Patents Represented by Attorney, Agent or Law Firm Carol Loeschorn
  • Patent number: 5424475
    Abstract: Colorless precursors of preformed image dyes are provided which are useful as the color image-forming materials in thermal imaging systems. These colorless precursors possess at least one thermal protecting group that undergoes fragmentation upon heating and at least one leaving group that undergoes irreversible elimination upon heating, said protecting and leaving groups maintaining the precursor in its colorless form until heat is applied to effect removal of these groups whereby the precursor is converted to an image dye.
    Type: Grant
    Filed: July 12, 1991
    Date of Patent: June 13, 1995
    Assignee: Polaroid Corporation
    Inventors: Roger A. Boggs, Alan L. Borror, Patrick R. Conlon, Richard L. Cournoyer, Ernest W. Ellis, David P. Waller
  • Patent number: 5413819
    Abstract: The storage and processing times of sprayed concrete can be significantly extended by the addition of a retarder, a chemical compound which is capable of chelating with calcium ions. Preferred retarders are phosphonic acid derivatives which have at least one amino and/or hydroxyl group. The retarder can be used for both wet- and dry-sprayed concrete, the usual accelerators can be used for activation, and the strength is not adversely affected.
    Type: Grant
    Filed: November 29, 1993
    Date of Patent: May 9, 1995
    Assignee: Sandoz Ltd.
    Inventor: Josef F. Drs
  • Patent number: 5399709
    Abstract: A novel class of N-substituted triarylmethane sulfonamides is provided which undergo reversible oxidation into colored form and reversible reduction of the oxidized form into colorless form. The N-substituted triarylmethane sulfonamides can be represented by the formulae: ##STR1## wherein B is a carbocyclic ring or rings; T is a 5- or 6-membered ring; Y is a moiety selected from ##STR2## wherein E, positioned ortho or para to said --OH group, is selected from --OH, --NH.sub.2, --NHR', --NR'R" and --NHSO.sub.
    Type: Grant
    Filed: June 11, 1993
    Date of Patent: March 21, 1995
    Assignee: Polaroid Corporation
    Inventors: Myron S. Simon, Marcis M. Kampe, David P. Waller
  • Patent number: 5387644
    Abstract: A hardenable monomer composition useful for flooring composition, grouts, mortars and the like comprises a mixture of crosslinkable acrylic monomer, carbon black and/or polyester- or polyether-methane oligomer having at least two polymerizable double bonds and a paraffin oil.The monomer is preferably of the formula I ##STR1## and there is preferably present other monomers, particularly hydroxypropyl methacrylate.
    Type: Grant
    Filed: December 14, 1993
    Date of Patent: February 7, 1995
    Assignee: Sandoz Ltd.
    Inventor: Karoly Discho
  • Patent number: 5370188
    Abstract: A method of accessing water from an aquifer which underlies an impervious stratum without contamination of the aquifer by polluted water from above the stratum by drilling a bore hole to the aquifer, comprises the steps of(a) drilling a first bore hole into, but not through the impervious stratum and a second bore hole of smaller diameter to the aquifer;(b) inserting therein a protective tube of diameter intermediate between those of the bore holes and which extends to the ground surface; and(c) adding a protective mortar to the annular space between the protective tube and the larger diameter bore hole;there being circumferentially wound around the tube at the level of the protective mortar, transfer tubing which comprises radial perforations which permit passage of fluids, e.g. sealing composition from the interior of the transfer tubing to the mortar. The method works best with certain reinforced mortar formulations.
    Type: Grant
    Filed: June 28, 1993
    Date of Patent: December 6, 1994
    Assignee: Sandoz Ltd.
    Inventor: Gabriel M. J. Cottrell
  • Patent number: 5358566
    Abstract: An aqueous solution, for use as a cement dispersing agent, of a polymer salt, which is formed by reacting a polycarboxylic acid with a nitrogenous acrylic polymer.
    Type: Grant
    Filed: November 5, 1990
    Date of Patent: October 25, 1994
    Assignee: Sandoz Ltd.
    Inventors: Yoshio Tanaka, Minoru Yaguchi, Teruhiko Yamamoto
  • Patent number: 5356671
    Abstract: A process for improving the rebound properties of sprayed concrete comprises the inclusion therein of micro-silica which has been pretreated with from 2 to 25% by weight thereof of a liquid selected from water, an alkanolamine, a polyol and an aqueous solution of at least one concrete additive, an alkanolamine, a polyol and a water-soluble cellulosic compound. The process is especially effective when used in conjunction with the dry spraying process.
    Type: Grant
    Filed: March 17, 1993
    Date of Patent: October 18, 1994
    Assignee: Sandoz Ltd.
    Inventor: Josef F. Drs
  • Patent number: 5350450
    Abstract: A method for applying a cementitious composition to a surface comprising1) adding to the cementitious compositiona) a set retarding agent;b) a cement quick-setting agent;c) a cement dispersing agent;d) a slow release dispersing agent, that hydrolyzes under alkaline conditions to form a dispersing agent; and2) applying the concrete to a surface while the concrete is fluid.
    Type: Grant
    Filed: April 30, 1993
    Date of Patent: September 27, 1994
    Assignee: Sandoz Ltd.
    Inventors: Kenkichi Hamabe, Shigemi Matsuo, Hiroshi Nomachi, Hideo Ogawa, Minoru Ueda
  • Patent number: 5350870
    Abstract: Leuco dyes are provided which comprise the coupling product of a N-acyl substituted aromatic amino color developer and a dye-forming coupler moiety substituted at the coupling carbon with a thermally removable leaving group. Thermal imaging systems employing these leuco dyes have the advantage of reduced bubble formation relative to thermal imaging systems employing prior art leuco dyes containing a group which thermally fragments into one or more gases.
    Type: Grant
    Filed: April 12, 1993
    Date of Patent: September 27, 1994
    Assignee: Polaroid Corporation
    Inventors: Roger A. Boggs, Richard L. Cournoyer, Ernest W. Ellis, Sandra E. Russo-Rodriguez, Stephen J. Telfer, David P. Waller, Michael J. Zuraw
  • Patent number: 5340689
    Abstract: There are disclosed dye-providing compounds comprising color coupler dyes substituted on the phenylene diamine portion with one or two cyclic 1,3 -sulfur-nitrogen groups. The dye-providing compounds are capable of releasing the coupler dye upon cleavage in the presence of silver ions or a soluble silver complex. The dye-providing compounds are useful as image-forming materials in color thermographic, photothermographic and other photographic processes.
    Type: Grant
    Filed: May 6, 1993
    Date of Patent: August 23, 1994
    Assignee: Polaroid Corporation
    Inventors: Efthimios Chinoporos, Robert H. Pauze, David P. Waller, David C. Whritenour
  • Patent number: 5334573
    Abstract: Sheet materials for use in thermal transfer imaging systems comprising a donor sheet and a receiving sheet are provided wherein the donor sheet and the receiving sheet do not stick to each other during thermal processing.
    Type: Grant
    Filed: December 2, 1991
    Date of Patent: August 2, 1994
    Assignee: Polaroid Corporation
    Inventor: Howard G. Schild
  • Patent number: 5332654
    Abstract: A novel class of N-substituted triarylmethane sulfonamides is provided which undergo reversible oxidation into colored form and reversible reduction of the oxidized form into colorless form. Preferred embodiments comprise xanthene sulfonamides having N-aryl substituents, e.g., hydroquinone substituents. These compounds possess redox potentials ranging between about +200 to -500 millivolts and thus are useful as dyes for producing photographic, photothermographic, thermal, and pressure-induced images, as well as being useful as redox indicators in a wide variety of biological and chemical reactions.
    Type: Grant
    Filed: June 11, 1993
    Date of Patent: July 26, 1994
    Assignee: Polaroid Corporation
    Inventors: Myron S. Simon, Marcis M. Kampe, David P. Waller
  • Patent number: 5328799
    Abstract: Photothermographic and thermographic diffusion transfer image-recording materials are provided wherein an auxiliary ligand for silver ions is employed to enhance transfer image density and discrimination.
    Type: Grant
    Filed: June 17, 1993
    Date of Patent: July 12, 1994
    Assignee: Polaroid Corporation
    Inventors: James R. Freedman, Stephen R. Sofen, Kent M. Young
  • Patent number: 5322562
    Abstract: A storable cement-mortar dry mix, which comprises the components cement, aggregate, reaction resin and hardener in a single mixture, wherein the hardener is present as the reaction product of the hardener with an organic acid or a functional derivative thereof.
    Type: Grant
    Filed: July 12, 1991
    Date of Patent: June 21, 1994
    Assignee: Sandoz Ltd.
    Inventors: Peter Ellenberger, Heinz W. Schmitt, Salvatore Valenti, Qiwei Yang
  • Patent number: 5320929
    Abstract: There are disclosed compounds comprising at least one cyclic 1,3-sulfur-nitrogen substituted color-providing material and at least one ballast group which are linked to each other through a triazine group. The compounds are capable of releasing the color-providing material upon cleavage in the presence of silver ions or a soluble silver complex. The color-providing compounds are useful as image-forming materials in color thermographic, photothermographic and other photographic processes.
    Type: Grant
    Filed: December 22, 1992
    Date of Patent: June 14, 1994
    Assignee: Polaroid Corporation
    Inventor: Michael J. Arnost
  • Patent number: 5319143
    Abstract: There are disclosed certain bis(aminoethanethiols) and the salts thereof which find utility as intermediates in the preparation of certain dye-providing compounds useful in photographic imaging systems.
    Type: Grant
    Filed: July 31, 1992
    Date of Patent: June 7, 1994
    Assignee: Polaroid Corporation
    Inventors: David Messersmith, David P. Waller
  • Patent number: 5316887
    Abstract: There are disclosed color-providing compounds comprising two or more cyclic 1,3 sulfur-nitrogen groups and two or more color-providing moieties, i.e., complete dyes or dye intermediates, capable of releasing the color-forming moieties upon cleavage in the presence of silver ions or a soluble silver complex. The color-providing compounds are useful as image-forming materials in color photographic processes.
    Type: Grant
    Filed: July 31, 1992
    Date of Patent: May 31, 1994
    Assignee: Polaroid Corporation
    Inventors: Michael J. Arnost, Efthimios Chinoporos, Donald A. McGowan, David P. Waller
  • Patent number: 5294375
    Abstract: Disclosed is a class of bridged phthalides and sulfinate esters which exhibit reversible thermochromism. At room temperature and in the presence of base, these compounds are substantially colorless but upon the application of heat they become colored, reverting to their original colorless or weakly colored state upon cooling. This colorless to colored, temperature-dependent cycle can be repeated many times. These compounds have utility as temperature sensors and as thermal pH indicators.
    Type: Grant
    Filed: August 20, 1991
    Date of Patent: March 15, 1994
    Assignee: Polaroid Corporation
    Inventors: Marcis M. Kampe, David P. Waller, David C. Whritenour
  • Patent number: 5278127
    Abstract: This invention relates to the use of a compound containing at least two epoxide moieties in the protective topcoat layer and/or in a layer on top of the protective topcoat layer of certain thermographic recording films to reduce gouging and streaking of the printed image film and to reduce head build-up on the thermal printhead.
    Type: Grant
    Filed: January 27, 1993
    Date of Patent: January 11, 1994
    Assignee: Polaroid Corporation
    Inventors: Edward J. Dombrowski, John R. McPherson, Sr.
  • Patent number: 5262089
    Abstract: An admixture for inhibiting chloride-induced corrosion in steel reinforcing in place in concrete comprises an O/W emulsion wherein the oil phase comprises an unsaturated fatty acid ester and ethoxylated nonyl phenol and the ester of an aliphatic carboxylic acid with a mono-, di- or trihydric alcohol and the water phase comprises a saturated fatty acid, an amphoteric compound, a glycol and a soap. The admixture is added to the concrete prior to placement.
    Type: Grant
    Filed: December 12, 1991
    Date of Patent: November 16, 1993
    Assignee: Sandoz Ltd.
    Inventors: Gregory S. Bobrowski, Mark A. Bury, Stephen A. Farrington, Charles K. Nmai