at least one of carbon or a transition metal, and wherein the nanostructured alloy particles are substantially free of crystalline domains greater than 50 nanometers in size. A method of making a negative electrode composition for a lithium ion battery including the nanostructured alloy particles is also disclosed.

Abstract: A buffing composition includes an emulsion having an aqueous liquid phase and an oily liquid phase; a solubilized zirconium carboxylate; and fine abrasive particles having a Mohs hardness of at least 4. The fine abrasive particles have a particle size distribution having at least one mode with a particle size of at least 5 micrometers. A method of finishing a surface of a material using the buffing composition is also disclosed.

Abstract: A structured abrasive article comprises an at least translucent film backing and an abrasive layer disposed on the backing. The abrasive layer comprises a plurality of shaped abrasive composites. The shaped abrasive composites comprise abrasive particles dispersed in a binder. The abrasive particles consist essentially of ceria particles having an average primary particle size of less than 100 nanometers. The binder comprises a polyether acid and a reaction product of components comprising a carboxylic(meth)acrylate and a poly(meth)acrylate, and, based on a total weight of the abrasive layer, the abrasive particles are present in an amount of at least 70 percent by weight. Methods of making and using the structured abrasive article are also disclosed.

Abstract: A deprotectable polymer, activating agent, and layered silicate are combined and the deprotectable polymer is at least partially deprotected to form a composite. The composite may be combined with a polymeric resin to form a nanocomposite.

Abstract: A repositionable mounting material comprises a mounting material having a major surface and comprising inorganic fibers. A layer of repositionable pressure-sensitive adhesive inwardly disposed along at least a portion of the first major surface. The layer of repositionable pressure-sensitive adhesive comprises: adhesive microspheres having a first particle size distribution with at least one mode, each of which has a D50 of at least 30 micrometers; and binder particles having a second particle size distribution with at least one mode, wherein each mode has a D50 that is less than 10 micrometers, and wherein at least one of the at least one modes has a D50 below one micrometer. The repositionable mounting material is useful in manufacture of pollution control devices. Methods of making the foregoing are also disclosed.

Abstract: A method of making a multilayer protective film. The method comprises: (a) forming a PU layer comprising an at least partially crosslinked polyurethane, the at least partially crosslinked polyurethane comprising at least one of a polyester-based polyurethane or a polycarbonate-based polyurethane; (b) forming a TPU layer comprising a polycaprolactone-based thermoplastic polyurethane; (c) forming a PSA layer comprising a pressure sensitive adhesive; (d) bonding one major surface of the PU layer to one major surface of the TPU layer; and (e) bonding the PSA layer to an opposite major surface of the TPU layer; wherein the TPU layer is sandwiched between the PU layer and the PSA layer. The multilayer film may be used to protect painted surfaces of vehicle body parts.

Abstract: Provided is a method of making microarrays that includes providing a substrate with discrete first microfeatures that have a first profile, and depositing vapor-coated materials onto the first microfeatures to form second microfeatures having a second profile that is substantially different from the first profile. Also provided is a method of adding a replication material to the vapor-coated microfeatures to form a mold. Microarrays made by this method can be used as substrates for surface-enhanced Raman spectroscopy (SERS).

Abstract: A coated abrasive disc has a backing comprising a synthetic woven fabric having a first major surface with a presize disposed thereon and a second major surface opposite the first major surface and having a backsize disposed thereon. The presize comprises a reaction product of a curable presize precursor comprising: at least one epoxy resin prepared by reaction of epichlorohydrin with at least one of bisphenol A or bisphenol F, polyfunctional (meth)acrylate, novolac resin, imidazole epoxy cure catalyst, dicyandiamide, and a photoinitiator. A glass woven fabric permeated with an at least partially crosslinked saturant is secured to the second major surface by a thermoplastic laminating adhesive disposed between the second major surface of the synthetic woven fabric and the glass woven fabric. A method of making the same is also disclosed.

Abstract: A structured abrasive article comprises a backing with a topographically structured abrasive layer secured thereto. The topographically structured abrasive layer comprises precisely-shaped abrasive composites. A solid overlayer comprising eroding particles with a Mohs scale hardness of at least 4 and a water-soluble polymer is disposed on at least a portion of the topographically structured abrasive layer. Methods of making and using the structured abrasive articles are also disclosed.

Abstract: An anisotropic electrically conductive structure comprising: a dielectric matrix having a first surface and a second surface; a heat curable adhesive layer disposed on at least one or both of said first surface and said second surface; a plurality of passages at least extending from said first surface of said matrix to said second surface of said matrix; and electrically conductive members in said passages; wherein said dielectric matrix does not exhibit thermal fluidization at a temperature required for heat curing of said heat curable adhesive layer.

Abstract: A nozzle, which is for in at least one embodiment a hot glue gun, has a resilient cap that is positioned within the nozzle's conduit. The resilient cap has at least one slit that serves as a check valve. The invention solves the problem of resilient caps in hot glue guns becoming unseated and wedging in the tapering section of the glue gun nozzle conduit by adding a collar inside the conduit that prevents the base section of the resilient cap from wedging in deeper into the nozzle's conduit, which would otherwise make the valve fail.

Abstract: A method of making a fluorinated ether includes combining, in a polar aprotic solvent: a fluorinated alcohol represented by the formula X—Rf1CH2OH, and a fluorinated sulfonate ester represented by the formula Rf2CH2OS(?O)2Rf3, and base; and obtaining a fluorinated ether represented by the formula Y—Rf1CH2OCH2Rf2—Y. Rf1 is selected from perfluorinated C1-C10 alkylene groups having from 1 to 10 carbon atoms and partially fluorinated C1-C10 alkylene groups, and derivatives thereof having catenated heteroatom(s). X represents H, F, or an HOCH2— group. Rf2 is selected from perfluorinated C1-C10 alkyl groups and partially fluorinated C1-C10 alkyl groups, and derivatives thereof having catenated heteroatom(s). Rf3 is a C1-C4 alkyl group. Y represents H, F, or an Rf2CH2OCH2— group. A variant method, useful for preparing symmetric fluorinated ethers, is also disclosed. The present disclosure also provides fluorinated ethers preparable according to the methods.

Abstract: Lofty open nonwoven abrasive articles, unitized abrasive wheels, and convolute abrasive wheels include a dipodal aminosilane. Methods of making the abrasive articles are also included.

Abstract: A phosphorus-containing silsesquioxane is represented by the formula [R13SiO1/2]m[R2SiO3/2]n[R3SiO3/2]p[(R4O)2PO(CH2)xSiO3/2]q wherein each of R1, R2, R3, and R4 independently represents a hydrocarbyl group; x represents an integer of from 1 to 8; m is a positive number less than 1.5; n and q are positive numbers greater than 0 and less than 1; and p is a number greater than or equal to 0 and less than 1. Further, (n+p)/q is in a range of from 0.5 to 99, and (n+p+q)=1. Curable and cured compositions comprising the phosphorus-containing silsesquioxane are disclosed.

Abstract: A method of making nanostructured polymeric film includes: providing a tool having a porous anodized aluminum surface or a metallic replica thereof, wherein the average depth of the pores and the average pore width fall with specified ranges; forming a continuous layer of thermoplastic polymer selected from cellulose esters, poly alpha-olefins, and combinations thereof on at least a portion of the surface of the tool such that the continuous layer extends into the pores of the surface; separating the continuous layer from the tool as a film having nanofibrils formed on a major surface of the tool, the surface of the tool having a fluorocarbon release agent thereon, or the continuous layer comprising a fluorocarbon melt additive, or both. Nanostructured films are also disclosed.

Abstract: Compositions comprising a plurality of carbon nanotubes, a host polymer, and A block copolymer comprising a first block and a second block, wherein no block is compatible with the host polymer. In one aspect, the block copolymer is amphiphilic. In another aspect, the block copolymer may comprise a first block and a second block, wherein at least one of the first and second blocks comprises repeating units derived from a monomer having the general formula: (R)2C?C(R)(Rf) wherein Rf is selected from fluorine, a C1 to C10 fluorinated or perfluorinated alkyl group, and a C1 to C10 fluorinated or perfluorinated alkoxy group; each R is independently selected from F, H, Cl, Rf, a C1 to C10 alkyl group, and R2A, wherein R2 is a C1 to C10 alkylene group and A is selected from CO2M and SO3M, wherein M is selected from H, an ammonium and organo onium group.

Abstract: A flame resistant RFID tag comprises: a first flame resistant polymer film having a major surface; an RFID device secured to the major surface of the first flame resistant polymer film, the RFID device having proximal and distal surfaces and comprising an antenna electrically connected to an integrated circuit; and a first flame resistant pressure sensitive adhesive layer covering the distal surface of the RFID device. Methods of making the flame resistant RFID tags are also disclosed.

Abstract: Methods of making a fluorinated sulfonate ester include combining a perfluoroalkanesulfonyl halide and a fluorinated alcohol in water in the presence of hydroxide ion, and recovering at least a portion of the resultant fluorinated sulfonate ester.