Abstract: A modified zeolite catalyst useful for the conversion of aromatic compounds to dialkylbenzene compounds rich in the 1,4-dialkylbenzene isomer. The reaction is carried out in the presence of a zeolite catalyst having a silica to alumina mole ratio of at least 12 and a constraint index of about 1-12, said catalyst having been modified by treatment with compounds of manganese and/or rhenium, and optionally phosphorus, to deposit a minor proportion of such elements on the zeolite.

Abstract: This specification discloses a method of treating water which contains oxygen dissolved therein to scavenge the oxygen therefrom and reduce the corrosiveness of the water. A sulfur-containing fuel is burned in a flue gas generator to generate a flue gas containing sulfur oxides and the flue gas is scrubbed with an aqueous sodium hydroxide solution to convert the sulfur oxides to a mixture of sodium sulfite and sodium bisulfite, the mixture being referred to generally as sodium sulfites. Ascorbic acid is included in the reaction to prevent the oxidation of the sodium sulfites to sodium sulfates and the sodium sulfites and ascorbic acid are recovered for use as an additive to scavenge oxygen from water. This additive is injected into an oxygen-containing water in an amount sufficient to scavenge the dissolved oxygen from the water. A catalyst may also be added to the water to catalyze the reaction of the sodium sulfites and oxygen.

Abstract: An oriented polypropylene film substrate and method of manufacturing an oriented polypropylene film having enhanced adhesion to metallized coatings which comprises the steps of coextruding the film substrate having a homopolymer polypropylene core layer, and an ethylene propylene outer layer on at least one side of the core layer, the core and outer layers containing no slip agent. The film substrate is biaxially oriented, and the outer layer is corona treated. A metal coating is then deposited on the corona treated outer layer.

Abstract: A continuous foam production system is disclosed wherein a molten thermoplastic resin is mixed with volatile blowing agent at elevated pressure to form an extrusion mass. A helical screw extruder means is adapted to extrude the molten resin with volatile blowing agent into a low pressure foaming zone to form a foam sheet, tube or other shape. An improved fluid handling system includes storage means for holding at least one of a plurality of disparate volatile liquids under pressure sufficient to maintain a normally gaseous blowing agent in liquified state and cooling means for receiving a pressurized first stream of liquified thermally-gaseous blowing agent and cooling below its autogenous temperature. A pump operatively connected between the cooling means and extruder means increases pressure of the first stream higher than the elevated pressure of the extruder, where it may be combined with a pressurized stream of second liquid blowing agent.

Abstract: This invention provides a two-component coating composition wherein:Component A contains a polyglycidyl ether of a bisphenol having an epoxy equivalent weight between about 170 and about 200 diluted with between about 10 weight percent and about 20 weight percent of butyl glycidyl ether; an organic thixotropic agent; a liquid polyglycidyl ether of a bisphenol having an epoxy equivalent weight between about 170 and about 210; a coumarone-indene resin having a softening point between about 40.degree. F. and about 60.degree. F.; a urea-formaldehyde resin; leafing aluminum paste; and 2-nitropropane; andComponent B contains a polyamide having a base number between about 300 and about 360; N-oleyl-1,3-propylenediamine oleate; a coumarone-indene resin having a softening point between about 40.degree. F. and about 60.degree. F.; microcrystalline silica; and 2,4,6-tris-(dimethylaminomethyl) phenol.

Abstract: The present invention provides for an economical thermoplastic bag which may be employed to contain foods during storage and, most importantly, may be used to contain such foods during reheating preparatory to serving. The bag structures of the present invention comprise a two layer laminate structure, the inner bag layer, or that surface layer in contact with the foodstuffs, being formed from a thin film of polyester. The outer layer of the bag laminate, or that surface of the bag which comes into direct contact with the cooking or reheating vessel, comprises a polyacrylonitrile homopolymer. The polyacrylonitrile layer, having a melting or sticking temperature on the order of above 210.degree. C. is stable and will not stick to the vessel side walls while foodstuffs are being reheated therein. Obviously the bag containing foodstuffs is intended to be immersed in a fluid such as water during the reheating operation.

Abstract: This invention provides a method for enhancing wettability of high density polyethylene film, that comprises subjecting said film to plasma surface treatment using oxygen or argon gas atmosphere.

Abstract: Apparatus and method of utilization for controlling exothermic reactions such as the conversion of methanol to hydrocarbons are discussed. More particularly, the arrangement of apparatus comprising heat exchange tubes and open end baffle tubes for maintaining the hydraulic diameter within restricted limits during contact between vaporous reactant and a fluid bed of catalyst is discussed.

Abstract: A method and apparatus are provided to continuously monitor and measure the average size of individual foam cells contained in a foam structure, such as polystyrene foam for example, as it is being fabricated. Such an arrangement permits the prompt adjustment of process conditions and/or the concentration of nucleating agents in the extrusion system in the event the size of the individual cells in the foam structure varies from a preselected standard.

Abstract: A flowable polymeric extrusion powder consisting essentially of acrylonitrile polymer particles is provided at low temperature treated with a non-sticking amount of solvent. Sufficient solvent can be added to dissolve the polymer at elevated temperature, for instance, more than 120 parts by weight of dimethyl sulfoxide solvent can be added per hundred parts of dry polymer below ambient temperature.

Abstract: Continuous film production from a high pressure feed stream is achieved in a system which provides methods and means for maintaining pressurized gas in an extrusion zone wherein the extrudate may be cooled to form a solid polymeric film. The product film is withdrawn from the extrusion zone continuously through a standing liquid column in fluid communication with the extrusion zone. The film is passed downwardly into a liquid leg below the extrusion zone and upwardly through the liquid column, which has an upper exit end elevated above the pressurized zone thereby exerting super-atmospheric pressure. The product is recovered from the liquid sealing medium, advantageously water, at ambient pressure. Hot aqueous solutions of polyacrylonitrile may be extruded at elevated pressure onto a cooled casting drum in a gaseous environment wherein flashing of the hot solvent is prevented.

Abstract: A process for the direct catalytic conversion of petroleum residual oils is disclosed wherein said oils, hydrogen and hot solid catalyst particles are contacted to form a suspension in a riser reactor thereby producing lower boiling components with the concomitant removal of impurities, e.g., metals, sulfur and nitrogen,, from the oils. Furthermore, the catalyst particles are regenerated in a partial oxidation mode, i.e. with oxygen and steam present to generate a synthesis gas comprising CO, CO.sub.2 and H.sub.2. Such synthesis gas can be subsequently shifted to produce a H.sub.2 --CO.sub.2 rich gas which could then serve as the hydrogen source in the riser reactor.

Abstract: A method of logging a wellbore to identify oil, gas and water zones in a hydrocarbon-bearing formation that is characterized by acoustic velocities which are maximum when saturated with oil, minimum when saturated with water and intermediate when saturated with gas. The formation is logged with a sonic logging system utilizing a frequency within the range of 0.1 to 10 KHz and logged with a lithologic logging system to account for variations in lithology on the sonic log. Thereafter the sonic log is compared with the known acoustic velocity characteristic of the hydrocarbon-bearing formation to identify the oil, gas and water zones therein.

Abstract: This invention provides a novel catalyst exemplified by cobalt-exchanged ZSM-5. The catalyst has unusual resistance to irreversible steam degradation. After long-term exposure to steam, it may be regenerated by sulfiding. The invention further provides a process for converting, in the presence of steam, compounds subject to catalytic conversion by acidic catalysts, including a process in which steam is inherently produced. The latter conversion is exemplified by the formation of higher carbon-numbered hydrocarbons from the lower alcohols or ethers thereof.

Abstract: Method and apparatus for pulsed neutron logging employing detectors of different energy-dependent sensitivities to neutrons at energy levels less than the chemical binding energy of hydrogen in hydrogenous fluids found in subterranean formations. Fast neutrons from the pulsed neutron source enter the subterranean formation under investigation and are moderated therein to form populations of slow neutrons during a thermalization period occurring subsequent to the fast neutron burst and a thermal equilibrium diffusion period occurring subsequent to the thermalization period. The detectors are employed to obtain count rate measurements during at least one and preferably two time windows falling within the thermalization period and during a later time window occurring within the thermal equilibrium diffusion period.

Abstract: Living plants and animals synthesize and often accumulate a wide variety of organic materials having a molecular weight greater than 150. These include different chemical types such as natural hydrocarbons including rubbery substances, natural resins, and natural glycerides such as oils and fats. These substances, formed in the anabolic process, are collectively called "anabolites".This invention provides a process for catalytically converting certain anabolites to liquid hydrocarbons useful for the manufacture of fuels such as gasoline and chemicals such as para-xylene. Crystalline aluminosilicate zeolites having an effective pore size of greater than about 5 Angstrom units are useful catalysts.

Abstract: An improved process for production of phenylalkylsulfonate compounds whereby the proportion of the 2-alkylphenylsulfonate isomer is reduced relative to the higher numbered isomers thereof (3-alkyl; 4-alkyl; etc.). After alkylation of aromatic compounds to produce a mixture of alkylbenzenes, the 2-alkylbenzene isomer is selectively cracked to lower boiling products, leaving the higher numbered isomers substantially unreacted. Subsequent sulfonation results in alkylphenylsulfonate derivatives having improved detergency properties.

Abstract: Multiple-layer, heat-sealable films comprising a substrate layer of polypropylene homopolymer or polypropylene copolymer, or blends thereof with compatible polyolefins; and at least one heat-sealable surface layer of a blend comprising a copolymer of ethylene and a higher olefin, and a different copolymer of higher olefins. The films are prepared by extrusion coating or coextrusion and can be oriented.

Abstract: A solvent extraction process for coal conversion wherein coal liquids are contacted with spent petroleum hydrogenation catalyst or spent demetallizing guard chamber adsorbent.