Patents Represented by Attorney C. S. Lynch
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Patent number: 4977272Abstract: This invention relates to new compounds of the formula: ##STR1## where each of R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.7 has zero to 10 C atoms, and no acetylenic unsaturation; each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 is independently selected from H and hydrocarbyl; with the proviso that R.sup.6 is C.sub.1 -C.sub.10 hydrocarbyl; each of R.sup.5 and R.sup.Type: GrantFiled: June 29, 1989Date of Patent: December 11, 1990Assignee: The Standard Oil CompanyInventors: Mark C. Cesa, James E. Rinz, Gilles Klopman, Teodora T. Kopp
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Patent number: 4960921Abstract: Certain novel multiply promoted Mn-Sb oxides are superior catalysts for the ammoxidation of olefins to the corresponding unsaturated nitriles, the selective oxidation of olefins to unsaturated aldehydes and acids, and the oxydehydrogenation of olefins to diolefins.Type: GrantFiled: February 12, 1990Date of Patent: October 2, 1990Assignee: The Standard Oil CompanyInventors: Dev. D. Suresh, Robert K. Grasselli, Frances I. Ratka, James F. Brazdil
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Patent number: 4937380Abstract: 1,3-butadienes are catalytically hydrocarbamylated to make 3-pentenamides.Type: GrantFiled: October 14, 1986Date of Patent: June 26, 1990Assignee: The Standard Oil CompanyInventors: Mark C. Cesa, Robert A. Dubbert, James D. Burrington
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Patent number: 4929755Abstract: In the process of hydrocarboxylating an .alpha.-enamide with CO and H.sub.2 O or an organic hydroxyl compound to produce an N-acyl-.alpha.-amino acid or ester, respectively, the improvement comprising using as the .alpha.-enamide reactant, an .alpha.-enamide which has a chiral center that is essentially all L or D, thereby producing a reaction mixture containing diastereomeric N-acyl-.alpha.-amino acids or esters having two chiral centers, said mixture having essentially no enantiomeric pairs.Type: GrantFiled: December 19, 1986Date of Patent: May 29, 1990Assignee: The Standard Oil CompanyInventors: Mark C. Cesa, Robert A. Dubbert, James D. Burrington
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Patent number: 4921985Abstract: Disclosed is a method of making a tri- or tetrahydrocarbylammonium hexahydroxyantimonate,[R.sub.3 R'N]Sb(OH).sub.6.xH.sub.2 O formula (1)containing 3 to 30 C atoms, which process comprises the steps of (1) contacting a compound selected fromR.sub.3 N and R.sub.4 NOHwith the H.sup.+ form of a solid cation exchange resin, and allowing the amine or the tetrahydrocarbylammonium hydroxide to react with the cation exchange resin, and thereafter (2) contacting the reacted resin with an aqueous solution of KSb(OH).sub.6,wherein each R contains 1-10 C atoms and is independently selected from alkyl, aralkyl and alkylaralkyl, R' is H or R, and wherein x is an indeterminate number of moles of H.sub.2 O.Type: GrantFiled: October 21, 1988Date of Patent: May 1, 1990Assignee: The Standard Oil CompanyInventors: Charles J. Besecker, William A. Marritt
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Patent number: 4918214Abstract: Disclosed is the reaction of propane and isobutane with O.sub.2 and NH.sub.3 to make .alpha.,.beta.-unsaturated nitriles and olefins, using certain complex metal oxide catalyst compositions and an excess of the paraffin over both the O.sub.2 and the NH.sub.3. Also disclosed are suitable catalyst compositions for such reactions.Type: GrantFiled: July 3, 1989Date of Patent: April 17, 1990Assignee: The Standard Oil CompanyInventors: James F. Brazdil, Jr., Linda C. Glaeser, Mark A. Toft
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Patent number: 4897504Abstract: Disclosed is ammoxidation of C.sub.3 to C.sub.5 acyclic alkanes with NH.sub.3 and O.sub.2 using (1) a mole ratio of alkane:NH.sub.3 in the range from 2 to 16 and a mole ratio of alkane:O.sub.2 in the range 1 to 10 and (2) a mixture of particulate catalyst compositions, the first being especially effective to promote formation of an unsaturated nitrile and an olefin from the paraffin, and the second catalyst composition being especially effective to promote the conversion of the olefin to the unsaturated mononitrile. Catalyst compositions useful in the process are also disclosed.Type: GrantFiled: November 14, 1988Date of Patent: January 30, 1990Assignee: The Standard Oil CompanyInventors: Linda C. Glaeser, James F. Brazdil, Jr., Mark A. Toft
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Patent number: 4894467Abstract: Disclosed is a process for making styrene oxide which comprises contacting styrene in the vapor phase with a molecular oxygen-containing gas over a silver metal catalyst containing a promoting amount of at least one alkali metal hydroxide selected from sodium, potassium and lithium hydroxides, on an inert solid inorganic support at contact times of from 0.6 to 10 seconds and temperatures from 200.degree. to 350.degree. C.Type: GrantFiled: October 16, 1986Date of Patent: January 16, 1990Assignee: The Standard Oil CompanyInventor: Patricia R. Blum
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Patent number: 4888438Abstract: Disclosed is ammoxidation of C.sub.3 to C.sub.5 acyclic alkanes with NH.sub.3 and O.sub.2 using (1) a mole ratio of alkane:NH.sub.3 in the range from 2 to 16 and a mole ratio of alkane:O.sub.2 in the range 1 to 10 and (2) a mixture of particulate catalyst compositions, the first being especially effective to promote formation of an unsaturated nitrile and an olefin from the paraffin, and the second catalyst composition being especially effective to promote the conversion of the olefin to the unsaturated nitrile. Catalyst compositions useful in the process are also disclosed.Type: GrantFiled: October 31, 1988Date of Patent: December 19, 1989Assignee: The Standard Oil CompanyInventors: Linda C. Glaeser, James F. Brazdil, Jr., Mark A. Toft
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Patent number: 4888117Abstract: A method of coalescence involves the use of a coalescer element consisting essentially of or comprising a sintered polymeric media having a fine porous structure. Suitable polymers include thermoplastics or thermosetting resins.The element is suitable for de-oiling oily water and dewatering crude oil.Type: GrantFiled: May 19, 1988Date of Patent: December 19, 1989Assignee: The British Petroleum Company p.l.c.Inventors: Giselle M. Brown, Anthony S. MacFarlane
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Patent number: 4883896Abstract: Disclosed is ammoxidation of C.sub.3 to C.sub.5 acyclic alkanes with NH.sub.3 and O.sub.2 using (1) a mole ratio of alkane:NH.sub.3 in the range from 2 to 16 and a mole ratio of alkane:O.sub.2 in the range 1 to 10 and (2) a mixture of particulate catalyst compositions, the first being especially effective to promote formation of an unsaturated nitrile and an olefin from the paraffin, and the second catalyst composition being especially effective to promote the conversion of the olefin to the unsaturated mononitrile. Catalyst compositions useful in the process are also disclosed.Type: GrantFiled: November 14, 1988Date of Patent: November 28, 1989Assignee: The Standard Oil CompanyInventors: Linda C. Glaeser, James F. Brazdil, Jr., Mark A. Toft
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Patent number: 4883895Abstract: Disclosed is the reaction of propane and isobutane with O.sub.2 and NH.sub.3 to make .alpha.,.beta.-unsaturated nitriles and olefins, using certain complex metal oxide catalyst compositions and an excess of the paraffin over both the O.sub.2 and the NH.sub.3. Also disclosed are suitable catalyst compositions for such reactions.Type: GrantFiled: May 8, 1989Date of Patent: November 28, 1989Assignee: The Standard Oil CompanyInventors: James F. Brazdil, Jr., Linda C. Glaeser, Mark A. Toft
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Patent number: 4879264Abstract: Disclosed is a method of making a catalyst precursor by aging an aqueous solution containing the monoperoxovanadium ion, VO(O.sub.2).sup.+, until a vanadium-containing sol or gel is formed, and reacting said vanadium while in said aqueous sol or gel form, with an antimony compound that contains Sb having a valence of 3. In one embodiment, the VO(O.sub.2).sup.+ ion is made by reacting H.sub.2 O.sub.2 with a vanadium compound.Also disclosed is making a catalyst by drying and calcining such precursor. When the drying is effected by spray drying a microspheroidal catalyst is produced. The catalysts useful for ammoxidation of propane are more attrition resitant than catalysts of the same empirical formula made by prior art methods.Type: GrantFiled: November 14, 1988Date of Patent: November 7, 1989Assignee: The Standard Oil CompanyInventors: Mark A. Toft, James F. Brazdil, Jr., Linda C. Glaeser
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Patent number: 4877764Abstract: Disclosed is ammoxidation of C.sub.3 to C.sub.5 acyclic alkanes with NH.sub.3 and O.sub.2 using (1) a mole ratio of alkane:NH.sub.3 in the range from 2 to 16 and a mole ratio of alkane:O.sub.2 in the range 1 to 10 and (2) a mixture of particulate catalyst compositions, the first being especially effective to promote formation of an unsaturated nitrile and an olefin from the paraffin, and the second catalyst composition being especially effective to promote the conversion of the olefin to the unsaturated nitrile. Catalyst compositions useful in the process are also disclosed.Type: GrantFiled: July 22, 1988Date of Patent: October 31, 1989Assignee: The Standard Oil CompanyInventors: Linda C. Glaeser, James F. Brazdil, Jr., Mark A. Toft
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Patent number: 4876348Abstract: Disclosed is a process comprising (1) dehydrocyclization of 2-methylglutaronitrile over Pt or Pd based catalysts to make a mixture containing 3-methylpyridine and lesser amounts of 3-methylpiperidine and (2) reacting such a mixture with NH.sub.3 and O.sub.2 over certain oxide catalysts containing P, V and Mo to obtain 3-cyanopyridine.Type: GrantFiled: October 29, 1985Date of Patent: October 24, 1989Assignee: The Standard Oil CompanyInventors: Robert DiCosimo, James D. Burrington, Dev D. Suresh
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Patent number: 4874738Abstract: Disclosed is the reaction of propane and isobutane with O.sub.2 and NH.sub.3 to make .alpha.,.beta.-unsaturated nitriles and olefins, using certain complex metal oxide catalyst compositions and an excess of the paraffin over both the O.sub.2 and the NH.sub.3. Also disclosed are suitable catalyst compositions for such reactions.Type: GrantFiled: September 9, 1988Date of Patent: October 17, 1989Assignee: The Standard Oil CompanyInventors: James F. Brazdil, Jr., Linda C. Glaeser, Mark A. Toft
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Patent number: 4873215Abstract: Disclosed is a process for the ammoxidation of paraffins having 3-5 C atoms using a complex metal oxide catalyst having the ingredients and the proportions which are represented by the following empirical formula:VSb.sub.m P.sub.n A.sub.a B.sub.b C.sub.c T.sub.t O.sub.xwhereA is one or more of W, Wn, Mo, B and Ge;B is one or more of Fe, Co, Ni, Cr, Mn, Cu, Zn, Se, Te, Pb and As;C is one or more of an alkali metal and TlT is one or more of Ca, Sr and Baand where m is greater than 1 and up to 10; n is greater than zero and up to 10, a is 0-10; b is 0-3; c is 0-1; t is 0-1; a is equal to or less than m; b is equal to or less than m; n is equal to or less than m; and wherein the antimony has an average valency higher than +3 and the vanadium has an average valency lower than +5, and the catalyst and how to make the catalyst.Type: GrantFiled: May 13, 1987Date of Patent: October 10, 1989Assignee: The Standard Oil CompanyInventors: James F. Brazdil, Andrew T. Guttmann
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Patent number: 4871706Abstract: Disclosed is the reaction of C.sub.3 to C.sub.4 paraffins with O.sub.2 and NH.sub.3 to make .alpha.,.beta.-unsaturated nitriles and olefins, using certain complex metal oxide catalysts containing V, Sb, W and certain optional elements.Type: GrantFiled: December 16, 1987Date of Patent: October 3, 1989Assignee: The Standard Oil CompanyInventors: James F. Brazdil, Jr., Linda C. Glaeser, Mark A. Toft
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Patent number: 4868061Abstract: This invention relates to new compounds of the formula: ##STR1## where each of R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 has zero to 10 C atoms, and no acetylenic unsaturation; each of R.sup.1, R.sup.2 and R.sup.3 is independently selected from H and hydrocarbyl; each of R.sup.4 and R.sup.Type: GrantFiled: May 19, 1988Date of Patent: September 19, 1989Assignee: The Standard Oil CompanyInventors: Mark C. Cesa, James E. Rinz, Teodora T. Kopp
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Patent number: 4866024Abstract: Disclosed is the reaction of propane and isobutane with O.sub.2 and NH.sub.3 to make .alpha.,.beta.-unsaturated nitriles and olefins, using certain complex metal oxide catalyst compositions and an excess of the paraffin over both the O.sub.2 and the NH.sub.3. Also disclosed are suitable catalyst compositions for such reactions.Type: GrantFiled: September 29, 1988Date of Patent: September 12, 1989Assignee: The Standard Oil CompanyInventors: James F. Brazdil, Jr., Linda C. Glaeser, Mark A. Toft