Abstract: The present invention relates to a process for catalytically converting a feedstock comprising an oxygenate to olefins utilizing a heat exchange device to transfer heat from at least a portion of an effluent of an oxygenate conversion reactor to the feedstock to cause at least a portion of the feedstock to vaporize.
Abstract: The present invention provides a method for converting a feed containing oxygenates to olefins and comprises the following steps: providing a feed including an oxygenate; contacting the feed in a reactor apparatus with a catalyst including a molecular sieve, the contacting taking place under conditions effective to convert the oxygenate to a product including a light olefin, the conditions including a gas superficial velocity of at least two meters per second; and recirculating a first portion of the catalyst to recontact the feed.
Type:
Grant
Filed:
October 7, 1999
Date of Patent:
September 24, 2002
Assignee:
ExxonMobil Chemical Patents Inc.
Inventors:
James R. Lattner, Stephen N. Vaughn, Keith H. Kuechler, David C. Skouby, Hsiang-Ning Sun
Abstract: The present invention provides a method for maintaining temperature during regeneration of an oxygenate to olefins catalyst using liquid water as a coolant in an amount sufficient either to reduce duty of a catalyst cooler or to avoid the need to use a catalyst cooler altogether. The method also may be used to hydrotreat fresh, non-hydrothermally treated catalyst which may be added to the regenerator and charged back to the conversion reactor along with the regenerated catalyst.
Abstract: An integrated process for converting a hydrocarbon feedstock having components boiling above about 100° C. into steam cracked products is described. The process first involves passing the feedstock to a hydrotreating zone to effect substantially complete decomposition of organic sulfur and/or nitrogen compounds. The product from the hydrotreating zone is passed to an aromatics saturation zone. The product is then passed to a steam cracking zone. Hydrogen and C1-C4 hydrocarbons, steam cracked naphtha, steam cracked gas oils and steam cracked tar are recovered. The amount of steam cracked tar produced is reduced by at least about 30 percent, and the amount of steam cracked tar produced is reduced by at least about 40 percent, basis the starting hydrocarbon feedstock which has not been subject to hydrotreating and aromatics saturation.
Type:
Grant
Filed:
May 8, 1997
Date of Patent:
April 3, 2001
Assignee:
Exxon Chemical Patents Inc.
Inventors:
Carl W. Bradow, Dane C. Grenoble, Richard M. Foley, Brendan D. Murray, Bruce H. C. Winquist, Stanley N. Milam
Abstract: A process comprises contacting an oxygenate feed with a molecular sieve catalyst in the presence of an electromagnetic energy and converting the oxygenate feed to olefins.
Abstract: Catalysts that are useful for hydrocarbon conversions and oxygenate conversions, and a method for making such catalysts. The method for making the catalysts comprises forming a mixture comprising molecular sieves comprising pores having a diameter smaller than about 10 Angstroms, an inorganic sol, and an external phosphorus source, and drying the mixture.
Type:
Grant
Filed:
October 29, 1997
Date of Patent:
November 28, 2000
Assignee:
Exxon Chemical Patents Inc.
Inventors:
William A. Wachter, Jeffrey T. Elks, Stephen Neil Vaughn
Abstract: The present invention relates to methods for selectively converting oxygenates to light olefins, preferably ethylene and propylene, in which desirable carbonaceous deposits are maintained on a total reaction volume of catalyst by totally regenerating only a portion of the total reaction volume of catalyst and mixing the regenerated portion with the unregenerated total reaction volume of catalyst.
Type:
Grant
Filed:
July 3, 1997
Date of Patent:
February 8, 2000
Assignee:
Exxon Chemicals Patents Inc.
Inventors:
James Richardson Lattner, Hsiang-ning Sun, Stephen Neil Vaughn, Keith H. Kuechler, David C. Skouby