Abstract: This invention is directed to a process for pretreating coal preliminary to a primary liquefaction or hydroconversion block. In the process, a coal feed, slurried in a solvent, is reacted with carbon monoxide in the presence of a chemical promoter at an elevated temperature and pressure. The promoter enhances the depolymerization and hydrogenation of the coal during pretreatment.
Type:
Grant
Filed:
December 21, 1989
Date of Patent:
September 29, 1992
Assignee:
Exxon Research and Engineering Company
Inventors:
Stephen N. Vaughn, Michael Siskin, Alan Katritzky, Glen Brons, Steve N. Reynolds, Claude C. Culross, Dan R. Neskora
Abstract: An improved process for the hydroconversion of coal, wherein coal is slurried in an organic solvent and subjected to pretreatment with carbon monoxide, followed by separation of a solvent-soluble phase comprising hydrocarbon material from the coal, and subsequently hydroconverting the extracted material in a hydroconversion reactor. The extracted material consists of a relatively hydrogen-rich material which is readily hydroconverted to valuable liquid products in high yield. The coal residue is relatively hydrogen deficient material which can be gasified to produce hydrogen and carbon monoxide for the hydroconversion and pretreatment stages, respectively.
Abstract: An improved process for the hydroconversion of coal comprising pretreating coal in an aqeuous carbon monoxide-containing environment, followed by extracting a soluble hydrocarbon material from the coal, and subsequently hydroconverting the extracted material in a hydroconversion reactor with a high catalyst loading to obtain a nearly finished product with low heteroatom levels. The extracted material consists of a relatively hydrogen-rich material which is readily converted to valuable liquid products in high yield. The residue from the extraction stage is relatively hydrogen deficient material which can be gasified to produce hydrogen and carbon monoxide for the hydroconversion and pretreatment stages, respectively.
Abstract: A method of reducing the concentration of metal contaminants, such as vanadium and nickel, in distillates of a fossil fuel feedstock is disclosed. The method comprises producing a selected distillate fraction and demetallizing this distillate by suitable means, thereby upgrading and making it suitable for use as feed to a catalytic cracker.